JP2004097263A - Air purifying device - Google Patents

Air purifying device Download PDF

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Publication number
JP2004097263A
JP2004097263A JP2002259711A JP2002259711A JP2004097263A JP 2004097263 A JP2004097263 A JP 2004097263A JP 2002259711 A JP2002259711 A JP 2002259711A JP 2002259711 A JP2002259711 A JP 2002259711A JP 2004097263 A JP2004097263 A JP 2004097263A
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Prior art keywords
discharge
air
electrodes
dielectric member
catalyst
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Pending
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JP2002259711A
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Japanese (ja)
Inventor
Shinichiro Nakamura
中村 真一郎
Keiichiro Yoshida
吉田 恵一郎
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Denso Corp
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Denso Corp
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Filing date
Publication date
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Priority to JP2002259711A priority Critical patent/JP2004097263A/en
Publication of JP2004097263A publication Critical patent/JP2004097263A/en
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an air purifying device which can easily generate an aerial discharge in a wide space, and also, in a vicinity of a catalyst. <P>SOLUTION: This air purifying device is equipped with paired electrodes 2 in an air passage 1a, generates discharge by applying a high voltage between the electrodes 2, and performs an air purification using the discharge. In the air purifying device, a fibrous dielectric member 3 is arranged between the electrodes 2, and air to be treated is made to pass therethrough. In this case, attention is paid to the fact that discharge is easily generated in a wide space by spatially arranging the dielectric member, and the dielectric member is formed into a fibrous member and is arranged in a space between the electrodes 2. Thus, a pressure loss is reduced, and in addition, discharge can be easily generated in the wide space. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、生活環境内で発生する室内の各種臭気や建材・家具等から発生するホルムアルデヒドや揮発性有機化合物(VOC)、および車両の車室内で発生したり外気から流入したりする各種臭気や排気ガスなど、空気中に含まれるガス状汚染物質を浄化する空気浄化装置に関するものであり、特に、放電のエネルギーを用いるものにおいて、その放電エネルギーを有効に活用ための構造に関する。
【0002】
【従来の技術】
従来、電極間でコロナ放電や沿面放電を生じさせ、その放電エネルギーによってガス状汚染物質を分解・除去する空気浄化装置がある。図2は、そのような放電のエネルギーを用いる従来の空気浄化装置の基本構造を表す模式図である。この装置では、筐体1の空気通路1a内で、電極2間に高電圧を掛けて放電を生じさせ、励起したプラズマが空気流れに乗って下流の触媒5を通過することにより脱臭を行っている。
【0003】
【発明が解決しようとする課題】
しかし、上記従来方法においては、放電のエネルギーが効率良く使われていないことと、放電により生じたオゾンが消費しきれずに空気中に流出してしまうという問題がある。オゾンの流出は環境基準に達しないまでも、処理空気中のオゾン濃度が高くなることは人体に悪影響を及ぼすものである。そこで、オゾン濃度を問題のないレベルまで下げるために放電のエネルギーを小さくすることとなるが、これは一方で脱臭性能が低下するという相反する問題となってしまう。
【0004】
本発明はこのような従来の問題に鑑みて成されたものであり、その目的は、広い空間で容易に、且つ触媒の近傍で気中放電を生じさせることのできる空気浄化装置を提供することにある。
【0005】
【課題を解決するための手段】
上記目的を達成するため、請求項1および請求項3記載の技術的手段を採用する。すなわち、請求項1に記載の発明では、空気通路(1a)中に対を成す電極(2)を備え、電極(2)間に高電圧を印加して放電を生じさせ、その放電を用いて空気浄化を行なう空気浄化装置において、電極(2)間に繊維状誘電部材(3)を配置して処理空気を通過させることを特徴とする。
【0006】
これは、誘電部材を空間的に配置することで広い空間で容易に放電が生じることに着目したものであり、本発明では誘電材を繊維状部材として電極(2)間の空間に配置している。これにより、低圧損としたうえ、広い空間で容易に放電を生じさせることができる。また、製品とした際の取り扱いが容易となる。
【0007】
請求項2に記載の発明では、繊維状誘電部材(3)に、常温でも触媒作用を発揮すると共に、放電のエネルギーによって活性化する触媒を担持させたことを特徴とする。これは、触媒部分に直接放電するという発想を基に、上記繊維状誘電部材(3)に触媒を担持させたものである。これにより、触媒の近傍で有毒ガスや酸素分子が放電エネルギーで解離するので、効果的に触媒によってガス処理を行なうことができる。尚且つ、繊維状部材とすることにより触媒表面積を広く確保することができる。
【0008】
請求項3に記載の発明では、電極(2)は、多孔状の金属網であることを特徴とする。これにより、放電を生じている両電極(2)そのものにガス状汚染物質が含まれる空気を流通させて効率良く浄化することができる。尚、上記各手段の括弧内の符号は、後述する実施形態記載の具体的手段との対応関係を示すものである。
【0009】
【発明の実施の形態】
以下、本発明の実施形態を図面に基づき説明する。図1(a)は本発明の一実施形態における空気浄化装置の基本構造を表す模式図、(b)は浄化部の拡大模式図、(c)は繊維状誘電体の更なる拡大模式図であり電荷分布と放電を模式で示す。この浄化部は、内部に空気通路1aを有する筐体1内に配置されている。そして、その空気通路1a中に対を成す電極2を備え、電極2間に高圧電源4から数kVの高電圧を印加して放電を生じさせ、その放電を用いて空気浄化を行なう空気浄化装置である。
【0010】
対を成す電極2は、穴開きメタルやメタルメッシュ等の多孔状の金属網で形成されている。また、放電のために印加される高電圧の波形は、鋸波、パルス波、矩形波、交流、脈流である。そして、本実施形態の特徴として、電極2間に繊維状誘電部材3を配置して処理空気を通過させると共に、その繊維状誘電部材3の各繊維3aに、常温でも触媒作用を発揮すると共に放電のエネルギーによって活性化する触媒を担持させている。
【0011】
担持させている触媒は、常温でも触媒作用を発揮すると共に、放電のエネルギーによって活性化する触媒であり、具体的には、マンガンと二酸化チタンとの混合物を用いているが、これに限らず、好ましくは、鉄(Fe)・マンガン(Mn)・アルミニウム(Al)のいずれかの酸化物と、鉄(Fe)・マンガン(Mn)に対して銀(Ag)・コバルト(Co)・銅(Cu)・アルミニウム(Al)・ニッケル(Ni)・チタン(Ti)のいずれかを組み合わせた複合酸化物と、それらの全てに対して二酸化チタン(TiO)または金(Au)を混合させたものとのいずれかを用いても良い。
【0012】
繊維状誘電部材3は、チタン酸バリウム・チタン酸ストロンチウム・二酸化チタン・チタニア等、ある程度の誘電率を持つ材質を繊維状に形成し、その繊維状のものを綿・織布・不織布状とした基材である。そして、上記物質の触媒を液体に混合したスラリーの中に、上記基材である繊維状誘電部材3を含浸して各繊維3aに触媒を付着させている。
【0013】
このような繊維状誘電部材3を介して電極2に高電圧を印加すると、電極2間全体で気中放電が生じることとなり、この放電により近傍の触媒が活性化されて臭い成分を酸化分解する。代表的な反応式としてアセトアルデヒド(CHCHO)の分解例を下記に示す。
【0014】
【化1】2CHCHO+5O→4CO+4H
次に、本実施形態の特徴と効果を述べる。まず、電極2間に繊維状誘電部材3を配置して処理空気を通過させている。これは、誘電部材を空間的に配置することで広い空間で容易に放電が生じることに着目したものであり、本実施形態では誘電材を繊維状部材として電極2間の空間に配置している。これにより、低圧損としたうえ、広い空間で容易に放電を生じさせることができる。また、製品とした際の取り扱いが容易となる。
【0015】
また、繊維状誘電部材3に、常温でも触媒作用を発揮すると共に、放電のエネルギーによって活性化する触媒を担持させている。これは、触媒部分に直接放電するという発想を基に、上記繊維状誘電部材3に触媒を担持させたものである。これにより、触媒の近傍で有毒ガスや酸素分子が放電エネルギーで解離するので、効果的に触媒によってガス処理を行なうことができる。尚且つ、繊維状部材とすることにより触媒表面積を広く確保することができる。
【0016】
また、電極2は、多孔状の金属網である。これにより、放電を生じている両電極2そのものにガス状汚染物質が含まれる空気を流通させて効率良く浄化することができる。尚、繊維状誘電部材3に通過させる風の向きは、電極2の面に対して垂直でも水平でも良い。また、電極2と繊維状誘電部材3とは接触させても良いし離しても良い。
【0017】
(他の実施形態)
上述の実施形態では、繊維状誘電部材3に触媒を担持させているが、対を成す電極2のメタル表面にも触媒を担持させても良い。また、上述の実施形態では電極2と繊維状誘電部材3との基本構成であるため、当然、複数対の電極2と複数の繊維状誘電部材3とを積層する構造としても良い。
【図面の簡単な説明】
【図1】(a)は本発明の一実施形態における空気浄化装置の基本構造を表す模式図、(b)は浄化部の拡大模式図、(c)は繊維状誘電体の更なる拡大模式図であり電荷分布と放電を模式で示す。
【図2】従来の空気浄化装置の基本構造を表す模式図である。
【符号の説明】
1a 空気通路
2 電極
3 繊維状誘電部材
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to various indoor odors generated in a living environment, formaldehyde and volatile organic compounds (VOC) generated from building materials and furniture, and various odors generated in a vehicle cabin or flowing from outside air. The present invention relates to an air purification device for purifying gaseous pollutants contained in air such as exhaust gas, and more particularly, to a structure for using discharge energy effectively in a device using discharge energy.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, there is an air purification device that generates corona discharge or creeping discharge between electrodes, and decomposes and removes gaseous pollutants by the discharge energy. FIG. 2 is a schematic diagram showing a basic structure of a conventional air purification device using such discharge energy. In this device, a high voltage is applied between the electrodes 2 in the air passage 1a of the housing 1 to generate a discharge, and the excited plasma passes through the downstream catalyst 5 in the air flow to deodorize. I have.
[0003]
[Problems to be solved by the invention]
However, in the above-mentioned conventional method, there are problems that the energy of the discharge is not used efficiently and that the ozone generated by the discharge flows out into the air without being completely consumed. Even if the outflow of ozone does not reach the environmental standard, an increase in the concentration of ozone in the treated air has a bad effect on the human body. Therefore, in order to reduce the ozone concentration to a level that does not cause a problem, the energy of the discharge is reduced, but this is a contradictory problem that the deodorizing performance is reduced.
[0004]
The present invention has been made in view of such conventional problems, and an object of the present invention is to provide an air purification device that can easily generate air discharge near a catalyst in a wide space. It is in.
[0005]
[Means for Solving the Problems]
In order to achieve the above object, the technical means described in claims 1 and 3 are adopted. That is, in the first aspect of the present invention, a pair of electrodes (2) is provided in the air passage (1a), a high voltage is applied between the electrodes (2) to generate a discharge, and the discharge is used. An air purifying apparatus for purifying air is characterized in that a fibrous dielectric member (3) is arranged between electrodes (2) to allow processing air to pass therethrough.
[0006]
This focuses on the fact that discharge is easily generated in a large space by spatially disposing the dielectric member. In the present invention, the dielectric material is disposed as a fibrous member in the space between the electrodes (2). I have. As a result, a low pressure loss can be achieved, and discharge can be easily generated in a wide space. In addition, it becomes easy to handle the product.
[0007]
The invention according to claim 2 is characterized in that the fibrous dielectric member (3) carries a catalyst that exhibits a catalytic action even at normal temperature and is activated by discharge energy. This is based on the idea of discharging directly to the catalyst portion, and the catalyst is carried on the fibrous dielectric member (3). As a result, the toxic gas and oxygen molecules are dissociated by the discharge energy in the vicinity of the catalyst, so that the gas can be effectively treated by the catalyst. In addition, by using a fibrous member, a wide catalyst surface area can be ensured.
[0008]
The invention according to claim 3 is characterized in that the electrode (2) is a porous metal net. Thereby, the air containing the gaseous pollutant can be circulated through the two electrodes (2) that are generating the electric discharge, and the two electrodes (2) can be efficiently purified. Note that the reference numerals in parentheses of the above means indicate the correspondence with specific means described in the embodiment described later.
[0009]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1A is a schematic diagram illustrating a basic structure of an air purification device according to an embodiment of the present invention, FIG. 1B is an enlarged schematic diagram of a purification unit, and FIG. 1C is a further enlarged schematic diagram of a fibrous dielectric. The charge distribution and discharge are schematically shown. This purifying section is disposed in the housing 1 having the air passage 1a inside. A pair of electrodes 2 is provided in the air passage 1a. A high voltage of several kV is applied between the electrodes 2 by a high voltage power supply 4 to generate a discharge, and an air purifying apparatus for purifying air using the discharge. It is.
[0010]
The electrodes 2 forming a pair are formed of a porous metal net such as a perforated metal or a metal mesh. The waveform of the high voltage applied for the discharge is a sawtooth wave, a pulse wave, a rectangular wave, an alternating current, and a pulsating flow. As a feature of this embodiment, the fibrous dielectric member 3 is arranged between the electrodes 2 to allow the processing air to pass therethrough, and at the same time, the fibers 3a of the fibrous dielectric member 3 exhibit a catalytic action even at normal temperature and discharge. The catalyst which is activated by the energy of is carried.
[0011]
The supported catalyst is a catalyst that exerts a catalytic action even at room temperature and is activated by the energy of discharge.Specifically, a mixture of manganese and titanium dioxide is used, but not limited thereto. Preferably, any one of iron (Fe), manganese (Mn), and aluminum (Al) oxides, and silver (Ag), cobalt (Co), and copper (Cu) with respect to iron (Fe) and manganese (Mn) A) a composite oxide combining any of aluminum (Al), nickel (Ni), and titanium (Ti), and a mixture of all of them mixed with titanium dioxide (TiO 2 ) or gold (Au). May be used.
[0012]
The fibrous dielectric member 3 is formed of a material having a certain dielectric constant, such as barium titanate, strontium titanate, titanium dioxide, titania, etc., into a fibrous form, and the fibrous form is made of cotton, woven fabric, or nonwoven fabric. It is a substrate. Then, the fibrous dielectric member 3 as the base material is impregnated in a slurry obtained by mixing a catalyst of the above substance with a liquid, so that the catalyst is attached to each fiber 3a.
[0013]
When a high voltage is applied to the electrodes 2 via such a fibrous dielectric member 3, air discharge occurs in the entire space between the electrodes 2, and this discharge activates a nearby catalyst to oxidatively decompose odor components. . An example of the decomposition of acetaldehyde (CH 3 CHO) is shown below as a typical reaction formula.
[0014]
Embedded image 2CH 3 CHO + 5O 2 → 4CO 2 + 4H 2 O
Next, features and effects of the present embodiment will be described. First, the fibrous dielectric member 3 is arranged between the electrodes 2 to allow the processing air to pass therethrough. This focuses on the fact that discharge is easily generated in a wide space by spatially disposing the dielectric member. In the present embodiment, the dielectric material is disposed as a fibrous member in the space between the electrodes 2. . As a result, a low pressure loss can be achieved, and discharge can be easily generated in a wide space. In addition, it becomes easy to handle the product.
[0015]
Further, the fibrous dielectric member 3 carries a catalyst that exhibits a catalytic action even at normal temperature and is activated by the energy of discharge. This is based on the idea that the catalyst portion is directly discharged, and a catalyst is carried on the fibrous dielectric member 3. As a result, the toxic gas and oxygen molecules are dissociated by the discharge energy in the vicinity of the catalyst, so that the gas can be effectively treated by the catalyst. In addition, by using a fibrous member, a wide catalyst surface area can be ensured.
[0016]
The electrode 2 is a porous metal net. Thus, the air containing the gaseous pollutant can be circulated through the two electrodes 2 that are generating the discharge, and the two electrodes 2 can be efficiently purified. The direction of the wind passing through the fibrous dielectric member 3 may be vertical or horizontal with respect to the surface of the electrode 2. Further, the electrode 2 and the fibrous dielectric member 3 may be in contact with each other or may be separated from each other.
[0017]
(Other embodiments)
In the above-described embodiment, the catalyst is supported on the fibrous dielectric member 3, but the catalyst may also be supported on the metal surfaces of the paired electrodes 2. In the above-described embodiment, since the basic configuration includes the electrode 2 and the fibrous dielectric member 3, a structure in which a plurality of pairs of electrodes 2 and a plurality of fibrous dielectric members 3 are naturally stacked may be employed.
[Brief description of the drawings]
1A is a schematic diagram showing a basic structure of an air purification device according to an embodiment of the present invention, FIG. 1B is an enlarged schematic diagram of a purification unit, and FIG. 1C is a further enlarged schematic diagram of a fibrous dielectric. It is a figure and shows a charge distribution and discharge schematically.
FIG. 2 is a schematic diagram illustrating a basic structure of a conventional air purification device.
[Explanation of symbols]
1a Air passage 2 Electrode 3 Fibrous dielectric member

Claims (3)

空気通路(1a)中に対を成す電極(2)を備え、前記電極(2)間に高電圧を印加して放電を生じさせ、その放電を用いて空気浄化を行なう空気浄化装置において、
前記電極(2)間に繊維状誘電部材(3)を配置して処理空気を通過させることを特徴とする空気浄化装置。
An air purifying apparatus comprising a pair of electrodes (2) in an air passage (1a), applying a high voltage between the electrodes (2) to generate a discharge, and purifying the air using the discharge.
An air purifying apparatus, wherein a fibrous dielectric member (3) is arranged between the electrodes (2) to allow processing air to pass therethrough.
前記繊維状誘電部材(3)に、常温でも触媒作用を発揮すると共に、放電のエネルギーによって活性化する触媒を担持させたことを特徴とする請求項1に記載の空気浄化装置。The air purification device according to claim 1, wherein the fibrous dielectric member (3) carries a catalyst that exhibits a catalytic action even at room temperature and is activated by discharge energy. 前記電極(2)は、多孔状の金属網であることを特徴とする請求項1または請求項2に記載の空気浄化装置。The air purification device according to claim 1 or 2, wherein the electrode (2) is a porous metal net.
JP2002259711A 2002-09-05 2002-09-05 Air purifying device Pending JP2004097263A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006068639A (en) * 2004-09-02 2006-03-16 Toshiba Home Technology Corp Catalyst reactor
JP2008221077A (en) * 2007-03-09 2008-09-25 Mitsubishi Electric Corp Air purifier and filter
JP2008221078A (en) * 2007-03-09 2008-09-25 Mitsubishi Electric Corp Air purifier and filter
CN105352051A (en) * 2015-12-09 2016-02-24 张展浩 Air purification device, automotive air purifier and vehicle
CN116592483A (en) * 2023-05-25 2023-08-15 张彧 Electronic equipment, air purification method, fresh air system and storage medium

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006068639A (en) * 2004-09-02 2006-03-16 Toshiba Home Technology Corp Catalyst reactor
JP2008221077A (en) * 2007-03-09 2008-09-25 Mitsubishi Electric Corp Air purifier and filter
JP2008221078A (en) * 2007-03-09 2008-09-25 Mitsubishi Electric Corp Air purifier and filter
CN105352051A (en) * 2015-12-09 2016-02-24 张展浩 Air purification device, automotive air purifier and vehicle
CN105352051B (en) * 2015-12-09 2019-05-28 张展浩 Air purifiers, air purifiers for vehicles and vehicles
CN116592483A (en) * 2023-05-25 2023-08-15 张彧 Electronic equipment, air purification method, fresh air system and storage medium

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