JP2008301788A - Premix composition and batter for heat cooking - Google Patents
Premix composition and batter for heat cooking Download PDFInfo
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Abstract
Description
本発明は、家庭などで手軽に加熱調理できるスポンジケーキ用の蛋白質含有プレミックス組成物およびこれを用いたバッターに関する。 The present invention relates to a protein-containing premix composition for sponge cake that can be easily cooked at home and the like, and a batter using the same.
スポンジケーキの基本的な組成は、鶏卵、砂糖、小麦粉である。溶いた鶏卵を強くかき混ぜて気泡を形成させ、これをオーブンなどで加熱すると気泡が膨張して生地が膨れ、蛋白質の熱変性によって空気を含んだまま熱凝固することによって生地の基本的な骨格が生成され、さらに、これに小麦粉が加えることにより、生地の中で形成されたグルテンと、焼き上げたときに糊化した澱粉とが生地の骨格をより強化させている。
しかし、ふっくらとしたスポンジケーキを調理するには、鶏卵を十分に泡立て、生地成分を配合し、均一に混練するなど、手間と時間を要した。
The basic composition of a sponge cake is chicken eggs, sugar and flour. Stir the melted chicken eggs to form bubbles, and when heated in an oven, the bubbles expand and the dough swells, and the basic skeleton of the dough is formed by heat coagulation while containing air by heat denaturation of the protein. Furthermore, the gluten formed in the dough and the starch gelatinized when baked further strengthens the skeleton of the dough by adding wheat flour to this.
However, cooking a plump sponge cake took time and effort, such as fully foaming chicken eggs, blending dough ingredients, and kneading uniformly.
このようなスポンジケーキを、より簡単に調理できるよう鶏卵に替えて膨張剤を添加した加熱調理用プレミックスが登場した。このプレミックスは、小麦粉や砂糖などの生地成分が予め配合されており、固形粉末成分からなるので、流通や保存性に優れ、調理に当たってはプレミックスに水あるいは牛乳を添加、混合し、得られたバッター液を加熱するだけで誰でも簡単にスポンジケーキを作ることができる。
しかしながら、膨張後の体積維持のため、加熱によってゲル化する成分である蛋白質などを加える必要があるが、適量範囲を超えて添加すると、蛋白質特有の味が強く出てしまい風味が落ちるとともに、べチャついた食感となり、粘度も高くなり取扱が難しくなるといった問題があった。
In order to make it easier to cook such a sponge cake, a premix for cooking has been added in which an expansion agent is added instead of chicken eggs. This premix is pre-mixed with dough ingredients such as flour and sugar, and consists of solid powder components, so it is excellent in distribution and storage, and is prepared by adding and mixing water or milk to the premix for cooking. Anyone can easily make a sponge cake just by heating the batter liquid.
However, in order to maintain the volume after expansion, it is necessary to add protein, which is a component that gels by heating, but if it is added beyond the appropriate amount range, the protein-specific taste will be strong and the flavor will be lowered. There was a problem that the texture became sticky, the viscosity increased, and handling became difficult.
さらに、このようなスポンジケーキを加熱するには、オーブンや蒸し器を必要とするが、これらの調理手段は、加熱時間が長く、予熱や放冷にも時間がかり手間がかかるものであった。そこで、各家庭に広く普及した電子レンジを使用することが考えられる。電子レンジを使用すれば、調理物の内部から加熱できるので、調理時間が短くて済み、操作も簡単となる。 Furthermore, in order to heat such a sponge cake, an oven and a steamer are required. However, these cooking means have a long heating time, and it takes time and effort to preheat and cool. Therefore, it is conceivable to use a microwave oven widely used in each home. If a microwave oven is used, cooking can be heated from the inside, so cooking time is short and operation is also simple.
しかし、小麦粉を含むスポンジケーキ用プレミックスを電子レンジで加熱調理した場合、内部から加熱されるため生地が膨張する際、加熱ゲルが膨張を阻害するため十分な膨化が行えなくなる。そのために、これを原料とするケーキのスポンジ組織は、グルテン特有の強い粘弾性となり、膨化もグルテンの緊縮力のために抑制されて不十分なものとなる。さらに、食感もオーブンで加熱したものと比較してゴム様の食感を呈するものとなり、加えて、加熱直後、膨化に関与した水蒸気が急速に凝縮するため焼縮みが発生し易いといった問題があった。 However, when a sponge cake premix containing wheat flour is cooked in a microwave oven, it is heated from the inside, so that when the dough expands, the heated gel inhibits the expansion, so that sufficient expansion cannot be performed. Therefore, the sponge structure of the cake made from this becomes a strong viscoelasticity peculiar to gluten, and the expansion is suppressed due to the gluten's contraction force and becomes insufficient. Furthermore, the texture also becomes a rubber-like texture compared to that heated in the oven, and in addition, immediately after heating, the water vapor involved in expansion is rapidly condensed, so that there is a problem that shrinkage tends to occur. there were.
このような問題を解決するものとして、電子レンジでもソフトで口解けが良く、加熱直後の焼き縮みを解消したカップケーキ用プレミックスが提案されている(特許文献1)。このプレミックスでは、熱凝固性蛋白とα化澱粉を添加することにより、ソフトな食感と加熱調理後のケーキの焼き縮みを少なくすることができる。
しかし、このプレミックスによっても、蛋白質や機能性素材などをさらに加えると食感が固くなることがあり、また、使用する熱凝固性蛋白は、穀粉に対し10〜120重量%、α化澱粉は穀粉中25〜55重量%添加しなければならず、調理の自由度が低くなり、さらに蛋白質の割合が多くなり風味が落ち、バッター液の粘度が高くなるため取扱が難しくなるという問題がある。
As a solution to such a problem, there has been proposed a pre-mix for cupcake that is soft and easy to melt even in a microwave oven and eliminates shrinkage immediately after heating (Patent Document 1). In this premix, the heat-coagulating protein and pregelatinized starch can be added to reduce the soft texture and the shrinkage of the cake after cooking.
However, even with this premix, the texture may become harder when protein or functional ingredients are further added, and the thermocoagulable protein used is 10 to 120% by weight of the flour, and the pregelatinized starch is There is a problem that 25 to 55% by weight of the flour must be added, the degree of freedom of cooking becomes low, the ratio of protein increases, the flavor is lowered, and the viscosity of the batter liquid becomes high, so that handling becomes difficult.
以上説明したように加熱調理用プレミックスは、一般家庭用だけでなく業務用としても需要が強いが、ふっくらとしたスポンジケーキとするためには、生地成分の配合の自由度が非常に低く、蛋白質の増量や機能性素材の添加することは事実上不可能であった。
本発明の目的は、蛋白質を多量に添加しても風味が良くソフトでふっくらした食感のスポンジケーキを製造することができる加熱調理用プレミックス組成物を提供することである。
また、本発明の他の目的は、電子レンジを使用しても、焼き縮みがなくソフトでふっくらした食感のスポンジケーキを製造することができる電子レンジ加熱調理用プレミックス組成物を提供することである。
An object of the present invention is to provide a premix composition for cooking that can produce a sponge cake having a good, soft and plump texture even when a large amount of protein is added.
Another object of the present invention is to provide a premix composition for cooking by heating in a microwave oven that can produce a sponge cake having a soft and plump texture without baking shrinkage even when a microwave oven is used. It is.
本発明者は、穀粉類を主成分とするプレミックス中に、蛋白質としてゲル化しない蛋白質を使用し、発酵多糖(カードラン)を加えると、蛋白質を穀粉類に対し30%添加しても、加熱後に焼き縮みすることなく、また電子レンジを使用してもソフトでふっくらした食感のスポンジケーキを製造することができることを見出し、本発明に至ったものである。 The present inventor uses a protein that does not gel as a protein in a premix mainly composed of flour, and when adding a fermentation polysaccharide (curdlan), even if the protein is added to the flour by 30%, The present inventors have found that a sponge cake having a soft and fluffy texture can be produced without heating and shrinking after heating and using a microwave oven.
すなわち、本発明は、以下の態様を含む。
(1)穀粉類、ゲル化しない蛋白質、膨張剤、および熱凝固性多糖類を含むことを特徴とする加熱調理用プレミックス組成物。
(2)前記穀粉類に対し0.1〜50重量%の熱凝固性多糖類を含むことを特徴とする(1)の加熱調理用プレミックス組成物。
(3)加熱が電子レンジによるものである(1)または(2)に記載される加熱調理用プレミックス組成物。
(4)熱凝固性多糖液、熱凝固性多糖液と水、熱凝固性多糖液と牛乳、熱凝固性多糖液と牛乳と水からなる群のいずれかを穀粉類、ゲル化しない各種蛋白質および膨張剤に加え、その粘度を500Pa・s以下とした加熱調理用バッター。
(5)さらに前記穀粉類に対し5〜15重量%の水不溶性食物繊維を加えたことを特徴とする(4)の加熱調理用バッター。
(6)加熱が電子レンジによるものである(1)または(2)に記載される加熱調理用バッター。
That is, the present invention includes the following aspects.
(1) A premix composition for cooking, comprising flour, non-gelling protein, swelling agent, and thermocoagulable polysaccharide.
(2) The premix composition for cooking according to (1), comprising 0.1 to 50% by weight of thermocoagulable polysaccharide with respect to the flour.
(3) The premix composition for cooking according to (1) or (2), wherein the heating is performed by a microwave oven.
(4) Thermocoagulable polysaccharide fluid, thermocoagulable polysaccharide fluid and water, thermocoagulable polysaccharide fluid and milk, or any of the group consisting of thermocoagulable polysaccharide fluid, milk and water, flours, various proteins that do not gel A batter for cooking that has a viscosity of 500 Pa · s or less in addition to the swelling agent.
(5) The batter for cooking according to (4), wherein 5 to 15% by weight of water-insoluble dietary fiber is further added to the flour.
(6) The batter for cooking according to (1) or (2), wherein the heating is performed by a microwave oven.
本発明によれば、穀粉類を利用して得る熱変性ゲルを熱変性多糖類として、さらに、その際に蛋白質を強化する目的で加熱ゲル化性の無い一般的な蛋白強化素材を小麦粉と代替としても十分なふっくら感を維持することができるので、プレミックスの配合組成の自由度が大きく、各種機能性素材を配合することが可能となる。 According to the present invention, a heat-denatured gel obtained by using flours is used as a heat-denatured polysaccharide, and a general protein-enhanced material without heat gelation is used instead of wheat flour for the purpose of strengthening the protein. However, since a sufficient plump feeling can be maintained, the degree of freedom of the premix blending composition is large, and various functional materials can be blended.
また、本発明のプレミックス組成物によれば、ゲル化しない蛋白質や機能性材料を多量に添加しても、電子レンジを使用し、家庭において簡単にソフトでふっくらした食感のスポンジケーキを製造することができる。 In addition, according to the premix composition of the present invention, even when a large amount of non-gelling protein or functional material is added, a soft and plump textured sponge cake is produced at home using a microwave oven. can do.
本発明の加熱調理用プレミックス組成物とは、穀粉類を主成分とし、これに糖類、ゲル化しない蛋白質、膨張剤、熱凝固性多糖、及び、必要に応じて機能性材料、香料や色素などの各種添加剤を含むものである。 The premix composition for cooking according to the present invention is mainly composed of flours, and saccharides, proteins that do not gel, swelling agents, thermocoagulable polysaccharides, and functional materials, flavors and pigments as necessary. And various other additives.
本発明で使用される穀粉類は、小麦粉、米粉など、スポンジケーキの原料として使用される公知の穀類、あるいはそれらの混合物が使用できる。本発明のプレミックス中の穀粉の配合量は、20〜80重量%であることが好ましく、40〜60重量%であることがより好ましい。プレミックス中の穀粉の配合量が80重量%を超えると機能性素材や蛋白強化素材を添加する目的を考えると、配合上の自由度が低くなり好ましくない。また20重量%未満では穀粉特有の風味や食感を維持できなくなるためスポンジケーキを設計する上では好ましくない。 As the cereal flour used in the present invention, known cereals used as a raw material for sponge cake, such as wheat flour and rice flour, or a mixture thereof can be used. It is preferable that the compounding quantity of the flour in the premix of this invention is 20 to 80 weight%, and it is more preferable that it is 40 to 60 weight%. When the blending amount of flour in the premix exceeds 80% by weight, the degree of freedom in blending becomes low, considering the purpose of adding functional materials and protein-enhanced materials. On the other hand, if it is less than 20% by weight, the flavor and texture peculiar to flour cannot be maintained, which is not preferable in designing a sponge cake.
本発明で使用される熱凝固性多糖類とは、発酵多糖(カードラン)をいう。カードランとは、主に増粘安定剤として使用される食品添加物で、グラム陰性細菌の培養液より分離して得られるものであり、主成分は、β−1,3−グルカンである。本発明のプレミックス中の熱凝固性多糖類の配合量は、穀粉に対し0.5〜30重量%であることが好ましく、5重量%程度であることがより好ましい。プレミックス中の穀粉全量とのバランスにより一概には決められないが、熱凝固性多糖類の配合量が穀粉に対し30重量%を超えるとふんわり感が出せなくなり、0.5重量%未満では焼き縮み抑制効果が発揮できなくなる・。 The thermocoagulable polysaccharide used in the present invention refers to a fermentation polysaccharide (curdlan). A curdlan is a food additive mainly used as a thickening stabilizer, which is obtained by separation from a culture solution of gram-negative bacteria, and the main component is β-1,3-glucan. The blending amount of the thermocoagulable polysaccharide in the premix of the present invention is preferably 0.5 to 30% by weight, more preferably about 5% by weight, based on flour. Although it cannot be determined unconditionally due to the balance with the total amount of flour in the premix, if the blending amount of the thermocoagulable polysaccharide exceeds 30% by weight with respect to the flour, a soft feeling cannot be produced, and if it is less than 0.5% by weight The shrinkage suppression effect can no longer be demonstrated.
本発明で使用されるゲル化しない蛋白とは、大豆蛋白、コラーゲン、乳などをいう。本発明のプレミックス中のゲル化しない蛋白質の配合量は、プレミックス中に含まれる全蛋白質量30重量%未満であることが好ましく、5〜25重量%であることがより好ましい。プレミックス中の蛋白質の配合量が5重量%未満では本発明を適用する意義が薄まる。プレミックス中に含まれるゲル化しない蛋白質量が30重量%以上の場合十分なふっくら感を維持することが出来なくなるため好ましくない。 The non-gelling protein used in the present invention refers to soy protein, collagen, milk and the like. The amount of the non-gelling protein in the premix of the present invention is preferably less than 30% by weight of the total protein contained in the premix, and more preferably 5 to 25% by weight. When the protein content in the premix is less than 5% by weight, the significance of applying the present invention is diminished. When the amount of non-gelling protein contained in the premix is 30% by weight or more, a sufficient plump feeling cannot be maintained, which is not preferable.
本発明で使用される機能性材料とは、体調や健康を維持・改善する目的で摂取する食品・食品添加物・医薬部外品・医薬品などをいう。本発明のプレミックス中の機能性材料の配合量は、各々の機能性素材に応じて必要とする量が異なるため一概には言えないが、風味のバランスを無視する場合ゲル化しない蛋白質と同様プレミックス中に含まれる全蛋白質量30重量%未満であることが好ましい。 The functional material used in the present invention refers to foods, food additives, quasi-drugs, pharmaceuticals, etc. that are ingested for the purpose of maintaining and improving physical condition and health. The blending amount of the functional material in the premix of the present invention cannot be unconditionally because the amount required differs depending on each functional material, but it is the same as the protein that does not gel when the balance of flavor is ignored. The total protein content contained in the premix is preferably less than 30% by weight.
本発明でいうスポンジケーキには、スポンジケーキ、シフォンケーキ、蒸しパン、カステラ、ホットケーキ、マフインのほか、クロワッサンなどの通常の焼パンも含まれる。 The sponge cake as used in the present invention includes sponge cake, chiffon cake, steamed bread, castella, hot cake, muffin, and ordinary baked bread such as croissant.
本発明のプレミックスを調理するには、本発明のプレミックスに、水及び/または牛乳を加え攪拌・混合してバッター液を作る。本発明のプレミックスに対する水および/又は牛乳の配合量は、プレミックス100gに対し、水および/又は牛乳が30〜250mlが好ましく、この範囲であれば、プレミックスの組成にもよるが、バッター液の粘度が取り扱い易い500Pa・s未満となる。水および/又は牛乳の配合量が30ml未満では粘度が大幅に上昇し500Pa・s未満を維持することが難しくなる。また、250mlを超えると、粘度は好ましいが、風味が薄まりおいしさの観点では好ましいとは言えない。 To cook the premix of the present invention, water and / or milk is added to the premix of the present invention and stirred and mixed to make a batter solution. The blending amount of water and / or milk with respect to the premix of the present invention is preferably 30 to 250 ml of water and / or milk with respect to 100 g of the premix, and within this range, depending on the composition of the premix, the batter The viscosity of the liquid is less than 500 Pa · s which is easy to handle. When the blending amount of water and / or milk is less than 30 ml, the viscosity is significantly increased and it is difficult to maintain less than 500 Pa · s. Moreover, when it exceeds 250 ml, although a viscosity is preferable, it cannot be said that it is preferable from a viewpoint of a taste thin and delicious.
次に、このバッター液を適宜の容器に入れ加熱調理する。
加熱調理には、オーブン、蒸し器などの一般的な加熱調理器具が使用できるが、本発明のプレミックスを使用すれば、電子レンジを使用してもふっくらとしたケーキを作ることができる。
Next, this batter liquid is put in a suitable container and cooked.
For cooking, general cooking utensils such as an oven and a steamer can be used, but if the premix of the present invention is used, a plump cake can be made even using a microwave oven.
また、プレミックスの包装容器として、内面を樹脂でコーティングした紙容器のような耐熱性を有する素材、あるいはポリエチレンテレフタレートのように電子レンジ対応の素材で作成すれば、容器内でバッターを作りそのままオーブンや電子レンジで調理することができる。 Also, as a premix packaging container, if it is made of a heat-resistant material such as a paper container whose inner surface is coated with a resin, or a material compatible with a microwave oven such as polyethylene terephthalate, a batter is created in the container and the oven is left as it is. And can be cooked in the microwave.
以下、本発明を実施例で説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention, this invention is not limited to these Examples.
(調理例1,2,3)
下記の表1に示す組成よりなるプレミックスを常法により混合して電子レンジ調理用ケーキミックス組成物を得た。このケーキミックスを容量350mlのカップ状容器に入れよく攪拌混合し、ケーキ用ミックスバッターを得た。この各バッターの粘度は表1の通りであった。次いで、この各バッターを出力500Wの電子レンジで2分間加熱し目的とするスポンジケーキを得た。各ケーキは、カードランを使用した調理例2と、加熱ゲル化するα化小麦デンプンを使用した調理例3で均一できめの細かい組織を呈し食感もふっくらとしていた。それ以外の調理例1は加熱時に膨張したものがレンジ終了後に急速に縮みベチャ付いてゴム様の食感となってしまった。
(Cooking examples 1, 2, 3)
A premix having the composition shown in Table 1 below was mixed by a conventional method to obtain a cake mix composition for microwave cooking. The cake mix was put into a cup-shaped container having a capacity of 350 ml and mixed well with stirring to obtain a cake mix batter. The viscosity of each batter was as shown in Table 1. Next, each batter was heated in a microwave oven with an output of 500 W for 2 minutes to obtain the intended sponge cake. Each cake had a uniform and fine texture and had a fluffy texture in cooking example 2 using curdlan and cooking example 3 using pregelatinized wheat starch that gelled by heating. In other cooking examples 1, the one that expanded during heating shrunk rapidly after the end of the range and became sticky, resulting in a rubbery texture.
(調理例4〜9)
下記の表2に示す組成よりなるプレミックスを定法により混合し電子レンジ調理用ケーキミックスを得た。各プレミックス10gに水10cc加えて混合し、得られたバッターをビーカーに注入し、出力1000Wの電子レンジで30秒間加熱した。加熱終了後の、ケーキの界面及び側面に残った膨張跡の高さを測定し、下記式で計算される加熱縮み率を求めた。
加熱縮み率(%) = (加熱終了時の膨化面の高さ/最大膨化面の高さ)×100
グルテン、α化澱粉、カードランなど、加熱によりゲル化する添加剤を配合することにより加熱後の焼き縮みの少ないケーキを得ることができた。
(Cooking examples 4-9)
A premix having the composition shown in Table 2 below was mixed by a conventional method to obtain a cake mixture for microwave cooking. 10 cc of water was added to 10 g of each premix and mixed. The resulting batter was poured into a beaker and heated in a microwave oven with an output of 1000 W for 30 seconds. After the heating, the height of the expansion trace remaining on the interface and side surface of the cake was measured, and the heat shrinkage calculated by the following formula was obtained.
Heat shrinkage rate (%) = (height of the expanded surface at the end of heating / height of the maximum expanded surface) × 100
By adding additives that gelled by heating, such as gluten, pregelatinized starch, and curdlan, a cake with little shrinkage after heating could be obtained.
(調理例10〜13)
下記の表3に示す組成よりなる蛋白素材配合プレミックスを常法により混合して電子レンジ調理用ケーキミックス組成物を得た。このバッターを出力500Wの電子レンジで2分間加熱し目的とするスポンジケーキを得た。カードランを使用した調理例10,11は、蛋白量が増加してもふっくらした食感を維持したのに対して、α化小麦デンプンを使用した調理例12,13は、蛋白量が増加するのに対して食感が重くベチャつく傾向が見られた。
(Cooking examples 10-13)
A protein material-containing premix having the composition shown in Table 3 below was mixed by a conventional method to obtain a cake mix composition for cooking in a microwave oven. The batter was heated in a microwave oven with an output of 500 W for 2 minutes to obtain the intended sponge cake. The cooking examples 10 and 11 using curdlan maintained a plump texture even when the protein amount increased, whereas the cooking examples 12 and 13 using pregelatinized wheat starch increased the protein amount. On the other hand, the texture was heavy and sticky.
(調理例14−18)
下記の表4に示す組成よりなるプレミックスを常法により混合して電子レンジ調理用ケーキミックス組成物を得た。このバッターを出力1000Wの電子レンジで30秒間加熱しレンジケーキの膨化面を観察した。カードランを穀粉に対し1.7〜5.3重量%使用した調理例14−17は、加熱縮みを抑制するともに、スポンジケーキ特有のふんわり感を出すことができたが、添加量がそれより増えると、加熱縮み抑制効果は優れるものの、組織の歯ごたえが増す傾向が見られた(調理例18)。
(Cooking example 14-18)
A premix composed of the composition shown in Table 4 below was mixed by a conventional method to obtain a cake mix composition for microwave cooking. The batter was heated in a microwave oven with an output of 1000 W for 30 seconds, and the expanded surface of the range cake was observed. In the cooking examples 14-17 using curdlan in the amount of 1.7 to 5.3% by weight with respect to the flour, the heat shrinkage was suppressed and the soft feeling peculiar to the sponge cake was exhibited. When increased, the effect of suppressing heat shrinkage was excellent, but a tendency to increase the texture of the tissue was observed (Cooking Example 18).
(調理例19,20)
得られた知見をもとに、クロワッサン生地にカードランを添加し、効果を確認した。
表4に示されるクロワッサン生地をL3“M4”でミキシングし、冷蔵発酵90分、冷凍発酵2分させたものを40gづつに分割した。次に3つ折りを3回行ない成形し、30℃、70%のホイロで70分間発酵させ、205℃15分で焼成した。なお、折り毎に30分のベンチタイムを取った。
(Cooking examples 19 and 20)
Based on the obtained knowledge, curdlan was added to the croissant dough, and the effect was confirmed.
The croissant dough shown in Table 4 was mixed with L3 “M4”, and chilled and fermented for 90 minutes and frozen for 2 minutes, and divided into 40 g units. Next, it was molded by performing three folds three times, fermented at 30 ° C. and 70% proofing for 70 minutes, and baked at 205 ° C. for 15 minutes. A 30 minute bench time was taken for each fold.
本発明の加熱調理用プレミックスは、流通、保存性に優れ、しかも簡単にだれにでもおいしいスポンジケーキを調理できるので、社会的な需要が高い。また、成分配合の自由度が高いので、機能性食品や健康食品とすることが簡単にできるという利点がある。 Since the premix for cooking according to the present invention is excellent in distribution and storage, and can easily cook delicious sponge cakes to anyone, there is a high social demand. Moreover, since the freedom degree of a component mixing | blending is high, there exists an advantage that it can be easily set as a functional food or a health food.
Claims (6)
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| JP2013132283A (en) * | 2011-12-27 | 2013-07-08 | Kracie Foods Ltd | Cooking powder for heat-formed food with drawing pattern, and combination kit for the heat-formed food |
| WO2017026470A1 (en) * | 2015-08-12 | 2017-02-16 | クラシエフーズ株式会社 | Combination confectionery |
| WO2018176111A1 (en) * | 2017-03-31 | 2018-10-04 | My Life Alimentos Ltda | Balanced cake mixture |
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