JP2004024993A - Cleaning equipment for containers - Google Patents

Cleaning equipment for containers Download PDF

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JP2004024993A
JP2004024993A JP2002183398A JP2002183398A JP2004024993A JP 2004024993 A JP2004024993 A JP 2004024993A JP 2002183398 A JP2002183398 A JP 2002183398A JP 2002183398 A JP2002183398 A JP 2002183398A JP 2004024993 A JP2004024993 A JP 2004024993A
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cleaning
water
ozone
containers
washing
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JP4013667B2 (en
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Shinobu Numata
沼田 忍
Kazutaka Takahashi
高橋 和孝
Akinori Kawamitsu
川満 昭範
Yujiro Kitade
北出 雄二郎
Takayuki Morioka
森岡 崇行
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Fuji Electric Co Ltd
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Fuji Electric Holdings Ltd
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Abstract

【課題】食品や医薬品等に使用する容器類のすすぎ洗浄に、従来は次亜塩素酸ナトリウムを添加した水を殺菌水として用いることもあり、刺激臭が強く、遅効性で、腐食性が高く、残留性があるなどの問題があった。また、オゾン水を容器類の洗浄に用いた場合、水質や周囲環境により、殺菌に必要なオゾン水が得られないといった問題があった。本発明の目的は、洗浄水の有効利用と、塩素系の消毒剤を使用せず、人体への悪影響を受けない容器類の洗浄方法および洗浄装置を提供することにある。
【解決手段】容器類のすすぎ洗浄を、アルカリ液の洗い流し洗浄、3ppm程度の溶存オゾン濃度のオゾン水を用いる殺菌洗浄と、0.1ppm程度の溶存オゾン濃度の低濃度オゾン水か、オゾンが揮発した無菌水を用い容器に対する最終洗浄である仕上げ洗浄から成る三つの工程で行い、また、仕上げ洗浄に使用した洗浄水を、溶存オゾン濃度を調整して殺菌用オゾン水として循環使用することで、洗浄水の節水を図る。
【選択図】図1
[PROBLEMS] For rinsing containers used for foods, pharmaceuticals, etc., water to which sodium hypochlorite is conventionally added may be used as sterilizing water, which has a strong pungent odor, is slow-acting, and highly corrosive. However, there are problems such as persistence. Further, when ozone water is used for cleaning containers, there is a problem that ozone water required for sterilization cannot be obtained depending on water quality and surrounding environment. An object of the present invention is to provide a method and an apparatus for cleaning containers that make effective use of cleaning water, do not use a chlorine-based disinfectant, and are not adversely affected by the human body.
Kind Code: A1 Rinsing of containers is performed by washing off with an alkaline solution, sterilizing cleaning using ozone water having a dissolved ozone concentration of about 3 ppm, and low concentration ozone water having a dissolved ozone concentration of about 0.1 ppm or volatilization of ozone. Performed in three steps consisting of final cleaning, which is the final cleaning of the container using the sterilized water, and the washing water used for final cleaning is adjusted to the dissolved ozone concentration and circulated and used as sterilizing ozone water, Save water for washing water.
[Selection diagram] Fig. 1

Description

【0001】
【発明の属する技術分野】
本発明は、食品・医薬品等の衛生的な容器類を必要とする分野に対し、汚れを洗い流して殺菌する容器類の洗浄装置に関する。
【0002】
【従来の技術】
飲料用ビンや食材トレイ等の飲食品や医薬品を充填または包装する容器類は、洗浄装置により衛生的に洗浄されている。
従来の一般的な容器洗浄方法は、容器類の予備洗浄、加熱したアルカリ溶液による本洗浄、洗浄液等を洗い流し、殺菌と仕上げを行うすすぎ洗浄の工程で行われている。
【0003】
例えば、特開2001−205213号公報に開示されている容器洗浄装置は、予備洗浄、70℃に過熱された苛性洗浄液による浸漬洗浄及び洗浄ノズルでのジェット洗浄、洗浄ノズルによる洗浄水や清水を噴射して行う、数段の仕上げ洗浄の工程が記載されている。
また、特開平8−243522号公報に開示されている容器洗浄装置は、容器類の供給部と排出部が同一方向にあるモノエンドタイプであり、常温よりやや高温の洗浄水による予備洗浄槽への浸漬、70℃の高温の苛性洗浄水で満たされている二段の浸漬層への浸漬、苛性洗浄水のジェット洗浄、五段のすすぎ洗浄による洗浄工程が示されている。すすぎ洗浄では、最終の二段は、清水を供給しての洗浄であるが、その上流側工程では、洗浄水を回収してポンプで吸い上げて再利用する方法が示されている。
【0004】
さらに、特開平8−206621号公報に開示されている容器洗浄装置においては、上記特開平8−243522号公報に開示されている内容に加えて、すすぎ洗浄部での最初に、容器類に付着した苛性洗浄液を除去し、最終的には次亜塩素殺菌部を設ける記載や、すすぎ洗浄廃液を予備洗浄に再利用する方法が示されている。
【0005】
従来の洗浄装置の代表的な構成例として、上記公知文献に示されていた容器洗浄装置の模式図を図2に示す。この洗浄装置は、容器供給部1と容器排出部5が同一方向にあるモノエンドタイプの例であり、予備洗浄部2、本洗浄部3、すすぎ洗浄工程26などで構成されている。以下に、この洗浄装置の洗浄工程の概要を説明する。
【0006】
まず、洗浄される容器類を容器供給部1から洗浄装置内に搬入し、予備洗浄部2で常温よりやや高温の洗浄水等で前洗浄を行い、簡単に除去可能な付着物や汚れを洗い流す。
次に、本洗浄部3では、加熱した苛性洗浄液が貯留されている洗浄槽9に浸漬させることで付着した汚れを溶かし、同時に加熱による殺菌も行なう。また、洗浄槽9から吸い上げポンプ13により洗浄液を吸い上げて吹き付ける、ジェット洗浄部8によって付着物を完全に洗い落とす。この際、図示しないブラシを用いることもある。この工程は、汚れを有効に溶かすためにアルカリ性の苛性洗浄液で満たされている複数の洗浄槽9の中で、複数回繰り返して行われる。
【0007】
苛性洗浄液によるアルカリ洗浄が終わった洗浄対象の容器類は、すすぎ洗浄工程26で洗浄液等を洗い流し、殺菌処理も行う。このすすぎ洗浄工程26に用いる仕上げ水は、殺菌された容器類の再汚染を防ぐために無菌水を用いる必要がある。そこで多くの場合は、次亜塩素酸ナトリウムを添加して数十ppmの塩素系殺菌水を用いている。
【0008】
すすぎ洗浄工程26は、上流側から洗い流し洗浄部11、循環仕上げ洗浄部4a、仕上げ洗浄部4および次亜塩素殺菌洗浄部12aにより構成されており、各洗浄部分には、ノズルから洗浄水を噴射する機構が備えられ、下方に配置されている内洗ジェット7は容器類内部の洗浄を行い、上方に配置されている外洗ジェットは容器類外周の洗浄を行う。
【0009】
すすぎ洗浄工程26中の循環仕上げ洗浄部4aでは、ノズル下方の洗浄水槽15aから洗浄水を吸い上げポンプ13aにて吸い上げて、洗浄対象の容器類に洗浄水の噴射を行う。また、仕上げ洗浄部4では、図示しない別系統から、清水を供給して噴射し、さらに次亜塩素殺菌洗浄部12aでは、次亜塩素水が噴射されて殺菌が行われる。
【0010】
以上に示す流れにより洗浄が完了した容器類は、容器排出部5を経て商品充填ラインへ移される。これらの洗浄工程は、搬送用コンベア10を使用して自動的に行われている。
オゾン水を用いた容器殺菌洗浄に関しては、容器類の口部からノズルを挿入し、あるいは容器類の外周近傍にノズルを配置して、オゾン水やオゾン霧を噴霧する殺菌洗浄装置が、特開2000−128131号公報、特開平9−165016号公報、特開平7−76325号公報、および特開平5−310295号公報に開示されている。しかし、オゾン水を容器類と接触させて殺菌洗浄することの記載のみであり、オゾン水を生成して容器類に噴霧するノズルまでの過程に関する方法の記述はされていない。
【0011】
また、食品の殺菌と洗浄を目的として、オゾン水を生成して噴霧する装置に関して、特開2001−321144号報には、海水を利用して0.05ppm〜10ppmのオゾン水を生成する装置構成が開示されている。さらに、特開平11−292032号公報には、洗浄部の下部にオゾン水タンクを兼ねた溶液タンクが配置され、循環ポンプにより溶液をオゾンガスとの混合器に送り、5ppmのオゾン水を生成し、洗浄対象物にオゾン水を噴霧する構成が開示されている。
【0012】
しかしながら、オゾン水を利用した上記公知文献においては、図2に記載した予備洗浄と苛性洗浄液によるアルカリ洗浄による過程を経て、すすぎ洗浄工程の最終段階として仕上げ洗浄を行う構成の記述はなく、オゾン水洗浄のみが記載された装置構成が示されている。
【0013】
【発明が解決しようとする課題】
このように、従来、容器類洗浄におけるすすぎ洗浄部に用いる水は、塩素を含む水道水を利用する例が多いが、より積極的に殺菌を十分に行うために、塩素を添加した殺菌水を用いる場合もある。例えば、塩素系の殺菌剤として多く使われている次亜塩素酸ナトリウムは安価であり、また食品添加物としての認可を受けているため、使いやすい殺菌剤である。しかし、次亜塩素酸ナトリウムを添加した水は、刺激臭が強く、遅効性であり、腐食性が高く、残留性がある等の短所があり、殺菌を目的とした実際の使用では、数十ppmの高濃度として使用するため、刺激臭や残留性の短所が目立つばかりか、人体への悪影響も問題とされている。
【0014】
また、食品関連へこの洗浄方法を適用する場合には、洗浄した後の容器類に食材を充填または配置すると、残留した塩素によって食材の酸化変質(酸敗)等が起こることもあり、問題となる。
オゾン水を利用した容器洗浄例も示されているが、オゾンは、自己分解により濃度低下が起こるために、残留性がなく安全である利点を有している反面、保存が困難である。オゾンの自己分解速度は、高温になる程またはpHが高い(アルカリ)程、加速される。従って、高温のアルカリ洗剤による容器洗浄実施後のすすぎ洗浄工程において、オゾン水を利用する実際の容器洗浄装置においては、アルカリ洗剤の影響や高温状態による水質や周囲環境から、容器殺菌洗浄部で、殺菌に有効な溶存オゾン濃度を有するオゾン水が得られないといった問題があった。
【0015】
この発明の目的は、殺菌を十分に行う容器類洗浄のすすぎ洗浄工程に、上記のような塩素系殺菌水を利用せず、また、すすぎ用の洗浄水を有効に利用して節約し、さらに人体への悪影響を受けないオゾン水を利用した容器類の洗浄方法および洗浄装置を提供することにある。
【0016】
【課題を解決するための手段】
上記課題を解決するために、容器類の洗浄過程で、仕上げ洗浄を無菌水で行い、仕上げ洗浄後の溶液を回収して殺菌水を生成し、仕上げ洗浄の前工程である殺菌洗浄部に供給する容器類の洗浄装置において、
殺菌水は、仕上げ洗浄後の回収溶液と、殺菌洗浄部の殺菌後の回収溶液とからなるアルカリ性質を持たない溶液を高濃度のオゾン水とすることにより生成され、この殺菌水を殺菌洗浄の前工程でも流用することとする。
【0017】
この際に、容器類の殺菌洗浄工程以前に、容器類に付着したアルカリ洗浄液を流用された殺菌水で洗い流す工程を設けたことにする。
【0018】
【発明の実施の形態】
以下、本発明を実施例に基づき説明する。
図1は、本発明の実施例に係る容器洗浄装置のすすぎ洗浄部の構造を示す模式図である。この図のように、すすぎ洗浄工程26は、容器類に付着したアルカリ溶液などを水洗で除く洗い流し洗浄部11と、容器類の殺菌を行う殺菌洗浄部12と、容器類を無菌水等の清水を用いて洗浄の最終状態として仕上げるための仕上げ洗浄部4と、仕上げ洗浄水廃液槽14と、殺菌洗浄水槽15と、仕上げ洗浄水用第1オゾナイザ19と、殺菌洗浄水用第2オゾナイザ24等とで構成している。
【0019】
本洗浄で、ブラシ洗い、熱殺菌、アルカリ洗浄等を終えた洗浄対象物である容器類は、すすぎ洗浄工程26に移行する。すすぎ洗浄工程26では、まず、洗い流し洗浄部11で本洗浄で容器類に付着したアルカリ溶液等を落とす。このために、洗い流し洗浄部11下部に設けられた仕上げ洗浄水廃液槽14内の水は、アルカリ性の水となり、pHが高いとオゾン自己分解速度が速くなるためにオゾン水への再利用には不向きとなるので、本洗浄や予備洗浄水として再利用する。
【0020】
次に、殺菌洗浄部12により、溶存オゾン濃度が数ppmのオゾン水を用いた容器類の殺菌を行い、仕上げ洗浄部4で溶存オゾン濃度が極低濃度オゾン水であるかオゾンが揮発した無菌水による最終洗浄を行なう。
オゾン水を生成するための水は、pHが高ければオゾン水中の溶存オゾン濃度の自己分解速度が速くなる。また、水質中に有機炭素成分が多く存在すると、オゾン水中の溶存オゾンが有機炭素と反応して溶存オゾン濃度が急激に低下する。この結果、殺菌対象の容器類に付着後のオゾン水に含まれる溶存オゾン濃度が急激に低下することは、菌との接触時間が短くなり、十分な殺菌が行えなくなる。そこで、pH調整をするか、初期溶存オゾン濃度を高く設定する必要となる。
【0021】
従って、食品容器類の殺菌洗浄装置としてのオゾン水濃度は、オゾン水を生成するための水質によって、必要となる溶存オゾン濃度が変化することになるため、オゾン水の濃度を規定できない。
オゾン水による殺菌効果は、厚生省予防衛生研究所により、次に示すデータが公表されている。対象微生物がBacillus subtilis菌(枯草菌)の場合は、水質として水温20.0℃でpH6.5の条件において、溶存オゾン濃度0.5ppmのオゾン水に30秒間接触した時、99.9%の殺菌率が得られている。また、食品衛生上問題とされる大腸菌やブトウ球菌を対象微生物とした場合には、水温21.0℃でpH7.0の条件において、溶存オゾン濃度1ppmのオゾン水に5秒間の接触で、略100%の殺菌が行われたことが示されている。
【0022】
従って、微生物との接触時間は1分程度あれば、微生物を不活性化できる。容器洗浄装置では、70℃程度の高温によるアルカリ洗浄を経て、すすぎ洗浄工程26に移行するため、すすぎ洗浄工程26で洗浄される容器類の温度が常温より高くなる。また水道法水質基準では、pH値が5.8以上8.6以下と決められている。オゾン水の水質が30℃でpH8とした場合は、オゾン自己分解によるオゾン濃度低下が、約1分で20%以下である。以上より、殺菌洗浄部12から噴射する殺菌用オゾン水としては、安全率を考慮しても、2〜3ppm程度の溶存オゾン濃度があれば良い。
【0023】
仕上げ洗浄部4では、長時間接触しても人体に影響のない0.1ppm程度であることが望ましいが、商品を容器類内に充填する次工程、または人が洗浄後の容器類に接触する時点で、商品の酸化や人体への影響を考慮して、揮発するオゾンガスの濃度による周囲環境も含めて、0.1ppm程度まで低下していれば良い。このため、仕上げ洗浄部では、必ずしも低濃度である必要無く、微生物の再付着を防ぐ無菌水の意味でのオゾン水であることが重要である。
【0024】
仕上げ洗浄部4に用いる低濃度オゾン水は、水道水等を受水槽16に給水し、第1Aポンプ17で2つのラインへ水を送り出す。一方は、第1エゼクタ18に送り、第1オゾナイザ19から発生させたオゾンガスと混合して、オゾン水を生成させ、混合タンク20に送り込む。もう一方の水は、直接混合タンク20に注入し、オゾン水との混合比を調節して、所定の低濃度オゾン水を生成する。混合タンク20で生成された低濃度オゾン水は、第1Bポンプ21で仕上げ洗浄部4に送り出される。この時、第1Bポンプ21から仕上げ洗浄部4までの配管が十分に長ければ、仕上げ洗浄部4に到達するまでの間で、オゾンの自己分解により、溶存オゾン濃度は、低濃度またはゼロに近い状態まで減少する。
【0025】
仕上げ洗浄部4で容器洗浄に使用された低濃度オゾン水は、洗浄された容器類から滴り落ちて、殺菌洗浄水槽15に流れ込む。殺菌洗浄水槽15内の水は、第2Aポンプ22で第2エゼクタ23を通る経路を循環し、第2エゼクタ23で、第2オゾナイザ24から発生させたオゾンガスとの混合を調節して、オゾン水を生成して、殺菌洗浄水槽15内をオゾン水に変える。この場合、殺菌洗浄水槽15内の液体をオゾン水にする手段として、第2エゼクタ23を使用しない方法として、殺菌洗浄水槽15に図示しない散気管を配置し、第2オゾナイザ24から発生するオゾンガスを直接殺菌洗浄水槽15に送り曝気することも可能である。
【0026】
殺菌洗浄水槽15内に生成されたオゾン水は、第2Bポンプ25で吸い上げられ、殺菌洗浄部12と洗い流し洗浄部11とで洗浄される容器類に吹き付けられる。殺菌洗浄部12から吹き出したオゾン水は、洗浄される容器類に当たった後、滴り落ちて殺菌洗浄水槽15に戻り、再びオゾン水として利用される。また、洗い流し洗浄部11から吹き出したオゾン水は、洗浄される容器類に当たった後に、仕上げ洗浄水廃液槽14に滴り落ち、本洗浄や予備洗浄等へ再利用される。
【0027】
殺菌洗浄水槽15には、仕上げ洗浄部4からの新しい洗浄水と殺菌洗浄部12からの再利用水とがオゾン水として流れ込む構成のため、洗い流し洗浄部11へ水を利用しないと殺菌洗浄水槽15ではオーバーフローを起こす。このためオーバーフロー分のオゾン水を、洗い流し洗浄部11で、容器類に付着したアルカリ洗浄液等を洗い流すことに流用する。
【0028】
【発明の効果】
この発明では、容器類洗浄におけるすすぎ洗浄工程を、従来の塩素系殺菌水にかえてオゾン水を使用することにし、本洗浄で容器類に付着したアルカリ溶液などを水洗で除く洗い流し洗浄と、溶存オゾン濃度が3ppm程度のオゾン水を用いて容器類の殺菌を行う殺菌洗浄と、溶存オゾン濃度がオゾンの刺激臭を排除した0.1ppm程度の低濃度オゾン水であるか、オゾンが揮発した後の無菌水を用いた仕上げ洗浄との三つの工程で行うことにした。
【0029】
この発明で使用したオゾンは、食品添加物質として既存添加物の扱いとなっており、どのような食品にも制約無く使用できる。本発明での容器類洗浄による、オゾン水洗浄は、下記の効果が得られる。
まず、第1は殺菌と仕上げ洗浄水を塩素系殺菌水からオゾン水に変更した効果である。オゾンは自然に消滅して残留しないため、従来の薬品殺菌材と異なり、人体に安全であり、衛生的に殺菌・洗浄を行なうことが可能である。また、十分な容器殺菌後に、充填、配置した食材自体の変質を防止できる。
【0030】
第2は仕上げ洗浄水の再利用の効果である。殺菌工程で使用するオゾン水は、殺菌の後工程の仕上げ洗浄に使用した水を、殺菌洗浄槽に溜めて殺菌用オゾン水の水として再利用することで、洗浄装置に供給する水道水量を節約できる。
第3は殺菌洗浄前の本洗浄で容器類に付着した洗浄液の洗い流しへのオゾン水を流用できる効果である。本洗浄で用いたアルカリ溶液等の洗浄液が容器類に付着したまま、殺菌用オゾン水を容器類に添加すると、洗剤等の有機物にオゾンが消費され、殺菌前にオゾンが消失されてしまう。また、アルカリ性中ではオゾンの自己消費を急激に加速する。そこで、殺菌洗浄水と仕上げ洗浄水が流れ込む最終槽は、オーバーフローするオゾン水を、洗い流し洗浄部で容器類に付着したアルカリ洗浄液等を洗い流すことに流用できるので、本洗浄で洗浄した容器類に汚染の心配がないオゾン水を使用でき、洗浄水として新たに水道水からの供給の必要がないため、洗浄装置としては、仕上げ洗浄水分のみの水道水供給で良く、水の節約効果が大きい。
【0031】
第4に、次亜塩素水等の殺菌剤を用い、すすぎ洗浄を行っている容器洗浄設備に対しては、すすぎ洗浄工程にオゾン水の生成循環設備と俳オゾン処理設備を追加し、若干の配管系統を変更するのみで、安価で容易に、オゾン水を利用した食環境の安全性を具備した設備を提供できる。
【図面の簡単な説明】
【図1】本発明の洗浄装置の実施例としてのすすぎ洗浄部の構造を示す模式図
【図2】従来の洗浄装置の代表的な構成例を示す模式図
【符号の説明】
1:    容器供給部
2:    予備洗浄部
3:    本洗浄部
4:    仕上げ洗浄部
4a:   循環仕上げ洗浄部
5:    容器排出部
6:    外洗ジェット
7:    内洗ジェット
8:    ジェット洗浄部
9:    洗浄槽
10:    搬送用コンベア
11:    洗い流し洗浄部
12:    殺菌洗浄部
12a:   次亜塩素殺菌洗浄部
13:    吸い上げポンプ
14:    仕上げ洗浄水廃液槽
15:    殺菌洗浄水槽
15a:   洗浄水槽
16:    受水槽
17:    第1Aポンプ
18:    第1エゼクタ
19:    第1オゾナイザ
20:    混合タンク
21:    第1Bポンプ
22:    第2Aポンプ
23:    第2エゼクタ
24:    第2オゾナイザ
25:    第2Bポンプ
26:    すすぎ洗浄工程
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a container cleaning device for washing and sterilizing dirt in a field requiring sanitary containers such as food and medicine.
[0002]
[Prior art]
2. Description of the Related Art Containers for filling or packaging foods and drinks and pharmaceuticals, such as beverage bottles and food trays, are hygienically cleaned by a cleaning device.
Conventional general container cleaning methods include a pre-cleaning process for containers, a main cleaning using a heated alkaline solution, a washing solution and the like, and a rinsing process for sterilization and finishing.
[0003]
For example, a container cleaning apparatus disclosed in Japanese Patent Application Laid-Open No. 2001-205213 discloses a preliminary cleaning, immersion cleaning with a caustic cleaning solution heated to 70 ° C., jet cleaning with a cleaning nozzle, and injection of cleaning water and fresh water with a cleaning nozzle. And several steps of finish cleaning.
Further, the container cleaning apparatus disclosed in Japanese Patent Application Laid-Open No. 8-243522 is a mono-end type in which a supply part and a discharge part of containers are in the same direction, and a pre-cleaning tank using cleaning water slightly higher than room temperature. Immersion, immersion in a two-stage immersion layer filled with hot caustic washing water at 70 ° C., jet washing of caustic washing water, and five-step rinsing are shown. In the rinsing cleaning, the last two stages are cleaning by supplying fresh water. In the upstream process, a method is described in which the cleaning water is collected, pumped up and reused.
[0004]
Further, in the container cleaning apparatus disclosed in Japanese Patent Application Laid-Open No. 8-206621, in addition to the contents disclosed in Japanese Patent Application Laid-Open No. 8-243522, the container is first attached to containers in a rinsing section. A description is given of removing the caustic cleaning solution and finally providing a hypochlorite sterilizing section, and a method of reusing the rinse cleaning waste solution for preliminary cleaning.
[0005]
As a typical configuration example of a conventional cleaning device, a schematic diagram of a container cleaning device disclosed in the above-mentioned known document is shown in FIG. This cleaning device is an example of a mono-end type in which the container supply unit 1 and the container discharge unit 5 are in the same direction, and includes a preliminary cleaning unit 2, a main cleaning unit 3, a rinsing cleaning step 26, and the like. Hereinafter, an outline of the cleaning process of the cleaning device will be described.
[0006]
First, the containers to be cleaned are carried into the cleaning device from the container supply unit 1 and pre-cleaned by the pre-cleaning unit 2 with cleaning water slightly higher than room temperature to wash away easily adhered substances and dirt. .
Next, in the main cleaning section 3, the adhered dirt is dissolved by immersing it in the cleaning tank 9 in which the heated caustic cleaning liquid is stored, and at the same time, sterilization by heating is performed. Further, the cleaning liquid is sucked up from the cleaning tank 9 by the suction pump 13 and sprayed, and the adhered substances are completely washed away by the jet cleaning unit 8. At this time, a brush (not shown) may be used. This step is repeatedly performed a plurality of times in a plurality of cleaning tanks 9 filled with an alkaline caustic cleaning solution to effectively dissolve the dirt.
[0007]
The containers to be cleaned after the alkaline cleaning with the caustic cleaning solution are rinsed with the cleaning solution and the like in the rinsing cleaning step 26, and sterilization is also performed. As the finishing water used in the rinsing step 26, it is necessary to use sterile water in order to prevent recontamination of sterilized containers. Therefore, in many cases, chlorinated water of several tens ppm is added by adding sodium hypochlorite.
[0008]
The rinsing cleaning step 26 includes the rinsing cleaning unit 11, the circulating finishing cleaning unit 4a, the finishing cleaning unit 4, and the hypochlorite sterilizing cleaning unit 12a from the upstream side. The inner washing jet 7 disposed below cleans the inside of the containers, and the outer cleaning jet disposed above cleans the outer periphery of the containers.
[0009]
In the circulating finish cleaning section 4a in the rinsing cleaning step 26, the cleaning water is suctioned from the cleaning water tank 15a below the nozzle by the pump 13a, and the cleaning water is sprayed to the containers to be cleaned. Further, in the finish cleaning section 4, fresh water is supplied and injected from another system (not shown), and further, in the hypochlorite sterilizing and cleaning section 12a, hypochlorite water is injected to perform sterilization.
[0010]
The containers that have been completely cleaned according to the flow described above are transferred to the product filling line via the container discharge unit 5. These cleaning steps are automatically performed using the conveyor 10 for conveyance.
Regarding container sterilization cleaning using ozone water, a sterilization cleaning device that inserts a nozzle from the mouth of the container or arranges a nozzle near the outer periphery of the container and sprays ozone water or ozone mist is disclosed in It is disclosed in JP-A-2000-128131, JP-A-9-165016, JP-A-7-76325, and JP-A-5-310295. However, the document only describes that ozone water is brought into contact with containers to perform sterilization cleaning, and does not describe a method relating to a process up to a nozzle for generating ozone water and spraying the containers.
[0011]
Further, with respect to a device for generating and spraying ozone water for the purpose of sterilizing and washing food, Japanese Patent Application Laid-Open No. 2001-321144 discloses a device configuration for generating 0.05 ppm to 10 ppm ozone water using seawater. Is disclosed. Further, in JP-A-11-292032, a solution tank also serving as an ozone water tank is disposed below the washing unit, and the solution is sent to a mixer with ozone gas by a circulation pump to generate 5 ppm ozone water, A configuration in which ozone water is sprayed on an object to be cleaned is disclosed.
[0012]
However, in the above-mentioned known document using ozone water, there is no description of a configuration in which finish cleaning is performed as a final stage of a rinsing cleaning process through a process of pre-cleaning and alkali cleaning with a caustic cleaning solution described in FIG. An apparatus configuration in which only cleaning is described is shown.
[0013]
[Problems to be solved by the invention]
As described above, conventionally, the water used for the rinsing part in the container cleaning often uses tap water containing chlorine, but in order to more positively perform sterilization sufficiently, sterilized water added with chlorine is used. Sometimes used. For example, sodium hypochlorite, which is widely used as a chlorine-based disinfectant, is inexpensive and has been approved as a food additive, so that it is an easy-to-use disinfectant. However, water to which sodium hypochlorite is added has disadvantages such as a strong irritating odor, a long-acting effect, a high corrosiveness, and persistence. Since it is used at a high concentration of ppm, it has not only noticeable irritating odors and disadvantages of persistence, but also has an adverse effect on the human body.
[0014]
In addition, when this cleaning method is applied to foods, if the foods are filled or arranged in the containers after the cleaning, oxidative deterioration (rancidity) of the foods may occur due to residual chlorine, which is a problem. .
Although an example of cleaning a container using ozone water is also shown, ozone has a merit that it is safe without residue because it is reduced in concentration by self-decomposition, but it is difficult to store ozone. The self-decomposition rate of ozone is accelerated as the temperature becomes higher or the pH is higher (alkali). Therefore, in the rinsing step after performing the container cleaning with a high-temperature alkaline detergent, in an actual container cleaning device using ozone water, from the influence of the alkaline detergent and the water quality and the surrounding environment due to the high temperature state, the container sterilization cleaning section There was a problem that ozone water having a dissolved ozone concentration effective for sterilization could not be obtained.
[0015]
An object of the present invention is to not use the chlorine-based sterilizing water as described above in the rinsing step of cleaning the containers to sufficiently perform sterilization, and also to effectively use the rinsing water for rinsing and save, It is an object of the present invention to provide a method and an apparatus for cleaning containers using ozone water which do not adversely affect the human body.
[0016]
[Means for Solving the Problems]
In order to solve the above problems, in the washing process of the containers, the final cleaning is performed with sterile water, the solution after the final cleaning is collected, sterilized water is generated, and the sterilized water is supplied to the sterilizing and cleaning unit which is a pre-process of the final cleaning. Cleaning equipment for containers
Sterilized water is generated by converting a non-alkali solution consisting of the recovered solution after the final cleaning and the recovered solution after the sterilization of the sterilizing and cleaning section into high-concentration ozone water, and disinfecting the sterilized water for sterilization and cleaning. It will be used in the previous process.
[0017]
At this time, before the sterilizing and cleaning step of the containers, a step of rinsing the alkaline cleaning liquid attached to the containers with the sterilized water diverted is provided.
[0018]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described based on examples.
FIG. 1 is a schematic diagram illustrating a structure of a rinse cleaning unit of a container cleaning device according to an embodiment of the present invention. As shown in this figure, the rinsing step 26 includes a rinsing and washing section 11 for removing the alkaline solution and the like attached to the containers by water washing, a sterilizing and washing section 12 for sterilizing the containers, and cleaning the containers with fresh water such as sterile water. , A finishing washing water waste tank 14, a sterilizing washing water tank 15, a first ozonizer 19 for finishing washing water, a second ozonizer 24 for sterilizing washing water, and the like. It consists of:
[0019]
In the main cleaning, the containers to be cleaned after brush cleaning, heat sterilization, alkali cleaning, and the like are transferred to the rinsing cleaning step 26. In the rinsing cleaning step 26, first, in the rinsing cleaning section 11, the alkaline solution or the like attached to the containers in the main cleaning is dropped. For this reason, the water in the final cleaning water waste liquid tank 14 provided at the lower portion of the rinsing cleaning unit 11 becomes alkaline water, and when the pH is high, the rate of self-decomposition of ozone is increased. It is unsuitable, so it is reused as main washing or pre-wash water.
[0020]
Next, the sterilization and cleaning unit 12 sterilizes the containers using ozone water having a dissolved ozone concentration of several ppm, and the sterilized cleaning unit 4 determines whether the dissolved ozone concentration is an extremely low concentration ozone water or the sterilized ozone is volatilized. Perform a final wash with water.
The higher the pH of the water for producing ozone water, the faster the rate of self-decomposition of the dissolved ozone concentration in the ozone water. In addition, when a large amount of organic carbon components are present in water quality, dissolved ozone in ozone water reacts with organic carbon, and the concentration of dissolved ozone rapidly decreases. As a result, the rapid decrease in the concentration of dissolved ozone contained in the ozone water after it has adhered to the containers to be sterilized shortens the contact time with the bacteria, making it impossible to perform sufficient sterilization. Therefore, it is necessary to adjust the pH or set the initial dissolved ozone concentration high.
[0021]
Therefore, the concentration of ozone water as a sterilizing and cleaning device for food containers cannot be defined because the required dissolved ozone concentration changes depending on the quality of water for generating ozone water.
The following data on the sterilization effect of ozone water has been published by the Ministry of Health, Labor and Welfare. In the case where the target microorganism is Bacillus subtilis (Bacillus subtilis), 99.9% of Bacillus subtilis is 99.9% when it is brought into contact with ozone water having a dissolved ozone concentration of 0.5 ppm for 30 seconds under the condition of a water temperature of 20.0 ° C. and a pH of 6.5. Sterilization rates have been obtained. In addition, when Escherichia coli or Bacillus staphylococci, which are considered to be food hygiene problems, are used as target microorganisms, under conditions of a water temperature of 21.0 ° C. and a pH of 7.0, the ozone water having a dissolved ozone concentration of 1 ppm is contacted for 5 seconds. It is shown that 100% sterilization has taken place.
[0022]
Therefore, if the contact time with the microorganism is about 1 minute, the microorganism can be inactivated. In the container cleaning apparatus, the process proceeds to the rinse cleaning step 26 after alkali cleaning at a high temperature of about 70 ° C., so that the temperature of the containers cleaned in the rinse cleaning step 26 becomes higher than normal temperature. Further, according to the water quality standard of the Water Supply Law, the pH value is determined to be 5.8 or more and 8.6 or less. When the quality of the ozone water is pH 8 at 30 ° C., the ozone concentration decrease due to the ozone self-decomposition is 20% or less in about 1 minute. As described above, the ozone water for sterilization injected from the sterilizing / cleaning unit 12 may have a dissolved ozone concentration of about 2 to 3 ppm even in consideration of the safety factor.
[0023]
In the finish washing section 4, it is desirable that the concentration is about 0.1 ppm which does not affect the human body even if the contact is performed for a long time, but the next step of filling the product into the containers or the person comes into contact with the washed containers. At this point, the concentration may be reduced to about 0.1 ppm, including the ambient environment due to the concentration of the volatilized ozone gas, in consideration of the oxidation of the product and the effect on the human body. For this reason, in the finish cleaning section, it is important that the ozone water is not necessarily a low concentration, but is ozone water in the sense of sterile water that prevents reattachment of microorganisms.
[0024]
As the low-concentration ozone water used in the finishing washing unit 4, tap water or the like is supplied to the water receiving tank 16, and the first A pump 17 sends out water to two lines. One is sent to a first ejector 18 and mixed with ozone gas generated from a first ozonizer 19 to generate ozone water and sent to a mixing tank 20. The other water is directly injected into the mixing tank 20, and the mixture ratio with ozone water is adjusted to generate a predetermined low-concentration ozone water. The low-concentration ozone water generated in the mixing tank 20 is sent out to the finish cleaning unit 4 by the first B pump 21. At this time, if the pipe from the first B pump 21 to the finish cleaning unit 4 is sufficiently long, the dissolved ozone concentration is low or close to zero due to the self-decomposition of ozone before reaching the finish cleaning unit 4. Decrease to the state.
[0025]
The low-concentration ozone water used for the container cleaning in the finish cleaning unit 4 drips from the cleaned containers and flows into the sterilizing and cleaning water tank 15. The water in the germicidal washing water tank 15 is circulated through a path passing through the second ejector 23 by the second A pump 22, and the second ejector 23 adjusts the mixing with the ozone gas generated from the second ozonizer 24 so that the ozone water Is generated, and the inside of the sterilizing / washing water tank 15 is changed to ozone water. In this case, as a method without using the second ejector 23 as a means for turning the liquid in the sterilizing / washing water tank 15 into ozone water, a diffuser tube (not shown) is disposed in the sterilizing / washing water tank 15 so that the ozone gas generated from the second ozonizer 24 is discharged. It is also possible to feed directly to the sterilizing / washing water tank 15 for aeration.
[0026]
The ozone water generated in the sterilizing / washing water tank 15 is sucked up by the second B pump 25 and sprayed on containers cleaned by the sterilizing / washing unit 12 and the washing unit 11. The ozone water blown out from the sterilizing / cleaning unit 12 hits the containers to be cleaned, then drops and returns to the sterilizing / cleaning water tank 15, and is used again as ozone water. Further, the ozone water blown out from the washing-out washing section 11 hits the containers to be washed and then drops into the finishing washing water waste liquid tank 14, and is reused for main washing, preliminary washing and the like.
[0027]
Since the sterilizing / washing tank 15 is configured such that new washing water from the finishing washing unit 4 and reused water from the sterilizing / washing unit 12 flow as ozone water, the sterilizing / washing tank 15 is used unless water is used for the washing / washing unit 11. Then overflow occurs. For this reason, the overflowed ozone water is used in the washing section 11 to wash away the alkaline washing liquid and the like attached to the containers.
[0028]
【The invention's effect】
In the present invention, ozone water is used instead of the conventional chlorinated sterilizing water in the rinsing step in cleaning the containers, and the rinsing is performed by removing the alkaline solution attached to the containers in the main cleaning by rinsing with water, and Sterilization washing to sterilize containers using ozone water with an ozone concentration of about 3 ppm, and after dissolving ozone concentration is low concentration ozone water of about 0.1 ppm, which eliminates the irritating odor of ozone, or after ozone is volatilized And the final washing using sterile water.
[0029]
The ozone used in the present invention is treated as an existing additive as a food additive substance, and can be used for any food without restriction. The following effects can be obtained by cleaning ozone water by cleaning containers in the present invention.
First, the effect of changing the sterilizing and finishing cleaning water from chlorine-based sterilizing water to ozone water is shown. Ozone naturally disappears and does not remain. Therefore, unlike conventional chemical sterilizers, ozone is safe for the human body and can be sanitized and washed hygienically. In addition, after sufficient sterilization of the container, deterioration of the filled and arranged food material itself can be prevented.
[0030]
The second is the effect of reusing the finishing washing water. The ozone water used in the sterilization process saves the amount of tap water supplied to the cleaning device by storing the water used for the final cleaning in the post-sterilization process in the sterilization cleaning tank and reusing it as ozone water for sterilization. it can.
The third effect is that ozone water can be used for rinsing off the cleaning liquid attached to the containers in the main cleaning before the sterilization cleaning. If ozone water for sterilization is added to the containers while the cleaning solution such as the alkaline solution used in the main cleaning is attached to the containers, ozone is consumed by organic substances such as detergents and ozone is lost before sterilization. In alkaline, self-consumption of ozone is rapidly accelerated. In the final tank into which the sterilizing cleaning water and the finishing cleaning water flow, the overflowing ozone water can be used to wash away the alkaline cleaning liquid and the like adhered to the containers in the cleaning section, thus contaminating the containers cleaned in the main cleaning. Since ozone water can be used without any worries, there is no need to newly supply cleaning water from tap water. Therefore, the cleaning device only needs to supply tap water with only the finish cleaning water, and the water saving effect is large.
[0031]
Fourth, for container cleaning equipment that performs rinsing using a disinfectant such as hypochlorous water, ozone water generation / circulation equipment and ozone treatment equipment have been added to the rinsing process. By simply changing the piping system, it is possible to provide equipment that is inexpensive and easily provided with food environment safety using ozone water.
[Brief description of the drawings]
FIG. 1 is a schematic diagram showing a structure of a rinse cleaning unit as an embodiment of a cleaning device of the present invention. FIG. 2 is a schematic diagram showing a typical configuration example of a conventional cleaning device.
1: Container supply unit 2: Pre-cleaning unit 3: Main cleaning unit 4: Finish cleaning unit 4a: Circulation finish cleaning unit 5: Container discharge unit 6: External cleaning jet 7: Internal cleaning jet 8: Jet cleaning unit 9: Cleaning tank 10: Conveying conveyor 11: Rinse-off washing unit 12: Sterilizing washing unit 12a: Hypochlorite sterilizing washing unit 13: Suction pump 14: Finishing washing water waste tank 15: Sterilizing washing water tank 15a: Washing water tank 16: Receiving tank 17: No. 1A pump 18: first ejector 19: first ozonizer 20: mixing tank 21: first B pump 22: second A pump 23: second ejector 24: second ozonizer 25: second B pump 26: rinse cleaning step

Claims (2)

容器類の洗浄過程で、仕上げ洗浄を無菌水で行い、仕上げ洗浄後の溶液を回収して殺菌水を生成し、仕上げ洗浄の前工程である殺菌洗浄部に供給する容器類の洗浄装置において、
殺菌水は、仕上げ洗浄後の回収溶液と、前記殺菌洗浄部の殺菌後の回収溶液とからなるアルカリ性質を持たない溶液を高濃度のオゾン水とすることにより生成され、該殺菌水を前記殺菌洗浄の前工程でも流用することを特徴とする容器類の洗浄装置。
In the cleaning process of the containers, the final cleaning is performed with aseptic water, the solution after the final cleaning is collected, sterilized water is generated, and the cleaning device for the containers to be supplied to the sterilizing cleaning unit which is a pre-process of the final cleaning,
The sterilized water is generated by converting a non-alkali solution consisting of the recovered solution after the final cleaning and the recovered solution after the sterilization of the sterilizing and cleaning unit into high-concentration ozone water, and sterilizing the sterilized water by the sterilization water. A container cleaning device characterized in that it is diverted even in a pre-cleaning process.
前記殺菌洗浄工程以前に、前記容器類に付着したアルカリ洗浄液を流用された前記殺菌水で洗い流す工程を有することを特徴とする請求項1に記載の容器類洗浄装置。The container cleaning apparatus according to claim 1, further comprising a step of washing the alkaline cleaning liquid adhered to the containers with the sterilized water before the sterilization cleaning step.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013065661A1 (en) * 2011-11-01 2013-05-10 株式会社昭和 Washing method and washing device
CN105026059A (en) * 2014-01-29 2015-11-04 株式会社昭和 cleaning device
JP2022113209A (en) * 2021-01-25 2022-08-04 アサヒ飲料株式会社 Container cleaning method
JP7597592B2 (en) 2021-01-25 2024-12-10 アサヒ飲料株式会社 How to clean the container

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013065661A1 (en) * 2011-11-01 2013-05-10 株式会社昭和 Washing method and washing device
JPWO2013065661A1 (en) * 2011-11-01 2015-04-02 株式会社昭和 Cleaning method and cleaning device
CN105026059A (en) * 2014-01-29 2015-11-04 株式会社昭和 cleaning device
CN105026059B (en) * 2014-01-29 2016-08-31 株式会社昭和 cleaning device
JP2022113209A (en) * 2021-01-25 2022-08-04 アサヒ飲料株式会社 Container cleaning method
JP7597592B2 (en) 2021-01-25 2024-12-10 アサヒ飲料株式会社 How to clean the container
JP7597593B2 (en) 2021-01-25 2024-12-10 アサヒ飲料株式会社 How to clean the container

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