JP2009235054A5 - - Google Patents

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JP2009235054A5
JP2009235054A5 JP2008172414A JP2008172414A JP2009235054A5 JP 2009235054 A5 JP2009235054 A5 JP 2009235054A5 JP 2008172414 A JP2008172414 A JP 2008172414A JP 2008172414 A JP2008172414 A JP 2008172414A JP 2009235054 A5 JP2009235054 A5 JP 2009235054A5
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JP
Japan
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ogo
reaction
hydrogen molecules
hydrogen
jacs
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JP2008172414A
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Japanese (ja)
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JP2009235054A (en
JP5371031B2 (en
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JACS 2002, 124, 597, Ogo et al.JACS 2002, 124, 597, Ogo et al. Science 2007, 316, 585, Ogo et al.Science 2007, 316, 585, Ogo et al.

水素分子から電子を抽出する反応のメカニズム
上記構造式（３）の低原子価金属錯体を経由し、水素発生を伴う水素分子の電子抽出反応のメカニズムは以下のように表される。
Mechanism of Reaction for Extracting Electrons from Hydrogen Molecules The mechanism of the electron extraction reaction for hydrogen molecules accompanied by hydrogen generation through the low-valent metal complex of the above structural formula (3) is expressed as follows.

JP2008172414A 2008-03-07 2008-07-01 Hydride metal complex and low valent metal complex, and method using them to extract electrons from hydrogen molecule, method for hydrogenating substrate, and method for producing hydrogen from deuterium Expired - Fee Related JP5371031B2 (en)

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Application Number Priority Date Filing Date Title
JP2008172414A JP5371031B2 (en) 2008-03-07 2008-07-01 Hydride metal complex and low valent metal complex, and method using them to extract electrons from hydrogen molecule, method for hydrogenating substrate, and method for producing hydrogen from deuterium

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2008058438 2008-03-07
JP2008058438 2008-03-07
JP2008172414A JP5371031B2 (en) 2008-03-07 2008-07-01 Hydride metal complex and low valent metal complex, and method using them to extract electrons from hydrogen molecule, method for hydrogenating substrate, and method for producing hydrogen from deuterium

Publications (3)

Publication Number Publication Date
JP2009235054A JP2009235054A (en) 2009-10-15
JP2009235054A5 true JP2009235054A5 (en) 2011-06-02
JP5371031B2 JP5371031B2 (en) 2013-12-18

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JP2008172414A Expired - Fee Related JP5371031B2 (en) 2008-03-07 2008-07-01 Hydride metal complex and low valent metal complex, and method using them to extract electrons from hydrogen molecule, method for hydrogenating substrate, and method for producing hydrogen from deuterium

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JP (1) JP5371031B2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2777764A1 (en) * 2009-10-22 2011-04-28 The Regents Of The University Of California Calixarene-bound iridium-containing metal colloids
JP5801662B2 (en) * 2011-09-09 2015-10-28 Jnc株式会社 Substrate oxidation method
JP5960577B2 (en) * 2012-10-23 2016-08-02 Jnc株式会社 Method for extracting electrons from hydrogen molecule using hydride metal complex and method for reducing substrate
US10975009B2 (en) * 2016-05-13 2021-04-13 Dsm Ip Assets B.V. Selective reduction of aldehydes and ketones
WO2017194663A1 (en) * 2016-05-13 2017-11-16 Dsm Ip Assets B.V. Selective reduction of esters to alcohols
WO2022133719A1 (en) * 2020-12-22 2022-06-30 Rhodia Operations Method for producing glycolic acid

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