JP2006224094A - イオン輸送膜システムにおける原料ガス汚染物質の除去 - Google Patents
イオン輸送膜システムにおける原料ガス汚染物質の除去 Download PDFInfo
- Publication number
- JP2006224094A JP2006224094A JP2006000059A JP2006000059A JP2006224094A JP 2006224094 A JP2006224094 A JP 2006224094A JP 2006000059 A JP2006000059 A JP 2006000059A JP 2006000059 A JP2006000059 A JP 2006000059A JP 2006224094 A JP2006224094 A JP 2006224094A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- membrane
- oxygen
- module
- pressure vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 290
- 230000037427 ion transport Effects 0.000 title claims abstract description 55
- 239000000356 contaminant Substances 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title abstract description 63
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 39
- 239000011343 solid material Substances 0.000 claims abstract description 32
- 239000000919 ceramic Substances 0.000 claims abstract description 23
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 14
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 12
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 9
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 claims abstract description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000000746 purification Methods 0.000 claims abstract 3
- 239000007789 gas Substances 0.000 claims description 318
- 229910052760 oxygen Inorganic materials 0.000 claims description 161
- 239000001301 oxygen Substances 0.000 claims description 161
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 149
- 235000012431 wafers Nutrition 0.000 claims description 111
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 85
- 239000000395 magnesium oxide Substances 0.000 claims description 51
- 239000003054 catalyst Substances 0.000 claims description 45
- 150000001875 compounds Chemical class 0.000 claims description 37
- 125000006850 spacer group Chemical group 0.000 claims description 36
- 230000003647 oxidation Effects 0.000 claims description 35
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 26
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 26
- 239000000047 product Substances 0.000 claims description 25
- 229910010293 ceramic material Inorganic materials 0.000 claims description 24
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 23
- -1 molybdenum oxyhydroxide Chemical compound 0.000 claims description 23
- 239000012466 permeate Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- 150000002430 hydrocarbons Chemical class 0.000 claims description 18
- 238000004891 communication Methods 0.000 claims description 17
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 17
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims description 16
- 229910001868 water Inorganic materials 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000011224 oxide ceramic Substances 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 13
- 239000005751 Copper oxide Substances 0.000 claims description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000292 calcium oxide Substances 0.000 claims description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 13
- 229910000431 copper oxide Inorganic materials 0.000 claims description 13
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 13
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 13
- 239000011787 zinc oxide Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 239000003344 environmental pollutant Substances 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 8
- 231100000719 pollutant Toxicity 0.000 claims description 8
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 239000010948 rhodium Substances 0.000 claims description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000009257 reactivity Effects 0.000 claims 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 claims 1
- 238000009413 insulation Methods 0.000 description 35
- 239000011651 chromium Substances 0.000 description 29
- 229910045601 alloy Inorganic materials 0.000 description 25
- 239000000956 alloy Substances 0.000 description 25
- 239000000203 mixture Substances 0.000 description 24
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 22
- 229910052804 chromium Inorganic materials 0.000 description 22
- 239000000376 reactant Substances 0.000 description 22
- 230000008569 process Effects 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 230000001590 oxidative effect Effects 0.000 description 14
- 241000894007 species Species 0.000 description 14
- 239000007800 oxidant agent Substances 0.000 description 13
- 230000036961 partial effect Effects 0.000 description 12
- 238000011084 recovery Methods 0.000 description 12
- 239000012774 insulation material Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000010926 purge Methods 0.000 description 8
- 230000032258 transport Effects 0.000 description 8
- 239000012071 phase Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000006870 function Effects 0.000 description 6
- 239000011810 insulating material Substances 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000264877 Hippospongia communis Species 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 229910001293 incoloy Inorganic materials 0.000 description 4
- 238000002407 reforming Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 239000012808 vapor phase Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- JWCPKKUXENYVPL-UHFFFAOYSA-N [Mg+2].[O-][Cr]([O-])=O Chemical compound [Mg+2].[O-][Cr]([O-])=O JWCPKKUXENYVPL-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010218 electron microscopic analysis Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009421 internal insulation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- DJZHPOJZOWHJPP-UHFFFAOYSA-N magnesium;dioxido(dioxo)tungsten Chemical compound [Mg+2].[O-][W]([O-])(=O)=O DJZHPOJZOWHJPP-UHFFFAOYSA-N 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011533 mixed conductor Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000009789 rate limiting process Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0251—Physical processing only by making use of membranes
- C01B13/0255—Physical processing only by making use of membranes characterised by the type of membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/08—Flat membrane modules
- B01D63/082—Flat membrane modules comprising a stack of flat membranes
- B01D63/084—Flat membrane modules comprising a stack of flat membranes at least one flow duct intersecting the membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/42—Catalysts within the flow path
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2319/00—Membrane assemblies within one housing
- B01D2319/04—Elements in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0216—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0222—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/1614—Controlling the temperature
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0046—Nitrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0051—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0062—Water
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Gas Separation By Absorption (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Abstract
【解決手段】(a)揮発性金属オキシ水酸化物、揮発性金属酸化物、及び揮発性水酸化ケイ素よりなる群から選ばれる1種以上の汚染物質を含有する原料ガス流を得ること、(b)この原料ガス流をガード床の反応性固体物質と接触させ、そして汚染物質の少なくとも一部を反応性固体物質と反応させてガード床において固体反応生成物を生成させること、そして、(c)ガード床から精製されたガス流を抜き出す。
【選択図】なし
Description
(a)高温の酸素含有原料ガスを、混合金属酸化物セラミック材料を含む膜の第一の表面と接触させ、この膜を通し酸素を膜の第二の表面へ透過させて、透過した酸素を得ること、
(b)高温の炭化水素含有原料ガスをこの透過した酸素と反応させて酸化生成物を生成させること、そして、
(d)次の(1)と(2)、すなわち、
(1)高温の酸素含有ガス流をガード床の反応性固体物質と接触させてそこから高温の酸素含有原料ガスを抜き出すことにより、高温の酸素含有原料ガスを得ること、及び、
(2)高温の炭化水素ガス流をガード床の反応性固体物質と接触させてそこから高温の炭化水素含有原料ガスを抜き出すことにより、高温の炭化水素含有原料ガスを得ること、
のいずれか又は両方を行うこと、
を含む酸化方法に関する。
(a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されそして直列に配列されている複数の平面状イオン輸送膜モジュールであって、各膜モジュールが、混合金属酸化物セラミック材料を含み、且つ内部領域と外部領域を持ち、該圧力容器の入口及び出口が膜モジュールの領域と連通している、複数の平面状イオン輸送膜モジュール、
(c)膜モジュールの内部領域及び圧力容器の外部と連通している、1又はそれ以上のガスマニホールド、並びに、
(d)次の(1)と(2)、すなわち、
(1)圧力容器の入口と連通しているガード床、及び、
(2)1又はそれ以上のガスマニホールドのうちの少なくとも1つと連通しているガード床、
のいずれか又は両者、
を含むイオン輸送膜システムに関する。
(a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されそして直列に配列されている複数の平面状イオン輸送膜モジュールであって、各膜モジュールが、混合金属酸化物セラミック材料を含み、且つ内部領域と外部領域を持ち、該圧力容器の入口及び出口が膜モジュールの外部領域と連通している、複数の平面状イオン輸送膜モジュール、
(c)膜モジュールの内部領域及び圧力容器の外部と連通している、1又はそれ以上のガスマニホールド、並びに、
(d)1又はそれ以上のガード床であって、各ガード床が圧力容器内部にある任意の二つの隣接する平面状イオン輸送膜モジュールの間に配置されている、1又はそれ以上のガード床、
を含むイオン輸送膜システムに関する。
(a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置された膜の積重体又はモジュールアセンブリであって、該アセンブリは、混合金属酸化物セラミック材料を含む複数の平面状ウェハーと複数の中空セラミックスペーサーを有し、各ウェハーには内部領域と外部領域があり、該積重体又はモジュールアセンブリは、ウェハー内部どうしが中空スペーサーを介して連通するようにウェハーとスペーサーを交互にすることにより形成され、ウェハーは互いに平行な向きにされており、そして、ウェハーが積重体(スタック)又はモジュールの軸線と垂直になるように積重体又はモジュールを形成させるため、交互になったスペーサーとウェハーが同軸方向に整列している、膜の積重体又はモジュールアセンブリ、
(c)圧力容器内部の膜の積重体又はモジュールアセンブリの周りに配置されたガスマニホールドシュラウドアセンブリであって、該シュラウドアセンブリは、積重体又はモジュールを少なくとも第一ウェハー区域と第二ウェハー区域に分離し、圧力容器の入口を第一ウェハー区域にあるウェハーの外部領域と連通させ、そして、第一ウェハー区域にあるウェハーの外部領域を第二ウェハー区域のウェハーの外部領域と直列に連通させている、ガスマニホールドシュラウドアセンブリ、並びに、
(d)圧力容器の入口及びガスマニホールドシュラウドアセンブリのいずれか又は両者に配置された1又はそれ以上のガード床、
を含むイオン輸送膜システムに関する。
(a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されている複数のイオン輸送膜モジュールであって、このモジュールの少なくとも一部は直列に配列されている、複数のイオン輸送膜モジュール、
(c)任意の二つの隣接する膜モジュールの間に配置されている触媒、並びに、
(d)1又はそれ以上のガード床であって、各ガード床は圧力容器内の任意の二つの隣接するイオン輸送膜モジュールの間に配置されている、1又はそれ以上のガード床、
を含むイオン輸送膜反応器システムに関する。
MgOが900℃の流動空気からクロム含有蒸気種をうまく除去できることを確認するため、実験室スケールの試験を実施した。直径1.0インチの垂直管状反応器に、MgOの棒体を、高温の酸化条件下で表面にクロム含有蒸気種を生成する合金である、インコロイ(Incoloy、登録商標)800Hの削りくずの床の上方に配置して詰めた。インコロイ(登録商標)800Hの削りくずの床とMgOの棒体はそれぞれ、長さが2.5インチ及び4.0インチであった。MgOの棒体は99.8wt%MgOを含有しており、Ozark Technical Ceramicsから入手した。この棒体は平均直径0.2cm、平均長0.4cm、そして開放気孔率30%であった。直径0.75インチの平らな円板の形をしたイオン輸送膜の底面を7個の先端を持つクラウンで支え、管状反応器の最上部の出口に配置し、空気が膜の底部と当該支持構造材の間を放射状に外側へ流れるようにさせた。平らな円板膜の組成は、La1-xCaxFeO3-z(式中、0.95>x>0.5であり、zはこの化合物の電荷を中性にする数である)であった。
例1の試験との比較のため、合金削りくずとイオン輸送膜との間にMgOガード床がないこと以外は例1と同じ実験室スケール反応器の構成でベースラインの実験を行った。新しい合金削りくずと新しい膜を反応器に装着した。3.0slpmの空気流量及び絶対圧1atmの圧力で、反応器を2℃/分で900℃まで加熱した。削りくずの入った反応器と膜をこの空気流量及び900℃で100時間運転し、次いで2℃/分で室温まで冷却した。膜を取り外して分析し、そしてこの分析から、膜表面のかなりのクロム汚染が示された。これと比較して、クロム源と膜の間のガード床を使用して900℃で750時間及び1500時間暴露後の例1の被験膜ではクロム汚染は観察されなかった。これらの結果から、MgOが高温のガス流から揮発性クロム含有種を効果的に除去できることが確認される。
各々が直径1.6インチ、長さ8インチの2つのMgOガード床を、膜の上流の空気供給部に直列に取り付けた。この膜は、米国特許出願公開第20040186018号明細書に記載の両面型平板膜であり、幅3.5インチ、長さ5インチであった。膜の組成はLa1-xCaxFeO3-d(式中、0.95>x>0.5であり、dは化合物の電荷を中性にする数である)であった。空気を分岐させ、内部流路を通して膜内部に流した。例1及び2で使用したものと同一の新しいMgOの棒体をガード床に装入した。0.25インチの直径を有する8フィートの加熱されるインコロイ(登録商標)800Hのチューブをガード床の上流に取り付け、空気を予熱した。チューブ、ガード床、及び膜を直列に運転し、空気流量32スタンダード立法フィート/時(scfh)、15psigで、900℃まで0.5℃/分で加熱した。チューブ、ガード床、及び膜を、ほぼ1400時間800℃と900℃の間の温度に保持した。次に反応器を室温に冷却し、膜の空気側表面を走査型電子顕微鏡を用いて調べた。膜表面にクロムの被着は見られなかった。
ガード床を使用しなかったこと以外は、例3の実験装置を例4用に利用した。チューブと膜を例3におけるように、800℃と900℃の間の温度でほぼ1400時間運転した。次に反応器を室温に冷却し、空気側の膜表面を走査型電子顕微鏡を用いて調べた。膜表面にかなりの量のクロムの被着が見いだされた。
Claims (29)
- (a)揮発性金属オキシ水酸化物、揮発性金属酸化物、及び揮発性水酸化ケイ素よりなる群から選ばれる1種以上の汚染物質を含有する原料ガス流を得ること、
(b)この原料ガス流をガード床の反応性固体物質に接触させ、そして汚染物質の少なくとも一部を反応性固体物質と反応させてガード床において固体反応生成物を生成させること、そして、
(c)精製されたガス流をガード床から抜き出すこと、
を含むガス精製方法。 - 反応性固体物質が、酸化マグネシウム、酸化カルシウム、酸化銅、炭酸カルシウム、炭酸ナトリウム、炭酸ストロンチウム、酸化亜鉛、酸化ストロンチウム、及びアルカリ土類含有ペロブスカイトよりなる群から選ばれる1種以上の化合物を含む、請求項1に記載の方法。
- 反応性固体物質が酸化マグネシウムを含む、請求項2に記載の方法。
- 1種以上の汚染物質が、CrO2(OH)2、Si(OH)4、WO2(OH)2、CrO3、及びモリブデンのオキシ水酸化物のいずれかを含む、請求項1に記載の方法。
- 原料ガス流が、窒素、酸素、水、及び二酸化炭素よりなる群から選ばれる1種以上の成分を含む、請求項1に記載の方法。
- 原料ガス流が、水素、一酸化炭素、二酸化炭素、メタン、及び水よりなる群から選ばれる1種以上の成分を含む、請求項1に記載の方法。
- 原料ガス流を600℃〜1100℃の範囲の温度で反応性固体物質と接触させる、請求項1に記載の方法。
- (a)酸素を含有するガスを加熱して高温の酸素含有ガスにすること、
(b)この高温の酸素含有ガスをガード床の反応性固体物質と接触させ、そこから精製された高温の酸素含有ガスを抜き出すこと、そして、
(c)この精製された高温の酸素含有ガスを、混合金属酸化物セラミック材料を含む膜の第一の表面と接触させ、この膜を通して酸素を膜の第二の表面へ透過させ、そしてそこから高純度酸素製品を抜き出すこと、
を含む酸素の製造方法。 - 高温の酸素含有ガスをガス燃料を空気とともに直接燃焼させることにより入手し、そしてこの高温の酸素含有ガスが酸素、窒素、二酸化炭素、及び水を含む、請求項8に記載の方法。
- 高温の酸素含有ガスが、CrO2(OH)2、Si(OH)4、WO2(OH)2、CrO3、及びモリブデンのオキシ水酸化物よりなる群から選ばれる1種以上の汚染化合物を更に含む、請求項9に記載の方法。
- 反応性固体物質が、酸化マグネシウム、酸化カルシウム、酸化銅、炭酸カルシウム、炭酸ナトリウム、炭酸ストロンチウム、酸化亜鉛、酸化ストロンチウム、及びアルカリ土類含有ペロブスカイトよりなる群から選ばれる1種以上の化合物を含む、請求項8に記載の方法。
- 反応性固体物質が酸化マグネシウムを含む、請求項11に記載の方法。
- (a)高温の酸素含有原料ガスを混合金属酸化物セラミック材料を含む膜の第一の表面と接触させ、そしてこの膜を通して酸素を膜の第二の表面へ透過させて、透過した酸素を得ること、
(b)高温の炭化水素含有原料ガスをこの透過した酸素と反応させて酸化生成物を生成させること、そして、
(d)次の(1)と(2)、すなわち、
(1)高温の酸素含有ガス流をガード床の反応性固体物質と接触させてそこから高温の酸素含有原料ガスを抜き出すことにより、高温の酸素含有原料ガスを得ること、及び、
(2)高温の炭化水素ガス流をガード床の反応性固体物質と接触させてそこから高温の炭化水素含有原料ガスを抜き出すことにより、高温の炭化水素含有原料ガスを得ること、
のいずれか又は両方を行うこと、
を含む酸化方法。 - (1)及び(2)のいずれか又は両者におけるガード床の反応性固体物質が、酸化マグネシウム、酸化カルシウム、酸化銅、炭酸カルシウム、炭酸ナトリウム、炭酸ストロンチウム、酸化亜鉛、酸化ストロンチウム、及びアルカリ土類含有ペロブスカイトよりなる群から選ばれる1種以上の化合物を含む、請求項13に記載の方法。
- 高温の酸素含有ガス流及び高温の炭化水素ガス流のいずれか又は両者が、CrO2(OH)2、Si(OH)4、WO2(OH)2、CrO3、及びモリブデンのオキシ水酸化物よりなる群から選ばれる1種以上の揮発性汚染化合物を含む、請求項13に記載の方法。
- 高温の酸素含有ガス流を、ガス燃料を空気とともに直接燃焼させることにより入手し、そしてこの高温の酸素含有ガス流が、酸素、窒素、二酸化炭素、及び水を含む、請求項13に記載の方法。
- 酸化生成物が、水素、一酸化炭素、及び水を含む合成ガスである、請求項13に記載の方法。
- (a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されそして直列に配列されている複数の平面状イオン輸送膜モジュールであって、各膜モジュールが、混合金属酸化物セラミック材料を含み、且つ内部領域と外部領域を持ち、該圧力容器の入口及び出口が膜モジュールの外部領域と連通している、複数の平面状イオン輸送膜モジュール、
(c)膜モジュールの内部領域及び圧力容器の外部と連通している、1以上のガスマニホールド、並びに、
(d)次の(1)と(2)、すなわち、
(1)圧力容器の入口と連通しているガード床、及び、
(2)1以上のガスマニホールドのうち少なくとも1つと連通しているガード床、
のいずれか又は両者、
を含むイオン輸送膜システム。 - (1)及び(2)のいずれか又は両者におけるガード床が、酸化マグネシウム、酸化カルシウム、酸化銅、炭酸カルシウム、炭酸ナトリウム、炭酸ストロンチウム、酸化亜鉛、酸化ストロンチウム、及びアルカリ土類含有ペロブスカイトよりなる群から選ばれる1種以上の化合物を含む反応性固体物質を含有する、請求項18に記載のシステム。
- (1)におけるガード床が圧力容器の外部に配置されている、請求項18に記載のシステム。
- (1)におけるガード床が圧力容器の内部に配置されている、請求項18に記載のシステム。
- (2)におけるガード床が圧力容器の外部に配置されている、請求項18に記載のシステム。
- (2)におけるガード床が圧力容器の内部に配置されている、請求項18に記載のシステム。
- (a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されそして直列に配列されている複数の平面状イオン輸送膜モジュールであって、各膜モジュールが、混合金属酸化物セラミック材料を含み、且つ内部領域と外部領域を持ち、該圧力容器の入口及び出口が膜モジュールの外部領域と連通している、複数の平面状イオン輸送膜モジュール、
(c)膜モジュールの内部領域及び圧力容器の外部と連通している、1以上のガスマニホールド、及び、
(d)1以上のガード床であって、各ガード床が圧力容器内部にある任意の2つの隣接する平面状イオン輸送膜モジュールの間に配置されている、1以上のガード床、
を含むイオン輸送膜システム。 - 圧力容器の内部に配置されている流動封じ込めダクトを更に含み、この流動封じ込めダクトが、(1)複数の平面状イオン輸送膜モジュール及び1以上のガード床を取り囲んでおり、且つ、(2)圧力容器の入口及び出口と連通している、請求項24に記載のシステム。
- (a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置された膜の積重体又はモジュールアセンブリであって、該アセンブリは、混合金属酸化物セラミック材料を含む複数の平面状ウェハーと複数の中空セラミックスペーサーを有し、各ウェハーには内部領域と外部領域があり、該積重体又はモジュールアセンブリは、ウェハー内部が中空スペーサーを介して連通するように、ウェハーとスペーサーを交互にすることにより形成され、ウェハーは互いに平行な向きにされており、そして、ウェハーが積重体又はモジュールの軸線と垂直になるように積重体又はモジュールを形成させるため、交互になったスペーサーとウェハーが同軸方向に整列している、膜の積重体又はモジュールアセンブリ、
(c)圧力容器内部の膜の積重体又はモジュールアセンブリの周りに配置されたガスマニホールドシュラウドアセンブリであって、このシュラウドアセンブリは、積重体又はモジュールを少なくとも第一ウェハー区域と第二ウェハー区域に分離し、圧力容器の入口を第一ウェハー区域にあるウェハーの外部領域と連通するように位置させ、そして、第一ウェハー区域にあるウェハーの外部領域を第二ウェハー区域のウェハーの外部領域と直列に連通させている、ガスマニホールドシュラウドアセンブリ、並びに、
(d)圧力容器の入口及びガスマニホールドシュラウドアセンブリのいずれか又は両者に配置された1以上のガード床、
を含むイオン輸送膜システム。 - (a)内部、外部、入口、及び出口を有する圧力容器、
(b)圧力容器の内部に配置されている複数のイオン輸送膜モジュールであって、このモジュールの少なくとも一部は直列に配列されている、複数のイオン輸送膜モジュール、
(c)任意の二つの隣接する膜モジュールの間に配置されている触媒、並びに、
(d)1以上のガード床であって、各ガード床は圧力容器内部の任意の二つの隣接するイオン輸送膜モジュールの間に配置されている、1以上のガード床、
を含むイオン輸送膜反応器システム。 - 触媒が、ニッケル、コバルト、白金、金、パラジウム、ロジウム、ルテニウム、及び鉄よりなる群から選ばれる1種以上の金属又はこれを含有する化合物を含む、請求項27に記載の反応器システム。
- 各ガード床が、酸化マグネシウム、酸化カルシウム、酸化銅、炭酸カルシウム、炭酸ナトリウム、炭酸ストロンチウム、酸化亜鉛、酸化ストロンチウム、及びアルカリ土類含有ペロブスカイトよりなる群から選ばれる1種以上の化合物を含む反応性固体物質を含む、請求項27に記載の反応器システム。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/028,124 | 2005-01-03 | ||
US11/028,124 US7425231B2 (en) | 2003-08-06 | 2005-01-03 | Feed gas contaminant removal in ion transport membrane systems |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010171460A Division JP5529667B2 (ja) | 2005-01-03 | 2010-07-30 | イオン輸送膜システムにおける原料ガス汚染物質の除去 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006224094A true JP2006224094A (ja) | 2006-08-31 |
JP2006224094A5 JP2006224094A5 (ja) | 2006-11-30 |
JP5161424B2 JP5161424B2 (ja) | 2013-03-13 |
Family
ID=36117655
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006000059A Expired - Fee Related JP5161424B2 (ja) | 2005-01-03 | 2006-01-04 | イオン輸送膜システムにおける原料ガス汚染物質の除去 |
JP2010171460A Expired - Fee Related JP5529667B2 (ja) | 2005-01-03 | 2010-07-30 | イオン輸送膜システムにおける原料ガス汚染物質の除去 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010171460A Expired - Fee Related JP5529667B2 (ja) | 2005-01-03 | 2010-07-30 | イオン輸送膜システムにおける原料ガス汚染物質の除去 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7425231B2 (ja) |
EP (2) | EP1676624B1 (ja) |
JP (2) | JP5161424B2 (ja) |
KR (1) | KR100793674B1 (ja) |
CN (2) | CN100548443C (ja) |
AU (1) | AU2006200004B2 (ja) |
CA (2) | CA2531706C (ja) |
EA (1) | EA010413B1 (ja) |
ES (1) | ES2538212T3 (ja) |
NO (1) | NO20060026L (ja) |
ZA (1) | ZA200600043B (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009045617A (ja) * | 2007-08-14 | 2009-03-05 | Air Products & Chemicals Inc | イオン輸送膜システムのためのライナー |
JP2011105557A (ja) * | 2009-11-19 | 2011-06-02 | Mitsubishi Heavy Ind Ltd | 水素製造装置 |
JP2011129491A (ja) * | 2009-12-21 | 2011-06-30 | Mitsubishi Heavy Ind Ltd | 固体酸化物燃料電池及びその運転方法 |
US8114193B2 (en) | 2003-08-06 | 2012-02-14 | Air Products And Chemicals, Inc. | Ion transport membrane module and vessel system |
KR101165186B1 (ko) | 2011-09-19 | 2012-07-11 | 박정봉 | 가스화 시스템에서 파울링 물질을 포집하여 제거하는 방법 및 장치 |
JP2018526797A (ja) * | 2015-09-09 | 2018-09-13 | エルジー フューエル セル システムズ インクLg Fuel Cell Systems Inc. | 燃料電池システム及び方法 |
JP2020119907A (ja) * | 2016-05-30 | 2020-08-06 | 東京瓦斯株式会社 | 燃料電池システム |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7954490B2 (en) | 2005-02-09 | 2011-06-07 | Vbox, Incorporated | Method of providing ambulatory oxygen |
US7922795B2 (en) * | 2005-04-29 | 2011-04-12 | University Of Rochester | Ultrathin nanoscale membranes, methods of making, and uses thereof |
EP1874443A4 (en) | 2005-04-29 | 2009-09-16 | Univ Rochester | ULTRA-THAN POROUS NANOSCAL MEMBRANES, MANUFACTURING METHOD AND USES THEREOF |
US7556675B2 (en) * | 2005-10-11 | 2009-07-07 | Air Products And Chemicals, Inc. | Feed gas contaminant control in ion transport membrane systems |
EP1999247A4 (en) * | 2006-03-14 | 2011-08-31 | Univ Rochester | CELL CULTURE DEVICES HAVING ULTRA-POROUS MEMBRANE AND USES THEREOF |
US8262755B2 (en) * | 2007-06-05 | 2012-09-11 | Air Products And Chemicals, Inc. | Staged membrane oxidation reactor system |
CN101571508B (zh) * | 2009-06-16 | 2012-10-10 | 清华大学 | 多层平板结构高场非对称波形离子迁移谱仪 |
MY163056A (en) * | 2009-10-26 | 2017-08-15 | Meidensha Electric Mfg Co Ltd | Membrane module,membrane unit,and membrane separation device |
US8148583B2 (en) | 2010-05-06 | 2012-04-03 | Air Products And Chemicals, Inc. | Feed gas contaminant removal in ion transport membrane systems |
US8455382B2 (en) * | 2010-05-25 | 2013-06-04 | Air Products And Chemicals, Inc. | Fabrication of catalyzed ion transport membrane systems |
RU2477649C1 (ru) * | 2011-07-26 | 2013-03-20 | Учреждение Российской академии наук Институт химии нефти Сибирского отделения РАН (ИХН СО РАН) | Способ очистки углеводородного газа от сероводорода |
TWI452992B (zh) * | 2011-10-17 | 2014-09-21 | Taichung Veterans General Hospital Vacrs | Interlocking plate system |
DE102012219141A1 (de) * | 2012-10-19 | 2014-04-24 | Robert Bosch Gmbh | Chromresistentes Brennstoffzellensystem und Verfahren zum Betrieb desselben |
US8945276B2 (en) * | 2013-06-07 | 2015-02-03 | Membrane Technology And Research, Inc. | Parallel feed gas separation membrane element assembly |
US9028720B1 (en) | 2014-03-05 | 2015-05-12 | Air Products And Chemicals, Inc. | Ion transport membrane reactor systems and methods for producing synthesis gas |
US9559366B2 (en) * | 2014-03-20 | 2017-01-31 | Versa Power Systems Ltd. | Systems and methods for preventing chromium contamination of solid oxide fuel cells |
US10084192B2 (en) | 2014-03-20 | 2018-09-25 | Versa Power Systems, Ltd | Cathode contact layer design for preventing chromium contamination of solid oxide fuel cells |
CN104474888B (zh) * | 2014-12-03 | 2016-04-20 | 华中科技大学 | 一种燃煤烟气中单质汞的处理方法 |
CN106268225A (zh) * | 2016-08-04 | 2017-01-04 | 李祖良 | 一种微波净化器 |
US20210129515A1 (en) * | 2017-05-31 | 2021-05-06 | Sharp Kabushiki Kaisha | Residual layer removal method, residual layer removal device, and display module |
RU2696906C2 (ru) * | 2017-08-22 | 2019-08-07 | Общество с ограниченной ответственностью "ВИРОТЕХ" | Термокаталитическая установка переработки и утилизации нерадиоактивных отходов |
NL2021248B1 (en) * | 2018-07-04 | 2020-01-15 | Redstack Bv | Flow distributor for a stack assembly |
WO2020123811A2 (en) | 2018-12-14 | 2020-06-18 | Exxonmobil Chemical Patents Inc. | Filtration of chromium from flue gas in furnace stacks |
ES2770149B2 (es) * | 2018-12-31 | 2023-02-23 | Kerionics S L | Procedimiento e instalación para la separación selectiva de gases en un proceso de oxicombustión mediante membranas permeables de oxígeno |
CN111569643A (zh) * | 2020-04-29 | 2020-08-25 | 江苏卓高环保科技有限公司 | 一种净化pm2.5甲醛的复合净化材料及其制备的空气净化器 |
CN113713606B (zh) * | 2021-07-22 | 2024-04-02 | 中国船舶重工集团公司第七一八研究所 | 一种用于化学氧气发生器的净化材料及净化床层 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993014862A1 (en) * | 1992-01-25 | 1993-08-05 | British Steel Plc | Treatment of gases discharged from metallurgical furnaces |
JPH0747252A (ja) * | 1993-05-22 | 1995-02-21 | Boc Group Plc:The | 炭化水素源の燃焼排ガスからの二酸化炭素および窒素の混合物を製造するための方法および装置 |
JPH09235101A (ja) * | 1995-10-26 | 1997-09-09 | L'air Liquide | 水素及びエネルギーの生成方法及び装置 |
JP2000334304A (ja) * | 1999-05-31 | 2000-12-05 | Tokyo Gas Co Ltd | ガス中coの選択的酸化触媒及びガス中coの選択的酸化方法 |
JP2001523546A (ja) * | 1997-11-18 | 2001-11-27 | プラクスエア・テクノロジー・インコーポレイテッド | 酸素選択性イオン輸送膜を組込む熱的に駆動される酸素/窒素プラント |
JP2002097007A (ja) * | 2000-09-22 | 2002-04-02 | Nippon Sanso Corp | 希ガスの回収方法及び装置 |
WO2006014655A1 (en) * | 2004-07-20 | 2006-02-09 | Entegris, Inc. | Removal of metal contaminants from ultra-high purity gases |
Family Cites Families (70)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US39601A (en) * | 1863-08-18 | Improved ship of war | ||
US3278266A (en) * | 1963-05-13 | 1966-10-11 | Petro Tex Chem Corp | Vapor phase separation of hydrogen halides from hydrocarbons |
US3935295A (en) * | 1973-01-23 | 1976-01-27 | Catalysts And Chemicals, Inc. | Process for removing chlorine-containing compounds from hydrocarbon streams |
DE2931169A1 (de) * | 1979-08-01 | 1981-02-19 | Alberta Chem Fab Gmbh | Verfahren zur beseitigung von sauren komponenten aus abgasen |
US4513093A (en) * | 1981-03-30 | 1985-04-23 | Ashland Oil, Inc. | Immobilization of vanadia deposited on sorbent materials during treatment of carbo-metallic oils |
US4542010A (en) * | 1982-06-30 | 1985-09-17 | Bend Research, Inc. | Method and apparatus for producing oxygen and nitrogen and membrane therefor |
DE3235558A1 (de) * | 1982-09-25 | 1984-03-29 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur abtrennung von schadstoffen aus abgasen |
US4595844A (en) * | 1984-01-16 | 1986-06-17 | Itt Corporation | CMOS high current output driver |
US4721824A (en) * | 1984-09-24 | 1988-01-26 | Mobil Oil Corporation | Guard bed catalyst for organic chloride removal from hydrocarbon feed |
US4629611A (en) * | 1985-04-29 | 1986-12-16 | International Business Machines Corporation | Gas purifier for rare-gas fluoride lasers |
US5714091A (en) * | 1987-03-13 | 1998-02-03 | The Standard Oil Company | Process for the partial oxydation of hydrocarbons |
US6488739B1 (en) * | 1987-03-13 | 2002-12-03 | Bp Corporation North America Inc. | Oxygen production process |
US5591315A (en) * | 1987-03-13 | 1997-01-07 | The Standard Oil Company | Solid-component membranes electrochemical reactor components electrochemical reactors use of membranes reactor components and reactor for oxidation reactions |
US5306411A (en) * | 1989-05-25 | 1994-04-26 | The Standard Oil Company | Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions |
US4980049A (en) * | 1988-06-10 | 1990-12-25 | Mobil Oil Corporation | Catalytic cracking of heavy oils |
NO304808B1 (no) | 1989-05-25 | 1999-02-15 | Standard Oil Co Ohio | Fast multikomponent membran, fremgangsmaate for fresmtilling av en slik membran samt anvendelse av denne |
EP0438902B2 (en) | 1989-12-27 | 2003-06-18 | The Standard Oil Company | Electrochemical reactors and multicomponent membranes useful for oxidation reactions |
US5174866A (en) * | 1990-05-24 | 1992-12-29 | Air Products And Chemicals, Inc. | Oxygen recovery from turbine exhaust using solid electrolyte membrane |
US5599510A (en) * | 1991-12-31 | 1997-02-04 | Amoco Corporation | Catalytic wall reactors and use of catalytic wall reactors for methane coupling and hydrocarbon cracking reactions |
US5750279A (en) * | 1992-02-28 | 1998-05-12 | Air Products And Chemicals, Inc. | Series planar design for solid electrolyte oxygen pump |
US5240473A (en) * | 1992-09-01 | 1993-08-31 | Air Products And Chemicals, Inc. | Process for restoring permeance of an oxygen-permeable ion transport membrane utilized to recover oxygen from an oxygen-containing gaseous mixture |
US5356728A (en) * | 1993-04-16 | 1994-10-18 | Amoco Corporation | Cross-flow electrochemical reactor cells, cross-flow reactors, and use of cross-flow reactors for oxidation reactions |
US5364506A (en) * | 1993-04-28 | 1994-11-15 | The Board Of Trustees Of The Leland Stanford Junior University | Method and apparatus for partial oxidation of methane and cogeneration of electrical energy |
US20020022568A1 (en) * | 1993-12-08 | 2002-02-21 | Richard Mackay | Ceramic membranes for use in catalytic membrane reactors with high ionic conductivities and improved mechanical properties |
US6355093B1 (en) | 1993-12-08 | 2002-03-12 | Eltron Research, Inc | Two component-three dimensional catalysis |
GB9412028D0 (en) * | 1994-06-16 | 1994-08-03 | Bp Chem Int Ltd | Waste processing |
CN1071592C (zh) * | 1994-11-14 | 2001-09-26 | 普拉塞尔技术有限公司 | 氧选择性吸咐剂 |
US5681373A (en) * | 1995-03-13 | 1997-10-28 | Air Products And Chemicals, Inc. | Planar solid-state membrane module |
CA2172301C (en) * | 1995-05-18 | 2001-08-07 | Ravi Prasad | Pressure driven solid electrolyte membrane gas separation method |
EP0747108B1 (en) * | 1995-06-07 | 2002-02-20 | Air Products And Chemicals, Inc. | Oxygen production by ion transport membranes with work recovery |
WO1997000925A1 (en) * | 1995-06-23 | 1997-01-09 | E.I. Du Pont De Nemours And Company | Method for monomer recovery |
US6090265A (en) * | 1996-09-26 | 2000-07-18 | Air Products And Chemicals, Inc. | Separation of oxygen from oxygen-containing gas |
US5868918A (en) * | 1996-09-26 | 1999-02-09 | Air Products And Chemicals, Inc. | Method for separating oxygen from an oxygen-containing gas |
US5980840A (en) * | 1997-04-25 | 1999-11-09 | Bp Amoco Corporation | Autothermic reactor and process using oxygen ion--conducting dense ceramic membrane |
US5820654A (en) | 1997-04-29 | 1998-10-13 | Praxair Technology, Inc. | Integrated solid electrolyte ionic conductor separator-cooler |
US5820655A (en) * | 1997-04-29 | 1998-10-13 | Praxair Technology, Inc. | Solid Electrolyte ionic conductor reactor design |
US6117210A (en) | 1997-04-29 | 2000-09-12 | Praxair Technology, Inc. | Solid electrolyte systems for producing controlled purity oxygen |
US6149714A (en) * | 1997-06-05 | 2000-11-21 | Praxair Technology, Inc. | Process for enriched combustion using solid electrolyte ionic conductor systems |
US5944874A (en) * | 1997-06-23 | 1999-08-31 | Praxair Technology, Inc. | Solid electrolyte ionic conductor systems for the production of high purity nitrogen |
US5851266A (en) * | 1997-06-23 | 1998-12-22 | Praxair Technology,Inc. | Hybrid solid electrolyte ionic conductor systems for purifying inert gases |
US6056807A (en) * | 1998-01-26 | 2000-05-02 | Air Products And Chemicals, Inc. | Fluid separation devices capable of operating under high carbon dioxide partial pressures which utilize creep-resistant solid-state membranes formed from a mixed conducting multicomponent metallic oxide |
US6060177A (en) * | 1998-02-19 | 2000-05-09 | United Technologies Corporation | Method of applying an overcoat to a thermal barrier coating and coated article |
US6139810A (en) * | 1998-06-03 | 2000-10-31 | Praxair Technology, Inc. | Tube and shell reactor with oxygen selective ion transport ceramic reaction tubes |
US6017646A (en) * | 1998-06-03 | 2000-01-25 | Praxair Technology, Inc. | Process integrating a solid oxide fuel cell and an ion transport reactor |
US6309612B1 (en) * | 1998-11-18 | 2001-10-30 | The United States Of America As Represented By The United States Department Of Energy | Ceramic membrane reactor with two reactant gases at different pressures |
US6255010B1 (en) | 1999-07-19 | 2001-07-03 | Siemens Westinghouse Power Corporation | Single module pressurized fuel cell turbine generator system |
RU2165471C1 (ru) * | 1999-11-02 | 2001-04-20 | Кожевников Георгий Николаевич | Способ извлечения рения и осмия из парогазовой смеси |
US6375913B1 (en) * | 2000-04-10 | 2002-04-23 | Pranair Technology | Integration of ceramic membrane into a silicon oxide production plant |
US6293084B1 (en) * | 2000-05-04 | 2001-09-25 | Praxair Technology, Inc. | Oxygen separator designed to be integrated with a gas turbine and method of separating oxygen |
EP1156026A1 (en) * | 2000-05-19 | 2001-11-21 | Shell Internationale Researchmaatschappij B.V. | Process for the production of liquid hydrocarbons |
DE10114173A1 (de) | 2000-06-16 | 2001-12-20 | Linde Ag | Reaktor |
DE10029882A1 (de) | 2000-06-16 | 2001-12-20 | Linde Ag | Separator zur Erzeugung von Sauerstoff |
US6492290B1 (en) * | 2000-08-22 | 2002-12-10 | Air Products And Chemicals, Inc. | Mixed conducting membranes for syngas production |
DE10056789A1 (de) | 2000-11-16 | 2002-05-23 | Linde Ag | Separator zur Erzeugung von Sauerstoff |
DE10056787A1 (de) | 2000-11-16 | 2002-05-23 | Linde Ag | Reaktor |
DE10064894A1 (de) * | 2000-12-23 | 2002-06-27 | Alstom Switzerland Ltd | Luftzerlegungseinrichtung |
KR100444885B1 (ko) | 2001-02-28 | 2004-08-18 | 주식회사 코캣 | 배가스에 함유된 입자상 물질 및 수분의 제거방법 |
US6777370B2 (en) * | 2001-04-13 | 2004-08-17 | Engelhard Corporation | SOx tolerant NOx trap catalysts and methods of making and using the same |
US6695983B2 (en) * | 2001-04-24 | 2004-02-24 | Praxair Technology, Inc. | Syngas production method utilizing an oxygen transport membrane |
US6623880B1 (en) * | 2001-05-29 | 2003-09-23 | The United States Of America As Represented By The Department Of Energy | Fuel cell-fuel cell hybrid system |
US20030039601A1 (en) | 2001-08-10 | 2003-02-27 | Halvorson Thomas Gilbert | Oxygen ion transport membrane apparatus and process for use in syngas production |
JP3914416B2 (ja) | 2001-11-06 | 2007-05-16 | 帝国石油株式会社 | 膜式反応器 |
US6602324B2 (en) * | 2001-11-15 | 2003-08-05 | Air Products And Chemicals, Inc. | Sulfur control in ion-conducting membrane systems |
US6565632B1 (en) * | 2001-12-17 | 2003-05-20 | Praxair Technology, Inc. | Ion-transport membrane assembly incorporating internal support |
RU2223138C1 (ru) * | 2002-08-15 | 2004-02-10 | Закрытое акционерное общество "Газоразделительные системы" | Генератор азота для создания инертной технологической газовой среды |
US6726893B2 (en) * | 2002-09-17 | 2004-04-27 | The University Of Chicago | Hydrogen production by high-temperature water splitting using electron-conducting membranes |
US6805728B2 (en) * | 2002-12-09 | 2004-10-19 | Advanced Technology Materials, Inc. | Method and apparatus for the abatement of toxic gas components from a semiconductor manufacturing process effluent stream |
US6929825B2 (en) * | 2003-02-04 | 2005-08-16 | General Electric Company | Method for aluminide coating of gas turbine engine blade |
US7279027B2 (en) * | 2003-03-21 | 2007-10-09 | Air Products And Chemicals, Inc. | Planar ceramic membrane assembly and oxidation reactor system |
US7179323B2 (en) | 2003-08-06 | 2007-02-20 | Air Products And Chemicals, Inc. | Ion transport membrane module and vessel system |
-
2005
- 2005-01-03 US US11/028,124 patent/US7425231B2/en not_active Expired - Fee Related
- 2005-12-22 EP EP20050028267 patent/EP1676624B1/en not_active Not-in-force
- 2005-12-22 ES ES05028267.2T patent/ES2538212T3/es active Active
- 2005-12-22 EP EP11191255A patent/EP2428265A1/en not_active Withdrawn
- 2005-12-28 EA EA200501894A patent/EA010413B1/ru not_active IP Right Cessation
- 2005-12-28 CA CA2531706A patent/CA2531706C/en not_active Expired - Fee Related
- 2005-12-29 CA CA2531922A patent/CA2531922C/en not_active Expired - Fee Related
- 2005-12-30 CN CNB2005101191789A patent/CN100548443C/zh not_active Expired - Fee Related
-
2006
- 2006-01-02 KR KR1020060000092A patent/KR100793674B1/ko not_active IP Right Cessation
- 2006-01-03 AU AU2006200004A patent/AU2006200004B2/en not_active Ceased
- 2006-01-03 CN CNB2006100040112A patent/CN100450593C/zh not_active Expired - Fee Related
- 2006-01-03 NO NO20060026A patent/NO20060026L/no not_active Application Discontinuation
- 2006-01-03 ZA ZA2006/00043A patent/ZA200600043B/en unknown
- 2006-01-04 JP JP2006000059A patent/JP5161424B2/ja not_active Expired - Fee Related
-
2010
- 2010-07-30 JP JP2010171460A patent/JP5529667B2/ja not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993014862A1 (en) * | 1992-01-25 | 1993-08-05 | British Steel Plc | Treatment of gases discharged from metallurgical furnaces |
JPH0747252A (ja) * | 1993-05-22 | 1995-02-21 | Boc Group Plc:The | 炭化水素源の燃焼排ガスからの二酸化炭素および窒素の混合物を製造するための方法および装置 |
JPH09235101A (ja) * | 1995-10-26 | 1997-09-09 | L'air Liquide | 水素及びエネルギーの生成方法及び装置 |
JP2001523546A (ja) * | 1997-11-18 | 2001-11-27 | プラクスエア・テクノロジー・インコーポレイテッド | 酸素選択性イオン輸送膜を組込む熱的に駆動される酸素/窒素プラント |
JP2000334304A (ja) * | 1999-05-31 | 2000-12-05 | Tokyo Gas Co Ltd | ガス中coの選択的酸化触媒及びガス中coの選択的酸化方法 |
JP2002097007A (ja) * | 2000-09-22 | 2002-04-02 | Nippon Sanso Corp | 希ガスの回収方法及び装置 |
WO2006014655A1 (en) * | 2004-07-20 | 2006-02-09 | Entegris, Inc. | Removal of metal contaminants from ultra-high purity gases |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8114193B2 (en) | 2003-08-06 | 2012-02-14 | Air Products And Chemicals, Inc. | Ion transport membrane module and vessel system |
JP2009045617A (ja) * | 2007-08-14 | 2009-03-05 | Air Products & Chemicals Inc | イオン輸送膜システムのためのライナー |
JP2011105557A (ja) * | 2009-11-19 | 2011-06-02 | Mitsubishi Heavy Ind Ltd | 水素製造装置 |
JP2011129491A (ja) * | 2009-12-21 | 2011-06-30 | Mitsubishi Heavy Ind Ltd | 固体酸化物燃料電池及びその運転方法 |
KR101165186B1 (ko) | 2011-09-19 | 2012-07-11 | 박정봉 | 가스화 시스템에서 파울링 물질을 포집하여 제거하는 방법 및 장치 |
JP2018526797A (ja) * | 2015-09-09 | 2018-09-13 | エルジー フューエル セル システムズ インクLg Fuel Cell Systems Inc. | 燃料電池システム及び方法 |
JP2020119907A (ja) * | 2016-05-30 | 2020-08-06 | 東京瓦斯株式会社 | 燃料電池システム |
Also Published As
Publication number | Publication date |
---|---|
KR20060079757A (ko) | 2006-07-06 |
CA2531706C (en) | 2010-09-14 |
CN100450593C (zh) | 2009-01-14 |
EA200501894A1 (ru) | 2006-08-25 |
CA2531922A1 (en) | 2006-07-03 |
CA2531922C (en) | 2010-09-14 |
EP2428265A1 (en) | 2012-03-14 |
AU2006200004B2 (en) | 2008-04-24 |
KR100793674B1 (ko) | 2008-01-10 |
CN1876220A (zh) | 2006-12-13 |
CA2531706A1 (en) | 2006-07-03 |
EP1676624B1 (en) | 2015-05-20 |
AU2006200004A1 (en) | 2006-07-27 |
EA010413B1 (ru) | 2008-08-29 |
US7425231B2 (en) | 2008-09-16 |
ES2538212T3 (es) | 2015-06-18 |
JP5529667B2 (ja) | 2014-06-25 |
CN100548443C (zh) | 2009-10-14 |
JP2010270002A (ja) | 2010-12-02 |
CN1830523A (zh) | 2006-09-13 |
US20080178736A1 (en) | 2008-07-31 |
EP1676624A3 (en) | 2009-07-29 |
NO20060026L (no) | 2006-07-04 |
EP1676624A2 (en) | 2006-07-05 |
ZA200600043B (en) | 2008-04-30 |
JP5161424B2 (ja) | 2013-03-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5161424B2 (ja) | イオン輸送膜システムにおける原料ガス汚染物質の除去 | |
EP1504811B1 (en) | Pressure vessel containing ion transport membrane modules and processes making use thereof | |
US7771519B2 (en) | Liners for ion transport membrane systems | |
KR100736651B1 (ko) | 유도된 내부 기체 흐름을 갖는 이온 수송 막 모듈 및 용기시스템 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061017 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20061017 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100202 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100430 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100510 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100730 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110705 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111005 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120724 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121024 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20121120 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20121214 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20151221 Year of fee payment: 3 |
|
LAPS | Cancellation because of no payment of annual fees |