JP2008201758A - Method for preventing insect pest damage - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for preventing the insect pest damages of plant seeds, stored cereal grains, stored beans, stored fruits, stored vegetables, stored feeds, stored flowers and importing or exporting wood materials, and having less effects to animals and plants. <P>SOLUTION: This method for preventing the insect pest damages is provided by applying a composition consisting of Etofenprox as an active ingredient on the plant seeds, stored cereal grains, stored beans, stored fruits, stored vegetables, stored feeds, stored flowers and importing or exporting wood materials. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a composition containing 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl ether (generic name etofenprox) as an active ingredient, as plant seeds, stored cereals, stored beans, stored fruits, The present invention relates to a method for preventing pest damage by applying to stored vegetables, stored feed, stored flower buds, and imported / exported wood.

  Pest control is extremely important for agriculture. Pest damage can occur not only in the above-ground parts of plants but also in soil. Most of the damage in the soil is caused by eating pests that damage the roots, i.e. plant roots, or by entering plant pathogens from damaged sites that have been harmed by the pests.

  Seed germination, sprouting, and initial plant growth are particularly important because the roots and stems of the growing plants are small and the entire plant can wither even in small amounts of damage. Control of pests that injure seeds and plant parts on the ground at the initial stage of plant growth has been variously studied in the agricultural field. Currently, it is common to apply pesticides mainly to soil or foliage to control pests that harm crops after germination.

  The foliage treatment usually requires treatment when pests are present in order to be most effective. Therefore, when it is difficult to treat the medicine due to rain or the like, there are cases where the effect cannot be exhibited. Furthermore, in order to efficiently control pests, it is necessary to closely observe the occurrence of pests. Many insecticides exhibiting an excellent control effect by being applied to the soil surface as such a foliar treatment agent or at the time of sowing are known. However, those pesticides have extremely high toxicity to aquatic organisms such as fish, so it is necessary to pay great attention to the movement into the water due to runoff or drift during soil surface treatment or foliage application There are also many.

  At present, the technology for protecting plants from damage caused by pests by plant foliage treatment and seed treatment is rapidly progressing, but some problems can still be pointed out. For example, it is useful if the amount of pesticide used can be further reduced. In addition, it is useful if it is possible to protect the crop over a wider range than the effect of a plant introduced with a gene to produce biopesticidal activity or insecticidal active substance alone.

  Etofenprox is an insecticidal compound, such as foliar spraying treatment and sprayed water spraying treatment, etc.Semiptera such as Spodoptera litura, Nika maiga, Monroe butterfly, etc. It is effective along with its production method to show effects on pests, Coleoptera such as rice weevil and kissing flea beetles, Diptera such as house flies and sand moth flies, Thrips such as Negia thrips, and Coleoptera such as black cockroaches It is described in the 61-21615 gazette. However, there is no description showing pest prevention in application methods such as spraying treatment, smearing treatment, dipping treatment, dressing treatment, coating treatment, and pressure injection on plant seeds. Moreover, although the description of the fumigant and the non-heated fumigant is made in the specification, the examples are not shown. In JP-A-63-287701, a cooperative effect by the combined use of a nitromethylene derivative and etofenprox is noted, and a formulation comprising a seed coating agent and a combustion device in the specification (for example, as a combustion device) , Fumigation and fumigation cartridges, cans and coils), but any description applicable to plant seeds, stored grains, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood unacceptable.

  In addition, organic phosphorus agents such as pyrimifosmethyl, fenitrothion, and marathon, and pyrethroid agents such as cypermethrin, deltamethrin, and permethrin are known as postharvest-approved agricultural chemicals. Some of these agents have been pointed out to have a toxic effect on mammals. In particular, regulations on organophosphorus agents have been strengthened in the United States and the like due to concerns about toxicity to the human body. From such a background, a highly safe control agent is demanded.

On the other hand, etofenprox is known to be particularly excellent in safety while being a synthetic pyrethroid. For example, in Japan, many synthetic pyrethroids cannot be used in paddy fields because of their influence on aquatic organisms, whereas etofenprox and silafluophene are synthetic pyrethroids that can be applied to rice plants for foliage.
Japanese Examined Patent Publication No. 61-21615 JP-A 63-287701

  An object of the present invention is to provide a method for preventing pest damage on plant seeds, stored grains, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood, which has little influence on animals and plants. is there.

  As a result of intensive studies in view of such circumstances, the present inventors have found that a composition containing etofenprox as an active ingredient is plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, imported / exported wood. As a result, the present inventors have found that the present invention exhibits a high preventive effect on a plurality of pests at a low dose, and has led to the present invention.

  That is, the present invention is a pest characterized by applying a composition containing etofenprox as an active ingredient to plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feeds, stored florets, and imported / exported wood. It provides a way to prevent damage.

  The preventive method of the present invention has a high preventive effect on plant seeds, plants grown from plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and pests generated on imported / exported wood. Demonstrate.

An example of a pest that can prevent the damage by the method of the present invention is given below.
As pests on plant seeds and plants grown from seeds,
Orthoptera (orthoptera): as BLATTIDAE, American cockroach (Periplaneta americana), black cockroach (Periplaneta fuliginosa), Yamato cockroach (Periplaneta japonica), etc., as BLATTELLIDAE, German cockroach (Blattella germanica), Hime German cockroach (Blattella lituricollis), etc., as TETTIGONIIDAE , Homocoryphis jezoensis, Hokurorihus lineosus, etc., GRYLLOTALIDIDAE, etc., Gryllotalpa sp., Etc., ACIDIDAE, Nago (Oxya hyla intricata), Kobaneinago (Oxya yezoensis), etc.,
Termites (ISOPTERA): Cryptoptermes domesticus, Copterterms formosanus, Reticulitermes formosanus, Odontotermes, etc.
Thysanoptera (THYSANOPTERA): as THRIPIDAE, grasses thrips (Anaphothrips obscurus), thorns but-thrips (Chirothrips manicatus), tea Roh black thrips (Dendrothrips minowai), Hirazuhanaazamiuma (Frankliniella intonsa), lily flower thrips (Frankliniella lilivora), Croton thrips ( Heliotrips haemorrhoidalis, Microcephalotrips abdominalis, Soybean thrips (Mycterothrips glycines), Pseudodendroth ips mori), yellow tea thrips (Scirtothrips dorsalis), red Obi thrips (Selenothrips rubrocinctus), rice thrips (Stenchaetothrips biformis), green onions black thrips (Thrips alliorum), loquat Hana thrips (Thrips coloratus), Yellow Hana thrips (Thrips flavas) , Hana thrips (Trips palae), Thrips nigropirusus, (Thrips palmi), Cyclelini larva ps setosus), gladiolus thrips (Thrips simplex), green onion thrips (Thrips tabaci), etc., as PHLAEOTHRIPIDAE, rice Kedah thrips (Haplothrips aculeatus), Sina Kedah thrips (Haplothrips chinensis), Hana Kedah thrips (Haplothrips kurdjumovi), clover Kedah thrips ( Haplotrips nigar), Shionagakuda thrips ((Leeuwania pasanii), Kusuda thrips (Liothripps floradensis), Yurinokuda thrips (Liothrips vanetheto pips) saniae), Kakikudaazamiuma (Ponticulothrips diospyrosi) and the like,
HEMIPTERA: As PENTATOMIDAE, Carpocoris purpureipennis, T. terridium moth, D. moss. Eysarcoris lewisi), Scarab beetle (Eysarcoris parvus), Shirahoshi stink bug (Eysarcoris ventralis), Glutenia physalis (Glaucias submuctus) Worms (Halyomorpha mista), Inekamemushi (Lagynotomus elongatus), order Hemiptera (Nezara antennata), southern green stink bug (Nezara viridula), Piezodorus stink bug (Piezodorus hybneri), Plautia crossota stali (Plautia stali), rice black bug (Scotinophara lurida) , Swords stink bug (Stariodes iwasakii), etc., as COREIDAE Clytus trigonus), Molipteryx fulginosa etc., ALYDIDAE, etc. , RHOPALIDAE, Aeschineles maculatus, Liorhyssus hyalinus, etc., LYGAEIDAE, Caverelius saccharivoruma, cropes obnubilus), Hirata gourd Naga bug (Pachybrachius luridus), Black-footed bombardier Naga bug (Paromius exguus), co spring gourd Naga bug (Togo hemipterus), etc., as Pyrrhocoridae, red-spotted stink bug (Dysdercus cingulatus), Anthrenus red Hoshi stink bug (Dysdercus poecilus) or the like, As TINGIDAE, Kikugunbui (Galeatus spinifrons), Yanagigunbui (Metasalis populi), Kusgunbui (Stephanitis fascicarina), Nashigunbui (Stephanitis sashii), Tsujigumbai tis pyrioides), Uhlerites debile, Uhlerites latius, etc., MIRIDAE, Adelphocoris lineolatus, Apifois olticus turtle, spinolai), red beetle turtle Creontides pallidifer, tobacco turtle (Cyrtopeltis tennuis), giant beetle turtle (Ectometopterus micanthulus), black beetle turtle (Halticiilus insululus) ris), apple black Kasumi turtle (Heterocordylus flavipes), Makiba Miridae (Lygus disponsi), Madara Miridae (Lygus saundersi), sugar beet Miridae (orthotylus flavosparsus), Mugikasumikame (Stenodema calcaratum), lid streaks Kasumi turtle (Stenotus binotatus), red streaks Miridae (Stenotos rubrovititus), Tylorilygus pallidulus, Trichotylus coelestialium, etc., CICADIDAE, Graptopsalt rofuscata), etc., as APHROPHORIDAE, Maekiawafuki (Aphrophora costalis), Matsuawafuki (Aphrophora flavipes), Budouawafuki (Aphrophora intermedia), Princess lid ten Naga Awa butterbur (Clovia punctata), Hosoawafuki (Philaenus spumarius), etc., as TETTIGELLIDAE, blacktip reef shark giant leafhopper ( Bothrogonia japonica, Cicella viridis, etc., CICADELLIDAE, Kashihime-meikobe (Aguriahana quercus), Hannohime-yokobai (Alnetodia aruneti), Kakitsuhime-Ameyo pheliona ferruginea, Arboridia apicaris, Edwardsiona flavescens, Edwardsianarasae, Ebomicoe, As DELTOCEPHALIDAE, Macrostels fascifrons, Nephotetti cinctice crocodile, N. pictus), Taiwan green rice leafhopper (Nephotettix virescens), apple spotted leafhopper (Orientus ishidai), Inazuma leafhopper (Recilia dorsalis), Mugiyokobai (Sorhoanus tritici), Han Roh Naga leafhopper (Speusotettix subfusculus), etc., as DELPHACIDAE, small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), sugarcane planthopper (Numata muiri), corn planthopper (Peregrinus maidis), black planthopper (Perkinsiella saccharicida), white-tailed planthopper (Sogronka) tella furcifera), Hieunka (Sogatella panicicola), etc., as PSYLLIDAE, Kuwakijirami (Anomomeura mori), Seguro Hime pheasant Rami (Calophya nigridorsalis), Diaphorina citri (Diaphorina citri), Yamaasakijirami (Mesohomotoma camphorae), Todokijirami (Psylla abieti), Han'nokijirami (Psylla alni), Yamato Whale (Psyla jamatonica), Apple Whale (Psyla mali), Black Whale (Psylla malivilella), Psylla pyrisuga, Psylla pyramila e), box kurtosis pheasant Rami (Trioza camphorae), chestnut kurtosis pheasant Rami (Trioza quercicola), etc., as ALEYRODIDAE, mandarin orange spiny whitefly (Aleurocanthus spiniferus), grape whitefly (Aleurolobus taonabae), tobacco whitefly (Bemisia tabaci), mandarin orange whitefly (Dialeurodes citri ), Whitefly whitefly (Trialeurodes vaporariorum), silver leaf whitefly, etc., as PHYLLOXERIDAE, grapevine aphids (Viteus vitifoliai), etc., PMPHIGIIDAE, apple nephidia (Aphidonulimus lily) Ngowatamushi (Eriosoma lanigerum), sugarcane Ne aphid (Geoica lucifuga), etc., pea aphid (Acyrthosiphon pisum) as Aphidiidae, spiraea aphid (Aphis citricola), bean aphid (Aphis craccivora), willow aphid (Aphis farinose yanagicola), cotton aphid ( Aphis gossypii), potato beetle aphid (Auracorthum solani), wheat aphid (Aphidium helichrysi), radish aphid (Brevicoryne brassicae), tulip D aphid aphis tulipae), birch cotton butterbur spotted aphid (Euceraphis punctipennis), Momoko butterbur aphid (Hyalopterus pruni), fake radish aphid (Lipaphis erysimi), chrysanthemum Princess aphid (Macrosiphoniella sanborni), tulip aphid (Macrosiphum euphorbiae), broad bean aphid ( Megaura crashicauda, Melanaphis siphonella, Myzus malistus, Myzumumecola, Myzmus pers cae), green onion aphid (Neotoxoptera formosana), apple green aphid (Ovatus malicolens), lotus constricted aphids (Rhopalosophum nymphaeae), wheat constricted aphid (Rhopalosophum padi), Oka Bono aphid (Rhopalosophum rufiabdominalis), no circle aphid (Sappaphis piri) , Schizophis piricola, Swanbion aphiae, Sitobion abarae, Toboptera aurantii, Toxopera aurantii era citricidus), peach Cobb aphid (Tuberocephalus momonis), Taiwan aphid (Uroeucon formosanum), etc., as MARGARODIDAE, giant straw sandals scale insects (Drosicha corpulenta), Iseria scale insects (Icerya purchasi), etc., as PSEUDOCOCCIDAE, Matsumoto mealybugs (Crisicoccus matsumotoi) , Pinus crispula (Crisicoccus pinii), Phytococcus aphid (Dysmicoccus wisteriae), Prunococcus citri, Planococcus kra uhiae),
Pseudococcus cryptus (Pseudococcus citriculus), mulberry mealybugs (Pseudococcus comstocki), etc., as COCCIDAE, Tsunoroumushi (Ceroplastes ceriferus), Rubiroumushi (Ceroplastes rubens), mandarin orange Hirata scale insects (Coccus discrepans), Hirata Kata scale insects (Coccus hesperidum), citrus Anchovy (Coccus pseudomagnoriariaum), scallop (Ericerus pela), eastern beetle (Lecanium corni), Lecanium persicae, citrus scale insect (Pulvinaria aurantii), Citrus aphidial (Pulvinia citrus) (Pulvinia citrus), DIASPIDIDAE, (Andapis aphid) Scale insect (Aspiditus destructor), White scale scale insect (Aspidiotus hederae), Red-footed scale Aphid (Chrysomphalus ficus), Agricultural scale scale (San Jose scale scale) rniciosa), black beetle scale (Duplaspidiotus claviger), citrus scale insect (Lepidosaphes bekii), apple seed scale (Lepidosaphes ulphi), pear scale beetle (ceps) (Parlatoria camelliae), Chanokurohoshi scale aphid (Parlatoria theae), Scaraba scale (Parlatoria ziziphi), Hara scale insect (Pinnaspisaspidistrae) ia duplex), living room Le scale insects (Pseudaonidia paeoniae), white peach scale (Pseudaulacaspis pentagona), plum white peach scale (Pseudaulacaspis prunicola), Unaspis yanonensis (Unaspis yanonensis), etc.,
Lepidoptera (LEPIDOPTERA): Koumoriga (Endoclyta excrecens), macular bats (Endoclytasinensis), white Ten bats (Palpifer sexnotata), Barahamaki (Acleris comariana), apple Coca summer fruit tortrix (Adoxophyes orana fasciata), smaller tea tortrix (Adoxophyes sp. ), Apples brevipicanus, Midekakumonmonaki (Archips fuscocuppreanus), Kakimon oyster (Archips xylostaneus), Bakutra furfuranane, Asakua Chiro reipalpana), Kurimiga (Cydia kurokoi), chestnut green sink bur (Eucoenogenes aestuosa), oriental fruit moth (Grapholita molesta), Chahamaki (Homona magnanima), apple fruit moth (Hoshimoa adumbratana), soybean pod borer, Leguminivora glycinivorella (Leguminivora glycinivorella), Azukisayamushiga (Matsumuraeses azukivora), Soybean mushroom (Matsumuraeses falcana), bean mushroom mushroom (Matsumuraeses phaseoli), apple spider leaflet (Spilonota lechriaspis), apple spruce leaf spider (Spirono) a ocellana), grapes bombardier moth (Eupoecillia ambiguella), Kuwaihosohamaki (Phalonidia mesotypa), mugwort giant bombardier moth (Phtheochroides clandestina), Minoga (Bambalina sp.), Oominoga (Eumeta japonica), Chaminoga (Eumeta minuscule), carvings (Nemapogon granellus ), Iga (Tinea translucens), prickly moth (Bucculatrix pyricorella), peach leaf moth (Lyonetia clarkerella), lingon leaf moth (Lyonetia prunifoiliella), lobster moth la), Chanohosoga (Caloptilia theivora), Ringohosoga (Caloptilia zachrysa), Kakihosoga (Cuphodes diospyrosella), the apple leaf miner (Phyllonorycter ringoniella), Nashihosoga (Spulerina astaurota), mandarin orange leafminer (Phyllocnistis citrella), grape leafminer (Phyllocnistis toparcha), Negikoga (Acrolepiopsis sapporensis), yamanoimokoga (Acroleopsis suzukiella), black moth (Plutella xylostella), apple corn cinchui (Argyresthia conjugel) la), grapes Sukashiba (Paranthrene regalis), Kosukashiba (Synanthedon hector), Kakinohetamushiga (Stathmopoda masinissa), Imokibaga (Brachmia triannulella), peach fruit moth (Carposina niponensis), apple moth black bar (Illiberis pruni), Kuroshitaaoiraga (Lotoia sinica), monema flavescens ( Monema flavescens, Nashiiraga (Nanosidedeus flavidosalis), Auraira (Parasa consocia), Siperodes consturacus, Chilo supresnosco Moth (Cnaphalocroscis medinalis), peach monopoda teltibell (Diaphania indica), papaver moth (Etamyelois pyridae) Black-backed shore moth (Euzophera batogensis), Glyphodes pylorialis, Hellulla undalis, Marasmia exigua, Maru mulberry, Moth (Notarcha derogate), the European corn borer (Ostrinia furnacalis), Azukinomeiga (Ostrinia scapulalis), Fukinomeiga (Ostrinia zaguliaevi), Shibatsutoga (Parapediasia teterrella), Ukon'nomeiga (Pleuroptya ruralis), Sankameiga (Scirpophaga incertulas), parnara guttata (Parnara guttata), Papilio Helenus, Papilio machaon hipporates, Papilio xutus, Monk butterfly (Colias erate polygraphus), Monshirocho (Pieris rapae crucivora), lampides boeticus (Lampides boeticus), Plum Eda Shakti (Angerona prunaria), mugwort Eda Shakti (Ascotis selenaria), Tobi Mont giant Eda Shakti (Biston robustum), Umeedashaku (Cystidia couaggaria), pine moth (Dendrolimus spectabilis), lackey moth ( Malacosoma neutria testacea, apple calcare (Odonestis pruni japonensis), hawk moth (Cephonodes hylas), grape sparrow (Acosmerix castanea) choreta), kelp killer whale pike (Clostera anastomosis), Mont black killer whale pike (Phalera flavescens), giant Tobi Mont killer whale pike (Phalerodonta manleyi), killer whale pike moth (Stauropus fagi persimilis), Arna Pseudoconspersa (Euproctis pseudoconspersa), Monshirodokuga (Euproctis similes), tussock (Euproctis subflava), Mymantia dispar, Orgyia thyella, Hyphantria cunea, Spirosoma imparilis, Spirosoma imparilis (Acanthoplusia agnata), Nakajiroshitaba (Aedia leucomelas), black cutworm (Agrotis ipsilon), Kaburayaga (Agrotis segetum), Akakiriba (Anomis mesogona), Tamanagin'uwaba (Autographa nigrisigna), Trichoplusia ni (Trichoplusia ni), cotton bollworm (Helicoverpa armigera), tobacco budworm (Helicoverpa assulta), crested saga (Heliothis maritime), mushroom (Mamestra brassicae), pterodactyl (Nangaga aenescens), Ayuyoto (Pseudaletia sepata) C (Sesamia inferens), Sujikiriyotou (Spodoptera depravata), beet armyworm (Spodoptera exigua), common cutworm (Spodoptera litura), Ringokenmon (Trianea intermedia), Nashikenmon (Viminia rumicis), Shiromon'yaga (Xestia c-nigrum) and the like,
Coleoptera (COLEOPTERA): Chairokogane (Adoretus tenuimaculatus), cupreous chafer (Anomala cuprea), rufocuprea (Anomala rufocuprea), flower chafer (Eucetonia pilifera), Blue flower chafer (Eucetonia roelofsi), Nagachakogane (Heptophylla picea), Kofukikogane (Melolontha japonica), Scarab beetles (Mimela splendens), core red clover (Oxycetonia jucunda), bean scallops (Popilia japonica), beetle beetle (Anthrenus verbasci), beetle worm beetle (Atun tussage nus) color japonicus), cigarette beetle (Lasioderma serricorne), Hirata beetle (Lyctus brunneus), Guy My Deo kiss Lee (Carpophilus dimidiatus), clear Keshikisui (Carpophilus hemipterus), giant beetle, Epilachna vigintioctopunctata (Epilachna vigintioctomaculata), the beetle, Epilachna vigintioctopunctata (Epilachna vintignoctopuncta), Japanese red beetle (Alphitobius laevigatas), Japanese red beetle (Neatus picipes), Japanese red beetle (Palorus ratzeburgii), Japanese red beetle subdepressus), Chai loco agate molitor (Tenebrio molitor), red flour beetle (Tribolium castaneum), Hirata red flour beetle (Tribolium confusum), beans Beetle (Epicauta gorhami), key sawyer (Aeolesthes chrysothrix), Gomadarakamikiri (Anoplophora malasiaca), Matsunomadara Japanese beetle (Monochamus alternatus), Japanese beetle (Psacothea hilaris), Grape tiger beetle (Xylotrechus pyrrhoderus), Ayojikamikiri (Xytrocena globosa), Azuki beetle bruchus chinensis), cucurbit leaf beetle (Aulacophara femoralis), Tenebrio monkey beetle (Basilepta balyi), Kamenokohamushi (Cassida nebulosa), Ten site bi potato beetle (Chaetocnema concinna), Imosaruhamushi Colasposoma dauricum), A person who spotted neck Naga leaf beetle (Crioceris quatuordecimpunctata)
, Inenekuihamushi (Donacia provosti), Rurihamushi (Linaeidea aenea), Kiashinomihamushi (Luperomorpha tunebrosa), lid streaks Anthrenus Beetle (Medythia nigrobilineata), Inedorooimushi (Oulema oryzae), Anthrenus key spring monkey Beetle (Pagria signata), daikon leaf beetle (Phaedon brassicae ), Phyllotreta striolata, Umechokuri weevil (Involvulus cupreus), peach weevil weevil (Rhynchites heros), Aryomo weevil (Cylas formmicarius) omorum), die consulting weevil (Ceuthorhynchidius albosuturalis), chestnut weevil (Curculio sikkimenesis), rice weevil (Echinocnemus squameus), Imozoumushi (Euscepes postfasciatus), clover weevil (Hypera nigrirostris), alfalfa weevil (Hypera postica), rice water weevil (Lissorhoptrus oryzophilus ), Weevil weevil (Listroderes costirostris), apple beetle weevil (Phyllobius armatus), chibi beetle weevil (Sitona japonicus), coconut Umushi (Sitophilus oryzae), maize weevil (Sitophilus zeamais), such as grass reed weevil (Sphenophrus venatus vestitus),
Hymenoptera: Japanese bee wasp (Athalia japonica), bee (Athalia rosae tuficornis), apple bee (Arge mali), Arge pagaura (Arge pagaura), D
Diptera: Tipula aino, Bradysia agrestis, Asphondylia sp., Ac (Dacus cucurbitae), D Cherry Leaf Spot fruit fly (Rhacochlaena japonica), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii), cherry fruit fly (Drosophila suzukii), Inekimoguribae Chlorops oryzae), Mugikimoguribae (Meromuza nigriventr s), rice leafminer (Agromyza oryzae), the pea (Chromatomyia horticola), eggplant leafminer (Liriomyza bryoniae), green onion leafminer (Liriomyza chinensis), legume leafminer (Liriomyza trifolii), tomato leafminer (Liriomyza sativae), reed Gros leafminer (Liriomyza huidobrensis ), Onion fly (Delia antiqua), fly fly (Delia platera), sugar beet fly (Pegomya cunicularia), house fly (Musca domestica), black fly (Phomia cue fly) ex pipiens pallens Coquillett), Culex pipiens (Culex pipiens molestus Forskal), Anopheles sinensis (Anopheles (Anopheles) sinensis Wiedemann), but albopictus (Aedes albopictus (Skuse) and the like, but is not limited thereto.

Moreover, as other stored grain pests,
Red-footed Hoshi stink bug (Necrobia rufipes), A Cairo bean weevil (Callospbruchus analis), red neck Hoshi cam Shi (Necrobia ruficollis), bromeliads Keshikisui (Urophorus humeralis), the United States leopard Hong Musi (Mezium americanum), Ittenkokuga (paralipsa gularis), kidney bean weevil (Acanthoscelides obectus, pea weevil, Australian leopard beetle (Ptinus tectus), large-footed beetle (Prostephanus truncates), large-footed beetle (Gnatoccerus corn) tus), multiview saw-tooth grain beetle (Oryzaephirus mercator), Casino Shima moth (Pyralis farinalis), Kashmir red flour beetle (Tribolium freemani), Kado Cobb bombardier grain beetle (Ahasvers advena), Guy My mealworm (Alphitobius diaperinus), Gaimaitsudzuriga (Corcyla cephalonica ), Nippus holoeucus, Granary weevil (Sitophilus granaries), Tribolium maedens, Tribolium destructor, N. grannella), maize weevil (Sitophilus zeamais), receptacle of void beetle (Caulophilus oryzae), red flour (Tenebrioides manuritanicus), Kokumaruhakibaga (Martyringa xeraula), small basket mealworm (Latheticus oryzae), tips Roh red flour beetle (Gnathocerus maxillosus), Konanagashinkui (Rhizopertha dominica), Kobuhimemakimushi (Aridius nodifer), Carpophilus pisellos, Tenebrio obscurus, Aglossa dimidia a), Rabbit beetle (Cryptoles ferruguneus), Ginseng beetle (Stegobium penichum), Ephestia cautella cucumber (Ephestia cautella), Bumblechus rum ), Tsunohime beetle (Holoparamecus signatus), corn beetle (Pagiocerus frontalis), Nesecria poppy squirrel (Carpophilus delkeskampi), Nisemaru leopard moth (Gibbium moth) Oryzaephilus surinamensis), Indian meal Madara My moth (Plodia interpunctella), Hara Giro carpet beetle (Dermestes maculates), Gray bean weevil (Callosobruchus phaseori), Howe Kaku breast grain beetle (Cryptolestes pusilloides), malt (Sitotroga cerealella), Princess red carpet beetle (Trogoderma granaries) , Ptinus clavipes, Tromadera inculus, Bruchus lentis, Callosobruchus susu innotatus), Brazil bean weevil (Zabrotes subfasciatus), vetch bean weevil (Bruchus brachialis), bombardier Chibi red flour (Lophocaterus pusillus), beam Navi Russia Hime Hamakimushi (Dienerella costulata), Mexican grain beetle (Pharaxonota kirschi), peach but-bean weevil (Caryedon serratus) , Japanese weevil (Callosobruchus maculatus), Rurihoshikamemushi (Necrobia violaceae), Rhodesia weevil (Callosobruchus rhodesianus), Watamihigenagasukurusu Culatus) and the like, but not limited thereto.

In addition, as a wood pest,
Two Issima bark beetles (Neohyrrhynchus niisimai), coffee bark beetle (Taphrorychus coffeae), sasanqua core Tomar bark beetle (Poecilips oblongus), Castanopsis saw bark beetle (Xylosandrus compactus), mulberry bark beetle eaves (Xyleborus atratus), lid Gray bark beetle (Xylosandrus bicolor), Akagashino Xylosandrus cincisus, Xylandrus glabratus, Xylosandrus insectus, Xylosandrus mutilatus, Todo pine oak (Xylosandrus validus) and the like, but are not limited thereto.

  Plant seeds refer to those that store nutrients for germination of young plants and are used for agricultural reproduction. For example, seeds such as corn, soybean, cotton, rice, sugar beet, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, green pea, pumpkin, sugar cane, tobacco, peppers, rye, oats and rape, etc. Examples include seed potatoes such as potato, sweet potato, and konjac, edible lily, bulbs such as tulips, and seed balls such as raccoon. In addition, pest damage control by application to plant seeds provided here extends not only to seeds, seed pods, seed balls, etc., but also to harvested crops such as stems, leaves and fruits of grown plants. It is.

  These may be plant seeds, grains, beans, vegetables, flower buds and the like that have undergone transformation, that is, plants that have been created by artificially manipulating genes and the like that do not originally exist in nature. Examples thereof include corn, cotton, potato and the like that have been provided with the ability to produce insecticides, such as soybean, corn, and cotton that have been given herbicide resistance, and rice and tobacco that have been adapted to cold regions.

  Stored cereals, stored beans, stored fruits, and stored vegetables refer to cereals, beans, fruits, vegetables, etc. stored and preserved for domestic distribution and import / export, and are generally used for food and processing. Rice, barley, wheat, corn, rye, oats, peas, green beans, bean, sultani beans, saltapia beans, butter beans, peggia beans, white beans, lima beans, broad beans, soybeans, azuki beans, apricots, ume, outo, Plum, Nectarine, Thigh, Orange, Grapefruit, Natsumikan, Lime, Lemon, Biwa, Quince, Apple, Avocado, Kiwi, Guava, Natsuya, Pineapple, Passionfruit, Banana, Papaya, Mango, Strawberry, Cranberry, Huckleberry, Blackberry, Blueberry, Oyster, Watermelon, Grape, Mushroom, Melon, Turnip, Cauliflower, Cuban, Watercress, Kale, Horseradish, Radish, Broccoli, Sweet Potato, Konjac Rice, Sweet Potato, Potato, Potato Cucumber, cucumber, bracken, artichoke, endive, burdock, salsify, chicory, lettuce, shiitake, mushroom, celery, carrot, parsnip, parsley, tomato, eggplant, bell pepper, asparagus, onion, garlic, green onion, shrimp, shrimp , Okra, sugar cane, ginger, sugar beet, spinach, immature beans, immature peas, oil seeds (sesame seeds, rapeseed, sunflowers, green leaves, cottonseed, etc.), nuts (almonds, ginnan, chestnuts, walnuts) , Pecans, etc.), cacao beans, coffee beans, tea, hops and the like.

  Stored feed refers to feed that is stored and preserved for domestic distribution and import / export, and is mainly used for raising livestock. Examples include cereals and beans.

  Stored florets refer to fresh flowers such as potted plants, cut flowers, bulbs, seeds, etc. that are stored and preserved for domestic distribution and import / export, and are mainly used for ornamental and cultivation purposes. Examples include orchid, rumora, chrysanthemum, xerophim, hisakaki, lily, freesia, nadesico, rose, anthurium, orchid, carnation, and tulip.

  Import / export wood refers to logs or lumber materials that are stored and preserved for the purpose of import / export, and are generally used for processing, construction, and the like. Hemlock, Douglas fir, spruce, spruce, todomatsu, larch, lawan and the like.

  The composition containing etofenprox of the present invention as an active ingredient can be applied as it is, but it is usually used by mixing with a carrier, and if necessary, a surfactant, a wetting agent, a fixing agent, an increase agent. Add formulation adjuvants such as sticking agents, preservatives, colorants, stabilizers, etc., and formulate them in a timely manner by generally known methods such as wettable powders, flowable powders, granular wettable powders, powders and emulsions. Used. The content of etofenprox as an active ingredient in these preparations is usually 0.01 to 99%, preferably 0.1 to 70% by weight.

  The carrier used in the above preparation can be either solid or liquid as long as it is usually used in agricultural chemical preparations, and is not particularly limited.

  For example, as a solid carrier, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, silica gel, ammonium sulfate, etc., soybean powder, sawdust, wheat flour, lactose, sucrose, glucose And vegetable organic substances such as urea and urea.

  Examples of the liquid carrier include aromatic hydrocarbons such as toluene, xylene, cumene and naphthenes, n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil, polybutene and other paraffinic hydrocarbons, acetone, methyl ethyl ketone, etc. Ketones, ethers such as dioxane and diethylene glycol dimethyl ether, alcohols such as ethanol, propanol and ethylene glycol, carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate, aprotic solvents such as dimethylformamide and dimethyl sulfoxide, and water Is mentioned.

  Further, in order to enhance the efficacy of the compound of the present invention, the following adjuvants, binders, disintegrants, pH adjustments may be used alone or in combination depending on the purpose in consideration of the dosage form and processing method of the preparation. Agents, thickeners, antifoaming agents, and antifreeze agents can also be used.

  As surfactants usually used for the purpose of emulsifying, dispersing, spreading and wetting in agricultural chemical formulations, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene fatty acid esters, Polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene castor oil, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, formalin condensate of polyoxyethylene alkyl phenyl ether, Polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer ether, alkylphenyl polyoxyethylene polymer Oxypropylene block polymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, polyoxyalkylene adduct of higher alcohol and polyoxy Nonionic surfactants such as ethylene ether and ester-type silicon and fluorine surfactants, alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene benzyl phenyl ether sulfates, polyoxy Ethylene styryl phenyl ether sulfate, polyoxyethylene polyoxypropylene Block polymer sulfate, paraffin sulfonate, alkane sulfonate, AOS, dialkyl sulfosuccinate, alkyl benzene sulfonate, naphthalene sulfonate, dialkyl naphthalene sulfonate, formalin condensate of naphthalene sulfonate, alkyl diphenyl ether disulfonate, lignin sulfonate, polyoxyethylene alkyl phenyl ether sulfonate , Polyoxyethylene alkyl ether sulfosuccinic acid half ester, fatty acid salt, N-methyl-fatty acid sarcosinate, resin acid salt, polyoxyethylene alkyl ether phosphate, polyoxyethylene phenyl ether phosphate, polyoxyethylene dialkyl phenyl ether phosphate, polyoxyethylene Benzylation Phenyl ether phosphate, polyoxyethylene benzylated phenyl phenyl ether phosphate, polyoxyethylene styrylated phenyl ether phosphate, polyoxyethylene styrylated phenyl phenyl ether phosphate, polyoxyethylene polyoxypropylene block polymer phosphate, phosphatidylcholine, phosphatidylethanolimine, alkyl Anionic surfactants such as phosphate, sodium tripolyphosphate, polyanionic polymer surfactants derived from acrylic acid and acrylonitrile, acrylamidomethylpropane sulfonic acid, alkyltrimethylammonium chloride, methylpolyoxyethylenealkylammonium chloride, alkyl N- Methylpyridinium bromide, Cationic surfactants such as nomethylated ammonium chloride, dialkylmethylated ammonium chloride, alkylpentamethylpropyleneamine dichloride, alkyldimethylbenzalkonium chloride, and benzethonium chloride; amphoteric surfactants such as dialkyldiaminoethylbenthine and alkyldimethylbenzylbentain However, it is not limited to these.

  Examples of the binder include sodium alginate, polyvinyl alcohol, gum arabic, CMC sodium, bentonite and the like.

  Examples of the disintegrant include CMC sodium and croscarmellose sodium, and examples of the stabilizer include hindered phenol-based antioxidants, benzotriazole-based and hindered amine-based ultraviolet absorbers, and the like.

  Use phosphoric acid, acetic acid, sodium hydroxide as a pH adjuster, or add industrial disinfectants such as 1,2-benzisothiazolin-3-one, antibacterial and antifungal agents, etc. You can also.

  As a thickener, xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, montmorillonite and the like can also be used.

  A silicone compound as an antifoaming agent and propylene glycol, ethylene glycol or the like as an antifreezing agent may be used as necessary.

  The composition containing etofenprox used in the present invention as an active ingredient can be added with an efficacy enhancer, if necessary. As the potentiator, sesamin, sesamolin, piperonyl butoxide, sesamex, propyl isome, safroxan, sulfoxide, piperonylcyclone, N- (2-ethyl) hexyl-5,6-norbornene dicarboximide, 2,2 ′, 3,3,3,3 ′, 3 ′, 3′-octachlorodipropyl ether, O-propargyl-O-propyl phenylphosphonate and the like. More seeds may be added.

  When the composition containing etofenprox of the present invention as an active ingredient is applied to plant seeds, the plant seeds may be immersed in the composition as they are. Moreover, after diluting the composition to be used to a suitable carrier to a suitable concentration, it can be used by dipping, dressing, spraying and smearing the plant seeds. The dilution factor is selected from a wide range depending on the application method and the like, but is usually selected from a range of 1 to 10,000 times.

  In addition, when applied to stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored florets, and imported / exported wood, they may be immersed in the composition as they are. Moreover, after diluting the composition to be used to an appropriate carrier to an appropriate concentration, it can be used after dipping, powder coating, spraying, smearing, coating, fumigation / smoke treatment, or pressure injection. The dilution factor is selected from a wide range depending on the application method and the like, but is usually selected from a range of 1 to 10,000 times.

  Suitable carriers are liquid carriers of organic solvents such as water or ethanol, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, silica gel, ammonium sulfate and other inorganic substances, soy flour, Sawdust, wheat flour, lactose, sucrose, plant organic substances such as glucose, and solid carriers such as urea are exemplified, but not limited thereto. The amount used for powder coating, spraying, and smearing treatment is usually about 0.05 to 50% of the dry plant seed weight, but such usage is not limited to these ranges. However, it may vary depending on the form of the preparation and the types of plant seeds, cereals, beans, fruits, vegetables, feed, and wood to be treated.

The following examples and test examples illustrate the invention in detail.
Example 1 (Dust)
5 parts of etofenprox, 94.5 parts of clay, and 0.5 part of Doreles B (Sankyo Co., Ltd.) were uniformly mixed and ground to obtain a powder containing 5% of active ingredient.

Example 2 (wettable powder)
10 parts of etofenprox, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 84 parts of diatomaceous earth were mixed and ground to obtain a wettable powder containing 10% of the active ingredient.

Example 3 (Flowable agent)
Etofenprox 20 parts, propylene glycol 5 parts, polyoxyethylene oleate 5 parts, polyoxyethylene diallyl ether sulfate 5 parts, silicon-based antifoaming agent 0.2 part, and water 64.8 parts with a sand grinder Wet pulverization gave a flowable agent with 20% active ingredient.

Example 4 (Emulsion)
10 parts of etofenprox, 10 parts of cyclohexane, 60 parts of xylene and 20 parts of Solpol (a surfactant manufactured by Toho Chemical) were uniformly dissolved and mixed to obtain an emulsion containing 10% of the active ingredient.

Example 5 (Granule wettable powder)
Granite wetter containing 20% active ingredient after uniformly mixing 20 parts of etofenprox, 3 parts of CMC sodium, 5 parts of alkyl sulfate ester and 72 parts of clay, followed by hydro-kneading, granulation, drying and sizing Got.

Test Example 1 1) Maize: Effect of controlling against crickets Using the wettable powder prepared in Example 2, the seed dressing machine (chemical injection in a rotating drum) was used.
The wettable powder 25 of Example 2, 50 g / 4000 corn seeds, 1 section 1.0 m ² (1.0 × 1.0 m) The section is surrounded by a surf sheet, and is subcultured in-house on the day before sowing. 15 larvae of Cabrayaga 3 to 4 instar were released. 40 seeds were sown per section. The number of buddings 21 days after sowing was investigated, and the budding rate was determined with respect to the number of buddings in the unreleased area, which was used as a control effect. (3 iterations). The results are shown in Table 1.
2) Chemical damage test: 1 section 1.0m ² (1.0 × 1.0m) The section was surrounded by a surf sheet, and 40 seeds were seeded per section. The number of budding 21 days after sowing was investigated, and the budding rate was determined with respect to the number of budding in the untreated group. (Three iterations) Table 2 shows the results.

Test Example 2 Control effect against Azuki beetle
The flowable agent prepared in Example 3 was smeared on 1 kg of azuki seeds for 5, 10, or 20 ml. After air drying, a part was transferred to a 9 cm waist high petri dish and left in a constant temperature room at 25 ° C. After 2 and 3 months of treatment, 10 male and female adult weevil were released per waist-high petri dish (5-line system). Two days after release, the number of dead insects and the number of eggs laid on azuki bean were examined.
The results are shown in Table 3.

Claims (7)

  A composition containing 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl ether (generic name etofenprox) as an active ingredient is converted into plant seeds, stored grains, stored beans, stored fruits, stored vegetables, A method for preventing pest damage characterized by being applied to stored feed, stored flower buds, and imported / exported wood.   Plant seeds, stored grains, stored beans, stored fruits, stored vegetables, stored feed, stored florets, corn, soybeans, cotton, rice, sugar beet, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, green peas, 2. The method according to claim 1, wherein the seeds are pumpkin, sugarcane, tobacco, pepper, rape, rye, oat seed or taro, potato, sweet potato, konjac seed, edible lily, and tulip bulb.   The method according to claim 1 or 2, wherein the application method to the plant seed is spraying, smearing, dipping or dressing.   Storage seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feeds, stored flower buds, and import / export wood are sprayed, smeared, coated, soaked, powdered, treated The method according to claim 1 or 2, which is steaming / smoke treatment or pressure injection.   A method for preventing pest damage to plant seeds or plants grown from plant seeds after application, comprising applying a composition containing etofenprox to plant seeds.   Plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored florets, and imported / exported wood to which the composition containing etofenprox is applied by the method according to claim 1 or 2.   The plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feeds according to claim 6, which are transformed plant seeds, stored cereals, stored beans, stored berries, stored vegetables, stored feed, stored florets Storage flowers.