JP2006021173A5 - - Google Patents

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JP2006021173A5
JP2006021173A5 JP2004203846A JP2004203846A JP2006021173A5 JP 2006021173 A5 JP2006021173 A5 JP 2006021173A5 JP 2004203846 A JP2004203846 A JP 2004203846A JP 2004203846 A JP2004203846 A JP 2004203846A JP 2006021173 A5 JP2006021173 A5 JP 2006021173A5
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flocculant
slaked lime
settling tank
dehydrator
tank
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焼却炉等の排ガスの洗浄排水には、無機フッ素化合物や重金属類およびSSなどが含まれている。これらの含有成分を除去することが環境保全あるいは人体の健康維持の上で要求されており、排水汚濁防止法によっても含有量が規定されている。従来から、重金属類については、アルカリ性物質を添加して、沈殿させる方法が行われてきたが、重金属の種類によって析出し易いpHが異なるなど一度の処理では充分に除去しきれないのが実情であった。また、被処理水中に含まれるフッ素イオンの除去方法としては、水中に消石灰等を添加して、フッ素イオンをフッ化カルシウムとして沈殿させるカルシウム凝集沈殿法が最も一般的に行われてきたが、充分な濃度まで除去することは難しかった。そこで、薬剤に加え、活性アルミナを添加し、フッ素イオンを除去する方法が考案されている(特許文献1参照)。 Cleaning wastewater for exhaust gas from incinerators contains inorganic fluorine compounds, heavy metals, SS, and the like. Removal of these components is required for environmental conservation or maintenance of human health, and the content is also defined by the Wastewater Pollution Prevention Law. Conventionally, heavy metals have been precipitated by adding an alkaline substance, but the actual situation is that they cannot be removed sufficiently by a single treatment, such as the pH at which they are likely to precipitate differs depending on the type of heavy metal. there were. Further, as a method for removing fluorine ions contained in the water to be treated, a calcium agglomeration precipitation method in which slaked lime or the like is added to water to precipitate fluorine ions as calcium fluoride has been most commonly performed. It was difficult to remove to a sufficient concentration. Therefore, a method has been devised in which activated alumina is added in addition to the drug to remove fluorine ions (see Patent Document 1).

また、請求項2に記載の発明に係る排水処理方法は、例えば図1および図4に示すように、請求項1に記載の排水処理方法において、第1の処理水E1を作る工程St11〜St14および第2の処理水E2を作る工程St21〜St24が、排水D1またはろ液L1に消石灰M1、M2を添加する工程St11、St21と;消石灰M1、M2を添加した後に凝集剤N1、N2、P1、P2、Q1、Q2を添加する工程St12〜St14、St22〜St24とを備える。 Moreover, as shown in FIGS. 1 and 4, for example, the waste water treatment method according to the invention described in claim 2 is a process St11 to St14 for producing the first treated water E1 in the waste water treatment method according to claim 1. And the steps St21 to St24 for producing the second treated water E2 are the steps St11 and St21 for adding the slaked lime M1 and M2 to the drainage D1 or the filtrate L1, and the flocculants N1, N2 and P1 after adding the slaked lime M1 and M2. , P2, Q1, and Q2 are added. St12 to St14, St22 to St24 are provided.

このように構成すると、消石灰と反応して、無機フッ素化合物が不溶性のフッ化カルシウムとなり、重金属類は不溶性の水酸化物となり微粒子として析出する。そこで、凝集剤の添加により析出した微粒子が凝集し、より大きな凝集物である固形物に成長する。 If comprised in this way, it will react with slaked lime , an inorganic fluorine compound will become insoluble calcium fluoride, and a heavy metal will become an insoluble hydroxide, and will precipitate as microparticles | fine-particles. Therefore, the fine particles precipitated by the addition of the flocculant aggregate and grow into a solid material which is a larger aggregate.

また、請求項4に記載の発明に係る排水処理方法は、例えば図1および図4に示すように、請求項3に記載の排水処理方法において、凝集剤がキレート化剤N1、N2と無機凝集剤P1、P2と高分子凝集剤Q1、Q2とを含み;第1の処理水E1を作る工程St11〜St14および第2の処理水E2を作る工程St21〜St24が、消石灰M1、M2を添加する工程St11、St21、その後キレート化剤N1、N2を添加する工程St12、St22、その後無機凝集剤P1、P2を添加する工程St13、St23、その後高分子凝集剤Q1、Q2を添加する工程St14、St24を含む。 Moreover, as shown in FIGS. 1 and 4, for example, the wastewater treatment method according to the invention described in claim 4 is the wastewater treatment method according to claim 3, wherein the flocculants are chelating agents N1 and N2 and inorganic agglomeration. Steps St11 to St14 for creating the first treated water E1 and St21 to St24 for creating the second treated water E2 add slaked lime M1 and M2. Steps St11 and St21, then adding the chelating agents N1 and N2, steps St12 and St22, then adding the inorganic flocculants P1 and P2, steps St13 and St23, and then adding the polymer flocculants Q1 and Q2, St14 and St24 including.

このように構成すると、消石灰と反応して、無機フッ素化合物が不溶性のフッ化カルシウムとなり、重金属類は不溶性の水酸化物となり、キレート化剤を添加すると重金属類の不溶性キレート化合物である固形物が生成する。無機凝集剤を添加すると、無機凝集剤はまず水に均一に溶解し、その後無機水酸化物が析出する。無機水酸化物は、析出するときにはすでに重金属類の水酸化物やフッ化カルシウムや不溶性キレート化合物の析出物が周囲に存在するため、それらを効率よく吸着してより大きな重い凝集物である固形物に成長する。高分子凝集剤により、更に大きな重い凝集物である固形物に成長する。よって、その後の沈降分離およびろ過工程で効率よく固液分離することができる。 With this configuration, the inorganic fluorine compound reacts with slaked lime to become insoluble calcium fluoride , the heavy metal becomes an insoluble hydroxide, and when a chelating agent is added, a solid substance that is an insoluble chelate compound of heavy metal becomes Generate. When the inorganic flocculant is added, the inorganic flocculant is first uniformly dissolved in water, and then the inorganic hydroxide is precipitated. When inorganic hydroxide is precipitated, there are already heavy metal hydroxides , calcium fluoride and insoluble chelate deposits around it. To grow. The polymer flocculant grows into a solid that is a larger heavy agglomerate. Therefore, solid-liquid separation can be efficiently performed in the subsequent sedimentation and filtration steps.

前記目的を達成するため、請求項7に記載の発明に係る排水処理装置は、例えば図1に示すように、所定粒径のSSを含む排水D1に消石灰M1および凝集剤N1、P1、Q1を添加し、第1の混合液E1とする第1の薬注装置61〜64と;第1の混合液E1をろ液L1と固形物とに分離し、該固形物によりろ過膜31にコーティングが形成される脱水機30と;脱水機30で分離されたろ液L1に消石灰M2および凝集剤N2、P2、Q2を添加し、第2の混合液E2とする第2の薬注装置66〜69と;第1の混合液E1を脱水機30に送り、ろ液L1と固形物とに分離し、ろ過膜31に前記固形物によりコーティングを形成し、コーティングが形成された脱水機30を用いて第2の混合液E2をろ過するように運転を制御する制御装置40とを備える。 In order to achieve the object, the wastewater treatment apparatus according to the invention described in claim 7 includes, as shown in FIG. 1, for example, slaked lime M1 and flocculants N1, P1, and Q1 added to wastewater D1 containing SS having a predetermined particle size. The first chemical injection devices 61 to 64 that are added to obtain the first mixed liquid E1; the first mixed liquid E1 is separated into the filtrate L1 and the solid, and the filtration membrane 31 is coated with the solid. A dehydrator 30 to be formed; and second chemical injection devices 66 to 69 in which slaked lime M2 and flocculants N2, P2, and Q2 are added to the filtrate L1 separated by the dehydrator 30 to form a second mixed liquid E2. The first mixed liquid E1 is sent to the dehydrator 30 and separated into the filtrate L1 and solid matter, and the coating is formed on the filter membrane 31 with the solid matter, and the dehydrator 30 on which the coating is formed is used. Control device for controlling the operation so as to filter the mixed liquid E2 And a 40.

このように構成すると、第1の薬注装置により添加された消石灰および凝集剤では析出しなかった無機フッ素化合物および重金属類を、第2の薬注装置により添加された消石灰および凝集剤で析出させ、除去することができるので、無機フッ素化合物および重金属類を低濃度まで除去する排水処理装置となる。更に、第1の薬注装置により消石灰および凝集剤が添加された第1の混合液をろ過し、その際粒径の大きなSSなどを含む固形物がろ過膜にコーティングされ、そのコーティングされたろ過膜を有する脱水機を用いて、第2の薬注装置により消石灰および凝集剤が添加された第2の混合液をろ過するので、第2の混合液に粒径の小さな粒子からなる凝集物である固形物だけが含まれる場合であっても、ろ過膜の目詰まりを生じにくい。 If comprised in this way, the inorganic fluorine compound and heavy metal which did not precipitate with the slaked lime and flocculant added by the 1st chemical injection apparatus are made to precipitate with the slaked lime and the flocculant added by the 2nd chemical injection apparatus. Therefore, the wastewater treatment apparatus removes inorganic fluorine compounds and heavy metals to a low concentration. Further, the first mixed solution to which the slaked lime and the flocculant are added is filtered by the first chemical injection device, and the solid matter containing SS having a large particle size is coated on the filtration membrane, and the coated filtration is performed. Since the second liquid mixture to which slaked lime and the flocculant are added is filtered by the second chemical injection device using a dehydrator having a membrane, the second liquid mixture is an aggregate composed of particles having a small particle diameter. Even when only certain solids are included, the filtration membrane is less likely to be clogged.

更に、前記目的を達成するため、請求項8に記載の発明に係る排水処理装置は、例えば図1および図2に示すように、所定粒径のSSを含む排水D1に消石灰M1および凝集剤N1、P1、Q1を添加し、第1の混合液E1とする第1の薬注装置61〜64と;第1の混合液E1をろ液L1と固形物とに分離し、該固形物によりろ過膜31にコーティングが形成される脱水機30と;脱水機30で分離されたろ液L1に消石灰M2および凝集剤N2、P2、Q2を添加し、第2の混合液とする第2の薬注装置66〜69と;第1の混合液E1を静置する第1の沈降槽11であって、第1の沈降槽11内の液面L近傍から第1の沈降槽11内に鉛直方向に設置され、第1の沈降槽11の内径より小さい内径を有する第1の排水導入筒14と、第1の排水導入筒14内に該筒14に対して接線方向に前記静置する第1の混合液E1を導入する第1の排水導入管51と、第1の沈降槽11の底面19近傍を掻き取るように回転する第1の掻き取り羽根16とを有する第1の沈降槽11、または、第2の混合液E2を静置する第2の沈降槽12であって、第2の沈降槽12内の液面L近傍から第2の沈降槽12内に鉛直方向に設置され、第2の沈降槽12の内径より小さい内径を有する第2の排水導入筒14’と、第2の排水導入筒14’内に該筒14’に対して接線方向に静置する第2の混合液E2を導入する第2の排水導入管54と、第2の排水導入筒14’の底面19’近傍を掻き取るように回転する第2の掻き取り羽根16’とを有する第2の沈降槽12とを備える。 Furthermore, in order to achieve the object, the wastewater treatment device according to the invention of claim 8, for example, as shown in FIGS. 1 and 2, slaked lime M1 and flocculant to the wastewater D1 containing SS of a predetermined grain size N1 , P1 and Q1 are added, and the first chemical injection devices 61 to 64 to be the first mixed liquid E1; the first mixed liquid E1 is separated into the filtrate L1 and the solid, and filtered through the solid A dehydrator 30 in which a coating is formed on the membrane 31; a second chemical injection device in which slaked lime M2 and flocculants N2, P2, and Q2 are added to the filtrate L1 separated by the dehydrator 30 to form a second mixed solution 66 to 69; a first settling tank 11 in which the first mixed liquid E1 is allowed to stand, and is installed in the first settling tank 11 from the vicinity of the liquid level L in the first settling tank 11 in the vertical direction. A first drainage introduction cylinder 14 having an inner diameter smaller than the inner diameter of the first sedimentation tank 11, The first drainage introduction pipe 51 for introducing the first mixed liquid E1 that is allowed to stand tangentially to the cylinder 14 and the vicinity of the bottom surface 19 of the first sedimentation tank 11 are scraped into the drainage introduction cylinder 14 of A first settling tank 11 having a first scraping blade 16 that rotates so as to take, or a second settling tank 12 in which the second mixed liquid E2 is allowed to stand, and the second settling tank 12 A second drainage introduction cylinder 14 ′ that is vertically installed in the second sedimentation tank 12 from the vicinity of the liquid level L inside thereof and has an inner diameter smaller than the inner diameter of the second sedimentation tank 12, and a second drainage introduction cylinder The second drainage introduction pipe 54 for introducing the second mixed liquid E2 that is placed in the tangential direction with respect to the cylinder 14 'and the vicinity of the bottom surface 19' of the second drainage introduction cylinder 14 'are scraped into the cylinder 14'. And a second settling tank 12 having a second scraping blade 16 ′ rotating to take.

このように構成すると、第1または第2の沈降槽内において、消石灰および凝集剤が添加された第1の混合液E1または第2の混合液E2を第1または第2の排水導入筒内で旋回させることにより、排水中の凝集物である固形物の密度分布に勾配をつけ、凝集物である固形物を大きく成長させることができ、その後、静置することにより、前記固形物を沈降させることができる。すなわち、一つの沈降槽で凝集物である固形物の成長と沈降を行うことができる排水処理装置となる。 If comprised in this way, in the 1st or 2nd sedimentation tank, the 1st liquid mixture E1 or the 2nd liquid mixture E2 to which slaked lime and the flocculant were added will be contained in the 1st or 2nd waste_water | drain introduction | transduction pipe | tube. By swirling, the density distribution of the solids that are aggregates in the wastewater can be graded, and the solids that are aggregates can be grown greatly, and then the solids are allowed to settle by allowing to stand. be able to. That is, the waste water treatment apparatus is capable of growing and settling solid matter that is an aggregate in one settling tank.

図1は、本発明の一実施の形態である排水処理装置1のブロック図である。排水処理装置1は、焼却炉等の排ガスの洗浄排水D0(以降、単に「排水D0]ともいう。)を受け入れ、SSなどを沈降させ上澄み液T0を分離する受入沈降槽10と、受入沈降槽10でSSなどを沈降させ濃縮した濃縮排水D1に後述する薬剤を添加した第1の混合液である第1の処理水E1を静置し、凝集物である固形物を沈降させ上澄み液T1を分離する第1の沈降槽11と、第1の沈降槽11で固形物を沈降させ濃縮した第1の濃縮液S1をろ過膜31でろ過する脱水機30と、脱水機30で分離されたろ液L1と上澄み液T1とが合流した合流液Gに後述する薬剤を添加した第2の混合液である第2の処理水E2を静置し、凝集物である固形物を沈降させ上澄み液T2を分離する第2の沈降槽12とを備える。更に、受入沈降槽10でSSなどを沈降させ濃縮した濃縮排水D1を吸い込み、後述の第1消石灰攪拌槽71へ圧送し、さらに第1の沈降槽11へ送る濃縮排水ポンプ20と、第1の沈降槽11で固形物を沈降させ濃縮した第1の濃縮液S1を吸い込み、脱水機30へ圧送する第1の濃縮液ポンプ21と、第2の沈降槽12で固形物を沈降させ濃縮した第2の濃縮液S2を吸い込み、脱水機30へ圧送する第2の濃縮液ポンプ22とを備える。 FIG. 1 is a block diagram of a wastewater treatment apparatus 1 according to an embodiment of the present invention. The wastewater treatment apparatus 1 receives a cleaning wastewater D0 (hereinafter also simply referred to as “drainage D0”) of exhaust gas from an incinerator, etc., and a receiving sedimentation tank 10 that settles SS and separates the supernatant T0, and a receiving sedimentation tank The first treated water E1, which is a first mixed solution to which a later-described chemical is added, is allowed to settle in the concentrated drainage D1 that has been concentrated by sedimenting SS and the like at 10, and the solids that are aggregates are allowed to settle to obtain a supernatant T1. The first sedimentation tank 11 to be separated, the dehydrator 30 that filters the first concentrated liquid S1 that has been precipitated and concentrated in the first sedimentation tank 11 through the filtration membrane 31, and the filtrate separated by the dehydrator 30. The second treated water E2, which is a second mixed liquid obtained by adding a later-described chemical, is allowed to stand in the combined liquid G in which L1 and the supernatant liquid T1 merge, and the solid liquid that is an aggregate is allowed to settle to obtain a supernatant liquid T2. A second settling tank 12 for separation, and a receiving settling tank. The concentrated drainage D1 concentrated by precipitating SS and the like at 10 is sucked, pumped to the first slaked lime stirring tank 71 described later, and further sent to the first sedimentation tank 11 and solidified in the first sedimentation tank 11 A first concentrated liquid S1 that sucks in and concentrates the first concentrated liquid S1 that has settled and concentrates the solid in the second sedimentation tank 12 and a second concentrated liquid S2 that settles and concentrates the solid in the second sedimentation tank 12. And a second concentrated liquid pump 22 for pumping to the dehydrator 30.

また、排水処理装置1は、受入沈降槽10の上澄み液T0を排出する配管50と、濃縮排水D1を受入沈降槽10から濃縮排水ポンプ20を経て第1消石灰攪拌槽71から第1の沈降槽11へと送る配管51と、第1の濃縮液S1を第1の沈降槽11から第1の濃縮液ポンプ21を経て脱水機30に送る配管53と、ろ液L1を脱水機30から第2消石灰攪拌槽76へと、そして第2の沈降槽12に送る配管54と、第1の沈降槽11から配管54に連接し上澄み液T1をろ液L1に混入させ合流液Gとするための配管52と、第2の沈降槽12の上澄み液T2を排出する配管55と、第2の濃縮液S2を第2の沈降槽12から第2の濃縮液ポンプ22を経て脱水機30に送る配管56と、脱水機30から配管55に連接しろ液L2を排出する配管57とを備える。配管54には、配管52が連接した位置の下流側に、クッション槽81が配置され、クッション槽81に貯留された合流液Gを第2の沈降槽12に吐出するクッション槽ポンプ82が備えられる。なお、配管50〜57は、管により構成された配管路に限られず、トレンチなどで形成された流路でもよく、配管には、それらの流路を含むものとする。 In addition, the waste water treatment apparatus 1 includes a pipe 50 for discharging the supernatant T0 of the receiving sedimentation tank 10 and a concentrated drainage D1 from the first sedimentation tank 10 to the first sedimentation tank 70 through the concentration drainage pump 20 from the receiving sedimentation tank 10. 11, a pipe 51 for sending the first concentrated liquid S1 from the first sedimentation tank 11 to the dehydrator 30 via the first concentrate pump 21, and a filtrate L1 for the second from the dehydrator 30 . A pipe 54 to be sent to the slaked lime stirring tank 76 and to the second settling tank 12, and a pipe connected to the pipe 54 from the first settling tank 11 to mix the supernatant liquid T1 into the filtrate L1 to be the combined liquid G 52, a pipe 55 for discharging the supernatant T2 of the second settling tank 12, and a pipe 56 for sending the second concentrated liquid S2 from the second settling tank 12 to the dehydrator 30 via the second concentrated liquid pump 22. Then, the filtrate L2 is discharged from the dehydrator 30 to the pipe 55. And a pipe 57. In the pipe 54, a cushion tank 81 is disposed downstream of the position where the pipe 52 is connected, and a cushion tank pump 82 that discharges the combined liquid G stored in the cushion tank 81 to the second sedimentation tank 12 is provided. . In addition, the piping 50-57 is not restricted to the piping path comprised with the pipe, The flow path formed with the trench etc. may be sufficient, and those flow paths shall be included in piping.

また、排水処理装置1においては、濃縮排水D1に、消石灰水酸化カルシウム:Ca(OH))スラリーを添加する第1消石灰注入装置61と、凝集剤あるいは重金属捕集剤としてのキレート化剤を添加する第1キレート化剤注入装置62と、無機凝集剤としての塩化第二鉄(FeCl)を添加する第1無機凝集剤注入装置63と、高分子凝集剤を添加する第1高分子凝集剤注入装置64とが、上流側からこの順で、配管51に接続している。消石灰(Ca(OH))スラリー、キレート化剤、塩化第二鉄および高分子凝集剤(以降、まとめて「薬剤」と総称する。)が濃縮排水D1に添加された下流側に、それぞれ第1消石灰攪拌槽71、第1キレート化剤攪拌槽72、第1無機凝集剤攪拌槽73、第1高分子凝集剤攪拌槽74(まとめて第1攪拌槽71〜74ともいう。)が配置され、濃縮排水D1と薬剤とを攪拌混合する。第1攪拌槽71〜74は、縦置きの容器であって、その中に内容液を攪拌するための攪拌翼(不図示)を有する。攪拌翼は、モータ軸(不図示)に接続され、モータの回転により攪拌翼が回転する構成となっている。これらの注入装置61〜64および第1攪拌槽71〜74が第1の薬注装置を構成する。 Moreover, in the waste water treatment apparatus 1, the 1st slaked lime injection | pouring apparatus 61 which adds slaked lime ( calcium hydroxide: Ca (OH) 2 ) slurry to the concentrated waste_water | drain D1, and the chelating agent as a flocculant or a heavy metal collection agent A first chelating agent injection device 62 for adding, a first inorganic flocculant injection device 63 for adding ferric chloride (FeCl 3 ) as an inorganic flocculant, and a first polymer for adding a polymer flocculant The flocculant injection device 64 is connected to the pipe 51 in this order from the upstream side. A slaked lime (Ca (OH) 2 ) slurry, a chelating agent, ferric chloride and a polymer flocculant (hereinafter collectively referred to as “medicine”) are added to the downstream side where the concentrated drainage D1 is added. A slaked lime stirring tank 71, a first chelating agent stirring tank 72, a first inorganic flocculant stirring tank 73, and a first polymer flocculant stirring tank 74 (collectively referred to as first stirring tanks 71 to 74) are arranged. Then, the concentrated waste water D1 and the drug are mixed with stirring. The 1st stirring tanks 71-74 are vertical installation containers, Comprising: It has a stirring blade (not shown) for stirring a content liquid in it. The stirring blade is connected to a motor shaft (not shown), and the stirring blade is rotated by the rotation of the motor. These injection | pouring apparatuses 61-64 and the 1st stirring tanks 71-74 comprise a 1st chemical injection apparatus.

合流液Gに、消石灰(Ca(OH))スラリーを添加する第2消石灰注入装置66と、凝集剤あるいは重金属捕集剤としてのキレート化剤を添加する第2キレート化剤注入装置67と、無機凝集剤としての塩化第二鉄(FeCl)を添加する第2無機凝集剤注入装置68と、高分子凝集剤を添加する第2高分子凝集剤注入装置69とが、上流側からこの順で、配管54のクッション槽ポンプ82の下流側に接続している。各々の薬剤が合流液Gに添加された下流側に、それぞれ第2消石灰攪拌槽76、第2キレート化剤攪拌槽77、第2無機凝集剤攪拌槽78、第2高分子凝集剤攪拌槽79(まとめて第2攪拌槽76〜79ともいう。)が配置され、合流液Gと薬剤とを攪拌混合する。第2攪拌槽76〜79の構成は、第1攪拌槽71〜74と同じであるので、説明を省略する。これらの注入装置66〜69および第2攪拌槽76〜79が第2の薬注装置を構成する。 A second slaked lime injection device 66 for adding slaked lime (Ca (OH) 2 ) slurry to the combined liquid G; a second chelating agent injection device 67 for adding a chelating agent as a flocculant or a heavy metal scavenger; A second inorganic flocculant injection device 68 for adding ferric chloride (FeCl 3 ) as an inorganic flocculant and a second polymer flocculant injection device 69 for adding a polymer flocculant are arranged in this order from the upstream side. Thus, the pipe 54 is connected to the downstream side of the cushion tank pump 82. A second slaked lime stirring tank 76, a second chelating agent stirring tank 77, a second inorganic flocculant stirring tank 78, and a second polymer flocculant stirring tank 79 are disposed downstream of the respective chemicals added to the combined liquid G. (Collectively also referred to as second stirring tanks 76 to 79) is arranged, and the combined liquid G and the drug are stirred and mixed. Since the structure of the 2nd stirring tanks 76-79 is the same as the 1st stirring tanks 71-74, description is abbreviate | omitted. These injection devices 66 to 69 and the second stirring tanks 76 to 79 constitute a second chemical injection device.

図1に戻って、排水処理装置1の説明を続ける。第1消石灰注入装置61、第1キレート化剤注入装置62、第1無機凝集剤注入装置63、第1高分子凝集剤注入装置64、第2消石灰注入装置66、第2キレート化剤注入装置67、第2無機凝集剤注入装置68および第2高分子凝集剤注入装置69は、それぞれ薬剤を収容する薬剤タンクと定量の薬剤を送出する往復動型ポンプと配管51あるいは配管54に接続する管路とを有する。ポンプは、他の形式でもよく、必要に応じて、流量調節弁を管路上に配して、流量を調節してもよい。あるいは、薬剤タンクを配管51、配管54より高い位置に設置し、重力で流れるようにしてもよい。 Returning to FIG. 1, the description of the waste water treatment apparatus 1 will be continued. First slaked lime injection device 61, first chelating agent injection device 62, first inorganic flocculant injection device 63, first polymer flocculant injection device 64, second slaked lime injection device 66, second chelating agent injection device 67 The second inorganic flocculant injecting device 68 and the second polymer flocculant injecting device 69 are respectively connected to a drug tank for storing a drug, a reciprocating pump for delivering a fixed amount of drug, and a pipe 51 or a pipe 54 connected to the pipe 54. And have. The pump may be of other types, and if necessary, a flow rate adjusting valve may be provided on the pipe to adjust the flow rate. Alternatively, the medicine tank may be installed at a position higher than the pipe 51 and the pipe 54 so as to flow by gravity.

図4に、排水処理装置1における排水の処理の手順を説明するフローチャートを示し、図1および図4を参照して、排水処理装置1の作用について説明する。先ず焼却炉(不図示)からの排水D0が受入沈降槽10に送られる。焼却炉からの排水D0中には、無機フッ素化合物や重金属類などの、そのまま廃棄しては環境に悪影響を及ぼす含有物に加え、焼却炉内で炭化したカーボン粒子などの懸濁物であるSSが含まれている。重金属類には、カドミウム、鉛、水銀、クロム、砒素、銅、ニッケル、マンガン、鉄、亜鉛などを含む。また、排水D0は、通常pH5〜7の弱酸性である。 FIG. 4 shows a flowchart for explaining the procedure of wastewater treatment in the wastewater treatment apparatus 1, and the operation of the wastewater treatment apparatus 1 will be described with reference to FIGS. 1 and 4. First, drainage D0 from an incinerator (not shown) is sent to the receiving sedimentation tank 10. In the wastewater D0 from the incinerator, SS, which is a suspension of carbon particles carbonized in the incinerator, in addition to the contents such as inorganic fluorine compounds and heavy metals, which are discarded as they are and has an adverse effect on the environment. It is included. The heavy metals, cadmium, lead, mercury, chromium, arsenic, copper, nickel, including manganese, iron, zinc and the like. The drainage D0 is usually weakly acidic with a pH of 5-7.

受入沈降槽10で排水D0を受け入れつつ、受け入れた排水D0を受入沈降槽10内で静置する。受入沈降槽10は、受け入れる排水D0の流量に対し、SSなどを沈降させるのに充分な容量を確保する。排水D0は、静置されることにより、SSなどが沈降する。SSなどが沈降した残りの上澄み液T0は、受入沈降槽10の側面から配管50を通じて排出され、不図示の焼却炉の排ガス洗浄装置に戻され、再利用される。これにより、処理すべき排水である濃縮排水D1の総量を減じ、後段の設備の小型化が図れる。 While receiving the drainage D0 in the receiving sedimentation tank 10, the received drainage D0 is allowed to stand in the receiving sedimentation tank 10. The receiving sedimentation tank 10 secures a capacity sufficient to settle SS and the like with respect to the flow rate of the drainage D0 to be received. As the drainage D0 is allowed to stand, SS and the like settle. The remaining supernatant T0 from which SS or the like has settled is discharged from the side surface of the receiving sedimentation tank 10 through the pipe 50, returned to the exhaust gas cleaning device of an incinerator (not shown), and reused. Thereby , the total amount of the concentrated waste water D1, which is the waste water to be treated, can be reduced, and the subsequent equipment can be downsized.

受入沈降槽10の底部の、SSなどを沈降させ濃縮した濃縮排水D1は、濃縮排水ポンプ20により吸い込まれ、タンク底部から配管51に流れる。配管51を流れる濃縮排水D1に第1消石灰注入装置61から消石灰スラリーM1が添加され、第1消石灰攪拌槽71で攪拌混合される(St11)。消石灰スラリーM1が添加されることにより濃縮排水D1のpHは、7.5以上9.5以下に調整される。濃縮排水D1のpHは、好ましくは8以上9以下に調整される。消石灰スラリーM1は、濃縮排水D1の1リットル中に300〜1800mg、好ましくは500〜1500mg添加される。濃縮排水D1に含まれる無機フッ素化合物や重金属類が消石灰と反応することにより、無機フッ素化合物からフッ化カルシウム(CaF)が生成し、重金属類から金属水酸化物(M(OH))が生成する。なお、Mは、重金属類を表す。また、消石灰を加えることによりpHが上昇し、無機フッ素化合物は水酸化マグネシウムと共沈し、すなわち、析出する。更に、消石灰微粒子は、フッ化カルシウムや重金属水酸化物を吸着する。このように、濃縮排水D1中の無機フッ素化合物および重金属類は析出し、消石灰微粒子に吸着されて、より大きな固形物に成長する。 Concentrated drainage D1 at the bottom of the receiving sedimentation tank 10 that has settled SS and the like is sucked by the concentrated drainage pump 20 and flows into the pipe 51 from the bottom of the tank. The slaked lime slurry M1 is added from the first slaked lime injection device 61 to the concentrated drainage D1 flowing through the pipe 51, and is stirred and mixed in the first slaked lime stirring tank 71 (St11). By adding the slaked lime slurry M1, the pH of the concentrated waste water D1 is adjusted to 7.5 or more and 9.5 or less. The pH of the concentrated drainage D1 is preferably adjusted to 8 or more and 9 or less. The slaked lime slurry M1 is added in an amount of 300 to 1800 mg, preferably 500 to 1500 mg, in 1 liter of the concentrated drainage D1. By inorganic fluorine compound and the heavy metals contained in the concentrate effluent D1 is reacted with slaked lime, calcium fluoride (CaF 2) is produced from the non-machine fluorine compound, a metal hydroxide from heavy metals (M (OH) X) Produces. M represents heavy metals . Also, pH is raised by adding calcium hydroxide, inorganic fluorine compounds are coprecipitated with magnesium hydroxide, i.e., precipitated. Furthermore, the slaked lime fine particles adsorb calcium fluoride and heavy metal hydroxide. Thus, the inorganic fluorine compound and heavy metals in the concentrated waste water D1 are deposited, adsorbed by the slaked lime fine particles, and grow into a larger solid substance.

消石灰スラリーM1は、生石灰を消化して生成したものが、粒径が細かく、重金属やフッ素との反応性や吸着性が向上するので好ましい。 The slaked lime slurry M1 is preferably produced by digesting quick lime because the particle size is fine and the reactivity and adsorption with heavy metals and fluorine are improved.

焼却炉の排ガスの洗浄排水には、粒径の大きなSSが含まれており、上記の重金属水酸化物の析出物、不溶性キレート化合物の析出物、フッ化カルシウムの析出物等が無機凝集剤および高分子凝集剤の添加により凝集したりして、SSを含む大きな凝集物である固形物に成長する。なお、凝集物とは、無機金属やフッ化物などが薬剤と反応して不溶化した微粒子同士またはSSと、ファンデルワールス力によって密集した固形物の総称である。そこで濃縮排水D1に含まれるSSと消石灰および凝集剤の処理により生成した固形物の総量との比をS/(F−S){ここで、Sは濃縮排水D1に含まれるSSの濃度(mg/リットル)、Fは第1の処理水E1に含まれる固形物の濃度(mg/リットル)}で表した場合に、S/(F−S)が0.1以上、好ましくは0.3以上、更に好ましくは0.5以上となるような濃度のSSが濃縮排水D1中に含まれていることが好適である。なお、濃縮排水D1に含まれるSSの濃度Sおよび第1の処理水E1に含まれる固形物の濃度Fは、JIS K 0102:1998「工場排水試験方法」に準じて求めるものとする。 The waste water from the exhaust gas from the incinerator contains SS having a large particle size, and the above-mentioned heavy metal hydroxide precipitates, insoluble chelate compound precipitates , calcium fluoride precipitates and the like are inorganic flocculants and It aggregates by the addition of a polymer flocculant, and grows into a solid substance that is a large aggregate containing SS. Note that the aggregate is a general term for fine particles in which inorganic metals or fluorides are insolubilized by reacting with a drug or SS and solids densely packed by van der Waals force. Therefore, the ratio of the SS contained in the concentrated wastewater D1 to the total amount of solids produced by the treatment of the slaked lime and the flocculant is S / (FS) {where S is the concentration of SS contained in the concentrated wastewater D1 (mg S / (FS) is 0.1 or more, preferably 0.3 or more when expressed by the concentration of solid matter contained in the first treated water E1 (mg / liter)}. Further, it is preferable that SS having a concentration of 0.5 or more is contained in the concentrated drainage D1. The SS concentration S contained in the concentrated wastewater D1 and the solid matter concentration F contained in the first treated water E1 are determined in accordance with JIS K 0102: 1998 “Factory Wastewater Test Method”.

脱水機30から取り出されたろ液L1が配管54に流れるように、制御装置40からの信号i3によりろ液管35の流路が切り替えられている。配管54には、前述のとおりに第1の沈降槽11からの配管52が接続し、ろ液L1に第1の沈降槽11の上澄み液T1が加わり、合流液Gとなる。上澄み液T1は連続的に流れるが、脱水機30からのろ液L1は間歇的に流れるので、合流液Gの流量は変化することになる。そこで、クッション槽81に合流液Gを貯留し、下流側に送る流量を安定させる。クッション槽81からは、クッション槽ポンプ82により定量的に合流液Gが送出される。合流液Gには、第2消石灰注入装置66から消石灰スラリーM2が添加される(St21)。消石灰スラリーM2が添加されることにより、合流液GのpHは8以上10以下に調整される。pHは、好ましくは8.5以上9.5以下に調整される。このように、第一段処理工程の第1の処理水E1と異なる範囲のpHに調整することにより、第一段処理工程では析出せず、分離されなかった重金属類および無機フッ素化合物を析出し、除去することができる。特に第一段処理工程では、濃縮排水D1に消石灰スラリーM1を添加することにより第1の処理水E1のpHを8.5前後とするので、鉛を析出し除去するのに好適であり、第二段処理工程では、合流液Gに消石灰スラリーM2を添加することにより第2の処理水E2のpHを9前後とするので、カドミウムやフッ素化合物を除去するのに好適である。このように、第一段処理工程における第1の処理水E1のpHを、第二段処理工程における第2の処理水E2のpHよりも低くすることが好ましい。 The flow path of the filtrate pipe 35 is switched by a signal i3 from the control device 40 so that the filtrate L1 taken out from the dehydrator 30 flows into the pipe 54. As described above, the pipe 52 from the first sedimentation tank 11 is connected to the pipe 54, and the supernatant liquid T1 of the first sedimentation tank 11 is added to the filtrate L1 to form the combined liquid G. Although the supernatant liquid T1 flows continuously, the filtrate L1 from the dehydrator 30 flows intermittently, so that the flow rate of the combined liquid G changes. Therefore, the combined liquid G is stored in the cushion tank 81, and the flow rate sent to the downstream side is stabilized. From the cushion tank 81, the combined liquid G is sent quantitatively by the cushion tank pump 82. The slaked lime slurry M2 is added to the combined liquid G from the 2nd slaked lime injection | pouring apparatus 66 (St21). By adding the slaked lime slurry M2, the pH of the combined liquid G is adjusted to 8 or more and 10 or less. The pH is preferably adjusted to 8.5 or more and 9.5 or less. Thus, by adjusting the pH to a range different from that of the first treated water E1 in the first stage treatment step, heavy metals and inorganic fluorine compounds that are not separated and separated in the first stage treatment step are precipitated. Can be removed. Particularly in the first stage treatment step, the pH of the first treated water E1 is adjusted to around 8.5 by adding the slaked lime slurry M1 to the concentrated drainage D1, and therefore, it is suitable for depositing and removing lead. In the two-stage treatment step, the pH of the second treated water E2 is adjusted to about 9 by adding the slaked lime slurry M2 to the combined liquid G, which is suitable for removing cadmium and fluorine compounds. Thus, it is preferable that the pH of the first treated water E1 in the first stage treatment step is lower than the pH of the second treated water E2 in the second stage treatment step.

排水処理装置1を用いて、排水を処理し、その処理液中に残留する重金属およびフッ素の量を測定した。排水中の元素およびpHの測定方法および測定装置を、図6にまとめて示す。焼却炉の排ガスの洗浄排水用い、未処理の排水(原水)、第一段処理工程による処理水および第二段処理工程による処理水に含まれる元素を測定した結果を図7に示す。なお、ここでいう原水とは、受入沈降槽10(図1参照)で沈降した濃縮排水D1(図1参照)を指す。図7には、薬剤添加量を僅かに変えた2回(実験No.1および2)の測定結果を示す。また、図7中、第二段処理後の除去率は、原水からの除去率を表す。 The wastewater treatment apparatus 1 was used to treat the wastewater, and the amounts of heavy metal and fluorine remaining in the treatment liquid were measured. FIG. 6 shows a method and an apparatus for measuring elements and pH in waste water. FIG. 7 shows the results of measurement of elements contained in untreated waste water (raw water), treated water in the first stage treatment process, and treated water in the second stage treatment process , using cleaning wastewater of exhaust gas from the incinerator. In addition, the raw | natural water here refers to the concentrated waste_water | drain D1 (refer FIG. 1) settled in the receiving sedimentation tank 10 (refer FIG. 1). In FIG. 7, the measurement result of 2 times (experiment No. 1 and 2) which changed the chemical | medical agent addition amount slightly is shown. In FIG. 7, the removal rate after the second stage treatment represents the removal rate from the raw water.

実験No.1において、原水に含まれるSSの濃度Sと消石灰および凝集剤の処理により生成した固形物の総量の濃度Fとを測定し、その比S/(F−S)を調べた。原水中に含まれるSSの濃度(S)は8370mg/リットルであり、第1処理工程による処理水に含まれる固形物の総量の濃度(F)は22500mg/リットルであった。これより、S/(F−S)は、0.59となった。 Experiment No. 1, the concentration S of SS contained in the raw water and the concentration F of the total amount of solids produced by the treatment with slaked lime and the flocculant were measured, and the ratio S / (FS) was examined. The concentration (S) of SS contained in the raw water was 8370 mg / liter, and the concentration (F) of the total amount of solids contained in the treated water in the first treatment step was 22500 mg / liter. Thus, S / (FS) was 0.59.

本発明の一実施の形態である排水処理装置を説明するブロック図である。It is a block diagram explaining the waste water treatment equipment which is one embodiment of the present invention. 第1の沈降槽および第2の沈降槽の構造を説明する模式的断面図である。It is typical sectional drawing explaining the structure of a 1st sedimentation tank and a 2nd sedimentation tank. フィルタープレス型脱水機を説明する斜視図である。図3(a)は、ろ室が形成され、第1または第2の濃縮液が圧入されるフィルタープレス型脱水機を示す。図3(b)は、第2の濃縮液の圧入後、空気で固形物を圧搾するフィルタープレス型脱水機を示す。図3(c)は、ろ板を開き、脱水ケーキを取り除くフィルタープレス型脱水機を示す。図3(d)は、洗浄でろ過膜を洗浄するフィルタープレス型脱水機を示す。It is a perspective view explaining a filter press type dehydrator. FIG. 3A shows a filter press type dehydrator in which a filter chamber is formed and the first or second concentrated liquid is press-fitted. FIG.3 (b) shows the filter press type | mold dehydrator which squeezes a solid substance with air after press injection of a 2nd concentrate. FIG.3 (c) shows the filter press type | mold dehydrator which opens a filter plate and removes a dewatering cake. FIG. 3 (d) shows a filter press type dehydrator for washing the filtration membrane with washing water . 排水処理装置1における排水の処理の手順を説明するフローチャートである。3 is a flowchart illustrating a procedure for wastewater treatment in the wastewater treatment apparatus 1. 脱水機のろ過膜上に形成されるコーティングを説明する斜視図である。It is a perspective view explaining the coating formed on the filter membrane of a dehydrator. 排水中の元素およびpHの分析方法および分析装置をまとめて示す図である。It is a figure which shows collectively the analysis method and analysis apparatus of the element in waste water, and pH. 本発明に係る処理方法で処理した排水に添加した薬剤と、処理水に含まれる元素の測定結果をまとめて示す図である。It is a figure which shows collectively the chemical | medical agent added to the waste_water | drain processed with the processing method which concerns on this invention, and the measurement result of the element contained in treated water.

1 排水処理装置
10 受入沈降槽
11 第1の沈降槽
12 第2の沈降槽
13、13’ 第1の容器、第2の容器
14、14’ 第1の排水導入筒、第2の排水導入筒
15、15’ 第1の回転軸、第2の回転軸
16、16’ 第1の掻き取り羽根、第2の掻き取り羽根
19、19’ 底面
20 濃縮排水ポンプ
21 第1の濃縮液ポンプ
22 第2の濃縮液ポンプ
30 脱水機
31 ろ過膜
32 ろ板
33 ろ室
34 給液口
35 ろ液管
36 コーティング
40 制御装置
50、52、53、55〜57 配管
51 配管(第1の排水導入管)
54 配管(第2の排水導入管)
61 第1消石灰注入装置(第1の薬注装置)
62 第1キレート化剤注入装置(第1の薬注装置)
63 第1無機凝集剤注入装置(第1の薬注装置)
64 第1高分子凝集剤注入装置(第1の薬注装置)
66 第2消石灰注入装置(第2の薬注装置)
67 第2キレート化剤注入装置(第2の薬注装置)
68 第2無機凝集剤注入装置(第2の薬注装置)
69 第2高分子凝集剤注入装置(第2の薬注装置)
71 第1消石灰攪拌槽
72 第1キレート化剤攪拌槽
73 第1無機凝集剤攪拌槽
74 第1高分子凝集剤攪拌槽
76 第2消石灰攪拌槽
77 第2キレート化剤攪拌槽
78 第2無機凝集剤攪拌槽
79 第2高分子凝集剤攪拌槽
81 クッション槽
82 クッション槽ポンプ
C 脱水ケーキ
D0 排水
D1 濃縮排水
E1 第1の処理水(第1の混合液)
E2 第2の処理水(第2の混合液)
F 第1の処理水中の固形物濃度(mg/リットル)
G 合流液
i1〜3 制御装置からの信号
L (第1のまたは第2の沈降槽の)液面
L1、L2 ろ液
M1、M2 消石灰スラリー(消石灰
N1、N2 キレート化剤(凝集剤)
P1、P2 塩化第二鉄(無機凝集剤)
Q1、Q2 高分子凝集剤
S 濃縮排水のSS濃度(mg/リットル)
S1 第1の濃縮液
S2 第2の濃縮液
SD 沈降物上面
T0〜T2 上澄み液
DESCRIPTION OF SYMBOLS 1 Waste water treatment apparatus 10 Acceptance sedimentation tank 11 1st sedimentation tank 12 2nd sedimentation tank 13, 13 '1st container, 2nd container 14, 14' 1st drainage introduction cylinder, 2nd drainage introduction cylinder 15, 15 'first rotating shaft, second rotating shaft 16, 16' first scraping blade, second scraping blade 19, 19 'bottom 20 concentrated drainage pump 21 first concentrated liquid pump 22 first 2 Concentrate pump 30 Dehydrator 31 Filter membrane 32 Filter plate 33 Filter chamber 34 Supply port 35 Filtrate pipe 36 Coating 40 Controllers 50, 52, 53, 55-57 Pipe 51 Pipe (first drainage introduction pipe)
54 Piping (second drainage introduction pipe)
61 1st slaked lime injection device (1st chemical injection device)
62 1st chelating agent injection device (1st chemical injection device)
63 1st inorganic flocculant injection device (1st chemical injection device)
64 1st polymer flocculant injection device (1st chemical injection device)
66 Second slaked lime injection device (second chemical injection device)
67 Second chelating agent injection device (second chemical injection device)
68 Second inorganic flocculant injection device (second chemical injection device)
69 Second polymer flocculant injection device (second chemical injection device)
71 1st slaked lime stirring tank 72 1st chelating agent stirring tank 73 1st inorganic flocculant stirring tank 74 1st polymer flocculant stirring tank 76 2nd slaked lime stirring tank 77 2nd chelating agent stirring tank 78 2nd inorganic aggregation Agent agitation tank 79 second polymer flocculant agitation tank 81 cushion tank 82 cushion tank pump C dewatering cake D0 drainage D1 concentrated drainage E1 first treated water (first mixed solution)
E2 Second treated water (second mixed solution)
F Concentration of solids in the first treated water (mg / liter)
G Combined liquids i1 to 3 Signal L from the control device Liquid level L1 (of the first or second settling tank), L2 Filtrate M1, M2 Slaked lime slurry ( slaked lime )
N1, N2 chelating agent (flocculating agent)
P1, P2 Ferric chloride (inorganic flocculant)
Q1, Q2 Polymer flocculant S SS concentration of concentrated drainage (mg / liter)
S1 1st concentrated liquid S2 2nd concentrated liquid SD Precipitate upper surface T0-T2 Supernatant liquid

Claims (4)

前記第1の処理水を作る工程および前記第2の処理水を作る工程が、前記排水または前記ろ液に消石灰を添加する工程と、
前記消石灰を添加した後に凝集剤を添加する工程とを備える
請求項1に記載の排水処理方法。
The step of making the first treated water and the step of making the second treated water include adding slaked lime to the waste water or the filtrate; and
Adding a flocculant after adding the slaked lime ;
The wastewater treatment method according to claim 1.
前記凝集剤がキレート化剤と無機凝集剤と高分子凝集剤とを含み;
前記第1の処理水を作る工程および前記第2の処理水を作る工程が、消石灰を添加する工程、その後キレート化剤を添加する工程、その後無機凝集剤を添加する工程、その後高分子凝集剤を添加する工程を含む;
請求項3に記載の排水処理方法。
The flocculant includes a chelating agent, an inorganic flocculant, and a polymer flocculant;
The step of making the first treated water and the step of making the second treated water are a step of adding slaked lime , a step of adding a chelating agent, a step of adding an inorganic flocculant, and then a polymer flocculant Adding
The wastewater treatment method according to claim 3.
所定粒径の浮遊物質を含む排水に消石灰および凝集剤を添加し、第1の混合液とする第1の薬注装置と;
前記第1の混合液をろ液と固形物とに分離し、該固形物によりろ過膜にコーティングが形成される脱水機と;
前記脱水機で分離されたろ液に消石灰および凝集剤を添加し、第2の混合液とする第2の薬注装置と;
前記第1の混合液を前記脱水機に送り、前記ろ液と前記固形物とに分離し、ろ過膜に前記固形物によりコーティングを形成し、前記コーティングが形成された脱水機を用いて前記第2の混合液をろ過するように運転を制御する制御装置とを備える;
排水処理装置。
A first chemical injection device in which slaked lime and a flocculant are added to wastewater containing suspended solids having a predetermined particle size to form a first mixed solution;
A dehydrator that separates the first mixture into a filtrate and a solid, and a coating is formed on the filtration membrane by the solid;
A second chemical injection device that adds slaked lime and a flocculant to the filtrate separated by the dehydrator to form a second mixed solution;
The first mixed liquid is sent to the dehydrator, separated into the filtrate and the solid, a coating is formed on the filtration membrane with the solid, and the dehydrator having the coating is used to form the first mixture. A controller for controlling the operation so as to filter the mixture of the two;
Wastewater treatment equipment.
所定粒径の浮遊物質を含む排水に消石灰および凝集剤を添加し、第1の混合液とする第1の薬注装置と;
前記第1の混合液をろ液と固形物とに分離し、該固形物によりろ過膜にコーティングが形成される脱水機と;
前記脱水機で分離されたろ液に消石灰および凝集剤を添加し、第2の混合液とする第2の薬注装置と;
前記第1の混合液を静置する第1の沈降槽であって、
前記第1の沈降槽内の液面近傍から前記第1の沈降槽内に鉛直方向に設置され、前記第1の沈降槽の内径より小さい内径を有する第1の排水導入筒と、
前記第1の排水導入筒内に該筒に対して接線方向に前記静置する第1の混合液を導入する第1の排水導入管と、
前記第1の沈降槽の底面近傍を掻き取るように回転する第1の掻き取り羽根とを有する第1の沈降槽、または
前記第2の混合液を静置する第2の沈降槽であって、
前記第2の沈降槽内の液面近傍から前記第2の沈降槽内に鉛直方向に設置され、前記第2の沈降槽の内径より小さい内径を有する第2の排水導入筒と、
前記第2の排水導入筒内に該筒に対して接線方向に前記静置する第2の混合液を導入する第2の排水導入管と、
前記第2の沈降槽の底面近傍を掻き取るように回転する第2の掻き取り羽根とを有する第2の沈降槽とを備える;
排水処理装置。
A first chemical injection device in which slaked lime and a flocculant are added to wastewater containing suspended solids having a predetermined particle size to form a first mixed solution;
A dehydrator that separates the first mixture into a filtrate and a solid, and a coating is formed on the filtration membrane by the solid;
A second chemical injection device that adds slaked lime and a flocculant to the filtrate separated by the dehydrator to form a second mixed solution;
A first settling tank in which the first mixed liquid is allowed to stand;
A first drainage introduction cylinder installed in a vertical direction in the first settling tank from near the liquid surface in the first settling tank, and having an inner diameter smaller than the inner diameter of the first settling tank;
A first drainage introduction pipe for introducing the first mixed liquid to be left stationary in a tangential direction with respect to the cylinder in the first drainage introduction cylinder;
A first sedimentation tank having a first scraping blade rotating so as to scrape the vicinity of the bottom surface of the first sedimentation tank, or a second sedimentation tank in which the second mixed liquid is allowed to stand. ,
A second drainage introduction cylinder installed in the vertical direction in the second settling tank from near the liquid surface in the second settling tank, and having an inner diameter smaller than the inner diameter of the second settling tank;
A second drainage introduction pipe for introducing the second mixed liquid to be stationary in a tangential direction with respect to the cylinder in the second drainage introduction cylinder;
A second settling tank having a second scraping blade rotating so as to scrape the vicinity of the bottom surface of the second settling tank;
Wastewater treatment equipment.
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