JP2010123556A - Substrate (case) for dye-sensitized solar cell - Google Patents

Substrate (case) for dye-sensitized solar cell Download PDF

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JP2010123556A
JP2010123556A JP2008320227A JP2008320227A JP2010123556A JP 2010123556 A JP2010123556 A JP 2010123556A JP 2008320227 A JP2008320227 A JP 2008320227A JP 2008320227 A JP2008320227 A JP 2008320227A JP 2010123556 A JP2010123556 A JP 2010123556A
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substrate
sensitized solar
housing
dye
solar cell
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Hiroshi Kitamura
浩 北村
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/542Dye sensitized solar cells

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  • Sealing Battery Cases Or Jackets (AREA)
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a substrate (a case) not only improving long-period safety by easily, simply and stably forming a dye-sensitized solar cell but also enabled to easily enlarge an area. <P>SOLUTION: The substrate (a case) is provided with concavo-convex protrusions, dents, steps or the like for jointing, sealing and electrodes on a substrate of a dye-sensitized solar cell beforehand, and molded so as to be in a sealing state by separating between an inner space and an outer part when they are interposed and jointed. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

合成樹脂材、ゴム材、繊維材あるいは金属材またはそれらの複合による色素増感太陽電池(結晶及び非結晶シリコン、化合物半導体及び有機半導体の太陽電池含む。)用の基板(以下「基板」)に、接合用、封止用及び電極用の凹凸状の突起物や窪みや段差あるいは隙間や孔を設け、それらを重ね合わせて接合する際に内部空間が密封状態となるように成形した色素増感太陽電池用の基板(筐体)に関する。  For substrates (hereinafter referred to as “substrates”) for dye-sensitized solar cells (including solar cells of crystalline and non-crystalline silicon, compound semiconductors and organic semiconductors) by synthetic resin materials, rubber materials, fiber materials or metal materials or a composite thereof. Dye sensitization formed by providing uneven projections, depressions, steps, gaps or holes for bonding, sealing, and electrodes, and sealing the internal space when they are overlapped and bonded The present invention relates to a substrate (housing) for a solar cell.

本発明の申請者が本年6月23日付けで特許出願した「色素増感太陽電池およびその製造方法」により多孔質酸化チタン、色素及び電解液等を高分子吸収体でゴム状ゲル材として成形する色素増感太陽電池があるが、それに最適な基板(筐体)はない。  Porous titanium oxide, dye, electrolyte, etc. as a rubbery gel material with a polymer absorber by the “dye-sensitized solar cell and its manufacturing method” filed on June 23, this year by the applicant of the present invention There is a dye-sensitized solar cell to be molded, but there is no optimal substrate (housing) for it.

現在、色素増感太陽電池の基板等には、文献1のガラス基板、文献2の透明電極用のガラス基板、文献3のプラスチック基板、文献4の金属セル容器用基板等が提案されているが、どれも溶液タイプ用でかつ実用化されていない。  Currently, as a substrate of a dye-sensitized solar cell, a glass substrate of Document 1, a glass substrate for a transparent electrode of Document 2, a plastic substrate of Document 3, a metal cell container substrate of Document 4, and the like have been proposed. None of these are solution-type and have not been put to practical use.

一方、我が国の伝統的な木造建築技術である柱や梁等の仕口や継手には数多くの接合方法があり、それらは必ず凹凸状の突起部分と窪みが一対となって完璧に接合されているため、常に剛性と柔軟性を合わせ持った最適かつ実用的な接合手法となっている。  On the other hand, there are many joining methods for joints and joints such as pillars and beams, which are the traditional wooden construction technology in Japan, and they are always perfectly joined together with a pair of concave and convex protrusions and depressions. Therefore, it is an optimal and practical joining method that always combines rigidity and flexibility.

文献1Reference 1

特願2007−60511Japanese Patent Application No. 2007-60511

文献2Reference 2

特願2008−81677Japanese Patent Application No. 2008-81677

文献3Reference 3

特願2002−333519Japanese Patent Application No. 2002-333519

文献4Reference 4

特願2006−194257Japanese Patent Application No. 2006-194257

上記の通り、本発明の申請者が本年6月23日付けで特許出願した色素増感太陽電池は、従前のものとは性質及び形状が全く異なるために最適となる基板(筐体)はなく、また実用化のためにも必須要件となっている。  As described above, the dye-sensitized solar cell for which the applicant of the present invention applied for a patent on June 23, this year is completely different in nature and shape from the previous one, so the optimal substrate (housing) is It is also an essential requirement for practical use.

現在の色素増感太陽電池の基板(筐体)は、単にガラスやプラスチック材をそのまま用いたり、それらに電極等を貼り付け、または漏れ防止用の工夫を付加しているに過ぎず、接合による容易かつ簡便で安定的なものはない。  Current dye-sensitized solar cell substrates (casings) are simply made of glass or plastic materials, or electrodes are attached to them, or leak-preventing devices are added. There is nothing easy, convenient and stable.

また、実用的な基板(筐体)として容易かつ大量に製造できるものはなく、さらに柔軟性を有するシリコン等の太陽電池の場合にも同様である。  In addition, there is no practical substrate (housing) that can be manufactured easily and in large quantities, and the same applies to solar cells such as silicon that have more flexibility.

さらに、それら基板(筐体)の実用化には、建築物等の内外装部や採光部に適合した面積や形状等としなければならず、また造形物においても積層や加工用の細工が必要である。  Furthermore, in order to put these substrates (housings) into practical use, they must have areas and shapes that are suitable for interior and exterior parts of buildings and daylighting parts. It is.

上記課題に対し、予め基板に接合用、封止用及び電極用の凹凸状の突起物や窪みあるいは段差を設けておき、それら基板を重ね合わせて接合させる際に内部空間が外部と遮断されて密封状態となるように成形した色素増感太陽電池用の基板(筐体)等を提供する。  In response to the above-mentioned problems, uneven projections, depressions or steps for bonding, sealing, and electrodes are provided on the substrate in advance, and the internal space is blocked from the outside when the substrates are overlapped and bonded. Provided is a substrate (housing) for a dye-sensitized solar cell molded so as to be sealed.

まず、一方の基板の内側周辺部に凸部あるいは段差を設け、その凸部等と合致して接合できるようにもう一方の基板の内側周辺部に凹部あるいは段差を設けるが、その際には内部空間の形状等を十分考慮して成形する。  First, a convex portion or a step is provided on the inner peripheral portion of one substrate, and a concave portion or a step is provided on the inner peripheral portion of the other substrate so that it can be joined with the convex portion. Molding with sufficient consideration for the shape of the space.

次に、それら基板に電極用、封止用あるいは電極用の隙間、孔、口等を設ける。これによって、接合による容易かつ簡便で安定的に内部空間を密封状態に維持できる色素増感太陽電池用の基本的な基板(筐体)が成形される。  Next, gaps, holes, ports or the like for electrodes, sealing or electrodes are provided on these substrates. As a result, a basic substrate (housing) for a dye-sensitized solar cell that can easily and simply and stably maintain the internal space in a sealed state is formed.

ただ、その空間にゴム状ゲル材等を使用する際には、厚さが数ミリ程度となることもあるため基板(筐体)に不均一な膨らみを生じる場合がある。  However, when a rubber-like gel material or the like is used in the space, the thickness may be several millimeters, which may cause uneven bulges in the substrate (housing).

その場合、基板の内側周辺部に設ける凹凸状の突起物や窪み等を、内部空間を含めた基板の内側全体に均等に点状あるいは線状に配置して均一化を図ったり、あるいはその内部空間を真空またはそれに近い状態として改善するための空気抜取用の孔等を設ける。  In that case, uneven projections and depressions provided on the inner periphery of the substrate are arranged uniformly in the form of dots or lines on the entire inner side of the substrate including the internal space, or the interior is made uniform. An air extraction hole or the like is provided to improve the space in a vacuum or a state close thereto.

一方、基板(筐体)の重ね合わせ部分の一部を予め製造段階等で接合あるいは成形(パッケージ化)しておくことで、結果として封止および接合作業の簡素化と密封状態の向上が図られる。  On the other hand, by joining or molding (packaging) a part of the overlapped portion of the substrate (housing) in advance at the manufacturing stage, etc., as a result, simplification of sealing and joining work and improvement of the sealed state can be achieved. It is done.

本発明は、主に本発明の申請者が先に特許出願した色素増感太陽電池用であるため、それを容易かつ簡便で安定的に成形できるだけでなくその効率化も図られ、また水分の蒸発防止や長期安定性も改善される。  Since the present invention is mainly for a dye-sensitized solar cell for which the applicant of the present invention previously applied for a patent, it can be molded easily, simply and stably, and its efficiency can be improved. Evaporation prevention and long-term stability are also improved.

また、従来の溶液による色素増感太陽電池においても、容易で簡便に成形できるだけでなくその効率化が図られ、また色素液や電解液の液漏れ及び蒸発防止や長期安定性が改善される。  In addition, in a dye-sensitized solar cell using a conventional solution, not only can it be molded easily and simply, but also its efficiency is improved, and the leakage and evaporation of the dye solution and electrolyte solution and long-term stability are improved.

さらに、柔軟性を持つシリコン等の太陽電池でも同様の長所が得られるだけでなく、上記太陽電池も含め製造工程等の簡素化による効率化が図られ、コスト低減等も図られる。  Further, not only the same advantages can be obtained with a flexible solar cell such as silicon, but also the efficiency of the manufacturing process including the solar cell can be simplified, and the cost can be reduced.

以下に、本発明の一実施例の形態を図面に基づいて説明する。但し本発明はこれらに限定されるものではない。  Hereinafter, an embodiment of the present invention will be described with reference to the drawings. However, the present invention is not limited to these.

図1は、基板1、2の内側周辺部に予め凹凸状の突起物等3を設け、それらが接合するよう重ね合わせて内部空間4を設けるが、その内部空間4は外部と遮断されて密封状態となるように成形する。  In FIG. 1, uneven projections 3 are provided in advance on the inner peripheral portions of the substrates 1 and 2, and an internal space 4 is provided so as to be joined, but the internal space 4 is sealed off from the outside. Mold to be in a state.

そして、基板1、2に封止及び接合用の隙間等5を設けるが、例えば基板1、2自体を電極としても良い。  The substrates 1 and 2 are provided with gaps 5 for sealing and bonding. For example, the substrates 1 and 2 themselves may be used as electrodes.

図2は図1における基板2の中央部底面6を底上げしたもので、図3〜図5は、基板1、2を重ね合わせた際の接合部分に変化を持たせたものである。  FIG. 2 is a diagram in which the bottom surface 6 of the central portion of the substrate 2 in FIG. 1 is raised, and FIGS. 3 to 5 are diagrams in which changes are made to the joint portion when the substrates 1 and 2 are overlapped.

図6は基板(筐体)の基板1、2の重ね合わせ部分の一部を予め製造段階等で接合(パッケージ化)して内部空間4を密封する際の作業を容易かつ簡便としたものである。  FIG. 6 shows an easy and simple operation for sealing the internal space 4 by joining (packaging) a part of the overlapped portion of the substrates 1 and 2 of the substrate (housing) in advance at the manufacturing stage. is there.

図7は、基板{筐体)を単体あるいは複数用いて大面積とする場合や柱等への巻付時の適切な接合の収まり等として、容易かつ簡便に接合できるよう予め基板1、2の端部を長めにして成形したものである。  FIG. 7 shows the case where the substrates 1 and 2 are preliminarily attached so that they can be easily and simply joined as a large area by using a single substrate or a plurality of substrates (cases) or as an appropriate fitting fit at the time of winding around a pillar or the like. It is formed with a long end.

図8は、例えば基板(筐体)に予め連結用の孔7を設けておき、それらを突き合わせた際に連結金具(プラスチック製)8を孔7に用いて大面積とするものである。  In FIG. 8, for example, a connecting hole 7 is provided in advance in a substrate (housing), and when they are abutted, a connecting metal fitting (made of plastic) 8 is used for the hole 7 to increase the area.

図9は、基板(筐体)を大面積にした場合等に不均一な膨らみを生じることがあるので、凹凸状の突起物等を内部空間4に均等に点状に設けたものである。  FIG. 9 shows uneven projections and the like that are evenly provided in the interior space 4 in the form of dots because uneven swelling may occur when the substrate (housing) has a large area.

本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention 本発明に係る一実施例の断面図  Sectional drawing of one Example which concerns on this invention

符号の説明Explanation of symbols

1 基板(上部用)
2 基板(下部用)
3 突起物等
4 内部空間
5 封止材及び接合材用の隙間等
6 中央部底面
7 連結用の孔
8 連結金具(プラスチック製)
1 Substrate (for upper part)
2 Substrate (for lower part)
3 Protrusions, etc. 4 Internal space 5 Sealing and bonding material gaps, etc. 6 Center bottom surface 7 Connection hole 8 Connection fitting (made of plastic)

Claims (5)

合成樹脂材、ゴム材、繊維材、金属材またはそれらの複合による色素増感太陽電池(結晶及び非結晶シリコン、化合物半導体及び有機半導体の太陽電池含む。)用の基板に、接合用、封止用及び電極用の凹凸状の突起物や窪みや段差あるいは隙間や孔を設け、それら基板を重ね合わせて接合する際に、内部空間が密封状態となるように成形したたことを特徴とする色素増感太陽電池用の基板(筐体)。  Bonding and sealing to substrates for dye-sensitized solar cells (including crystalline and non-crystalline silicon, compound semiconductor and organic semiconductor solar cells) by synthetic resin materials, rubber materials, fiber materials, metal materials or their composites Dye characterized by providing projections and depressions, depressions, steps, gaps or holes for use and electrodes, and molded so that the internal space is sealed when the substrates are stacked and joined A substrate (housing) for sensitized solar cells. 請求項1の基板(筐体)において、その凹凸状の突起物等を内部空間を含めて基板全体に点状や線状として配置するように設けたことを特徴とする請求項1記載の色素増感太陽電池用の基板(筐体)。  2. The pigment according to claim 1, wherein the uneven projections and the like are provided so as to be arranged as dots or lines on the entire substrate including the internal space. A substrate (housing) for sensitized solar cells. 請求項1及び2の基板(筐体)において、その内部空間を真空状態あるいはそれに近い状態とするための空気抜取用の孔、隙間、口を設けたことを特徴とする請求項1及び2記載の色素増感太陽電池用の基板(筐体)。  3. The substrate (housing) according to claim 1 or 2, wherein an air extraction hole, a gap, or an opening is provided for making the internal space in a vacuum state or a state close thereto. A substrate (housing) for a dye-sensitized solar cell. 請求項1、2、3及び4の基板(筐体)において、その重ね合わせて接合する部分の一部を予め接合あるいは成形しておくことで封止及び接合作業の簡素化と内部空間の密封状態の向上を図ったことを特徴とする請求項1、2及び3記載の色素増感太陽電池用の基板(筐体)。  5. The substrate (housing) according to claim 1, wherein a part of the overlapping and joining parts is joined or molded in advance, thereby simplifying the sealing and joining work and sealing the internal space. The substrate (housing) for a dye-sensitized solar cell according to claim 1, 2 or 3, wherein the state is improved. 上記各請求項の基板(筐体)を単体あるいは複数用いて、積層としたり、平面的に大面積となるよう接合したり、立体的な造形物(例えば球状体)となるよう接合したり、柱表面や建築物や構築物の内外装部及び採光部に取付可能とするように基板の端部を接合用に加工したことを特徴とする請求項1、2、3、4及び5記載の色素増感太陽電池基板(筐体)。  Using a single substrate or a plurality of substrates (casings) of the above claims, laminating, joining to have a large area in a plane, joining to form a three-dimensional shaped object (for example, a spherical body), 6. The pigment according to claim 1, wherein the edge of the substrate is processed for bonding so that it can be attached to a column surface, an interior / exterior portion of a building or a structure, and a daylighting portion. Sensitized solar cell substrate (housing).
JP2008320227A 2008-11-21 2008-11-21 Substrate (case) for dye-sensitized solar cell Pending JP2010123556A (en)

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