JP2005334758A - Ventilation filter - Google Patents

Ventilation filter Download PDF

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JP2005334758A
JP2005334758A JP2004156461A JP2004156461A JP2005334758A JP 2005334758 A JP2005334758 A JP 2005334758A JP 2004156461 A JP2004156461 A JP 2004156461A JP 2004156461 A JP2004156461 A JP 2004156461A JP 2005334758 A JP2005334758 A JP 2005334758A
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water
ventilation filter
porous membrane
conductive
resin porous
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Toshiteru Yanagi
俊輝 柳
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Nitto Denko Corp
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Nitto Denko Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a ventilation filter provided with a water-proofing property, a ventilation or sound transmission property, and an electromagnetic wave shielding property. <P>SOLUTION: The ventilation filter 1 of this invention is a laminate containing at least one layer of a water-repelling resin porous film 2 and the laminate includes a conductive ventilation layer 3. Another ventilation filter of this invention is a ventilation filter containing at least one layer of a water-repelling resin porous film and a conductive substance adheres to at least one layer of the water-repelling resin porous film. The ventilation filter 1 preferable further includes a ventilation support layer overlayering the water-repelling resin porous film and the water-repelling resin porous film is preferable to include a PTFE (polytetrafluoroethylene) porous film. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、電子機器の筐体の開口部に取り付けられ、防水性、防塵性、通音性および通気性等を有する通気フィルタに関する。   The present invention relates to a ventilation filter that is attached to an opening of a casing of an electronic device and has waterproofness, dustproofness, sound permeability, air permeability, and the like.

精密機器等の電子機器の筐体には、音声の伝搬、筐体内部で発生したガスの放出、温度変化による筐体内部の圧力変化の緩和等のために、開口部が形成されている。特に、携帯電話、ノートパソコン、または電子手帳等の携帯情報通信機器において、スピーカー、レシーバー、マイク等の発音部および受音部は、その機能上高度な通音性を有する必要性があるため、必然的に大きな開口部となる。これらの開口部は、水や埃の浸入による電子機器の故障防止のために、撥水性不織布、撥水性ネット、薄層プラスチックフィルム等の通気フィルタによって覆われている。   A housing of an electronic device such as a precision device has an opening for propagation of sound, release of gas generated inside the housing, relaxation of pressure change inside the housing due to temperature change, and the like. In particular, in portable information communication devices such as mobile phones, notebook computers, or electronic notebooks, sound generators and sound receivers such as speakers, receivers, microphones, etc. need to have a high sound transmission capability in terms of their functions. Inevitably a large opening. These openings are covered with a ventilation filter such as a water-repellent nonwoven fabric, a water-repellent net, and a thin plastic film in order to prevent failure of the electronic device due to the ingress of water or dust.

上記通気フィルタに特に好適な材料として、撥水性を有する樹脂多孔質膜(以下、「撥水樹脂多孔質膜」という。)、例えば、ポリテトラフルオロエチレン(以下、「PTFE」という)多孔質膜がある(例えば、特許文献1参照)。撥水樹脂多孔質膜は高い通気性または通音性と防水性とをあわせもっている。
特開平10−165787号公報(2頁)
As a material suitable for the ventilation filter, a water-repellent resin porous membrane (hereinafter referred to as “water-repellent resin porous membrane”), for example, polytetrafluoroethylene (hereinafter referred to as “PTFE”) porous membrane. (For example, refer to Patent Document 1). The water-repellent resin porous membrane has high breathability or sound permeability and waterproofness.
JP-A-10-165787 (2 pages)

近年、無線機器の増加等により、筐体内へ電磁波が入る機会が増加している。電磁波が筐体内に入ることを阻止するために、筐体7は、通常、導電性を有する材料から形成されているが、開口部から電磁波が侵入して、電子機器の動作等に悪影響をおよぼすことが問題となっている。   In recent years, due to an increase in wireless devices and the like, the opportunity for electromagnetic waves to enter the housing has increased. In order to prevent electromagnetic waves from entering the casing, the casing 7 is usually made of a conductive material, but electromagnetic waves enter through the opening and adversely affect the operation of the electronic device. Is a problem.

本発明の通気フィルタは、少なくとも1層の撥水樹脂多孔質膜を含む積層体であって、前記積層体が導電性通気層を含むことを特徴とする。   The ventilation filter of the present invention is a laminate including at least one water-repellent resin porous membrane, and the laminate includes a conductive ventilation layer.

本発明の別の通気フィルタは、少なくとも1層の撥水樹脂多孔質膜を含む通気フィルタであって、前記少なくとも1層の撥水樹脂多孔質膜のうちの少なくとも1層の撥水樹脂多孔質膜に導電性物質が付着していることを特徴とする。   Another vent filter of the present invention is a vent filter including at least one layer of water-repellent resin porous membrane, and at least one layer of the water-repellent resin porous membrane of the at least one layer of water-repellent resin porous membrane. A conductive substance is attached to the film.

本発明では、防水性、通気性または通音性、および電磁波シールド性を備えた通気フィルタを提供できる。   In the present invention, it is possible to provide a ventilation filter having waterproofness, breathability or sound permeability, and electromagnetic shielding properties.

以下に、本発明の通気フィルタの一例を、図面を参照しながら説明する。   Hereinafter, an example of the ventilation filter of the present invention will be described with reference to the drawings.

(実施の形態1)
図1に示すように、本実施の形態の通気フィルタ1は、少なくとも1層の撥水樹脂多孔質膜2を含む積層体であって、積層体は導電性通気層3を含んでいる。通気フィルタ1では、導電性通気層3を含んでいるので、通気フィルタ1を筐体の開口部に取り付ければ、筐体の開口部に電磁波に対するシールドを付与でき、電磁波による電子機器への悪影響を低減できる。
(Embodiment 1)
As shown in FIG. 1, the ventilation filter 1 of the present embodiment is a laminate including at least one water-repellent resin porous film 2, and the laminate includes a conductive ventilation layer 3. Since the ventilation filter 1 includes the conductive ventilation layer 3, if the ventilation filter 1 is attached to the opening of the housing, a shield against electromagnetic waves can be imparted to the opening of the housing, and the adverse effect of the electromagnetic waves on the electronic device can be prevented. Can be reduced.

本実施の形態の通気フィルタ1では、通気フィルタ1(積層体)の一方の面が、導電性通気層3の一方の面から形成されているので、上記一方の面を筐体側に向けて通気フィルタ1を筐体の開口部に取り付ければ、筐体の開口部に電磁波に対する効果的なシールドを付与できる。   In the ventilation filter 1 of the present embodiment, since one surface of the ventilation filter 1 (laminated body) is formed from one surface of the conductive ventilation layer 3, ventilation is performed with the one surface facing the housing. If the filter 1 is attached to the opening of the housing, an effective shield against electromagnetic waves can be imparted to the opening of the housing.

導電性通気層3の材料は、導電性を有する物質を含んでいれば特に制限はないが、例えば、金、銀、銅、白金、アルミニウム、鉄、ニッケル等の金属、カーボンブラックおよびグラファイトからなる群から選ばれる少なくとも1種の導電体を含んでいることが好ましい。例えば、上記金属単体、上記導電体と樹脂とを含む複合材、例えば金属メッキ繊維等であってもよい。上記樹脂には、例えば、ポリエステル、ポリエチレン(PE)、ポリプロピレン(PP)等のポリオレフィン、ポリアミド等が挙げられる。   The material of the conductive air-permeable layer 3 is not particularly limited as long as it contains a conductive substance. For example, the conductive gas-permeable layer 3 is made of metal such as gold, silver, copper, platinum, aluminum, iron, nickel, carbon black, and graphite. It is preferable that at least one conductor selected from the group is included. For example, the metal simple substance, the composite material containing the conductor and the resin, for example, metal plating fiber may be used. Examples of the resin include polyolefins such as polyester, polyethylene (PE), and polypropylene (PP), and polyamide.

導電性通気層3は、その形態について特に制限はないが、撥水樹脂多孔質膜2よりも通気性が高い、例えば、不織布、ネット(網目状シート)、または織布等であることが好ましい。導電性通気層3が、例えば、不織布である場合は、その目付け量は30〜100g/m2、厚さは0.05〜0.3mmであることが好ましい。図2に示すように、導電性通気層3が、複数の開口部3aを有するネットである場合は、開口部3aの平均面積(個々の開口部の平均面積)が0.0001〜0.01mm2であり、開口率が40〜70%であることが好ましい。上記のような形態の導電性通気層3を用いれば、適当な通気性または通音性と、電磁波に対する良好なシールド性とを両立させることができるからである。尚、本発明において、上記目付け量、および開口率は、下記の方法により得た値である。 The form of the conductive air-permeable layer 3 is not particularly limited, but is preferably higher in air permeability than the water-repellent resin porous membrane 2, for example, a nonwoven fabric, a net (mesh-like sheet), or a woven fabric. . When the conductive air-permeable layer 3 is, for example, a nonwoven fabric, the basis weight is preferably 30 to 100 g / m 2 and the thickness is preferably 0.05 to 0.3 mm. As shown in FIG. 2, when the conductive air-permeable layer 3 is a net having a plurality of openings 3a, the average area of the openings 3a (average area of each opening) is 0.0001 to 0.01 mm. 2 and the aperture ratio is preferably 40 to 70%. This is because the use of the conductive air-permeable layer 3 having the above-described configuration makes it possible to achieve both appropriate air permeability or sound permeability and good shielding properties against electromagnetic waves. In the present invention, the weight per unit area and the aperture ratio are values obtained by the following method.

(1)目付け量
導電性通気層3を100cm2サンプリングし、その重さを電子天秤により測定して1m2当たりの質量(g)を求めた。
(1) Weight per unit area 100 cm 2 of the conductive air-permeable layer 3 was sampled, and the weight was measured with an electronic balance to determine the mass (g) per 1 m 2 .

(2)開口率
開口率=[開口部の面積の総和/ネット全体の面積]×100
撥水樹脂多孔質膜2の材料は、撥水性を有する材料を含んでいれば特に制限はないが、例えば、フッ素樹脂を含んでいることが好ましい。フッ素樹脂としては、PTFE、ポリクロロトリフルオロエチレン、テトラフルオロエチレン−ヘキサフルオロプロピレン共重合体、テトラフルオロエチレン−パ−フルオロアルキルビニルエーテル共重合体、テトラフルオロエチレン−エチレン共重合体などが挙げられる。特に、撥水樹脂多孔質膜2は、小面積でも通気性が維持でき、筐体内部への水や塵の侵入を阻止する機能が高い、PTFE多孔質膜が好ましい。
(2) Aperture ratio Aperture ratio = [total area of openings / area of entire net] × 100
The material of the water-repellent resin porous membrane 2 is not particularly limited as long as it includes a material having water repellency, but for example, preferably contains a fluororesin. Examples of the fluororesin include PTFE, polychlorotrifluoroethylene, tetrafluoroethylene-hexafluoropropylene copolymer, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, tetrafluoroethylene-ethylene copolymer, and the like. In particular, the water-repellent resin porous membrane 2 is preferably a PTFE porous membrane that can maintain air permeability even in a small area and has a high function of preventing water and dust from entering the inside of the housing.

撥水樹脂多孔質膜2は、その形態について特に制限はないが、通常、厚みが5〜300μmであり、平均孔径が0.1〜5μm、気孔率が60〜95%、通気度(フラジール通気度)が0.01〜20cc/cm2・secの膜が好適である。尚、上記通気度は、JIS L 1096(6.27.A法)に従い、フラジール試験機(東洋精機製作所製)を用いて測定した値である。 The form of the water-repellent resin porous membrane 2 is not particularly limited, but is usually 5 to 300 μm in thickness, 0.1 to 5 μm in average pore diameter, 60 to 95% in porosity, and air permeability (fragile ventilation). A film having a degree of 0.01 to 20 cc / cm 2 · sec is suitable. The air permeability is a value measured using a Frazier tester (manufactured by Toyo Seiki Seisakusho) according to JIS L 1096 (6.27.A method).

上記した撥水樹脂多孔質膜は、従来から用いられてきた方法により作製できる。以下にその作製方法の一例を、PTFE多孔質膜を例に挙げて説明する。   The water-repellent resin porous membrane described above can be produced by a conventionally used method. An example of the production method will be described below by taking a PTFE porous membrane as an example.

まず、PTFEファインパウダーに液状潤滑剤を加えたペースト状の混合物を予備成形する。液状潤滑剤としては、PTFEファインパウダーの表面を濡らすことができ、抽出や加熱することより除去できるものであれば特に限定されず、例えば、ナフサ、ホワイトオイルなどの炭化水素を使用できる。液状潤滑剤の添加量は、PTFEファインパウダー100重量部に対して5〜50重量部程度が適当である。上記した予備成形は、液状潤滑剤が絞り出されない程度の圧力で行う。次に、予備成形体を押出しおよび/または圧延してシート状に成形し、このようにして得られたシート状の成形体を少なくとも一軸方向に延伸してPTFE多孔質膜を得る。尚、延伸は、液状潤滑剤を除去してから行うとよい。延伸条件は、適宜設定でき、通常、温度は30〜320℃であり、延伸倍率は、縦方向、横方向ともに2〜30倍である。また、延伸後のPTFE多孔質膜について、PTFEの融点以上に加熱して焼成すれば、強度を高めることができる。   First, a paste-like mixture obtained by adding a liquid lubricant to PTFE fine powder is preformed. The liquid lubricant is not particularly limited as long as it can wet the surface of the PTFE fine powder and can be removed by extraction or heating. For example, hydrocarbons such as naphtha and white oil can be used. The addition amount of the liquid lubricant is suitably about 5 to 50 parts by weight with respect to 100 parts by weight of PTFE fine powder. The above preforming is performed at a pressure that does not squeeze out the liquid lubricant. Next, the preformed body is extruded and / or rolled to form a sheet, and the sheet-like formed body thus obtained is stretched at least in a uniaxial direction to obtain a PTFE porous membrane. The stretching may be performed after removing the liquid lubricant. Stretching conditions can be set as appropriate. Usually, the temperature is 30 to 320 ° C., and the stretching ratio is 2 to 30 times in both the longitudinal and transverse directions. In addition, if the PTFE porous membrane after stretching is heated and fired to a melting point of PTFE or higher, the strength can be increased.

導電性通気層3と撥水樹脂多孔質膜2とは、単に重ねあわせるだけでもよく、互いに接合してもよい。接合は、例えば、感圧接着剤、熱硬化型接着剤等の接着剤による接着、または熱溶着等の方法により行うことができるが、接合に際して、通気フィルタ1の通気性または通音性を損なわないように配慮する必要がある。具体的には、導電性通気層3に上記接着剤を点状、網状に塗布して、導電性通気層3と撥水樹脂多孔質膜2とを接合することが好ましい。または、通気フィルタ1を所定の形状に切断したときに、切断された通気フィルタ1の周縁部のみにおいて、導電性通気層3と撥水樹脂多孔質膜2とが接合されているように、上記接着剤を導電性通気層3に塗布してもよい。   The conductive air-permeable layer 3 and the water-repellent resin porous membrane 2 may be simply overlapped or joined together. Joining can be performed by a method such as adhesion using an adhesive such as a pressure-sensitive adhesive or a thermosetting adhesive, or heat welding, but the breathability or sound permeability of the ventilation filter 1 is impaired during the joining. It is necessary to be careful not to. Specifically, it is preferable that the conductive air-permeable layer 3 and the water-repellent resin porous film 2 are bonded to each other by applying the adhesive to the conductive air-permeable layer 3 in the form of dots or nets. Alternatively, when the ventilation filter 1 is cut into a predetermined shape, the conductive ventilation layer 3 and the water-repellent resin porous membrane 2 are joined only at the peripheral edge of the cut ventilation filter 1. An adhesive may be applied to the conductive ventilation layer 3.

図1に示した例では、通気フィルタ1は、導電性通気層3と撥水樹脂多孔質膜2とからなるが、強度やハンドリング性向上のために、図3に示すように、撥水樹脂多孔質膜2に積層された通気性支持層4をさらに含んでいてもよい。   In the example shown in FIG. 1, the ventilation filter 1 includes a conductive ventilation layer 3 and a water-repellent resin porous film 2, but in order to improve strength and handling properties, as shown in FIG. A breathable support layer 4 laminated on the porous membrane 2 may be further included.

通気性支持層4は、その材質、構造、形態について特に制限されないが、撥水樹脂多孔質膜2よりも通気性が高い材料、例えば、不織布、織布、ネット、スポンジ、フォーム、その他の多孔材料を用いることが好ましい。特に、強度、柔軟性、作業性の点からは不織布が好ましい。通気性支持層4の材料について特に制限はなく、ポリオレフィン(PE、PP、超高分子量ポリエチレン(UHMWPE)など)、ポリアミド、ポリエステル(ポリエチレンテレフタレート(PET)など)、芳香族ポリアミド、あるいはこれらの複合材などを用いることができる。通気性支持層4が、例えば不織布である場合は、通常、目付け量は30〜100g/m2、厚さは0.05〜0.3mmであり、複数の開口部を有するネットである場合は、開口部の平均面積(個々の開口部の平均面積)は0.0001〜0.01mm2であり、開口率は40〜70%であることが望ましい。 The material, structure, and form of the breathable support layer 4 are not particularly limited. However, the breathable support layer 4 has a higher breathability than that of the water-repellent resin porous membrane 2, for example, non-woven fabric, woven fabric, net, sponge, foam, and other porous materials. It is preferable to use a material. In particular, a nonwoven fabric is preferable from the viewpoint of strength, flexibility, and workability. There is no restriction | limiting in particular about the material of the air permeable support layer 4, Polyolefin (PE, PP, ultra high molecular weight polyethylene (UHMWPE) etc.), polyamide, polyester (polyethylene terephthalate (PET) etc.), aromatic polyamide, or these composite materials Etc. can be used. When the breathable support layer 4 is, for example, a nonwoven fabric, the weight per unit area is usually 30 to 100 g / m 2 , the thickness is 0.05 to 0.3 mm, and the net has a plurality of openings. The average area of the openings (average area of the individual openings) is preferably 0.0001 to 0.01 mm 2 and the opening ratio is preferably 40 to 70%.

通気性支持層4と撥水樹脂多孔質膜2とは、単に重ねあわせるだけでもよく、互いに接合してもよい。接合は、例えば、接着剤ラミネート、熱ラミネート、加熱溶着、超音波溶着、振動溶着、接着剤による接着などの方法により行うことができる。例えば、熱ラミネートにより積層する場合は、加熱により通気性支持層4の一部を溶融し接着すればよい。また、ホットメルトパウダーのような融着剤を介在させて接着してもよい。   The breathable support layer 4 and the water-repellent resin porous membrane 2 may be simply overlapped or joined together. Joining can be performed by methods such as adhesive laminating, thermal laminating, heat welding, ultrasonic welding, vibration welding, and adhesion using an adhesive. For example, when laminating by thermal lamination, a part of the breathable support layer 4 may be melted and bonded by heating. Moreover, you may adhere | attach by interposing a fusing agent like hot melt powder.

通気フィルタ1には、必要に応じて撥水処理、撥油処理などの撥液処理を施してもよい。撥液処理は、表面張力の小さな物質を塗布し、乾燥後、キュアすることにより行うことができる。撥液剤としては、撥水樹脂多孔質膜2よりも低い表面張力の被膜を形成できれば特に限定されないが、パーフルオロアルキル基を有する高分子が好適である。このような高分子としては、例えば、「フロラード」(住友スリーエム製)、「スコッチガード」(住友スリーエム製)、「テックスガード」(ダイキン工業製)、「ユニダイン」(ダイキン工業製)、「アサヒガード」(旭硝子製)など(すべて商品名)を利用してもよい。撥液剤の塗布は、含浸、スプレーなどにより行えばよい。撥液剤の塗布量は十分な撥液効果が得られ、かつ通気フィルタ1の通気性が妨げられないように調整することが好ましい。撥液処理は、撥水樹脂多孔質膜2にのみ施してもよいし、通気フィルタ1の全体に施してもよい。   The ventilation filter 1 may be subjected to liquid repellent treatment such as water repellent treatment and oil repellent treatment as necessary. The liquid repellent treatment can be performed by applying a substance having a small surface tension, curing it after drying. The liquid repellent is not particularly limited as long as a film having a lower surface tension than the water repellent resin porous film 2 can be formed, but a polymer having a perfluoroalkyl group is suitable. Such polymers include, for example, “Florard” (manufactured by Sumitomo 3M), “Scotch guard” (manufactured by Sumitomo 3M), “Tex Guard” (manufactured by Daikin Industries), “Unidyne” (manufactured by Daikin Industries), “Asahi” “Guard” (manufactured by Asahi Glass) and the like (all trade names) may be used. The liquid repellent may be applied by impregnation or spraying. The amount of the liquid repellent applied is preferably adjusted so that a sufficient liquid repellent effect is obtained and the air permeability of the air filter 1 is not hindered. The liquid repellent treatment may be performed only on the water-repellent resin porous membrane 2 or on the entire ventilation filter 1.

通気フィルタ1の筐体7への取り付け方法について特に制限はないが、例えば、金属製ネジによるネジ止め、通気フィルタ1の周縁に設けられた金属枠等と筐体との嵌合、熱可塑性樹脂系接着剤や粘着テープ等による接着等により行うことができる。   Although there is no restriction | limiting in particular about the attachment method to the housing | casing 7 of the ventilation filter 1, For example, the screwing with a metal screw, the fitting of the metal frame etc. which were provided in the periphery of the ventilation filter 1, and a housing | casing, a thermoplastic resin It can be carried out by adhesion with a system adhesive or an adhesive tape.

筐体7への短絡および取付けの確実性および簡便性を考慮すれば、図4に示すように、通気フィルタ1は、筐体7の開口部8を覆うことができる形状をしており、導電性通気層3の一方の面の周縁に配置された導電性粘着層5を含み、導電性粘着層5によって通気フィルタ1を筐体7へ取り付けることが好ましい。   Considering the reliability and simplicity of short circuiting and attachment to the housing 7, the ventilation filter 1 has a shape that can cover the opening 8 of the housing 7, as shown in FIG. It is preferable that the air-permeable filter 1 is attached to the housing 7 by the conductive adhesive layer 5 including the conductive adhesive layer 5 disposed on the periphery of one surface of the conductive air-permeable layer 3.

導電性粘着層5の材料には、例えば、アクリル系の粘弾性ポリマーに導電性物質を混入した感圧接着剤等を用いることができる。導電性物質には、例えば、粉末状または繊維状の金、銀、銅、白金、アルミニウム、鉄、ニッケル等の金属、カーボンブラックおよびグラファイトからなる群から選ばれる少なくとも1種の導電体が使用できる。上記感圧接着剤をドーナツ状に加工して粘着テープとし、上記粘着テープを導電性通気層3の一方の面の周縁に配置すれば、通気フィルタ1について筐体7への短絡および取り付けが容易となり、筐体7の開口部8に、電磁波に対する効果的なシールドを付与できる。   As the material for the conductive adhesive layer 5, for example, a pressure sensitive adhesive in which a conductive substance is mixed in an acrylic viscoelastic polymer can be used. As the conductive material, for example, at least one conductive material selected from the group consisting of powdered or fibrous gold, silver, copper, platinum, aluminum, iron, nickel, and the like, carbon black, and graphite can be used. . If the pressure sensitive adhesive is processed into a donut shape to form an adhesive tape, and the adhesive tape is disposed on the periphery of one surface of the conductive ventilation layer 3, the ventilation filter 1 can be easily short-circuited and attached to the housing 7. Thus, an effective shield against electromagnetic waves can be imparted to the opening 8 of the housing 7.

導電性粘着層5は、導電性通気層3の一方の面に形成された導電性の小突起(図示せず)と、小突起を囲うように配置された感圧接着剤等とから構成されていてもよい。   The conductive adhesive layer 5 is composed of conductive small protrusions (not shown) formed on one surface of the conductive air-permeable layer 3 and a pressure-sensitive adhesive disposed so as to surround the small protrusions. It may be.

(実施の形態2)
図5に示すように、本実施の形態の通気フィルタ21は、1層の撥水樹脂多孔質膜2からなり、撥水樹脂多孔質膜2に導電性物質6が付着している。通気フィルタ21では、撥水樹脂多孔質膜2に導電性物質6が付着しているので、通気フィルタ21を、筐体の開口部に取り付ければ、筐体の開口部に電磁波に対するシールドを付与でき、電磁波による電子機器への悪影響を低減できる。
(Embodiment 2)
As shown in FIG. 5, the ventilation filter 21 of the present embodiment includes a single layer of the water-repellent resin porous film 2, and the conductive substance 6 is attached to the water-repellent resin porous film 2. In the ventilation filter 21, the conductive substance 6 adheres to the water-repellent resin porous membrane 2. Therefore, if the ventilation filter 21 is attached to the opening of the casing, a shield against electromagnetic waves can be provided to the opening of the casing. , The adverse effects of electronic waves on electronic equipment can be reduced.

撥水樹脂多孔質膜2の材料、構造、形態については、実施の形態1と同様である。通気フィルタ21では、平均孔径が0.1〜5μmである撥水樹脂多孔質膜2の少なくとも一方の面および孔内に導電性物質6が付着しているので、電磁波に対するシールド性が高い。   The material, structure, and form of the water-repellent resin porous membrane 2 are the same as those in the first embodiment. In the ventilation filter 21, since the conductive substance 6 adheres to at least one surface of the water-repellent resin porous membrane 2 having an average pore diameter of 0.1 to 5 μm and the pores, the shielding property against electromagnetic waves is high.

図5に示した例では、通気フィルタ21は、1層の撥水樹脂多孔質膜2単体に導電性物質6が付着した構造であるが、本実施の形態の通気フィルタ21はこれに制限されるものではなく、例えば図6に示すように、撥水樹脂多孔質膜2に積層されて撥水樹脂多孔質膜2を補強する通気性支持層4をさらに含んでいてもよいし、通気性支持層4にも導電性物質6が付着していてもよい。通気性支持層4の材料、構造、形態は、実施の形態1と同様である。   In the example shown in FIG. 5, the ventilation filter 21 has a structure in which the conductive material 6 is attached to a single layer of the water-repellent resin porous membrane 2, but the ventilation filter 21 of the present embodiment is not limited to this. For example, as shown in FIG. 6, a breathable support layer 4 that is laminated on the water-repellent resin porous membrane 2 and reinforces the water-repellent resin porous membrane 2 may be further included. The conductive material 6 may also adhere to the support layer 4. The material, structure, and form of the breathable support layer 4 are the same as those in the first embodiment.

図5および図6に示した例では、通気フィルタ21は、その一方の面が、導電性物質6が付着した撥水樹脂多孔質膜2の一方の面から形成されており、当該撥水樹脂多孔質膜2の少なくとも上記一方の面および孔内に導電性物質6が付着しているので、通気フィルタ21を、通気フィルタ21の上記一方の面を筐体側に向けて筐体の開口部に取り付ければ、筐体の開口部に電磁波に対する効果的なシールドを付与できる。   In the example shown in FIGS. 5 and 6, the ventilation filter 21 has one surface formed from one surface of the water-repellent resin porous membrane 2 to which the conductive substance 6 is attached. Since the conductive substance 6 adheres to at least the one surface and the hole of the porous membrane 2, the ventilation filter 21 is placed in the opening of the housing with the one surface of the ventilation filter 21 facing the housing. If attached, an effective shield against electromagnetic waves can be imparted to the opening of the housing.

導電性物質6は、導電性を有する物質であれば特に制限はないが、粉末状または繊維状の金、銀、銅、白金、アルミニウム、鉄、ニッケル等の金属、カーボンブラックおよびグラファイトからなる群から選ばれる少なくとも1種の導電体であることが好ましい。導電性物質6の形状が粉末状である場合、その平均粒径は、0.01〜1μmであり、繊維状である場合は、その平均繊維長は0.1〜10μm、平均繊維径は0.01〜1μmであることが好ましい。例えば、撥水樹脂多孔質膜2の平均孔径が0.5μm〜5μmである場合に、導電性物質6が上記した範囲内のものが適当である。   The conductive material 6 is not particularly limited as long as it is a conductive material. However, the conductive material 6 is a powder or fibrous metal such as gold, silver, copper, platinum, aluminum, iron, nickel, carbon black, and graphite. It is preferable that it is at least 1 sort (s) of conductors chosen from these. When the conductive material 6 is in a powder form, the average particle diameter is 0.01 to 1 μm, and when it is fibrous, the average fiber length is 0.1 to 10 μm and the average fiber diameter is 0. It is preferably 0.01 to 1 μm. For example, when the average pore size of the water repellent resin porous membrane 2 is 0.5 μm to 5 μm, the conductive material 6 within the above range is suitable.

撥水樹脂多孔質膜2単体または撥水樹脂多孔質膜2と通気性支持層4とを含む積層体(以下「撥水樹脂多孔質膜2等」という)に導電性物質6を付着させる方法は、例えば、(1)撥水樹脂多孔質膜2等へ、導電性物質6をそのまま吹き付ける方法、(2)導電性物質をアルコールなどの分散媒に分散させた分散液を撥水樹脂多孔質膜2等へ吹き付けた後、撥水樹脂多孔質膜2等から分散媒を乾燥して除去する方法、(3)撥水樹脂多孔質膜2等を上記分散液に浸漬した後、撥水樹脂多孔質膜2等から分散媒を乾燥して除去する方法等が挙げられる。   Method of attaching conductive substance 6 to water-repellent resin porous membrane 2 alone or a laminate including water-repellent resin porous membrane 2 and air-permeable support layer 4 (hereinafter referred to as “water-repellent resin porous membrane 2 etc.”) For example, (1) a method in which the conductive substance 6 is sprayed as it is onto the water-repellent resin porous membrane 2 or the like, and (2) a dispersion in which the conductive substance is dispersed in a dispersion medium such as alcohol is used. A method of drying and removing the dispersion medium from the water-repellent resin porous membrane 2 etc. after spraying on the membrane 2 etc., (3) After immersing the water-repellent resin porous membrane 2 etc. in the dispersion liquid, Examples thereof include a method of drying and removing the dispersion medium from the porous membrane 2 and the like.

撥水樹脂多孔質膜2等を上記分散液へ浸漬した後、撥水樹脂多孔質膜2等から分散媒を乾燥除去する場合は、撥水樹脂多孔質膜2等、およびこれらが浸漬された分散液を超音波により振動させながら、導電性物質6を撥水樹脂多孔質膜2等に含浸させることが好ましい。通気フィルタにおける導電性物質6の均一性が高まり、電磁波シールド性の高い通気フィルタを提供できるからである。   When the dispersion medium is dried and removed from the water-repellent resin porous membrane 2 etc. after the water-repellent resin porous membrane 2 etc. is immersed in the dispersion, the water-repellent resin porous membrane 2 etc. and these are immersed. It is preferable to impregnate the water-repellent resin porous membrane 2 or the like with the conductive substance 6 while vibrating the dispersion with ultrasonic waves. This is because the uniformity of the conductive material 6 in the ventilation filter is increased, and a ventilation filter having high electromagnetic shielding properties can be provided.

分散媒は、撥水樹脂多孔質膜2が濡れ易く、導電性物質6の分散性が良い、例えば、エタノール、イソプロピルアルコール、アセトン、メチルエチルケトン、界面活性剤水溶液、フッ素系溶媒等であることが好ましい。   The dispersion medium is preferably a water-repellent resin porous membrane 2 that is easily wetted and has good dispersibility of the conductive material 6, for example, ethanol, isopropyl alcohol, acetone, methyl ethyl ketone, an aqueous surfactant solution, a fluorine-based solvent, or the like. .

導電性物質6の付着量は、撥水樹脂多孔質膜2等の重量の10〜40重量%であることが好ましい。少なすぎると十分な電磁波シールド効果が得られず、多すぎると撥水樹脂多孔質膜2の孔が過剰に閉塞され、通気性または通音性を低下させるおそれがあるからである。また、導電性物質6の付着量が上記した範囲内であれば、撥水樹脂多孔質膜2の孔が導電性物質6によってある程度塞がれても、通気性または通音性には影響しない。   The adhesion amount of the conductive material 6 is preferably 10 to 40% by weight of the weight of the water repellent resin porous membrane 2 and the like. If the amount is too small, a sufficient electromagnetic shielding effect cannot be obtained. If the amount is too large, the pores of the water-repellent resin porous membrane 2 are excessively blocked, and there is a possibility that air permeability or sound permeability may be reduced. Further, if the amount of the conductive material 6 attached is within the above-described range, even if the pores of the water-repellent resin porous membrane 2 are blocked to some extent by the conductive material 6, there is no effect on the air permeability or sound permeability. .

本実施の形態の通気フィルタ21においても、実施の形態1と同様、必要に応じて撥液処理を施してもよい。   Also in the ventilation filter 21 of the present embodiment, liquid repellent treatment may be performed as necessary, as in the first embodiment.

通気フィルタ21の筐体7への取り付け方法についても実施の形態1とかわるところはなく、図7に示すように、通気フィルタ21が、開口部8を覆うことができる形状をしており、導電性物質6が付着した撥水性プラスチック多孔質膜2の一方の面の周縁に配置された導電粘着層5をさらに含んでいれば、通気フィルタ21について、筐体7への短絡および取り付けが容易となり、筐体7の開口部8に電磁波に対する効果的なシールドを付与できる。   The method of attaching the ventilation filter 21 to the housing 7 is not different from that of the first embodiment. As shown in FIG. 7, the ventilation filter 21 has a shape that can cover the opening 8 and is electrically conductive. If the conductive adhesive layer 5 disposed on the periphery of one surface of the water-repellent plastic porous membrane 2 to which the conductive material 6 is attached is further included, the ventilation filter 21 can be easily short-circuited and attached to the housing 7. An effective shield against electromagnetic waves can be imparted to the opening 8 of the housing 7.

以下に、実施例により本発明の通気フィルタの一例をより具体的に説明する。   Hereinafter, an example of the ventilation filter of the present invention will be described more specifically with reference to examples.

PTFE多孔質膜(厚さ15μm、気孔率90%、平均孔径5μm、フラジール通気度7cc/cm2・sec)と、芯鞘構造の不織布(目付け量30g/m2、厚さ0.1mm、芯成分PP、鞘成分PE)とを、1対の熱ロール(ロール温度200℃)により熱ラミネートした。次に、芯成分をポリエステル、鞘成分をニッケルとする金属メッキ繊維からなる不織布(セーレン社製、Si−80−301、目付け量45g/m2、厚さ0.07mm)にアクリル系感圧接着剤を点状に数箇所塗布し、金属メッキ繊維からなる不織布とポリオレフィン不織布が積層されたPTFE多孔質膜とを貼り合せて、通気フィルタAを得た。この通気フィルタAを所定の形状に打ち抜き、金属メッキ繊維からなる不織布の一方の面の周縁に、ドーナツ状に加工された導電性感圧接着剤(日本インク社製、#8350AD)を貼り付けて、導電性粘着層を形成した。 PTFE porous membrane (thickness 15 μm, porosity 90%, average pore diameter 5 μm, fragile air permeability 7 cc / cm 2 · sec) and core-sheathed nonwoven fabric (weight per unit area 30 g / m 2 , thickness 0.1 mm, core The component PP and the sheath component PE) were heat-laminated by a pair of heat rolls (roll temperature 200 ° C.). Next, an acrylic pressure-sensitive adhesive is bonded to a non-woven fabric (made by Seiren Co., Si-80-301, basis weight 45 g / m 2 , thickness 0.07 mm) made of a metal-plated fiber having a core component of polyester and a sheath component of nickel. The agent was applied in several spots, and a non-woven fabric made of metal-plated fibers and a PTFE porous membrane laminated with a polyolefin non-woven fabric were bonded together to obtain a ventilation filter A. This vent filter A is punched into a predetermined shape, and a conductive pressure-sensitive adhesive processed into a donut shape (manufactured by Nippon Ink Co., Ltd., # 8350AD) is attached to the periphery of one surface of a nonwoven fabric made of metal-plated fibers A conductive adhesive layer was formed.

PTFE多孔質膜(厚さ15μm、気孔率90%、平均孔径5μm、フラジール通気度7cc/cm2・sec)と、芯鞘構造の不織布(目付量30g/m2、厚さ0.1mm、芯成分PP、鞘成分PE)とを、1対の熱ロール(ロール温度200℃)により熱ラミネートした。次に、エタノール1リットルに、高導電性カーボンブラック(ライオン社製、「ケッチェンブラックEC」、比表面積1000m2/g)20gを分散した分散液を用意した。この分散液を金属製の超音波加振槽に入れ、28kHzの超音波振動を与えながら、芯鞘構造の不織布がラミネートされたPTFE多孔質膜を1分間浸漬し、分散液から引き上げた後100℃の雰囲気中で5分間乾燥して、通気フィルタBを得た。カーボンブラックの付着量は、芯鞘構造の不織布とPTFE多孔質膜とからなる積層体の重量の25重量%であった。 PTFE porous membrane (thickness 15 μm, porosity 90%, average pore diameter 5 μm, fragile air permeability 7 cc / cm 2 · sec) and core-sheathed nonwoven fabric (weight per unit area 30 g / m 2 , thickness 0.1 mm, core The component PP and the sheath component PE) were heat laminated with a pair of hot rolls (roll temperature 200 ° C.). Next, a dispersion liquid in which 20 g of highly conductive carbon black (manufactured by Lion Corporation, “Ketjen Black EC”, specific surface area 1000 m 2 / g) was dispersed in 1 liter of ethanol was prepared. The dispersion was placed in a metal ultrasonic vibration vessel, and a porous PTFE membrane laminated with a core-sheath nonwoven fabric was immersed for 1 minute while applying ultrasonic vibration of 28 kHz, and then pulled up from the dispersion. The ventilation filter B was obtained by drying in an atmosphere of 5 ° C. for 5 minutes. The amount of carbon black attached was 25% by weight of the weight of the laminate composed of the core-sheath nonwoven fabric and the PTFE porous membrane.

「ユニダインTG−725」(ダイキン工業社製)をトルエンで希釈した固形分5重量%の撥水撥油処理剤に、実施例2で得た通気フィルタBを5秒間浸漬し、取出した後130℃で3分間加熱して、撥水撥油処理された通気フィルタCを得た。通気フィルタCを所定の形状に打ち抜き、金属メッキ繊維からなる不織布の一方の面の周縁に、ドーナツ状に加工された導電性感圧接着剤(日本インク社製、#8350AD)を貼り付けて、導電性粘着層を形成した。   The air filter B obtained in Example 2 was immersed for 5 seconds in a water / oil repellent with a solid content of 5% by weight obtained by diluting “Unidyne TG-725” (manufactured by Daikin Industries) with toluene. Heating at 3 ° C. for 3 minutes yielded a breathable filter C that had been treated to be water and oil repellent. The ventilation filter C is punched into a predetermined shape, and a conductive pressure-sensitive adhesive (Nippon Ink Co., Ltd., # 8350AD) processed into a donut shape is attached to the periphery of one surface of a nonwoven fabric made of metal-plated fibers to conduct An adhesive layer was formed.

(比較例1)
金属メッキ繊維からなる不織布を設けないこと以外は実施例1と同様にして通気フィルタDを得た。
(Comparative Example 1)
A ventilation filter D was obtained in the same manner as in Example 1 except that a non-woven fabric made of metal-plated fibers was not provided.

(比較例2)
芯成分をポリエステル、鞘成分をニッケルとする金属メッキ繊維からなる不織布(セーレン社製、Si−80−301)を、「ユニダインTG−725」(ダイキン工業社製)をトルエンで希釈した固形分5重量%の撥水撥油処理剤に5秒間浸漬し、取出した後130℃で3分間加熱して、撥水撥油処理された通気フィルタEを得た。
(Comparative Example 2)
Solid content 5 obtained by diluting “Unidyne TG-725” (manufactured by Daikin Kogyo Co., Ltd.) with toluene, a non-woven fabric (Seren Co., Si-80-301) made of a metal-plated fiber whose core component is polyester and whose sheath component is nickel. It was immersed in a weight% water / oil repellent treatment agent for 5 seconds, taken out, and then heated at 130 ° C. for 3 minutes to obtain a breathable filter E subjected to water / oil repellent treatment.

通気フィルタA〜Eについて、下記に示す方法により電磁波シールド性、防水性、通気性および通音性を調べ、その結果を表1に示した。   The ventilation filters A to E were examined for electromagnetic wave shielding properties, waterproof properties, breathability and sound permeability by the methods shown below, and the results are shown in Table 1.

[電磁波シールド性] 電磁波シールド性は、KEC法により評価した。KEC法とは、社団法人関西電子工業振興センターの生駒電波測定所で開発された方法であり、近接界における材料のシールド効果を測定する方法である。測定装置にはスペクトラムアナライザーを用い、周波数1MHz〜1000MHzまで連続掃引して電界値の減衰量(dB)の測定を行った。減衰量が10dB以上である場合は良(○)、10dB未満である場合は不良(×)と判断した。   [Electromagnetic wave shielding property] The electromagnetic wave shielding property was evaluated by the KEC method. The KEC method is a method developed at the Ikoma Radio Measurement Station of the Kansai Electronics Industry Promotion Center, which measures the shielding effect of materials in the near field. A spectrum analyzer was used as a measuring apparatus, and the electric field value attenuation (dB) was measured by continuously sweeping the frequency from 1 MHz to 1000 MHz. When the attenuation was 10 dB or more, it was judged as good (◯), and when it was less than 10 dB, it was judged as bad (x).

[防水性] 防水性は、ステンレスホルダーにセットされた通気フィルタに98kPaの水圧(深度1mの水圧の10倍に相当する)をかけ、水漏れが発生する時間を測定した。水漏れが2時間発生しない場合は、水漏れなし(○)と判断した。   [Waterproofness] The waterproofness was measured by applying a water pressure of 98 kPa (corresponding to 10 times the water pressure at a depth of 1 m) to a ventilation filter set in a stainless steel holder, and measuring the time when water leakage occurred. When no water leak occurred for 2 hours, it was judged that there was no water leak (O).

[通気性] JIS L 1096(6.27.A法)に従い、フラジール試験機(東洋精機製作所製)を用いて測定した。フラジール通気度が2cc/cm2・sec以上である場合は良(○)と、通気度が2cc/cm2・sec未満である場合は不良(×)と判断した。 [Breathability] Measured according to JIS L 1096 (6.27.A method) using a Frazier tester (manufactured by Toyo Seiki Seisakusho). When the fragile air permeability was 2 cc / cm 2 · sec or more, it was judged as good (◯), and when the air permeability was less than 2 cc / cm 2 · sec, it was judged as poor (x).

[通音性] 通音性は、図8に示した通音性測定室を用いて次の手順で測定した。通音性測定室は、残響室9および無響室10からなり、残響室9と無響室10との間には開口部11(280×280mm)を設けた。開口部11には、PTFE延伸多孔質膜面が残響室9側となるように通気フィルタのサンプル12を張設した。残響室9にはスピーカー41とマイクロホン42が設けられており、残響室9を250〜10000Hzの全周波数帯域で一様なホワイトノイズで飽和した。各周波数帯域での音圧は90dBであった。無響室10にはサンプル7の膜面から70mmの位置にマイクロホン51が設けられており、本実施例においては4000Hzにおける音圧を測定した。4000Hzとは、人間の耳が最も良好な感度を有する周波数である。音圧の表記単位はデシベル(dB)である。無響室10における音圧の測定結果から得られる音圧の損失量を、音響透過損失(以下、TLと記す。)を用いて示した。TLは以下の式より求められる。TLが小さいほど、通気性が高く通気フィルタとして性能が良いことになる。TLが5dB以下である場合は良(○)と、TLが5dBより大きい場合は不良(×)と判断した。   [Sound permeability] The sound permeability was measured by the following procedure using the sound permeability measurement chamber shown in FIG. The sound-transmitting measurement chamber is composed of a reverberation chamber 9 and an anechoic chamber 10, and an opening 11 (280 × 280 mm) is provided between the reverberation chamber 9 and the anechoic chamber 10. A sample 12 of a ventilation filter was stretched in the opening 11 so that the PTFE stretched porous membrane surface was on the reverberation chamber 9 side. The reverberation chamber 9 is provided with a speaker 41 and a microphone 42. The reverberation chamber 9 was saturated with uniform white noise in the entire frequency band of 250 to 10000 Hz. The sound pressure in each frequency band was 90 dB. The anechoic chamber 10 is provided with a microphone 51 at a position 70 mm from the film surface of the sample 7. In this embodiment, the sound pressure at 4000 Hz was measured. 4000 Hz is a frequency at which the human ear has the best sensitivity. The notation unit of sound pressure is decibel (dB). The amount of sound pressure loss obtained from the sound pressure measurement result in the anechoic chamber 10 is shown using sound transmission loss (hereinafter referred to as TL). TL is obtained from the following equation. The smaller the TL, the higher the air permeability and the better the performance as a ventilation filter. When TL was 5 dB or less, it was judged as good (◯), and when TL was larger than 5 dB, it was judged as bad (×).

TL=(開口部開放時の音圧)−(開口部にサンプルを張設した時の音圧)   TL = (Sound pressure when opening is opened) − (Sound pressure when a sample is stretched over the opening)

Figure 2005334758
Figure 2005334758

表1に示すように、少なくとも撥水樹脂多孔質膜と導電性通気層とを含む通気フィルタ、または導電性物質が付着した撥水樹脂多孔質膜を含む通気フィルタでは、防水性、通気性または通音性、および電磁波シールド性が良好であることが確認された。   As shown in Table 1, in a ventilation filter including at least a water repellent resin porous membrane and a conductive ventilation layer, or a ventilation filter including a water repellent resin porous membrane to which a conductive substance is adhered, It was confirmed that sound permeability and electromagnetic shielding properties were good.

本発明の通気フィルタは、防水性、通気性または通音性、および電磁波シールド性を備えているので、通気フィルタとして有用である。   The ventilation filter of the present invention is useful as a ventilation filter because it is waterproof, breathable or sound permeable, and has electromagnetic shielding properties.

本発明の通気フィルタの一例を示す断面図Sectional drawing which shows an example of the ventilation filter of this invention 導電性通気層として用いられるネットを説明する図The figure explaining the net used as a conductive ventilation layer 本発明の通気フィルタの他の例を示す断面図Sectional drawing which shows the other example of the ventilation filter of this invention 本発明の通気フィルタの他の例が筐体の開口部に取り付けられた状態を説明する断面図Sectional drawing explaining the state in which the other example of the ventilation filter of this invention was attached to the opening part of the housing | casing 本発明の通気フィルタの他の例を示す断面図Sectional drawing which shows the other example of the ventilation filter of this invention 本発明の通気フィルタの他の例を示す断面図Sectional drawing which shows the other example of the ventilation filter of this invention 本発明の通気フィルタの他の例が筐体の開口部に取り付けられた状態を説明する断面図Sectional drawing explaining the state in which the other example of the ventilation filter of this invention was attached to the opening part of the housing | casing 本発明の実施例において、通気フィルタの通音性を測定する方法を模式的に説明する図The figure which illustrates typically the method to measure the sound permeability of a ventilation filter in the Example of this invention.

符号の説明Explanation of symbols

1、21 通気フィルタ
2 撥水樹脂多孔質膜
3 導電性通気層
3a 開口部
4 通気性支持層
5 導電性粘着層
6 導電性物質
7 筐体
8 筐体の開口部
DESCRIPTION OF SYMBOLS 1,21 Ventilation filter 2 Water repellent resin porous film 3 Conductive ventilation layer 3a Opening 4 Breathable support layer 5 Conductive adhesive layer 6 Conductive substance 7 Housing 8 Opening of housing

Claims (11)

少なくとも1層の撥水樹脂多孔質膜を含む積層体であって、前記積層体が導電性通気層を含むことを特徴とする通気フィルタ。   A ventilation filter comprising at least one water-repellent resin porous membrane, wherein the laminate includes a conductive ventilation layer. 前記積層体の一方の面が、前記導電性通気層の一方の面から形成された請求項1に記載の通気フィルタ。   The ventilation filter according to claim 1, wherein one surface of the laminate is formed from one surface of the conductive ventilation layer. 前記導電性通気層の前記一方の面の周縁に、導電性粘着層が形成された請求項2に記載の通気フィルタ。   The ventilation filter according to claim 2, wherein a conductive adhesive layer is formed on a peripheral edge of the one surface of the conductive ventilation layer. 前記導電性通気層が、金属、カーボンブラック、およびグラファイトからなる群から選ばれる少なくとも1種の導電体を含む請求項1〜3のいずれかの項に記載の通気フィルタ。   The ventilation filter according to any one of claims 1 to 3, wherein the conductive ventilation layer includes at least one conductor selected from the group consisting of metal, carbon black, and graphite. 前記導電性通気層が、不織布、ネット、または織布である請求項1〜4のいずれかの項に記載の通気フィルタ。   The ventilation filter according to any one of claims 1 to 4, wherein the conductive ventilation layer is a nonwoven fabric, a net, or a woven fabric. 少なくとも1層の撥水樹脂多孔質膜を含む通気フィルタであって、前記少なくとも1層の撥水樹脂多孔質膜のうちの少なくとも1層の撥水樹脂多孔質膜に導電性物質が付着していることを特徴とする通気フィルタ。   A ventilation filter including at least one water-repellent resin porous membrane, wherein a conductive substance adheres to at least one water-repellent resin porous membrane of the at least one water-repellent resin porous membrane. Ventilation filter characterized by being. 一方の面が、前記導電性物質が付着した前記撥水樹脂多孔質膜の一方の面から形成されており、当該撥水樹脂多孔質膜の少なくとも前記一方の面および孔内に前記導電性物質が付着した請求項6に記載の通気フィルタ。   One surface is formed from one surface of the water-repellent resin porous membrane to which the conductive material is adhered, and the conductive material is present in at least the one surface and the hole of the water-repellent resin porous membrane. The ventilation filter according to claim 6, to which is attached. 前記撥水樹脂多孔質膜の前記一方の面の周縁に、導電性粘着層が形成された請求項7に記載の通気フィルタ。   The ventilation filter according to claim 7, wherein a conductive adhesive layer is formed on a peripheral edge of the one surface of the water-repellent resin porous membrane. 前記導電性物質が、金属、カーボンブラック、およびグラファイトからなる群から選ばれる少なくともと1種の導電体である請求項6〜8のいずれかの項に記載の通気フィルタ。   The ventilation filter according to any one of claims 6 to 8, wherein the conductive substance is at least one kind of conductor selected from the group consisting of metal, carbon black, and graphite. 前記撥水樹脂多孔質膜に積層された通気性支持層をさらに含む請求項1〜9のいずれかの項に記載の通気フィルタ。   The ventilation filter according to any one of claims 1 to 9, further comprising a breathable support layer laminated on the water-repellent resin porous membrane. 前記撥水樹脂多孔質膜が、ポリテトラフルオロエチレン多孔質膜を含む請求項1〜10のいずれかの項に記載の通気フィルタ。   The ventilation filter according to any one of claims 1 to 10, wherein the water-repellent resin porous membrane includes a polytetrafluoroethylene porous membrane.
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