JP2004130248A - Ultrasonic cleaner, vibration plate for ultrasonic cleaner, and ultrasonic wave application apparatus for ultrasonic cleaner - Google Patents

Ultrasonic cleaner, vibration plate for ultrasonic cleaner, and ultrasonic wave application apparatus for ultrasonic cleaner Download PDF

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JP2004130248A
JP2004130248A JP2002298592A JP2002298592A JP2004130248A JP 2004130248 A JP2004130248 A JP 2004130248A JP 2002298592 A JP2002298592 A JP 2002298592A JP 2002298592 A JP2002298592 A JP 2002298592A JP 2004130248 A JP2004130248 A JP 2004130248A
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ultrasonic
cleaning
cleaning liquid
vibrator
cleaning tank
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Kazumasa Onishi
大西 一正
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a ultrasonic cleaner with a high washing power and ability of carrying out washing evenly. <P>SOLUTION: The ultrasonic cleaner comprises one or more ultrasonic vibrators whose ultrasonic radiation faces are fixed in a bottom or side face of the outer side of a washing tank and flat plate type fiber-reinforced resin materials each of which has a larger surface area than the surface area of the ultrasonic radiation face of one ultrasonic vibrator or the total surface area of the ultrasonic radiation faces of two or more ultrasonic vibrators and each of which is composed of binder resin and a plurality of highly elastic fibers arranged in the binder resin parallel to the flat plate faces. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、超音波洗浄器、超音波洗浄器用の振動板、および超音波洗浄器用の超音波付与装置に関する。
【0002】
【従来の技術】
超音波洗浄器は、眼鏡や指輪などの日用品、カメラや時計に用いる精密機械部品、そして半導体素子の作製に用いるウエハなどの様々な物品の洗浄に用いられている。超音波洗浄器は、容器(洗浄槽)に入れた洗浄液中に洗浄する物品を浸し、そして洗浄液に超音波を付与することによって、物品に付着した汚れを取り除く器具である。超音波洗浄器は、洗浄液を入れる洗浄槽と、洗浄液に超音波を付与するための超音波振動子などから構成されている。洗浄液としては、物品に付着した汚れの種類により、水、有機溶媒、水と有機溶媒との混合溶媒、酸性溶液、もしくはアルカリ性溶液などが用いられる。
【0003】
図1〜図3は、従来の超音波洗浄器の代表的な構成を示す断面図である。図1の超音波洗浄器は、洗浄槽タイプと呼ばれており、洗浄液11を入れる洗浄槽12の底面に、超音波振動子13が固定された構成を有している。図2の超音波洗浄器は、振動板タイプと呼ばれており、洗浄槽22の底部に、振動板部材25に超音波振動子23が固定された振動板が備えられた構成を有している。洗浄槽22の底部には、洗浄槽から洗浄液11が漏れ出さないようにパッキン25が備えられている。振動板は、ボルト27やナット28などの固定具により洗浄槽に固定されている。図3の超音波洗浄器は、投込振動子タイプと呼ばれており、洗浄槽32の内部に、水密容器35の内側面に超音波振動子33が固定された超音波付与装置が配置された構成を有している。また、図1〜図3に示す超音波洗浄器の他にも、洗浄槽の側面に超音波振動子を付設するなど、様々な構成の超音波洗浄器が知られている(例えば、非特許文献1、p.228−232参照)。
【0004】
超音波洗浄器においては、一般に、以下の三つの作用によって洗浄が行われていると推定されている(非特許文献1、p223−224参照)。
【0005】
(1)キャビテーション
洗浄液に超音波が付与されると、超音波振動により、洗浄液には減圧力と加圧力が繰り返し加わる。この減圧力によって、洗浄液中に気泡が生じる(この現象は、キャビテーションと呼ばれている)。この気泡が加圧力により消滅する際に生じる衝撃波によって、物品に付着している汚れが取り除かれる。超音波の音圧は、周波数が高くなるほど小さくなる。従って、洗浄液に付与する超音波の周波数が低いほど、キャビテーションに基づく洗浄力は強くなる。他方、超音波の周波数が低いと、洗浄する物品の表面に損傷を与える場合がある。
【0006】
(2)加速度
洗浄液に超音波が付与されると、超音波振動により洗浄液が振動する。この洗浄液の振動の加速度の力によって、物品に付着している汚れが取り除かれる。従って、洗浄液に付与する超音波の周波数が高いほど、加速度による洗浄力は強くなる。
【0007】
(3)直進流
洗浄液に超音波が付与されると、超音波の伝わる方向に洗浄液の流れが生じる。この洗浄液の流れによって、物品表面の近くにある洗浄液が攪拌され、物品に付着している汚れが取り除かれる。
【0008】
以下、一般に広く用いられている洗浄槽タイプの超音波洗浄器(図1参照)を例として、従来の超音波洗浄器について説明する。図1の超音波洗浄器においては、洗浄槽12に入れた洗浄液11に十分な超音波を伝えるために、洗浄槽の底面には、一個もしくは二個以上の超音波振動子13が付設される。
【0009】
超音波洗浄器においては、物品の洗浄ムラを少なくするため、即ち、超音波を洗浄液に均一に伝えるために、超音波振動子13によって洗浄槽12の底面を均一にピストン振動(上下方向に振動)させることが好ましい。また、超音波洗浄器の洗浄力を強くするため、即ち、超音波振動子から放射される超音波を、効率良く洗浄液に伝えるためにも、超音波振動子13によって洗浄槽12の底面を均一にピストン振動させることが好ましい。洗浄槽12の底面を均一にピストン振動させると、超音波振動子から放射され、洗浄槽の底板を伝わる超音波に、洗浄槽底面に沿った方向の振動(超音波)成分が発生しにくくなり、好ましい。すなわち、このような振動成分が存在すると、超音波が効率良く洗浄液に伝わりにくくなるからである。従って、洗浄槽12の底面には、超音波振動子をなるべく密集させて固定することが好ましい。実用的には、超音波洗浄器の製造コストを考え、洗浄槽12の底面には、適当な個数の超音波振動子が固定される(非特許文献2、p247−248参照)。
【0010】
超音波振動子から放射された超音波を、効率良く洗浄液に伝えるために、洗浄槽と超音波振動子との間に音響整合層が付設された超音波洗浄器が知られている(例えば、特許文献1、第1図参照)。音響整合層を付設することにより、超音波振動子から放射された超音波の洗浄槽底面における反射が抑えられ、超音波が効率良く洗浄液に伝わりやすい。
【0011】
また、超音波振動子の超音波放射面に繊維強化樹脂材を付設することにより、繊維強化樹脂材中の高弾性繊維に垂直な方向に伝わる超音波を強く発生できることが知られている(例えば、特許文献2参照)。特許文献2においては、超音波放射面に繊維強化樹脂材を備えた超音波振動子を、超音波洗浄器に用いることが示唆されている。
【0012】
従来の超音波洗浄器は、洗浄に用いる超音波の周波数により、周波数が20〜50kHzの超音波を用いた超音波洗浄器(以下、低周波タイプの超音波洗浄器と記載する)と、周波数が数MHzの超音波を用いた超音波洗浄器(以下、高周波タイプの超音波洗浄器と記載する)とに大別される。
【0013】
低周波タイプの超音波洗浄器においては、主にキャビテーションによる洗浄が主体的であり、洗浄力が強い反面、洗浄する物品の表面に損傷を与えやすいことが知られている。他方、高周波タイプの超音波洗浄器においては、キャビテーションは殆ど発生せず、主に洗浄液の加速度の力による洗浄が主体的であり、洗浄力は低周波タイプの洗浄器より劣るものの、洗浄する物品の表面に損傷を与えにくく、微細な汚れを除去しやすいことが知られている。
【0014】
従って、一般的には、低周波タイプの超音波洗浄器は、大きな汚れを取り除く必要がある眼鏡などの日用品の洗浄に用いられ、高周波タイプの超音波洗浄器は、物品表面に損傷を与えずに、微細な汚れを取り除く必要がある半導体素子作製用のウエハや精密機械部品の洗浄に用いられている。
【0015】
このような低周波タイプと高周波タイプの超音波洗浄器に用いられる周波数の間の値の周波数の超音波を用いた、コンタクトレンズの洗浄に適した超音波洗浄器が知られている(例えば、特許文献3参照)。この超音波洗浄器においては、コンタクトレンズに付着した微細な汚れを取り除くために、周波数が60〜800kHzの超音波が用いられている。
【0016】
【非特許文献1】
二橋裕之,「最新強力超音波技術」,初版,株式会社総合技術センター,昭和62年9月,p.223−224,p.228−232
【非特許文献2】
(社)日本電子機械工業会,「超音波工学」,初版,株式会社コロナ社,1993年1月,p.247−248
【特許文献1】
特開2001−29907号公報(第1図)
【特許文献2】
特開平7−284198号公報
【特許文献3】
特開昭59−183872号公報
【0017】
【発明が解決しようとする課題】
従来の超音波洗浄器においては、音響整合層や、超音波放射面に繊維強化樹脂材を備えた超音波振動子を用いることにより、超音波を効率良く洗浄液に伝えて洗浄力を高める工夫がなされているものの、洗浄槽の底面を均一にピストン振動させて、洗浄ムラを少なくしたり、あるいは洗浄力を強くするためには、洗浄槽の底面に多くの個数の超音波振動子の付設が必要となる問題がある。
【0018】
別の問題として、従来の超音波洗浄器によって、物品を、その表面に損傷を与えずに、且つある程度の強さの洗浄力で洗浄することが難しいことが挙げられる。半導体素子作製用のウエハや精密機械部品においては、その用途(例えば、ウエハの場合には、ウエハに形成する半導体素子の集積度が低い場合など)によっては、表面に損傷を与えずに、比較的大きなゴミの除去が必要とされる場合がある。このような場合には、超音波の周波数を、低周波タイプと高周波タイプの超音波洗浄器に用いられている周波数の間の値(80〜500kHz程度)に設定することが好ましいと考えられる。ところが、上記コンタクトレンズ用の超音波洗浄器のように、超音波の周波数を高く設定するのみでは、周波数が高くなるにつれてキャビテーションが生じにくくなり、前記の半導体素子作製用のウエハや精密部品に対する十分な洗浄力を得ることが難しいと考えられる。
【0019】
超音波洗浄器において、超音波振動子の個数をなるべく増加させずに、超音波を効率良く洗浄液に伝えることができれば、物品表面に損傷を与えにくい周波数(80〜500kHz程度)の超音波を用い、そしてある程度の強い洗浄力を備えた実用的な超音波洗浄器が実現できると考えられる。
【0020】
本発明の目的は、超音波振動子の個数をなるべく増加させずに、洗浄ムラが少なく、そして洗浄力の強い超音波洗浄器を提供することにある。
本発明の目的はまた、洗浄する物品の表面に与える損傷が少なく、そして洗浄力の強い超音波洗浄器を提供することにもある。
【0021】
【課題を解決するための手段】
本発明者は、超音波洗浄器の洗浄槽底面に固定する超音波振動子の個数や配置、さらには洗浄槽の形状などを工夫することにより、少ない個数の超音波振動子により洗浄槽の底面を均一にピストン振動させ、洗浄ムラを少なくしたり、洗浄力を強くすることについて検討したが、十分な結果を得ることができなかった。このため、本発明者はさらに、超音波振動子の個数や配置などを工夫するのではなく、超音波振動子から放射された超音波が洗浄槽底板を伝わるときに、底板の底面に沿った方向の振動の発生を抑えることにより、洗浄槽底面を均一にピストン振動させることについて検討した。その結果、洗浄槽の底板に繊維強化樹脂材を付設することにより、底板の底面に沿った方向の振動の発生が抑えられ、超音波振動子の個数を増加させなくても、洗浄ムラが少なく、そして洗浄力の強い超音波洗浄器が提供できることを見出した。
【0022】
本発明は、洗浄槽の外側面の底面もしくは側面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器において、前記超音波振動子の固定位置と対応する洗浄槽の外側面もしくは内側面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及びバインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器にある。
【0023】
本発明はまた、上記本発明の超音波洗浄器の洗浄槽に洗浄液を入れ、次いで洗浄液に物品を浸し、そして前記超音波洗浄器の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を洗浄することを特徴とする超音波洗浄方法にもある。
【0024】
本発明はまた、振動板部材の下面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器用の振動板において、前記超音波振動子の固定位置と対応する振動板部材の上面もしくは下面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及びバインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器用の振動板にもある。
【0025】
本発明はまた、洗浄槽にその底板として上記本発明の振動板を固定したのちに洗浄液を入れ、次いで洗浄液に物品を浸し、そして前記振動板の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を洗浄することを特徴とする超音波洗浄方法にもある。
【0026】
本発明はまた、水密容器の内側面の少なくとも一面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器用の超音波付与装置において、前記超音波振動子の固定位置と対応する水密容器の外側面もしくは内側面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及びバインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器用の超音波付与装置にもある。
【0027】
本発明はまた、洗浄槽に洗浄液と上記本発明の超音波付与装置を入れ、次いで洗浄液に物品を浸し、そして前記超音波付与装置の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を洗浄することを特徴とする超音波洗浄方法にもある。
【0028】
【発明の実施の形態】
本発明の超音波洗浄器を、添付の図面を用いて説明する。図4は、本発明に従う超音波洗浄器の一例の構成を示す断面図であり、そして図5は、図4の超音波洗浄器の底面図である。図4と図5に示す超音波洗浄器は、洗浄液41を入れる洗浄槽42の底面に、九個の超音波振動子43をその超音波放射面にて固定してなる超音波洗浄器において、超音波振動子43の固定位置と対応する洗浄槽42の外側面に、前記九個の超音波振動子43の超音波放射面の合計面積よりも大きな面積の平面を有する平板状の繊維強化樹脂材44が備えられた構成を有している。
【0029】
平板状の繊維強化樹脂材44は、バインダ樹脂と、バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維(図示は略する)とから構成されている。このような構成の繊維強化樹脂材44は、高弾性繊維の長さ方向に沿った方向、即ち平板状繊維強化樹脂材の平面に沿った方向に伸縮し難い。このような繊維強化樹脂材44の付設により、洗浄槽42の底板はその底面に沿った方向に伸縮しにくくなり、超音波振動子43から放射された超音波が洗浄層42の底板を伝わるときに、底板の底面に沿った振動の発生が抑えられる。従って、超音波振動子の個数を増加させなくとも、洗浄槽底面の均一なピストン振動が促され、超音波洗浄器の洗浄ムラが少なくなり、そして洗浄力も強くなる。
【0030】
なお、洗浄液を伝わる超音波の波長に対応して、洗浄槽に入れた洗浄液には、超音波振動子の超音波放射面に垂直な方向に音圧の周期的な変動を生じ、この音圧変動と対応した周期的な洗浄ムラが生じることが知られている。このような音圧変動に対応する周期的な洗浄ムラについては、超音波振動子の配置や、超音波振動子に印加する交流電圧を変調するなどの多くの解決方法が知られている(例えば、非特許文献1,p231,p236−237参照)。本明細書においては、このような超音波振動子の超音波放射面に垂直な方向(図4の超音波洗浄器の場合には、洗浄槽の深さ方向)における洗浄ムラについては、記載を略する。本発明の超音波洗浄器において、このような音圧変動に対応する周期的な洗浄ムラが生じる問題については、前記非特許分文献1の記載に基づいて、同様に解決することができる。
【0031】
洗浄槽42の底面を均一にピストン振動させるためには、繊維強化樹脂材44の平面の面積を、なるべく洗浄槽底面と一致する程度まで大きくすることが好ましい。特許文献2に記載されている、超音波放射面にその面と同じ面積の平面を有する繊維強化樹脂材を備えた超音波振動子を洗浄槽に付設するのみでは、洗浄槽底板の底面を均一にピストン振動させる効果は小さい。本発明においては、少なくとも超音波振動子の超音波放射面よりも大きな面積の平面を有する繊維強化樹脂材を洗浄槽に付設する必要がある。
【0032】
洗浄する物品が大きい場合には、洗浄槽は大型となり、その底面の面積も大きくなる。大型の洗浄槽の底面に繊維強化樹脂材を付設する場合には、洗浄槽の底面に沿って複数個の繊維強化樹脂材を付設しても良い。複数個の繊維強化樹脂材は、それらが互いに間隔を空けた状態で付設されていても良い。
【0033】
繊維強化樹脂材の厚みは、超音波振動子から放射された超音波の洗浄槽底面における反射を抑えるために、繊維強化樹脂材をその平面に垂直な方向に伝わる超音波の波長の実質的に1/4の厚みであることが好ましい。また、繊維強化樹脂材の厚みは、繊維強化樹脂材中における超音波の減衰が大きい場合には、前記の波長の1/4の厚みよりもさらに薄くすることが好ましい。
【0034】
繊維強化樹脂材の複数本の高弾性繊維は、繊維強化樹脂材の平面と平行に整列配置されていれば、その配置に特に制限はない。複数本の高弾性繊維は、繊維強化樹脂材の平面と平行な一方向に整列配置していることが好ましく、前記平面と平行で、そして複数本の高弾性繊維が互いに直交するような二方向に整列配置していることがさらに好ましい。
【0035】
バインダ樹脂の例としては、エポキシ樹脂、ポリアミド樹脂、ポリイミド樹脂、PEEK(ポリエーテルエーテルケトン)樹脂、フェノール樹脂、不飽和ポリエステル樹脂、ポリアミド樹脂、ポリカーボネート樹脂、およびポリアミドイミド樹脂などが挙げられる。高弾性繊維の例としては、炭素繊維、炭化ケイ素繊維、ポリアミド繊維、およびアラミド繊維などが挙げられる。
【0036】
図4の超音波洗浄器においては、各々の超音波振動子43としては、二個の圧電振動子45a及び45bを、上部金属部材46aと下部金属部材46bとで挟んだ状態でボルト締めした構成のランジュバン型振動子が用いられている。図4の断面図において、上部金属部材46aと下部金属部材46bを締め付けるボルトとナットの記載は省略した。各々の圧電振動子の上下面に備えられた電極層に電気的エネルギーを供給して、各々の圧電振動子を振動させると、超音波振動子43の上部金属部材46aの頂面から超音波が放射される。
【0037】
超音波振動子の例としては、電歪振動子および磁歪振動子が挙げられる。電歪振動子の例としては、圧電振動子、および圧電振動子を一対の金属部材でボルト締めした構成のランジュバン型振動子が挙げられる。磁歪振動子の例としては、金属磁歪振動子、およびフェライト振動子が挙げられる。超音波振動子としては、その構成が簡単であることから、電歪振動子を用いることが好ましい。
【0038】
洗浄槽42は、一般に、洗浄液に対する耐食性を考慮して、ステンレススチールなどの金属材料から形成される。洗浄液として酸性溶液もしくはアルカリ性溶液のような腐食性の高い液体を用いる場合、洗浄槽を、樹脂(例:塩化ビニル樹脂、フッ素樹脂)、ガラス、もしくはセラミックスなどから形成することが好ましい。また、洗浄槽を金属材料から形成する場合、洗浄槽と繊維強化樹脂材とが電気的に導通することを防止するために、洗浄槽に絶縁材を介して繊維強化樹脂材を付設しても良い。絶縁材の例としては、樹脂材料やガラスエポキシ材が挙げられる。絶縁材の厚みは、1mm以下、好ましくは0.5mm以下であることが好ましい。
【0039】
次に、図4の超音波洗浄器を用いた物品の超音波洗浄方法について説明する。まず、超音波洗浄器の洗浄槽42に洗浄液41を入れ、次いで洗浄液に物品(図示は略する)を浸し、そして超音波洗浄器の超音波振動子43により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を超音波洗浄する。このような周波数の超音波を用いることにより、物品表面に与える損傷を抑え、そして強い洗浄力で物品を超音波洗浄することができる。
【0040】
図6は、本発明に従う超音波洗浄器の別の一例の構成を示す断面図である。図6の超音波洗浄器の構成は、繊維強化樹脂材44が洗浄槽42の内側面に備えられていること以外は、図4の超音波洗浄器と同様である。このように、洗浄槽42の内側面に繊維強化樹脂材44を付設することによっても、洗浄槽底板の底面に沿った方向の振動の発生を抑えることができる。
【0041】
図7は、本発明に従う超音波洗浄器用の振動板の一例の構成と、その使用の態様を示す断面図である。図7の超音波洗浄器用の振動板は、振動板部材75の下面に、九個の超音波振動子(圧電振動子)73をその超音波放射面にて固定してなる超音波洗浄器用の振動板において、前記超音波振動子の固定位置と対応する振動板部材の下面に、前記九個の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有する平板状の繊維強化樹脂材74が備えられた構成を有している。平板状の繊維強化樹脂材74は、バインダ樹脂と、バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維とから構成されている。
【0042】
繊維強化樹脂材74の付設により、図4の超音波洗浄器の場合と同様に、振動板部材75の平面に沿った方向の振動の発生が抑えられ、洗浄層72に入れた洗浄液に均一に、そして効率良く超音波を伝えることができる。図7の超音波洗浄器は、超音波振動子73を備えた振動板が交換可能であるために、超音波洗浄器のメンテナンスが容易である利点を有している。
【0043】
次に、図7の超音波洗浄器を用いた物品の超音波洗浄方法について説明する。まず、洗浄槽72にその底板として振動板を固定したのちに洗浄液41を入れ、次いで洗浄液に物品を浸し、そして振動板の超音波振動子73により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を超音波洗浄する。このような周波数の超音波を用いることにより、物品表面に与える損傷を抑え、そして強い洗浄力で物品を超音波洗浄することができる。
【0044】
図8は、本発明に従う超音波洗浄器用の振動板の別の一例の構成と、その使用の態様を示す断面図である。図8の超音波洗浄器用の振動板の構成は、繊維強化樹脂材74が振動板部材75の上面に備えられていること以外は、図7の振動板と同様である。このように、繊維強化樹脂材74を振動板部材75の上面に付設することによっても、振動板部材75の平面に沿った方向の振動の発生を抑えることができる。
【0045】
図9は、本発明に従う超音波洗浄器用の超音波付与装置の一例の構成と、その使用の態様を示す断面図である。図9の超音波洗浄器用の超音波付与装置は、水密容器95の内側面の一面に、九個の超音波振動子(圧電振動子)93をその超音波放射面にて固定してなる超音波洗浄器用の超音波付与装置において、前記超音波振動子の固定位置と対応する水密容器の内側面に、前記九個の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有する平板状の繊維強化樹脂材94が備えられた構成を有している。平板状の繊維強化樹脂材94は、バインダ樹脂と、バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維とから構成されている。また、各々の超音波振動子93に電気的エネルギーを供給するために、超音波振動子にはリード線96が接続されている。
【0046】
繊維強化樹脂材94の付設により、図4の超音波洗浄器の場合と同様に、水密容器95の超音波振動子付設面に沿った方向の振動の発生が抑えられ、洗浄槽92に入れた洗浄液に均一に、そして効率良く超音波を伝えることができる。図9の超音波洗浄器は、その洗浄槽92として既存の容器を用いることができる利点を有している。
【0047】
次に、図9の超音波洗浄器を用いた物品の超音波洗浄方法について説明する。まず、洗浄槽92に洗浄液41と超音波付与装置を入れ、次いで洗浄液に物品を浸し、そして超音波付与装置の超音波振動子93により周波数が80乃至500kHzの超音波を洗浄液中に発して物品を超音波洗浄する。このような周波数の超音波を用いることにより、物品表面に与える損傷を抑え、そして強い洗浄力で物品を超音波洗浄することができる。
【0048】
図10は、本発明に従う超音波洗浄器用の超音波付与装置の別の一例の構成と、その使用の態様を示す断面図である。図10の超音波洗浄器用の超音波付与装置の構成は、繊維強化樹脂材94が水密容器95の外側面に備えられていること以外は、図9の超音波付与装置と同様である。このように、繊維強化樹脂材94を水密容器95の外側面に付設することによっても、水密容器の超音波振動子付設面に沿った方向の振動の発生を抑えることができる。
【0049】
本発明において、繊維強化樹脂材の付設により、超音波が均一に、そして効率良く洗浄液に伝わっていることを確認するために、一例として、洗浄槽タイプの超音波洗浄器の超音波振動子を振動させたときの洗浄液中の音圧分布を、コンピュータシミュレーションした。シミュレーションには、有限要素法を用いた解析用のソフトウエア「ANSYS」(ANSYS社製)を用いた。
【0050】
図11に、シミュレーションに用いた従来の超音波洗浄器の構成を示す。図11の(a)は、超音波洗浄器の底面図であり、そして(b)はその側面図である。洗浄槽112は、外径が144mm、内径が140mm、そして長さが70mmの円筒状部材の一端に、直径が144mm、そして厚さが2mmの底板を取り付けた構成とした。洗浄槽112を形成する材料は、ステンレススチールとした。洗浄槽112の底面の中央には、超音波振動子として、直径が18mm、そして厚さが3mmの圧電振動子113を固定した。シミュレーションにおいては、洗浄液として水を用い、水を洗浄槽112の上端まで入れた状態とした。
【0051】
そして、圧電振動子113に、周波数が118kHzで、振幅が1Vの交流電圧を印加したときの、洗浄槽に入れた水中の音圧分布をシミュレーションした。その結果、圧電振動子の上方においては水中の音圧が大きく、これ以外の場所では音圧が小さいことが確認できた。
【0052】
図12に、シミュレーションに用いた本発明に従う超音波洗浄器の構成を示す。図12の(a)は、超音波洗浄器の底面図であり、そして(b)はその側面図である。洗浄槽112と圧電振動子113は、図11の超音波洗浄器と同じ構成とした。洗浄槽112の底面には、直径が84mm、そして厚さが6mmの繊維強化樹脂材124を付設した。繊維強化樹脂材124のバインダ樹脂は、エポキシ樹脂とし、そして高弾性繊維は炭素繊維とした。なお、繊維強化樹脂材の厚みは、繊維強化樹脂材中をその平面に垂直な方向に伝わる超音波の波長が25mmであるため、その約1/4の厚みとした。
【0053】
そして、圧電振動子113に、周波数が114kHzで、振幅が1Vの交流電圧を印加したときの、洗浄槽に入れた水中の音圧分布をシミュレーションした。その結果、水中の音圧分布が、図11の超音波洗浄器と較べて均一となることが確認できた。また、水中の音圧の最大値も3倍程度に強くなり、超音波振動子から洗浄液に効率良く超音波が伝わっていることが確認できた。
【0054】
以上のシミュレーション結果から、超音波洗浄器に繊維強化樹脂材を付設することにより、超音波振動子から放射された超音波を均一に、そして効率良く洗浄液に伝えることができることを確認した。
【0055】
また、図12の超音波洗浄器の繊維強化樹脂材の平面の面積をパラメータとして、同様に洗浄液(水)中の音圧分布をシミュレーションした。その結果、繊維強化樹脂材の平面の面積は、洗浄液中の音圧分布を均一とするためには、洗浄槽の内側面の底面の面積に対して30%以上とすることが好ましいことも確認できた。
【0056】
【発明の効果】
本発明の超音波洗浄器、あるいは本発明の振動板もしくは超音波付与装置を用いた超音波洗浄器は、洗浄ムラが少なく、そして洗浄力も強い。このような超音波洗浄器においては、特に、周波数が80〜500kHz程度の超音波を洗浄に用いることが好ましい。このような周波数の超音波を用いた超音波洗浄器は、半導体素子作製用のウエハや精密機械部品のなどの表面に損傷を受けやすい物品の洗浄に特に好ましく用いることができる。
【図面の簡単な説明】
【図1】従来の超音波洗浄器の一例の構成を示す断面図である。
【図2】従来の超音波洗浄器の別の一例の構成を示す断面図である。
【図3】従来の超音波洗浄器のさらに別の一例の構成を示す断面図である。
【図4】本発明に従う超音波洗浄器の一例の構成を示す断面図である。
【図5】図4の超音波洗浄器の底面図である。
【図6】本発明に従う超音波洗浄器の別の一例の構成を示す断面図である。
【図7】本発明に従う超音波洗浄器用の振動板の一例の構成と、その使用の態様とを示す断面図である。
【図8】本発明に従う超音波洗浄器用の振動板の別の一例の構成と、その使用の態様とを示す断面図である。
【図9】本発明に従う超音波洗浄器用の超音波付与装置の一例の構成と、その使用の態様とを示す断面図である。
【図10】本発明に従う超音波洗浄器用の超音波付与装置の別の一例の構成と、その使用の態様とを示す断面図である。
【図11】コンピュータシミュレーションした超音波洗浄器の構成を示す図である。
【図12】コンピュータシミュレーションした超音波洗浄器の構成を示す図である。
【符号の説明】
11 洗浄液
12、22、32 洗浄槽
13、23、33 超音波振動子
25 振動板部材
26 パッキン
27 ボルト
28 ナット
35 水密容器
36 リード線
41 洗浄液
42、72、92 洗浄槽
43 超音波振動子
44、74、94 繊維強化樹脂材
45a、45b 圧電振動子
46a 上部金属部材
46b 下部金属部材
73、93 超音波振動子
75 振動板部材
76 パッキン
77 ボルト
78 ナット
95 水密容器
112 洗浄槽
113 圧電振動子
124 繊維強化樹脂材
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an ultrasonic cleaner, a vibration plate for the ultrasonic cleaner, and an ultrasonic wave applying device for the ultrasonic cleaner.
[0002]
[Prior art]
Ultrasonic cleaners are used for cleaning various articles such as daily necessities such as glasses and rings, precision mechanical parts used for cameras and watches, and wafers used for manufacturing semiconductor elements. An ultrasonic cleaner is an instrument for immersing an article to be washed in a washing liquid contained in a container (washing tank) and applying ultrasonic waves to the washing liquid to remove dirt attached to the article. The ultrasonic cleaning device includes a cleaning tank for storing a cleaning liquid, an ultrasonic vibrator for applying ultrasonic waves to the cleaning liquid, and the like. As the cleaning liquid, water, an organic solvent, a mixed solvent of water and an organic solvent, an acidic solution, an alkaline solution, or the like is used depending on the type of dirt attached to the article.
[0003]
1 to 3 are cross-sectional views showing a typical configuration of a conventional ultrasonic cleaner. The ultrasonic cleaning device of FIG. 1 is called a cleaning tank type, and has a configuration in which an ultrasonic vibrator 13 is fixed to a bottom surface of a cleaning tank 12 into which a cleaning liquid 11 is charged. The ultrasonic cleaner of FIG. 2 is called a diaphragm type, and has a configuration in which a diaphragm in which an ultrasonic vibrator 23 is fixed to a diaphragm member 25 is provided at the bottom of the cleaning tank 22. I have. A packing 25 is provided at the bottom of the cleaning tank 22 so that the cleaning liquid 11 does not leak from the cleaning tank. The diaphragm is fixed to the cleaning tank by fixing tools such as bolts 27 and nuts 28. The ultrasonic cleaning device of FIG. 3 is called an injection vibrator type, and an ultrasonic wave applying device in which an ultrasonic vibrator 33 is fixed to an inner surface of a watertight container 35 is disposed inside a cleaning tank 32. Configuration. In addition to the ultrasonic cleaners shown in FIGS. 1 to 3, various types of ultrasonic cleaners, such as an ultrasonic vibrator attached to a side surface of a cleaning tank, are known (for example, non-patented). Reference 1, pages 228-232).
[0004]
In an ultrasonic cleaning device, it is generally estimated that cleaning is performed by the following three actions (see Non-Patent Document 1, pages 223-224).
[0005]
(1) Cavitation
When ultrasonic waves are applied to the cleaning liquid, a pressure reduction force and a pressing force are repeatedly applied to the cleaning liquid by the ultrasonic vibration. Due to this reduced pressure, bubbles are generated in the cleaning liquid (this phenomenon is called cavitation). The dirt adhering to the article is removed by a shock wave generated when the bubbles disappear due to the pressing force. The sound pressure of the ultrasonic wave decreases as the frequency increases. Therefore, the lower the frequency of the ultrasonic wave applied to the cleaning liquid, the stronger the cleaning power based on cavitation. On the other hand, if the frequency of the ultrasonic wave is low, the surface of the article to be cleaned may be damaged.
[0006]
(2) acceleration
When ultrasonic waves are applied to the cleaning liquid, the cleaning liquid vibrates due to ultrasonic vibration. The dirt adhering to the article is removed by the force of the acceleration of the vibration of the cleaning liquid. Therefore, the higher the frequency of the ultrasonic wave applied to the cleaning liquid, the stronger the cleaning power due to the acceleration.
[0007]
(3) Straight flow
When ultrasonic waves are applied to the cleaning liquid, a flow of the cleaning liquid occurs in the direction in which the ultrasonic waves propagate. The flow of the cleaning liquid agitates the cleaning liquid near the article surface, and removes the dirt attached to the article.
[0008]
Hereinafter, a conventional ultrasonic cleaning device will be described by taking a cleaning tank type ultrasonic cleaning device (see FIG. 1) generally and widely used as an example. In the ultrasonic cleaning device of FIG. 1, one or more ultrasonic vibrators 13 are attached to the bottom of the cleaning tank in order to transmit sufficient ultrasonic waves to the cleaning liquid 11 placed in the cleaning tank 12. .
[0009]
In the ultrasonic cleaning device, the bottom of the cleaning tank 12 is evenly piston-vibrated (vertically vibrated) by the ultrasonic vibrator 13 in order to reduce unevenness in cleaning the articles, that is, to uniformly transmit ultrasonic waves to the cleaning liquid. ). Further, in order to increase the cleaning power of the ultrasonic cleaning device, that is, to efficiently transmit the ultrasonic waves radiated from the ultrasonic vibrator to the cleaning liquid, the ultrasonic vibrator 13 makes the bottom surface of the cleaning tank 12 uniform. It is preferable to cause the piston to vibrate. When the bottom surface of the cleaning tank 12 is uniformly vibrated by the piston, the vibration (ultrasonic) component emitted in the direction along the bottom surface of the cleaning tank is hardly generated in the ultrasonic wave radiated from the ultrasonic transducer and transmitted through the bottom plate of the cleaning tank. ,preferable. That is, if such a vibration component is present, it becomes difficult for the ultrasonic wave to be efficiently transmitted to the cleaning liquid. Therefore, it is preferable that the ultrasonic vibrators are fixed as densely as possible on the bottom surface of the cleaning tank 12. Practically, in consideration of the manufacturing cost of the ultrasonic cleaning device, an appropriate number of ultrasonic transducers are fixed to the bottom surface of the cleaning tank 12 (see Non-Patent Document 2, p247-248).
[0010]
Ultrasonic cleaners in which an acoustic matching layer is provided between a cleaning tank and an ultrasonic vibrator in order to efficiently transmit ultrasonic waves radiated from an ultrasonic vibrator to a cleaning liquid are known (for example, Patent Document 1, FIG. 1). By providing the acoustic matching layer, the reflection of the ultrasonic waves radiated from the ultrasonic transducer at the bottom of the cleaning tank is suppressed, and the ultrasonic waves are easily transmitted to the cleaning liquid efficiently.
[0011]
Also, it is known that by providing a fiber reinforced resin material on the ultrasonic wave emitting surface of the ultrasonic vibrator, it is possible to strongly generate ultrasonic waves transmitted in a direction perpendicular to the high elastic fiber in the fiber reinforced resin material (for example, , Patent Document 2). Patent Literature 2 suggests using an ultrasonic vibrator having a fiber reinforced resin material on an ultrasonic radiation surface for an ultrasonic cleaner.
[0012]
Conventional ultrasonic cleaners include an ultrasonic cleaner using an ultrasonic wave having a frequency of 20 to 50 kHz (hereinafter, referred to as a low-frequency ultrasonic cleaner) depending on the frequency of the ultrasonic wave used for cleaning. Are generally classified into ultrasonic cleaners using ultrasonic waves of several MHz (hereinafter, referred to as high-frequency type ultrasonic cleaners).
[0013]
It is known that a low-frequency ultrasonic cleaner mainly performs cleaning by cavitation, and has a strong cleaning power, but easily damages the surface of an article to be cleaned. On the other hand, in a high-frequency type ultrasonic cleaner, cavitation hardly occurs, and cleaning is mainly performed mainly by the acceleration force of the cleaning liquid. It is known that the surface is hardly damaged and fine dirt is easily removed.
[0014]
Therefore, in general, the low-frequency type ultrasonic cleaner is used for cleaning daily necessities such as eyeglasses that need to remove large stains, and the high-frequency type ultrasonic cleaner does not damage the article surface. In addition, they are used for cleaning wafers and precision machine parts for producing semiconductor elements, which need to remove fine dirt.
[0015]
Ultrasonic cleaners suitable for cleaning contact lenses using ultrasonic waves having a frequency between the frequencies used for such low-frequency and high-frequency ultrasonic cleaners are known (for example, Patent Document 3). In this ultrasonic cleaner, an ultrasonic wave having a frequency of 60 to 800 kHz is used to remove fine dirt attached to the contact lens.
[0016]
[Non-patent document 1]
Hiroyuki Futashi, "Latest Ultrasonic Technology", First Edition, Sogo Gijutsu Center, September 1987, p. 223-224, p. 228-232
[Non-patent document 2]
(Japan) Electronic Machinery Manufacturers Association, "Ultrasonic Engineering", first edition, Corona Co., Ltd., January 1993, p. 247-248
[Patent Document 1]
JP 2001-29907 A (FIG. 1)
[Patent Document 2]
JP-A-7-284198
[Patent Document 3]
JP-A-59-183882
[0017]
[Problems to be solved by the invention]
In conventional ultrasonic cleaners, the use of an acoustic matching layer and an ultrasonic vibrator with a fiber-reinforced resin material on the ultrasonic radiation surface allows for efficient transmission of ultrasonic waves to the cleaning liquid to enhance the cleaning power. Despite this, a large number of ultrasonic vibrators must be attached to the bottom of the cleaning tank to make the bottom of the cleaning tank evenly vibrate with a piston to reduce uneven cleaning or increase the cleaning power. There are issues that need to be addressed.
[0018]
Another problem is that it is difficult to clean an article with a conventional ultrasonic cleaner without damaging its surface and with a certain level of cleaning power. Depending on the application (for example, in the case of a wafer, when the degree of integration of the semiconductor element formed on the wafer is low) in a wafer for manufacturing a semiconductor device or a precision machine component, the surface can be compared without damaging the surface. It may be necessary to remove very large debris. In such a case, it is considered preferable to set the frequency of the ultrasonic wave to a value between the frequencies used in the low-frequency type and high-frequency type ultrasonic cleaners (about 80 to 500 kHz). However, only by setting the frequency of the ultrasonic waves high, as in the case of the ultrasonic cleaning device for contact lenses, cavitation is unlikely to occur as the frequency increases, which is sufficient for the wafers and precision parts for producing the semiconductor element. It is considered that it is difficult to obtain a good detergency.
[0019]
In an ultrasonic cleaning device, if the ultrasonic waves can be efficiently transmitted to the cleaning liquid without increasing the number of ultrasonic transducers as much as possible, ultrasonic waves having a frequency (about 80 to 500 kHz) that does not easily damage the article surface are used. It is considered that a practical ultrasonic cleaner having a certain level of cleaning power can be realized.
[0020]
An object of the present invention is to provide an ultrasonic cleaner having less cleaning unevenness and high cleaning power without increasing the number of ultrasonic transducers as much as possible.
It is also an object of the present invention to provide an ultrasonic cleaner that has less damage to the surface of the article to be cleaned and has a strong cleaning power.
[0021]
[Means for Solving the Problems]
The present inventor has proposed that the number and arrangement of the ultrasonic vibrators fixed to the bottom of the cleaning tank of the ultrasonic cleaning device, and further, the shape of the cleaning tank, and the like, allows the bottom of the cleaning tank to be reduced by a small number of ultrasonic vibrators. Were examined to reduce the unevenness of cleaning and to increase the cleaning power, but could not obtain sufficient results. For this reason, the present inventor further does not devise the number or arrangement of the ultrasonic vibrators, but when the ultrasonic waves radiated from the ultrasonic vibrators propagate through the bottom plate of the cleaning tank, the ultrasonic waves along the bottom surface of the bottom plate. A study was conducted to make the bottom of the cleaning tank evenly vibrate by suppressing the generation of vibration in the direction. As a result, by attaching the fiber reinforced resin material to the bottom plate of the cleaning tank, the generation of vibration in the direction along the bottom surface of the bottom plate is suppressed, and the cleaning unevenness is reduced without increasing the number of ultrasonic vibrators. And an ultrasonic cleaner having a strong detergency can be provided.
[0022]
The present invention is directed to an ultrasonic cleaner in which one or two or more ultrasonic vibrators are fixed to the bottom or side surface of the outer surface of the cleaning tank at the ultrasonic radiation surface thereof, wherein the ultrasonic vibrator is fixed. On the outer surface or inner surface of the cleaning tank corresponding to the position, the area larger than the area of the ultrasonic emission surface of the one ultrasonic oscillator or the total area of the ultrasonic emission surfaces of the two or more ultrasonic oscillators Ultrasonic cleaning characterized by having a flat fiber-reinforced resin material comprising a binder resin and a plurality of high-elasticity fibers arranged in parallel with the plane in the binder resin. In the bowl.
[0023]
The present invention also provides a cleaning liquid in the cleaning tank of the ultrasonic cleaning device of the present invention, then immerses the article in the cleaning liquid, and applies ultrasonic waves having a frequency of 80 to 500 kHz by the ultrasonic vibrator of the ultrasonic cleaning device. There is also an ultrasonic cleaning method characterized by cleaning the article by emitting the inside.
[0024]
The present invention also provides a diaphragm for an ultrasonic cleaning device in which one or two or more ultrasonic vibrators are fixed on the lower surface of a diaphragm member on the ultrasonic radiation surface thereof, wherein the ultrasonic vibrator is fixed. On the upper surface or the lower surface of the diaphragm member corresponding to the position, the area of the ultrasonic radiation surface of the one ultrasonic transducer or the area larger than the total area of the ultrasonic radiation surfaces of the two or more ultrasonic transducers For an ultrasonic cleaning device, having a flat surface, a flat-plate fiber reinforced resin material comprising a binder resin and a plurality of high elastic fibers arranged in parallel with the flat surface in the binder resin is provided. There is also a diaphragm.
[0025]
The present invention also provides a cleaning tank, in which the above-mentioned diaphragm of the present invention is fixed as a bottom plate, and then the cleaning liquid is poured into the cleaning tank, and then the article is immersed in the cleaning liquid, and the ultrasonic vibrator of the diaphragm has a frequency of 80 to 500 kHz. There is also an ultrasonic cleaning method characterized in that an article is cleaned by emitting a sound wave in a cleaning liquid.
[0026]
The present invention also provides an ultrasonic wave applicator for an ultrasonic cleaning device having one or two or more ultrasonic transducers fixed on at least one inner surface of a watertight container at its ultrasonic radiation surface. On the outer surface or inner surface of the watertight container corresponding to the fixed position of the ultrasonic transducer, the area of the ultrasonic radiation surface of the one ultrasonic transducer or the total of the ultrasonic radiation surfaces of the two or more ultrasonic transducers A flat fiber-reinforced resin material having a plane having an area larger than the area, and comprising a binder resin and a plurality of high elastic fibers arranged in parallel with the plane in the binder resin is provided. There is also an ultrasonic wave applying device for an ultrasonic cleaner.
[0027]
In the present invention, the cleaning liquid and the ultrasonic applying apparatus of the present invention are put into a cleaning tank, and then the article is immersed in the cleaning liquid, and the ultrasonic vibrator of the ultrasonic applying apparatus applies ultrasonic waves having a frequency of 80 to 500 kHz to the cleaning liquid. There is also an ultrasonic cleaning method characterized by cleaning the article by emitting the inside.
[0028]
BEST MODE FOR CARRYING OUT THE INVENTION
The ultrasonic cleaner according to the present invention will be described with reference to the accompanying drawings. FIG. 4 is a cross-sectional view showing the configuration of an example of the ultrasonic cleaner according to the present invention, and FIG. 5 is a bottom view of the ultrasonic cleaner of FIG. The ultrasonic cleaner shown in FIGS. 4 and 5 is an ultrasonic cleaner in which nine ultrasonic vibrators 43 are fixed on the bottom surface of a cleaning tank 42 containing a cleaning liquid 41 at the ultrasonic radiation surface thereof. A flat fiber-reinforced resin having a plane having an area larger than the total area of the ultrasonic radiation surfaces of the nine ultrasonic transducers 43 on the outer surface of the cleaning tank 42 corresponding to the fixing position of the ultrasonic transducer 43. It has a configuration in which a member 44 is provided.
[0029]
The flat fiber-reinforced resin material 44 is composed of a binder resin and a plurality of high-elastic fibers (not shown) arranged in the binder resin in parallel with the plane. The fiber reinforced resin material 44 having such a configuration is unlikely to expand and contract in the direction along the length direction of the high elasticity fiber, that is, in the direction along the plane of the flat fiber reinforced resin material. By providing such a fiber reinforced resin material 44, the bottom plate of the cleaning tank 42 is less likely to expand and contract in the direction along the bottom surface, and when ultrasonic waves radiated from the ultrasonic vibrator 43 propagate through the bottom plate of the cleaning layer 42. In addition, the generation of vibration along the bottom surface of the bottom plate is suppressed. Therefore, even if the number of ultrasonic vibrators is not increased, uniform piston vibration on the bottom of the cleaning tank is promoted, cleaning unevenness of the ultrasonic cleaning device is reduced, and cleaning power is also increased.
[0030]
In addition, according to the wavelength of the ultrasonic wave propagating through the cleaning liquid, the cleaning liquid put in the cleaning tank has a periodic fluctuation in sound pressure in a direction perpendicular to the ultrasonic wave emitting surface of the ultrasonic vibrator. It is known that periodic cleaning unevenness corresponding to the fluctuation occurs. With respect to the periodic cleaning unevenness corresponding to such a sound pressure fluctuation, many solutions are known such as an arrangement of an ultrasonic oscillator and a modulation of an AC voltage applied to the ultrasonic oscillator (for example, , Non-Patent Document 1, p231, p236-237). In the present specification, the description of the cleaning unevenness in the direction perpendicular to the ultrasonic wave emitting surface of the ultrasonic transducer (in the case of the ultrasonic cleaning device of FIG. 4, the depth direction of the cleaning tank) is described. Abbreviate. In the ultrasonic cleaning device of the present invention, the problem of periodic cleaning unevenness corresponding to such sound pressure fluctuation can be similarly solved based on the description of Non-Patent Document 1.
[0031]
In order to uniformly oscillate the piston of the bottom surface of the cleaning tank 42, it is preferable to increase the area of the plane of the fiber-reinforced resin material 44 as much as possible so as to coincide with the bottom surface of the cleaning tank. By simply attaching an ultrasonic vibrator provided with a fiber-reinforced resin material having a plane having the same area as the ultrasonic radiation surface described in Patent Document 2 to the cleaning tank, the bottom surface of the cleaning tank bottom plate is made uniform. The effect of vibrating the piston is small. In the present invention, it is necessary to attach a fiber-reinforced resin material having a plane having an area larger than at least the ultrasonic wave emitting surface of the ultrasonic transducer to the cleaning tank.
[0032]
When the article to be washed is large, the washing tank becomes large and the area of the bottom surface also becomes large. When a fiber-reinforced resin material is attached to the bottom surface of a large-sized washing tank, a plurality of fiber-reinforced resin materials may be attached along the bottom surface of the washing tank. The plurality of fiber-reinforced resin materials may be provided in a state where they are spaced from each other.
[0033]
The thickness of the fiber-reinforced resin material is substantially equal to the wavelength of the ultrasonic wave transmitted through the fiber-reinforced resin material in a direction perpendicular to the plane of the cleaning tank in order to suppress the reflection of the ultrasonic waves radiated from the ultrasonic transducer at the bottom of the cleaning tank. The thickness is preferably 1/4. Further, when the attenuation of the ultrasonic wave in the fiber reinforced resin material is large, it is preferable that the thickness of the fiber reinforced resin material is further thinner than 厚 み of the wavelength.
[0034]
The arrangement of the plurality of high elasticity fibers of the fiber reinforced resin material is not particularly limited as long as they are arranged in parallel with the plane of the fiber reinforced resin material. The plurality of high-elastic fibers are preferably arranged in one direction parallel to the plane of the fiber-reinforced resin material, and two directions parallel to the plane and such that the high-elastic fibers are orthogonal to each other. More preferably, they are arranged in a line.
[0035]
Examples of the binder resin include an epoxy resin, a polyamide resin, a polyimide resin, a PEEK (polyetheretherketone) resin, a phenol resin, an unsaturated polyester resin, a polyamide resin, a polycarbonate resin, and a polyamideimide resin. Examples of the high elasticity fiber include carbon fiber, silicon carbide fiber, polyamide fiber, and aramid fiber.
[0036]
In the ultrasonic cleaning device shown in FIG. 4, each of the ultrasonic vibrators 43 is configured such that two piezoelectric vibrators 45a and 45b are bolted while being sandwiched between an upper metal member 46a and a lower metal member 46b. Langevin type vibrator is used. In the cross-sectional view of FIG. 4, the description of the bolts and nuts for fastening the upper metal member 46a and the lower metal member 46b is omitted. When electric energy is supplied to the electrode layers provided on the upper and lower surfaces of each piezoelectric vibrator to vibrate each piezoelectric vibrator, ultrasonic waves are generated from the top surface of the upper metal member 46a of the ultrasonic vibrator 43. Radiated.
[0037]
Examples of the ultrasonic vibrator include an electrostrictive vibrator and a magnetostrictive vibrator. Examples of the electrostrictive vibrator include a piezoelectric vibrator and a Langevin type vibrator in which the piezoelectric vibrator is bolted with a pair of metal members. Examples of the magnetostrictive vibrator include a metal magnetostrictive vibrator and a ferrite vibrator. As the ultrasonic vibrator, it is preferable to use an electrostrictive vibrator because its configuration is simple.
[0038]
The cleaning tank 42 is generally formed of a metal material such as stainless steel in consideration of corrosion resistance to a cleaning liquid. When a highly corrosive liquid such as an acidic solution or an alkaline solution is used as the cleaning liquid, the cleaning tank is preferably formed from a resin (eg, vinyl chloride resin, fluororesin), glass, ceramics, or the like. Further, when the cleaning tank is formed of a metal material, the cleaning tank may be provided with a fiber-reinforced resin material via an insulating material in order to prevent electrical conduction between the cleaning tank and the fiber-reinforced resin material. good. Examples of the insulating material include a resin material and a glass epoxy material. The thickness of the insulating material is preferably 1 mm or less, preferably 0.5 mm or less.
[0039]
Next, an ultrasonic cleaning method of an article using the ultrasonic cleaner of FIG. 4 will be described. First, a cleaning liquid 41 is put into a cleaning tank 42 of an ultrasonic cleaning device, then an article (not shown) is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are applied by an ultrasonic vibrator 43 of the ultrasonic cleaning device. The product is ultrasonically cleaned by emitting in a cleaning solution. By using ultrasonic waves of such a frequency, damage to the surface of the article can be suppressed, and the article can be ultrasonically cleaned with a strong cleaning power.
[0040]
FIG. 6 is a sectional view showing a configuration of another example of the ultrasonic cleaner according to the present invention. The configuration of the ultrasonic cleaner of FIG. 6 is the same as the ultrasonic cleaner of FIG. 4 except that the fiber reinforced resin material 44 is provided on the inner surface of the cleaning tank 42. As described above, by providing the fiber reinforced resin material 44 on the inner surface of the cleaning tank 42, the generation of vibration in the direction along the bottom surface of the cleaning tank bottom plate can be suppressed.
[0041]
FIG. 7 is a cross-sectional view showing a configuration of an example of a diaphragm for an ultrasonic cleaning device according to the present invention and a mode of use thereof. The vibration plate for the ultrasonic cleaning device of FIG. 7 has a structure in which nine ultrasonic vibrators (piezoelectric vibrators) 73 are fixed on the lower surface of the vibration plate member 75 on the ultrasonic radiation surface thereof. In the diaphragm, a flat fiber having a plane having an area larger than the total area of the ultrasonic radiation surfaces of the nine ultrasonic transducers on the lower surface of the diaphragm member corresponding to the fixing position of the ultrasonic transducer. It has a configuration in which a reinforced resin material 74 is provided. The flat fiber-reinforced resin material 74 is composed of a binder resin and a plurality of high elastic fibers arranged in the binder resin in parallel with the plane.
[0042]
By the provision of the fiber reinforced resin material 74, as in the case of the ultrasonic cleaner of FIG. 4, the generation of vibration in the direction along the plane of the diaphragm member 75 is suppressed, and the cleaning liquid put in the cleaning layer 72 is evenly dispersed. , And can transmit ultrasonic waves efficiently. The ultrasonic cleaning device of FIG. 7 has an advantage that the maintenance of the ultrasonic cleaning device is easy because the diaphragm provided with the ultrasonic vibrator 73 is replaceable.
[0043]
Next, an ultrasonic cleaning method of an article using the ultrasonic cleaning device of FIG. 7 will be described. First, after the diaphragm is fixed as the bottom plate in the cleaning tank 72, the cleaning liquid 41 is put therein, then the article is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are introduced into the cleaning liquid by the ultrasonic vibrator 73 of the vibration plate. Emit and ultrasonically clean the article. By using ultrasonic waves of such a frequency, damage to the surface of the article can be suppressed, and the article can be ultrasonically cleaned with a strong cleaning power.
[0044]
FIG. 8 is a cross-sectional view showing a configuration of another example of the vibration plate for an ultrasonic cleaning device according to the present invention, and a mode of use thereof. The configuration of the diaphragm for the ultrasonic cleaner of FIG. 8 is the same as that of the diaphragm of FIG. 7 except that the fiber reinforced resin material 74 is provided on the upper surface of the diaphragm member 75. In this way, by providing the fiber reinforced resin material 74 on the upper surface of the diaphragm member 75, the generation of vibration in the direction along the plane of the diaphragm member 75 can be suppressed.
[0045]
FIG. 9 is a cross-sectional view showing an example of the configuration of an ultrasonic wave applying apparatus for an ultrasonic cleaning device according to the present invention, and a mode of use thereof. The ultrasonic wave applicator for an ultrasonic cleaning device shown in FIG. 9 includes an ultrasonic wave fixing device having nine ultrasonic vibrators (piezoelectric vibrators) 93 fixed on one surface of the inner surface of a watertight container 95 at the ultrasonic radiation surface. In the ultrasonic wave applicator for the ultrasonic cleaner, the inner surface of the watertight container corresponding to the fixing position of the ultrasonic vibrator, a plane having an area larger than the total area of the ultrasonic radiation surfaces of the nine ultrasonic vibrators. And a flat-plate-shaped fiber-reinforced resin material 94 having the following configuration. The flat fiber-reinforced resin material 94 is composed of a binder resin and a plurality of high elastic fibers arranged in the binder resin in parallel with the plane. Further, a lead wire 96 is connected to each of the ultrasonic vibrators 93 to supply electric energy to the ultrasonic vibrators 93.
[0046]
By the provision of the fiber reinforced resin material 94, the generation of vibration in the direction along the ultrasonic vibrator mounting surface of the watertight container 95 is suppressed as in the case of the ultrasonic cleaning device of FIG. Ultrasonic waves can be transmitted uniformly and efficiently to the cleaning liquid. The ultrasonic cleaning device of FIG. 9 has an advantage that an existing container can be used as the cleaning tank 92.
[0047]
Next, an ultrasonic cleaning method of an article using the ultrasonic cleaning device of FIG. 9 will be described. First, the cleaning liquid 41 and the ultrasonic wave applicator are put into the cleaning tank 92, then the article is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are emitted into the cleaning liquid by the ultrasonic vibrator 93 of the ultrasonic wave applicator. Is ultrasonically cleaned. By using ultrasonic waves of such a frequency, damage to the surface of the article can be suppressed, and the article can be ultrasonically cleaned with a strong cleaning power.
[0048]
FIG. 10 is a cross-sectional view showing the configuration of another example of the ultrasonic wave applying device for an ultrasonic cleaning device according to the present invention, and the mode of use thereof. The configuration of the ultrasonic wave application device for the ultrasonic cleaning device in FIG. 10 is the same as that of the ultrasonic wave application device in FIG. 9 except that the fiber-reinforced resin material 94 is provided on the outer surface of the watertight container 95. In this way, by providing the fiber reinforced resin material 94 on the outer surface of the watertight container 95, it is possible to suppress the generation of vibration in the direction along the ultrasonic vibrator mounting surface of the watertight container.
[0049]
In the present invention, by providing a fiber reinforced resin material, in order to confirm that ultrasonic waves are transmitted uniformly and efficiently to the cleaning liquid, as an example, an ultrasonic vibrator of a cleaning tank type ultrasonic cleaning device is used. Computer simulation was performed on the sound pressure distribution in the cleaning liquid when vibrated. For the simulation, software "ANSSYS" (manufactured by ANSYS) for analysis using the finite element method was used.
[0050]
FIG. 11 shows a configuration of a conventional ultrasonic cleaner used for the simulation. FIG. 11 (a) is a bottom view of the ultrasonic cleaner, and FIG. 11 (b) is a side view thereof. The cleaning tank 112 was configured such that a bottom plate having a diameter of 144 mm and a thickness of 2 mm was attached to one end of a cylindrical member having an outer diameter of 144 mm, an inner diameter of 140 mm, and a length of 70 mm. The material forming the cleaning tank 112 was stainless steel. A piezoelectric vibrator 113 having a diameter of 18 mm and a thickness of 3 mm was fixed as an ultrasonic vibrator at the center of the bottom of the cleaning tank 112. In the simulation, water was used as the cleaning liquid, and the water was filled up to the upper end of the cleaning tank 112.
[0051]
The sound pressure distribution in the water placed in the cleaning tank when an alternating voltage having a frequency of 118 kHz and an amplitude of 1 V was applied to the piezoelectric vibrator 113 was simulated. As a result, it was confirmed that the underwater sound pressure was high above the piezoelectric vibrator, and the sound pressure was low in other places.
[0052]
FIG. 12 shows the configuration of the ultrasonic cleaner according to the present invention used in the simulation. FIG. 12A is a bottom view of the ultrasonic cleaner, and FIG. 12B is a side view thereof. The cleaning tank 112 and the piezoelectric vibrator 113 have the same configuration as the ultrasonic cleaning device of FIG. A fiber reinforced resin material 124 having a diameter of 84 mm and a thickness of 6 mm was provided on the bottom surface of the cleaning tank 112. The binder resin of the fiber reinforced resin material 124 was an epoxy resin, and the high elasticity fiber was a carbon fiber. The thickness of the fiber reinforced resin material was set to about 4 of the thickness of the ultrasonic wave transmitted through the fiber reinforced resin material in a direction perpendicular to the plane thereof was 25 mm.
[0053]
Then, the sound pressure distribution in the water placed in the cleaning tank when an AC voltage having a frequency of 114 kHz and an amplitude of 1 V was applied to the piezoelectric vibrator 113 was simulated. As a result, it was confirmed that the sound pressure distribution in the water was uniform as compared with the ultrasonic cleaner of FIG. Also, the maximum value of the sound pressure in water was about three times stronger, and it was confirmed that the ultrasonic wave was efficiently transmitted from the ultrasonic vibrator to the cleaning liquid.
[0054]
From the above simulation results, it was confirmed that the ultrasonic waves emitted from the ultrasonic vibrator can be uniformly and efficiently transmitted to the cleaning liquid by attaching the fiber reinforced resin material to the ultrasonic cleaning device.
[0055]
The sound pressure distribution in the cleaning liquid (water) was similarly simulated using the planar area of the fiber-reinforced resin material of the ultrasonic cleaner of FIG. 12 as a parameter. As a result, it was also confirmed that the plane area of the fiber-reinforced resin material is preferably 30% or more of the area of the bottom surface of the inner surface of the cleaning tank in order to make the sound pressure distribution in the cleaning liquid uniform. did it.
[0056]
【The invention's effect】
The ultrasonic cleaning device of the present invention, or the ultrasonic cleaning device using the vibration plate or the ultrasonic applying device of the present invention has less cleaning unevenness and a stronger cleaning power. In such an ultrasonic cleaner, it is particularly preferable to use ultrasonic waves having a frequency of about 80 to 500 kHz for cleaning. The ultrasonic cleaner using the ultrasonic waves having such a frequency can be particularly preferably used for cleaning an article which is easily damaged on the surface such as a wafer for manufacturing a semiconductor element and a precision machine part.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view illustrating a configuration of an example of a conventional ultrasonic cleaning device.
FIG. 2 is a cross-sectional view showing the configuration of another example of the conventional ultrasonic cleaner.
FIG. 3 is a cross-sectional view illustrating a configuration of still another example of the conventional ultrasonic cleaner.
FIG. 4 is a sectional view showing a configuration of an example of an ultrasonic cleaner according to the present invention.
FIG. 5 is a bottom view of the ultrasonic cleaner of FIG. 4;
FIG. 6 is a sectional view showing a configuration of another example of the ultrasonic cleaner according to the present invention.
FIG. 7 is a cross-sectional view showing a configuration of an example of a vibration plate for an ultrasonic cleaning device according to the present invention and a mode of use thereof.
FIG. 8 is a cross-sectional view showing a configuration of another example of a diaphragm for an ultrasonic cleaning device according to the present invention, and an aspect of its use.
FIG. 9 is a sectional view showing a configuration of an example of an ultrasonic wave applying device for an ultrasonic cleaning device according to the present invention and a mode of use thereof.
FIG. 10 is a cross-sectional view showing the configuration of another example of the ultrasonic wave applying device for an ultrasonic cleaning device according to the present invention and the mode of use thereof.
FIG. 11 is a diagram showing a configuration of an ultrasonic cleaning device subjected to computer simulation.
FIG. 12 is a diagram showing a configuration of an ultrasonic cleaning device subjected to computer simulation.
[Explanation of symbols]
11 Cleaning liquid
12, 22, 32 Cleaning tank
13,23,33 Ultrasonic transducer
25 diaphragm member
26 Packing
27 volts
28 nuts
35 Watertight container
36 Lead wire
41 Cleaning liquid
42, 72, 92 Cleaning tank
43 Ultrasonic transducer
44, 74, 94 Fiber reinforced resin material
45a, 45b piezoelectric vibrator
46a Upper metal member
46b Lower metal member
73, 93 ultrasonic transducer
75 diaphragm member
76 Packing
77 volts
78 nut
95 Watertight container
112 Cleaning tank
113 Piezoelectric vibrator
124 fiber reinforced resin material

Claims (6)

洗浄槽の外側面の底面もしくは側面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器において、前記超音波振動子の固定位置と対応する洗浄槽の外側面もしくは内側面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及び該バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器。In an ultrasonic cleaner in which one or two or more ultrasonic vibrators are fixed on the ultrasonic radiation surface on the bottom surface or side surface of the outer surface of the cleaning tank, the ultrasonic vibrator corresponds to a fixing position of the ultrasonic vibrator. The outer surface or the inner surface of the cleaning tank has a plane having an area larger than the area of the ultrasonic radiation surface of the one ultrasonic transducer or the total area of the ultrasonic radiation surfaces of the two or more ultrasonic transducers. An ultrasonic cleaner comprising: a binder resin; and a flat fiber-reinforced resin material including a plurality of high-elastic fibers arranged in parallel with the plane in the binder resin. 請求項1の超音波洗浄器の洗浄槽に洗浄液を入れ、次いで該洗浄液に物品を浸し、そして該洗浄器の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して当該物品を洗浄することを特徴とする超音波洗浄方法。A cleaning liquid is poured into the cleaning tank of the ultrasonic cleaning device according to claim 1, and then the article is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are emitted into the cleaning liquid by the ultrasonic vibrator of the cleaning device. An ultrasonic cleaning method, characterized by cleaning the substrate. 振動板部材の下面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器用の振動板において、前記超音波振動子の固定位置と対応する振動板部材の上面もしくは下面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及び該バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器用の振動板。In a vibration plate for an ultrasonic cleaning device in which one or two or more ultrasonic vibrators are fixed on the lower surface of a vibration plate member at its ultrasonic radiation surface, a vibration corresponding to a fixing position of the ultrasonic vibrator is provided. On the upper surface or the lower surface of the plate member, a plane having an area larger than the area of the ultrasonic radiation surface of the one ultrasonic transducer or the total area of the ultrasonic radiation surfaces of the two or more ultrasonic transducers, A diaphragm for an ultrasonic cleaning device, comprising: a binder resin; and a flat fiber-reinforced resin material made of a plurality of high-elastic fibers arranged in parallel with the plane in the binder resin. 洗浄槽にその底板として請求項3に記載の振動板を固定したのちに洗浄液を入れ、次いで該洗浄液に物品を浸し、そして該振動板の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して当該物品を洗浄することを特徴とする超音波洗浄方法。After fixing the diaphragm according to claim 3 as a bottom plate in the cleaning tank, the cleaning liquid is poured into the cleaning tank, and then the article is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are transmitted by the ultrasonic vibrator of the vibration plate. An ultrasonic cleaning method characterized by cleaning the article by emitting in a cleaning liquid. 水密容器の内側面の少なくとも一面に、一個もしくは二個以上の超音波振動子をその超音波放射面にて固定してなる超音波洗浄器用の超音波付与装置において、前記超音波振動子の固定位置と対応する水密容器の外側面もしくは内側面に、前記一個の超音波振動子の超音波放射面の面積もしくは前記二個以上の超音波振動子の超音波放射面の合計面積よりも大きな面積の平面を有し、バインダ樹脂及び該バインダ樹脂中に前記平面と平行に整列配置された複数本の高弾性繊維からなる平板状の繊維強化樹脂材が備えられていることを特徴とする超音波洗浄器用の超音波付与装置。In at least one surface of the inner surface of the watertight container, one or two or more ultrasonic transducers are fixed on the ultrasonic radiation surface thereof in an ultrasonic wave applying device for an ultrasonic cleaning device, wherein the ultrasonic transducer is fixed. On the outer surface or inner surface of the watertight container corresponding to the position, the area larger than the area of the ultrasonic radiation surface of the one ultrasonic transducer or the total area of the ultrasonic radiation surfaces of the two or more ultrasonic transducers Wherein a flat fiber-reinforced resin material comprising a binder resin and a plurality of high-elastic fibers aligned in parallel with the plane is provided in the binder resin. Ultrasonic wave application device for washing machine. 洗浄槽に洗浄液と請求項5に記載の超音波付与装置を入れ、次いで該洗浄液に物品を浸し、そして該超音波付与装置の超音波振動子により周波数が80乃至500kHzの超音波を洗浄液中に発して当該物品を洗浄することを特徴とする超音波洗浄方法。The cleaning liquid and the ultrasonic wave applying device according to claim 5 are put in the cleaning tank, and then the article is immersed in the cleaning liquid, and ultrasonic waves having a frequency of 80 to 500 kHz are introduced into the cleaning liquid by the ultrasonic vibrator of the ultrasonic wave applying device. An ultrasonic cleaning method characterized by emitting and cleaning the article.
JP2002298592A 2002-10-11 2002-10-11 Ultrasonic cleaner, vibration plate for ultrasonic cleaner, and ultrasonic wave application apparatus for ultrasonic cleaner Pending JP2004130248A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007215119A (en) * 2006-02-13 2007-08-23 Mitsubishi Electric Engineering Co Ltd Electroacoustic transducer
CN107348921A (en) * 2017-08-30 2017-11-17 浙江默客机电有限公司 A kind of novel dish-washing machines
CN113663980A (en) * 2021-08-20 2021-11-19 陕西师范大学 Ultrasonic transducer, ultrasonic cleaning device and cleaning method capable of vibrating in multiple directions
CN118273024A (en) * 2024-06-03 2024-07-02 杭州奔马化纤纺丝有限公司 Ultrasonic cleaning device and method for regenerated polyester staple fiber production

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007215119A (en) * 2006-02-13 2007-08-23 Mitsubishi Electric Engineering Co Ltd Electroacoustic transducer
CN107348921A (en) * 2017-08-30 2017-11-17 浙江默客机电有限公司 A kind of novel dish-washing machines
CN113663980A (en) * 2021-08-20 2021-11-19 陕西师范大学 Ultrasonic transducer, ultrasonic cleaning device and cleaning method capable of vibrating in multiple directions
CN118273024A (en) * 2024-06-03 2024-07-02 杭州奔马化纤纺丝有限公司 Ultrasonic cleaning device and method for regenerated polyester staple fiber production

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