JP2003301250A - Age-hardened welded pipe and method of manufacturing the same - Google Patents
Age-hardened welded pipe and method of manufacturing the sameInfo
- Publication number
- JP2003301250A JP2003301250A JP2002108180A JP2002108180A JP2003301250A JP 2003301250 A JP2003301250 A JP 2003301250A JP 2002108180 A JP2002108180 A JP 2002108180A JP 2002108180 A JP2002108180 A JP 2002108180A JP 2003301250 A JP2003301250 A JP 2003301250A
- Authority
- JP
- Japan
- Prior art keywords
- age
- minutes
- welded pipe
- treatment
- copper alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000003483 aging Methods 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 35
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 27
- 238000004049 embossing Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 22
- 238000003466 welding Methods 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 13
- 239000010949 copper Substances 0.000 claims description 36
- 238000010438 heat treatment Methods 0.000 claims description 34
- 239000012535 impurity Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 229910052718 tin Inorganic materials 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910052790 beryllium Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- 229910052745 lead Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 229910052716 thallium Inorganic materials 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 238000009827 uniform distribution Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 29
- 238000005096 rolling process Methods 0.000 description 9
- 238000010791 quenching Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 4
- 102220253765 rs141230910 Human genes 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Bending Of Plates, Rods, And Pipes (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
Abstract
Description
【0001 】[0001]
【発明の属する技術分野】本発明は、時効硬化性銅合金
を用いた時効硬化溶接管およびその製造方法に関する。TECHNICAL FIELD The present invention relates to an age-hardened welded pipe using an age-hardenable copper alloy and a method for producing the same.
【0002 】[0002]
【従来の技術】一般に、空調機や冷蔵庫用の熱交換器に
は、冷媒の流路として多数の銅管が用いられており、冷
媒をこれら銅管に流すことにより銅管外部と冷媒との間
で熱交換させ、冷却や加熱が行われている。2. Description of the Related Art In general, a heat exchanger for an air conditioner or a refrigerator uses a large number of copper pipes as a refrigerant flow path. Heat is exchanged between them, and cooling and heating are performed.
【0003 】銅管内部の冷媒と銅管との伝熱効率を向
上するため、銅管の内面に螺旋溝等の凹凸構造をエンボ
ス加工により形成することも行われている。このような
凹凸構造を形成することにより、銅管内面に沿って流れ
る冷媒が攪拌され、銅管内面に沿って境界層が発生する
ことが抑制され、冷媒と銅管との間の伝熱効率が高めら
れるからである。なお、銅管内面にエンボス加工を行う
場合には、まず板条材の表面にエンボス加工を行った
後、この板条材を管状に成形して溶接する、いわゆる電
縫管方式が採用される。In order to improve the efficiency of heat transfer between the refrigerant inside the copper tube and the copper tube, an uneven structure such as a spiral groove is also formed on the inner surface of the copper tube by embossing. By forming such a concavo-convex structure, the refrigerant flowing along the inner surface of the copper tube is agitated, the occurrence of a boundary layer along the inner surface of the copper tube is suppressed, and the heat transfer efficiency between the refrigerant and the copper tube is reduced. Because it can be raised. When the inner surface of the copper pipe is embossed, a so-called ERW pipe method is used in which the surface of the strip material is first embossed and then the strip material is formed into a tubular shape and welded. .
【0004 】[0004]
【発明が解決しようとする課題】ところで、この種の銅
管の用途は更に拡大しつつあり、従来よりも管の径を細
くしたり、管の肉厚を薄くしたり、管を曲線状に成型し
て自立状態で使用する熱交換装置も開発されつつある。
このような場合、管の変形を防ぐために、管の素材とし
て高純度の銅よりも強度の高い銅合金を使用することが
好ましいが、単に高強度銅合金を使用したのでは、溶接
のムラが生じて溶接部の強度が不均一に低下する問題が
あった。また、管の内面にエンボス加工を行う場合に
は、高強度銅合金を使用するとエンボス加工装置の摩耗
が激しくなって、装置の寿命が短くなるばかりか、必要
十分な深さを有する凹凸構造が形成できないなどの問題
が生じた。By the way, the use of this type of copper pipe is expanding further, and the diameter of the pipe is made thinner, the wall thickness of the pipe is made thinner than before, and the pipe is curved. A heat exchange device that is molded and used in a self-supporting state is also being developed.
In such a case, in order to prevent the deformation of the pipe, it is preferable to use a copper alloy having a higher strength than high-purity copper as the material of the pipe, but simply using a high-strength copper alloy causes unevenness in welding. There was a problem that the strength of the welded part was unevenly reduced due to the occurrence. Further, when embossing the inner surface of the pipe, using a high-strength copper alloy causes severe wear of the embossing device, shortens the life of the device, and creates an uneven structure with a necessary and sufficient depth. There was a problem that it could not be formed.
【0005 】本発明は上記事情に鑑みてなされたもの
で、管の強度が高く、溶接部の強度が安定しており、エ
ンボス加工を施す場合にはエンボス加工が容易に行える
時効硬化溶接管およびその製造方法を提供することを課
題としている。The present invention has been made in view of the above circumstances, and has a high strength pipe, a stable weld strength, and an age-hardened welded pipe that enables easy embossing when embossing is performed. It is an object to provide a manufacturing method thereof.
【0006 】[0006]
【課題を解決するための手段】上記課題を解決するた
め、本発明に係る時効硬化溶接管の製造方法は、時効硬
化性銅合金からなる条材を加熱することにより溶質原子
を均一分布させる溶体化処理を行う溶体化処理工程と、
前記溶体化処理を施した条材を複数のフォーミングロー
ルを通して管状に成形する管成形工程と、管状に成形さ
れた条材の両端縁を加熱したうえ突き合わせて溶接する
溶接工程と、前記溶接により得られた溶接管を加熱して
前記溶質原子を母材中に析出させ溶接管を硬化させる時
効硬化処理工程とを具備する。In order to solve the above-mentioned problems, a method for producing an age-hardened welded pipe according to the present invention is a solution for uniformly distributing solute atoms by heating a strip made of an age-hardenable copper alloy. Solution treatment step for performing the chemical treatment,
A tube forming step of forming the solution-treated strip into a tubular shape through a plurality of forming rolls, a welding step of heating both end edges of the tubular strip and then butt-welding the same, and the welding step And an age hardening treatment step of heating the obtained welded tube to precipitate the solute atoms in the base material and hardening the welded tube.
【0007 】この方法は、前記溶体化処理が行われた
条材の少なくとも一面にエンボス加工を行うエンボス加
工工程をさらに具備していてもよい。This method may further include an embossing step of performing embossing on at least one surface of the solution-treated strip.
【0008 】前記時効硬化性銅合金は、銅を50wt
%以上含み、Be,Mg,Ca,Ti,Zr,Hf,
V,Nb,Ta,Cr,Mo,W,Mn,Fe,Co,
Rh,Ir,Ni,Pd,Pt,Ag,Au,Zn,C
d,B,Al,Ga,In,Tl,C,Si,Ge,S
n,Pb,P,As,Sb,Bi,O,S,Se,T
e,および希土類元素の中から選択される1または2以
上の元素を0.01〜49wt%含むものであってもよ
い。The age hardening copper alloy contains 50 wt% of copper.
%, Be, Mg, Ca, Ti, Zr, Hf,
V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co,
Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, C
d, B, Al, Ga, In, Tl, C, Si, Ge, S
n, Pb, P, As, Sb, Bi, O, S, Se, T
It may contain 0.01 to 49 wt% of one or more elements selected from e and rare earth elements.
【0009 】また、本発明に係る時効硬化溶接管は、
上記製造方法により得られた時効硬化溶接管であって、
形状は任意であるが、例えばU字状や螺旋状であっても
よい。このような形状にする場合には、溶接管を得た
後、この溶接管を曲げて所定の形状に整形し、そのうえ
で形状を付与した溶接管を加熱して時効硬化処理を行う
ことが好ましい。Further, the age hardening welded pipe according to the present invention is
An age hardening welded pipe obtained by the above manufacturing method,
The shape is arbitrary, but may be U-shaped or spiral. In the case of such a shape, it is preferable that after obtaining a welded pipe, the welded pipe is bent and shaped into a predetermined shape, and then the welded pipe having the shape is heated to perform an age hardening treatment.
【0010 】[0010]
【発明の実施の形態】図1は本発明に係る時効硬化溶接
管の製造方法の一実施形態を実施する際に使用される熱
処理およびスリッター装置を示す側面図である。図中符
号1は、アンコイラであり、一定厚さで幅広の条材Tを
そのコイルから連続的に一定速度で繰り出す。アンコイ
ラ1から繰り出された条材Tは加熱炉4を通過させら
れ、加熱炉4内に設けられた加熱機構6により加熱さ
れ、加熱炉4から出た後に急冷される。DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a side view showing a heat treatment and slitting apparatus used when carrying out an embodiment of a method for manufacturing an age hardening welded pipe according to the present invention. Reference numeral 1 in the figure denotes an uncoiler, which continuously feeds a wide strip T having a constant thickness from the coil at a constant speed. The strip T fed from the uncoiler 1 passes through the heating furnace 4, is heated by the heating mechanism 6 provided in the heating furnace 4, and is rapidly cooled after being discharged from the heating furnace 4.
【0011 】加熱炉4の後段に、条材Tを急冷するた
めの急冷機構を設けてもよいが、条材Tが薄ければ空気
中で放熱させることにより十分に急冷を行うことができ
る。急冷機構としては、不活性ガスや液体などを条材T
に接触させるもの、あるいは金属製のロールを条材Tに
接触させて急冷させる方法などが実施容易である。A quenching mechanism for quenching the strip T may be provided in the subsequent stage of the heating furnace 4. However, if the strip T is thin, it can be sufficiently cooled by radiating heat in the air. As a quenching mechanism, an inert gas or liquid is used for the strip T.
It is easy to carry out such a method as to bring the strip material into contact with the strip material or a method of bringing a metal roll into contact with the strip material T to quench it.
【0012 】この加熱・急冷によって、時効硬化性銅
合金中の溶質原子が均一に分布され、溶体化処理が行わ
れる。溶体化処理工程加熱炉4内は窒素ガス等の不活性
ガス雰囲気に保たれている。ただし、本発明はこれに限
定されず、還元ガス雰囲気であってもよいし、弱酸化性
雰囲気であってもよい。加熱機構6の種類は限定され
ず、例えば電気抵抗加熱、バーナーによる加熱、高周波
誘導加熱など如何なる種類であってもよい。By this heating and quenching, solute atoms in the age-hardenable copper alloy are uniformly distributed, and solution treatment is performed. The inside of the solution treatment process heating furnace 4 is kept in an inert gas atmosphere such as nitrogen gas. However, the present invention is not limited to this, and a reducing gas atmosphere or a weakly oxidizing atmosphere may be used. The type of the heating mechanism 6 is not limited, and may be any type such as electric resistance heating, burner heating, and high frequency induction heating.
【0013 】溶体化処理とは、銅合金に含まれる溶質
・溶媒が形成する固溶体の溶解度曲線より高い温度に銅
合金を加熱し,固溶体として溶質原子を均一に分布させ
てから、溶質が再び析出しないうちに急冷する操作であ
る。溶体化処理に必要な加熱温度および加熱時間は条材
Tの材質によって異なる。The solution treatment is to heat the copper alloy to a temperature higher than the solubility curve of the solid solution formed by the solute / solvent contained in the copper alloy, uniformly distribute the solute atoms as the solid solution, and then precipitate the solute again. It is an operation of quenching before it is done. The heating temperature and the heating time required for the solution treatment differ depending on the material of the strip material T.
【0014 】条材Tの材質としては、銅を50wt%
以上含み、Be,Mg,Ca,Ti,Zr,Hf,V,
Nb,Ta,Cr,Mo,W,Mn,Fe,Co,R
h,Ir,Ni,Pd,Pt,Ag,Au,Zn,C
d,B,Al,Ga,In,Tl,C,Si,Ge,S
n,Pb,P,As,Sb,Bi,O,S,Se,T
e,および希土類元素の中から選択される1または2以
上の元素を0.01〜49wt%含むものが好ましい。The material of the strip material T is 50 wt% of copper.
Including the above, Be, Mg, Ca, Ti, Zr, Hf, V,
Nb, Ta, Cr, Mo, W, Mn, Fe, Co, R
h, Ir, Ni, Pd, Pt, Ag, Au, Zn, C
d, B, Al, Ga, In, Tl, C, Si, Ge, S
n, Pb, P, As, Sb, Bi, O, S, Se, T
It is preferable to contain 0.01 to 49 wt% of one or more elements selected from e and rare earth elements.
【0015 】この中でも好ましい時効硬化性銅合金の
組成と、その合金の溶体化処理に適した加熱温度および
加熱時間は以下の通りである。後述する時効硬化処理に
適した加熱温度および加熱時間も併記する。Among these, the preferable composition of the age-hardenable copper alloy and the heating temperature and heating time suitable for the solution treatment of the alloy are as follows. The heating temperature and heating time suitable for the age hardening treatment described later are also shown.
【0016 】(1)Be:0.005〜3wt%、N
i:0.002〜3wt%、Co:0.0002〜0.
9wt%、不可避不純物、およびCu:残部。この場合
の溶体化処理は600〜950℃×0.05〜30分の
条件で行い、時効硬化処理は250〜580℃×0.0
5〜600分の条件で行うことが好ましい。(1) Be: 0.005 to 3 wt%, N
i: 0.002 to 3 wt%, Co: 0.0002 to 0.
9 wt%, inevitable impurities, and Cu: balance. The solution treatment in this case is performed under the condition of 600 to 950 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 580 ° C. × 0.0.
It is preferable to carry out under conditions of 5 to 600 minutes.
【0017 】(2)Ag:0.08〜5wt%、不可
避不純物、およびCu:残部の組成。この場合の溶体化
処理は600〜900℃×0.05〜30分の条件で行
い、前記時効硬化処理は250〜580℃×0.05〜
600分の条件で行うことが好ましい。(2) Composition of Ag: 0.08 to 5 wt%, inevitable impurities, and Cu: balance. The solution treatment in this case is performed under the conditions of 600 to 900 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 580 ° C. × 0.05 to
It is preferable to carry out under the condition of 600 minutes.
【0018 】(3)Sn:0.5〜4wt%、Ni:
0.5〜3wt%、Si:0.05〜0.5wt%、Z
n:0.01〜0.8wt%、不可避不純物、およびC
u:残部の組成。この場合の溶体化処理は600〜95
0℃×0.05〜30分の条件で行い、前記時効硬化処
理は250〜550℃×0.05〜600分の条件で行
うことが好ましい。(3) Sn: 0.5-4 wt%, Ni:
0.5-3 wt%, Si: 0.05-0.5 wt%, Z
n: 0.01 to 0.8 wt%, unavoidable impurities, and C
u: Composition of the balance. The solution heat treatment in this case is 600 to 95.
It is preferable that the treatment is performed under conditions of 0 ° C. × 0.05 to 30 minutes, and the age hardening treatment is performed under the conditions of 250 to 550 ° C. × 0.05 to 600 minutes.
【0019 】(4)Cr:0.1〜0.6wt%、Z
r:0.0002〜0.3wt%、Si:0.0002
〜0.1wt%、Al:0.0002〜0.2wt%、
Sn:0.0002〜0.3wt%、Mg:0.000
2〜0.2wt%、Zn:0.0002〜0.5wt
%、不可避不純物、およびCu:残部の組成。この場合
の溶体化処理は600〜980℃×0.05〜30分の
条件で行い、前記時効硬化処理は250〜590℃×
0.05〜600分の条件で行うことが好ましい。(4) Cr: 0.1 to 0.6 wt%, Z
r: 0.0002 to 0.3 wt%, Si: 0.0002
~ 0.1 wt%, Al: 0.0002-0.2 wt%,
Sn: 0.0002 to 0.3 wt%, Mg: 0.000
2 to 0.2 wt%, Zn: 0.0002 to 0.5 wt
%, Unavoidable impurities, and Cu: composition of balance. The solution treatment in this case is performed under the condition of 600 to 980 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 590 ° C. ×
It is preferable to carry out the condition for 0.05 to 600 minutes.
【0020 】(5)Fe:0.3〜1.8wt%、S
n:0.01〜3wt%、P:0.003〜0.4wt
%、不可避不純物、およびCu:残部の組成。この場合
の溶体化処理は600〜980℃×0.05〜30分の
条件で行い、前記時効硬化処理は250〜580℃×
0.05〜600分の条件で行うことが好ましい。(5) Fe: 0.3 to 1.8 wt%, S
n: 0.01 to 3 wt%, P: 0.003 to 0.4 wt
%, Unavoidable impurities, and Cu: composition of balance. The solution treatment in this case is performed under the conditions of 600 to 980 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 580 ° C. ×
It is preferable to carry out the condition for 0.05 to 600 minutes.
【0021 】(6)Zr:0.01〜0.3wt%、
不可避不純物、およびCu:残部の組成。この場合の溶
体化処理は700〜1000℃×0.05〜30分の条
件で行い、前記時効硬化処理は250〜600℃×0.
05〜600分の条件で行うことが好ましい。(6) Zr: 0.01 to 0.3 wt%,
Inevitable impurities, and Cu: the balance composition. In this case, the solution treatment is performed under the condition of 700 to 1000 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 600 ° C. × 0.
It is preferable to carry out under conditions of 05 to 600 minutes.
【0022 】(7)Ni:0.3〜4wt%、Si:
0.02〜1wt%、Sn:0.003〜1wt%、Z
n:0.003〜3wt%、Mg:0.0002〜0.
2wt%、不可避不純物、およびCu:残部の組成。こ
の場合の溶体化処理は600〜950℃×0.05〜3
0分の条件で行い、前記時効硬化処理は250〜550
℃×0.05〜600分の条件で行うことが好ましい。(7) Ni: 0.3-4 wt%, Si:
0.02-1 wt%, Sn: 0.003-1 wt%, Z
n: 0.003 to 3 wt%, Mg: 0.0002 to 0.
2 wt%, inevitable impurities, and Cu: the balance composition. The solution treatment in this case is 600 to 950 ° C. × 0.05 to 3
It is performed under the condition of 0 minutes, and the age hardening treatment is 250 to 550.
It is preferable to carry out under the condition of ℃ × 0.05 to 600 minutes.
【0023 】(8)Fe:0.05〜0.3wt%、
P:0.003〜0.1wt%、不可避不純物、および
Cu:残部の組成。この場合の溶体化処理は500〜9
50℃×0.05〜30分の条件で行い、前記時効硬化
処理は250〜480℃×0.05〜600分の条件で
行うことが好ましい。(8) Fe: 0.05 to 0.3 wt%,
P: 0.003 to 0.1 wt%, inevitable impurities, and Cu: the composition of the balance. The solution treatment in this case is 500 to 9
It is preferable to perform the treatment at 50 ° C. × 0.05 to 30 minutes, and the age hardening treatment to the condition of 250 to 480 ° C. × 0.05 to 600 minutes.
【0024 】(9)Fe:1.5〜3wt%、P:
0.003〜0.4wt%、Zn:0.01〜0.5w
t%、Mg:0.0002〜0.2wt%、Ni:0.
001〜0.2wt%、Sn:0.001〜0.2wt
%、不可避不純物、およびCu:残部の組成。この場合
の溶体化処理は700〜980℃×0.05〜30分の
条件で行い、前記時効硬化処理は250〜680℃×
0.05〜600分の条件で行うことが好ましい。(9) Fe: 1.5 to 3 wt%, P:
0.003 to 0.4 wt%, Zn: 0.01 to 0.5 w
t%, Mg: 0.0002 to 0.2 wt%, Ni: 0.
001 to 0.2 wt%, Sn: 0.001 to 0.2 wt
%, Unavoidable impurities, and Cu: composition of balance. The solution treatment in this case is performed under the condition of 700 to 980 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 680 ° C. ×
It is preferable to carry out the condition for 0.05 to 600 minutes.
【0025 】(10)Ti:0.03〜4wt%、F
e:0.002〜0.9wt%、Mg:0.0002〜
0.2wt%、不可避不純物、およびCu:残部の組成
を有し、前記溶体化処理は560〜980℃×0.05
〜30分の条件で行い、前記時効硬化処理は250〜5
50℃×0.05〜600分の条件で行うことが好まし
い。(10) Ti: 0.03-4 wt%, F
e: 0.002-0.9 wt%, Mg: 0.0002-
0.2 wt%, unavoidable impurities, and Cu: balance composition, and the solution treatment is 560 to 980 ° C. × 0.05.
~ 30 minutes, the age hardening treatment is 250 ~ 5
It is preferable to carry out under conditions of 50 ° C. × 0.05 to 600 minutes.
【0026 】(11)Mg:0.1〜0.9wt%、
P:0.0002〜0.2wt%、Sn:0.0002
〜0.3wt%,Be:0.0001〜0.3wt%、
不可避不純物、およびCu:残部の組成。この場合の溶
体化処理は550〜950℃×0.05〜30分の条件
で行い、前記時効硬化処理は180〜500℃×0.0
5〜600分の条件で行うことが好ましい。(11) Mg: 0.1 to 0.9 wt%,
P: 0.0002 to 0.2 wt%, Sn: 0.0002
~ 0.3 wt%, Be: 0.0001-0.3 wt%,
Inevitable impurities, and Cu: the balance composition. The solution treatment in this case is performed under the condition of 550 to 950 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 180 to 500 ° C. × 0.0.
It is preferable to carry out under conditions of 5 to 600 minutes.
【0027 】(12)Co:0.02〜3wt%、
P:0.0003〜0.2wt%、不可避不純物、およ
びCu:残部の組成。この場合の溶体化処理は650〜
980℃×0.05〜30分の条件で行い、前記時効硬
化処理は250〜600℃×0.05〜600分の条件
で行うことが好ましい。(12) Co: 0.02 to 3 wt%,
P: 0.0003 to 0.2 wt%, inevitable impurities, and Cu: the composition of the balance. The solution treatment in this case is 650 to
It is preferable to perform the treatment at 980 ° C. for 0.05 to 30 minutes, and the age hardening treatment to be performed at 250 to 600 ° C. for 0.05 to 600 minutes.
【0028 】加熱炉4を通過した条材Tは、外周縁を
噛み合わせて配置された複数のスリッターロールを備え
たスリッター8を通され、複数本の一定幅の条材T1に
分割される。分割された条材T1はロール10を経て複
数のリコイラ12に巻き取られていく。各リコイラ12
に十分な条材T1が蓄積されたら、装置を停止してリコ
イラ12から条材T1のコイルを外し、図2に示すエン
ボス加工・電縫装置にセットする。ただし、本発明では
必ずしも加熱処理後に連続して条材Tを分割しなくても
よい。分割は必要に応じて随時行えばよい。The strip T which has passed through the heating furnace 4 is passed through a slitter 8 having a plurality of slitter rolls arranged so that the outer peripheral edges thereof are meshed with each other, and divided into a plurality of strips T1 having a constant width. The strip | belt material T1 divided | segmented passes through the roll 10, and is wound up by the some ricoiler 12. Each recoiler 12
When a sufficient amount of the strip material T1 has been accumulated, the apparatus is stopped, the coil of the strip material T1 is removed from the ricoiler 12, and the strip material T1 is set in the embossing / electric sewing device shown in FIG. However, in the present invention, the strip material T does not necessarily have to be continuously divided after the heat treatment. The division may be performed as needed.
【0029 】図2中符号20は、溶体化処理が施され
た条材T1をそのコイルから連続的に繰り出すアンコイ
ラであり、繰り出された条材T1は一対の押さえロール
22を経て、対向して配置されたフィン転造ロール24
および受けロール26の間を通される。この実施形態で
は、フィン転造ロール24と受けロール26がエンボス
加工機構を構成する。フィン転造ロール24により、例
えば条材T1の長手方向に対して一定角度を有する直線
状のフィンおよび溝が条材T1の表面に形成される一
方、受けロール26に当接した条材T1の裏面は平滑の
ままに保たれる。ただし、エンボス加工の種類は直線状
のフィンおよび溝の形成に限定されず、ディンプル状な
ど如何なる形状の凹凸構造を形成してもよい。また、管
の用途によってはエンボス加工を行わなくてもよい。Reference numeral 20 in FIG. 2 denotes an uncoiler for continuously feeding the solution-treated strip T1 from its coil, and the strip T1 fed out is opposed to each other via a pair of pressing rolls 22. Arranged fin rolling roll 24
And between the receiving rolls 26. In this embodiment, the fin rolling roll 24 and the receiving roll 26 form an embossing mechanism. By the fin rolling roll 24, for example, linear fins and grooves having a constant angle with respect to the longitudinal direction of the strip T1 are formed on the surface of the strip T1, while the strip T1 abutting on the receiving roll 26 is formed. The back side remains smooth. However, the type of embossing is not limited to the formation of linear fins and grooves, and an uneven structure of any shape such as dimples may be formed. Also, embossing may not be performed depending on the use of the tube.
【0030 】前記エンボス加工においては、条材T1
に予め溶体化処理が施され、条材T1の硬度が低くされ
ているため、エンボス加工に要する加圧力が小さくて済
み、フィン転造ロール24の損耗が少ない上、素材が変
形し安いために深いエンボス加工が容易に行える。In the embossing, the strip material T1
Since the solution heat treatment is performed in advance and the hardness of the strip material T1 is reduced, the pressing force required for embossing can be small, the fin rolling roll 24 is less worn, and the material is deformed cheaply. Easy deep embossing.
【0031 】フィン転造ロール24および受けロール
26により転造加工された板条材Tは、一対のロール2
8を経て、複数対配列されたフォーミングロール30を
通して徐々に管状に丸められ、ローリングセパレータ3
2により突き合わせるべき両端縁間の間隙量が一定に保
たれたうえ、誘導加熱コイル34に通されて両側縁部が
加熱される。この実施形態ではフィンが内周面側に位置
するように板条材Tを丸めるが、逆に、フィンが外周面
側に位置するように条材T1を丸めることも可能であ
る。The sheet material T rolled by the fin rolling roll 24 and the receiving roll 26 is a pair of rolls 2.
8 through which the rolling separator 3 is gradually rolled into a tubular shape through a plurality of pairs of forming rolls 30.
The gap amount between the both edges to be abutted by 2 is kept constant, and the both edges are heated by the induction heating coil 34. In this embodiment, the strip material T is rounded so that the fins are located on the inner peripheral surface side, but conversely, the strip material T1 can be rounded so that the fins are located on the outer peripheral surface side.
【0032 】管状に成形され加熱された条材T1は、
一対のスクイズロール36を通され、両側方から押され
ることにより加熱された両側縁部が突き合わされ、溶接
される。このとき、条材T1は溶体化処理が施されて軟
質化しているため、ロールフォーミングおよび溶接が安
定して行われる。したがって、溶接強度の安定性を高め
ることが可能となる。こうして溶接された溶接管P(溶
接管)の外周面には、塑性流動によりはみ出したビード
(アプセット)が形成されるので、このビードを切削す
るためのビードカッタ38が設けられている。The strip material T1 formed into a tubular shape and heated is
The pair of squeeze rolls 36 are passed through, and both side edges heated by being pressed from both sides are butted against each other and welded. At this time, since the strip material T1 is subjected to the solution treatment and softened, roll forming and welding are stably performed. Therefore, it becomes possible to improve the stability of the welding strength. Since a bead (upset) protruding by plastic flow is formed on the outer peripheral surface of the welded pipe P (welded pipe) thus welded, a bead cutter 38 for cutting the bead is provided.
【0033 】ビードが切削された溶接管Pは冷却槽4
0を通されて強制冷却されたうえ、複数対配列されたサ
イジングロール42を通され、所定の外径までに縮径さ
れる。さらに、縮径された溶接管Pは、ラフコイラ44
で巻き取られる。ラフコイラ44で巻き取られたコイル
がある程度大きくなったら、装置を停止して成形工程に
移行する。The welded pipe P whose bead is cut is the cooling tank 4
After passing 0 through forced cooling, a plurality of pairs of sizing rolls 42 are passed through and the diameter is reduced to a predetermined outer diameter. Furthermore, the reduced diameter welded pipe P is used in the rough coiler 44.
Is wound up in. When the coil wound by the rough coiler 44 becomes large to some extent, the apparatus is stopped and the molding process is started.
【0034 】成形工程では、コイルから再び溶接管P
を繰り出しつつ、溶接管Pを一定の長さに切断して、さ
らに所定の製品形状に成形する。本発明では製品形状は
限定されないが、例えば曲がりを矯正した直線状の直
管、一般的な空調装置または冷蔵装置等の熱交換器に取
り付けられる図3に示すようなU字状のU字管、別の形
式の熱交換器に使用される図4に示すような螺旋状の螺
旋管などが挙げられる。この場合にも、溶接管Pの素材
はまだ硬化していないので、この時点での成形は容易に
行える利点を有する。In the forming process, the welded pipe P
While unwinding, the welded pipe P is cut into a certain length and further shaped into a predetermined product shape. In the present invention, the product shape is not limited, but for example, a straight straight tube with straightened bend, a U-shaped tube as shown in FIG. 3 attached to a heat exchanger such as a general air conditioner or a refrigerating device. Another example is a spiral tube as shown in FIG. 4 used in another type of heat exchanger. Also in this case, since the material of the welded pipe P is not yet hardened, there is an advantage that molding at this point can be easily performed.
【0035 】次に、製品形状に成形された溶接管Pを
加熱して、溶質原子を母材中に析出させ溶接管Pを硬化
させる時効硬化処理を行う。時効硬化処理は、合金の過
飽和固溶体が時間の経過によって硬化する現象であり、
室温放置でおこるものを室温時効あるいは自然時効とい
い、加熱によっておこるものを高温時効あるいは人工時
効と称する。本発明が利用するのは後者である。過飽和
固溶体を2相領域まで加熱すると、微細な析出物が生じ
て硬化する。しかし、長時間加熱しすぎると析出物は粗
大化し、硬度はかえって低下する。微細な析出物の中に
は、G−P集合体と称されるものもあり、合金の時効硬
化の初期に、固溶体中の溶質原子が集まって析出した大
きさ約10nm以下の板状あるいは球状の集合体もある。Next, the welded pipe P formed into a product shape is heated to perform an age hardening treatment for precipitating solute atoms in the base material and hardening the welded pipe P. Age hardening is a phenomenon in which a supersaturated solid solution of an alloy hardens over time,
What occurs when left at room temperature is called room temperature aging or natural aging, and what occurs when heated is called high temperature aging or artificial aging. The latter is used by the present invention. When the supersaturated solid solution is heated to the two-phase region, fine precipitates are formed and hardened. However, if the material is heated for too long, the precipitates become coarse and the hardness rather decreases. Some of the fine precipitates are also called G-P aggregates, which are plate-like or spherical particles with a size of about 10 nm or less that are formed by the aggregation of solute atoms in the solid solution at the early stage of age hardening of the alloy. There is also a collection of.
【0036 】時効硬化処理の条件に必要な加熱温度お
よび加熱時間は、前述したように条材Tの材質によって
異なる。The heating temperature and the heating time required for the conditions of the age hardening treatment differ depending on the material of the strip T as described above.
【0037 】上記の時効硬化溶接管の製造方法によれ
ば、条材Tに溶体化処理を施して溶質原子を均一分布さ
せ、条材Tを軟化させることにより、ロールフォーミン
グおよび溶接を安定して円滑に行うことができ、溶接強
度を管の全長に亘って均一化かつ向上することが可能で
ある。また、前記のようにエンボス加工を行う場合に
は、エンボス加工を容易かつ十分に行うことができる。
さらに、エンボス加工、管成形工程、および溶接工程が
完了した後に、溶接管Pを加熱して溶質の微細結晶を母
材中に析出させ、溶接管Pを硬化させるため、最終的に
十分な強度を有する溶接管Pを得ることが可能である。According to the above-mentioned method for manufacturing an age-hardened welded pipe, the strip material T is subjected to solution treatment so that the solute atoms are uniformly distributed and the strip material T is softened, so that roll forming and welding are stably performed. It can be performed smoothly and the welding strength can be made uniform and improved over the entire length of the pipe. Moreover, when performing embossing as mentioned above, embossing can be performed easily and fully.
Furthermore, after the embossing process, the pipe forming process, and the welding process are completed, the welded pipe P is heated to precipitate fine crystals of the solute in the base material and harden the welded pipe P, so that the welded pipe P has a final sufficient strength. It is possible to obtain a welded pipe P having
【0038 】また、本発明の時効硬化溶接管は、十分
な強度を有するため、使用時における形状変化が少な
く、自立性にも優れる。さらに、U字状または螺旋状等
の形状を付与した後に時効硬化処理を施すことにより、
形状付与は容易でありながら、その最終形状からの変形
を防ぐことが可能であり、形状精度が高く、しかも高い
強度により自立性の優れた任意形状の伝熱管Pを得るこ
とができる。Since the age-hardened welded pipe of the present invention has sufficient strength, it has little change in shape during use and is excellent in self-supporting property. Furthermore, by applying a shape such as a U-shape or a spiral shape and then subjecting it to age hardening treatment,
Although it is easy to give a shape, it is possible to prevent deformation from the final shape, and it is possible to obtain a heat transfer tube P having an arbitrary shape with high shape accuracy and high strength and high self-sustainability.
【0039 】[0039]
【実施例】表1に記載した組成を有する各種時効硬化性
銅合金の条材(幅450mm×厚さ0.5mm)を用い、表
1に記載した条件の溶体化処理、高さ0.2mmでピッ
チ0.47mmのフィン転造、ロールフォーミング、突
き合わせ溶接、および表1に記載した条件の時効処理を
行い、実施例1〜12の伝熱管(外径9.52mm、肉厚
0.3mm)を得た。一方、伝熱管の材質として汎用され
ているリン脱酸銅(JIS合金番号C1220)を用
い、上記と同じフィン転造、ロールフォーミング、およ
び突き合わせ溶接を行い、実施例と同じ寸法の伝熱管を
比較例として得た。Examples Using age-hardening copper alloy strips (width 450 mm × thickness 0.5 mm) having the compositions shown in Table 1, solution treatment under the conditions shown in Table 1, height 0.2 mm Fin rolling with a pitch of 0.47 mm, roll forming, butt welding, and aging treatment under the conditions described in Table 1, and the heat transfer tubes of Examples 1 to 12 (outer diameter 9.52 mm, wall thickness 0.3 mm) Got On the other hand, using phosphorus deoxidized copper (JIS alloy No. C1220) which is widely used as the material of the heat transfer tube, the same fin rolling, roll forming and butt welding as the above were performed, and the heat transfer tube of the same size as the example was compared. Got as an example.
【0040 】次に、実施例1〜12および比較例の伝
熱管について、破裂強度および繰り返し耐圧回数を測定
した。破裂強度の測定方法はJISH3320試験法に
従い、管の内側に水圧をかけていき、管が破裂したとき
の水圧を測定した。繰り返し耐圧回数の測定方法はJI
SZ2273試験法に従い、2.94MPaの水圧を管
内に繰り返し加え、管が破裂したときの回数を測定し
た。結果を表1に示す。Next, the burst strength and the number of times of repeated withstand pressure were measured for the heat transfer tubes of Examples 1 to 12 and Comparative Example. The burst strength was measured according to the JIS H3320 test method by applying water pressure to the inside of the pipe and measuring the water pressure when the pipe burst. JI
According to the SZ2273 test method, a water pressure of 2.94 MPa was repeatedly applied to the inside of the pipe, and the number of times the pipe ruptured was measured. The results are shown in Table 1.
【0041 】[0041]
【表1】 [Table 1]
【0042 】表1から明らかなように、溶体化処理を
行った状態では実施例1〜12の条材の硬さは、比較例
の条材の硬さと同程度であり、フィン転造、ロールフォ
ーミングおよび溶接が安定して容易に行えた。一方、時
効硬化処理後の実施例1〜12の硬度は比較例に比して
格段に高く、破裂強度および繰り返し耐圧試験の結果も
優れていた。As is clear from Table 1, the hardness of the strips of Examples 1 to 12 in the state of being subjected to the solution heat treatment is about the same as the hardness of the strips of the comparative example. Forming and welding were stable and easy. On the other hand, the hardness of Examples 1 to 12 after the age hardening treatment was markedly higher than that of Comparative Example, and the results of the burst strength and the repeated pressure resistance test were also excellent.
【0043 】[0043]
【発明の効果】以上説明したとおり、本発明に係る時効
硬化溶接管の製造方法によれば、条材に溶体化処理を施
して溶質原子を均一分布させることにより、ロールフォ
ーミングおよび溶接を安定して容易に行うことができ、
溶接のムラに起因する溶接部の強度ばらつきを防止する
ことが可能である。As described above, according to the method for manufacturing an age-hardened welded pipe according to the present invention, the solution forming treatment is performed on the strip material to uniformly distribute the solute atoms, so that the roll forming and the welding are stabilized. Easy to do,
It is possible to prevent variations in the strength of the welded portion due to uneven welding.
【0044 】また、管内面にエンボス加工を行う場合
にも、エンボス加工を容易に行うことが可能となり、エ
ンボス加工装置の寿命を短くすることなく、必要十分な
深さを有する凹凸構造が形成できる。Further, even when the inner surface of the pipe is embossed, the embossing can be easily performed, and a concavo-convex structure having a necessary and sufficient depth can be formed without shortening the life of the embossing device. .
【0045 】さらに、溶接工程が完了した後に、溶接
管を加熱して溶質の微細結晶を母材中に析出させ溶接管
を硬化させるため、最終的に十分な強度を有する溶接管
を得ることが可能である。Furthermore, after the welding process is completed, the welded pipe is heated to precipitate fine crystals of solute in the base metal and harden the welded pipe, so that finally a welded pipe having sufficient strength can be obtained. It is possible.
【0046 】一方、本発明の時効硬化溶接管は、十分
な強度を有するため、使用時における形状変化が少な
く、自立性にも優れる。On the other hand, since the age-hardened welded pipe of the present invention has sufficient strength, the shape change during use is small and the self-standing property is excellent.
【図1】 本発明に係る時効硬化溶接管の製造方法の一
実施形態に使用される熱処理およびスリッター装置を示
す側面図である。FIG. 1 is a side view showing a heat treatment and slitter device used in an embodiment of a method for manufacturing an age-hardened welded pipe according to the present invention.
【図2】 同実施形態に使用されるエンボス加工・電縫
装置を示す側面図である。FIG. 2 is a side view showing an embossing / electric sewing device used in the same embodiment.
【図3】 時効硬化溶接管の一例としてU字管を示す平
面図である。FIG. 3 is a plan view showing a U-shaped tube as an example of an age hardening welded tube.
【図4】 時効硬化溶接管の他の例として螺旋管を示す
平面図である。FIG. 4 is a plan view showing a spiral tube as another example of the age hardening welded tube.
T 時効硬化性銅合金からなる条材 1 アンコイラ 4 加熱炉 8 スリッター T1 溶体化処理された条材 12 リコイラ 20 アンコイラ 24 フィン転造ロール 26 受けロール 30 フォーミングロール 34 誘導加熱コイル 36 スクイズロール P 溶接管 44 ラフコイラ T Strip made of age hardening copper alloy 1 Uncoiler 4 heating furnace 8 slitters T1 solution-treated strip 12 Ricoira 20 Uncoilers 24 fin rolling roll 26 Receiver roll 30 forming rolls 34 Induction heating coil 36 Squeeze Roll P welded pipe 44 rough coiler
フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C22F 1/08 C22F 1/08 L M N P B21C 37/08 B21C 37/08 F 37/083 37/083 Z B21D 5/12 B21D 5/12 J 22/08 22/08 // C22C 9/00 C22C 9/00 9/01 9/01 9/02 9/02 9/04 9/04 9/06 9/06 9/10 9/10 C22F 1/00 602 C22F 1/00 602 626 626 630 630A 630K 630M 651 651A 673 673 682 682 691 691B 691C Front page continuation (51) Int.Cl. 7 Identification code FI theme code (reference) C22F 1/08 C22F 1/08 L MN P B21C 37/08 B21C 37/08 F 37/083 37/083 Z B21D 5 / 12 B21D 5/12 J 22/08 22/08 // C22C 9/00 C22C 9/00 9/01 9/01 9/02 9/02 9/04 9/04 9/06 9/06 9/10 9/10 C22F 1/00 602 C22F 1/00 602 626 626 630 630A 630K 630M 651 651A 673 673 682 682 691 691B 691C
Claims (16)
ることにより溶質原子を均一分布させる溶体化処理を行
う溶体化処理工程と、 前記溶体化処理を施した条材を複数のフォーミングロー
ルを通して管状に成形する管成形工程と、 管状に成形された条材の両端縁を加熱したうえ突き合わ
せて溶接する溶接工程と、 前記溶接により得られた溶接管を加熱して前記溶質原子
を母材中に析出させ溶接管を硬化させる時効硬化処理工
程とを具備することを特徴とする時効硬化溶接管の製造
方法。1. A solution treatment step of performing a solution treatment for uniformly distributing solute atoms by heating a strip made of an age-hardenable copper alloy, and a plurality of forming rolls formed by the solution treatment. Through a tube forming step to form a tubular shape, a welding step in which both end edges of a tubular material that has been formed into a tubular shape are heated and then butt welded, and the solute atom is heated to heat the welded tube obtained by the welding A process for producing an age-hardened welded pipe, which comprises: an age-hardening treatment step of precipitating it inside and hardening the welded pipe.
とも一面にエンボス加工を行うエンボス加工工程をさら
に具備することを特徴とする請求項1記載の時効硬化溶
接管の製造方法。2. The method of manufacturing an age-hardened welded pipe according to claim 1, further comprising an embossing step of performing embossing on at least one surface of the solution-treated strip.
%以上含み、Be,Mg,Ca,Ti,Zr,Hf,
V,Nb,Ta,Cr,Mo,W,Mn,Fe,Co,
Rh,Ir,Ni,Pd,Pt,Ag,Au,Zn,C
d,B,Al,Ga,In,Tl,C,Si,Ge,S
n,Pb,P,As,Sb,Bi,O,S,Se,T
e,および希土類元素の中から選択される1または2以
上の元素を0.01〜49wt%含むことを特徴とする
請求項1または2記載の時効硬化溶接管の製造方法。3. The age hardening copper alloy contains 50 wt% of copper.
%, Be, Mg, Ca, Ti, Zr, Hf,
V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co,
Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, C
d, B, Al, Ga, In, Tl, C, Si, Ge, S
n, Pb, P, As, Sb, Bi, O, S, Se, T
3. The method for producing an age-hardened welded pipe according to claim 1, further comprising 0.01 to 49 wt% of one or more elements selected from e and rare earth elements.
05〜3wt%、Ni:0.002〜3wt%、Co:
0.0002〜0.9wt%、不可避不純物、およびC
u:残部の組成を有し、前記溶体化処理は600〜95
0℃×0.05〜30分の条件で行い、前記時効硬化処
理は250〜580℃×0.05〜600分の条件で行
うことを特徴とする請求項1または2記載の時効硬化溶
接管の製造方法。4. The age-hardenable copper alloy is Be: 0.0.
05-3 wt%, Ni: 0.002-3 wt%, Co:
0.0002 to 0.9 wt%, inevitable impurities, and C
u: The balance is the composition, and the solution treatment is 600 to 95.
The age hardening welded pipe according to claim 1 or 2, wherein the age hardening treatment is performed under conditions of 0 ° C x 0.05 to 30 minutes and the age hardening treatment is performed under conditions of 250 to 580 ° C x 0.05 to 600 minutes. Manufacturing method.
8〜5wt%、不可避不純物、およびCu:残部の組成
を有し、前記溶体化処理は600〜900℃×0.05
〜30分の条件で行い、前記時効硬化処理は250〜5
80℃×0.05〜600分の条件で行うことを特徴と
する請求項1または2記載の時効硬化溶接管の製造方
法。5. The age-hardenable copper alloy is Ag: 0.0
8 to 5 wt%, inevitable impurities, and Cu: the balance composition, and the solution treatment is 600 to 900 ° C. × 0.05.
~ 30 minutes, the age hardening treatment is 250 ~ 5
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is performed under the conditions of 80 ° C x 0.05 to 600 minutes.
〜4wt%、Ni:0.5〜3wt%、Si:0.05
〜0.5wt%、Zn:0.01〜0.8wt%、不可
避不純物、およびCu:残部の組成を有し、前記溶体化
処理は600〜950℃×0.05〜30分の条件で行
い、前記時効硬化処理は250〜550℃×0.05〜
600分の条件で行うことを特徴とする請求項1または
2記載の時効硬化溶接管の製造方法。6. The age-hardenable copper alloy is Sn: 0.5.
~ 4 wt%, Ni: 0.5-3 wt%, Si: 0.05
.About.0.5 wt%, Zn: 0.01 to 0.8 wt%, unavoidable impurities, and Cu: balance composition, and the solution treatment is performed at 600 to 950 ° C. for 0.05 to 30 minutes. The age hardening treatment is 250 to 550 ° C. × 0.05 to
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is performed under the condition of 600 minutes.
〜0.6wt%、Zr:0.0002〜0.3wt%、
Si:0.0002〜0.1wt%、Al:0.000
2〜0.2wt%、Sn:0.0002〜0.3wt
%、Mg:0.0002〜0.2wt%、Zn:0.0
002〜0.5wt%、不可避不純物、およびCu:残
部の組成を有し、前記溶体化処理は600〜980℃×
0.05〜30分の条件で行い、前記時効硬化処理は2
50〜590℃×0.05〜600分の条件で行うこと
を特徴とする請求項1または2記載の時効硬化溶接管の
製造方法。7. The age-hardenable copper alloy is Cr: 0.1.
~ 0.6 wt%, Zr: 0.0002 to 0.3 wt%,
Si: 0.0002 to 0.1 wt%, Al: 0.000
2 to 0.2 wt%, Sn: 0.0002 to 0.3 wt
%, Mg: 0.0002 to 0.2 wt%, Zn: 0.0
002 to 0.5 wt%, inevitable impurities, and Cu: balance composition, and the solution treatment is 600 to 980 ° C.
It is performed for 0.05 to 30 minutes, and the age hardening treatment is 2
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is performed under conditions of 50 to 590 ° C x 0.05 to 600 minutes.
〜1.8wt%、Sn:0.01〜3wt%、P:0.
003〜0.4wt%、不可避不純物、およびCu:残
部の組成を有し、前記溶体化処理は600〜980℃×
0.05〜30分の条件で行い、前記時効硬化処理は2
50〜580℃×0.05〜600分の条件で行うこと
を特徴とする請求項1または2記載の時効硬化溶接管の
製造方法。8. The age hardening copper alloy is Fe: 0.3
-1.8 wt%, Sn: 0.01-3 wt%, P: 0.
003 to 0.4 wt%, unavoidable impurities, and Cu: balance composition, and the solution treatment is 600 to 980 ° C.
It is performed for 0.05 to 30 minutes, and the age hardening treatment is 2
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is carried out under the condition of 50 to 580 ° C x 0.05 to 600 minutes.
1〜0.3wt%、不可避不純物、およびCu:残部の
組成を有し、前記溶体化処理は700〜1000℃×
0.05〜30分の条件で行い、前記時効硬化処理は2
50〜600℃×0.05〜600分の条件で行うこと
を特徴とする請求項1または2記載の時効硬化溶接管の
製造方法。9. The age-hardenable copper alloy is Zr: 0.0.
1 to 0.3 wt%, inevitable impurities, and Cu: the balance composition, and the solution treatment is 700 to 1000 ° C.
It is performed for 0.05 to 30 minutes, and the age hardening treatment is 2
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is carried out under conditions of 50 to 600 ° C x 0.05 to 600 minutes.
3〜4wt%、Si:0.02〜1wt%、Sn:0.
003〜1wt%、Zn:0.003〜3wt%、M
g:0.0002〜0.2wt%、不可避不純物、およ
びCu:残部の組成を有し、前記溶体化処理は600〜
950℃×0.05〜30分の条件で行い、前記時効硬
化処理は250〜550℃×0.05〜600分の条件
で行うことを特徴とする請求項1または2記載の時効硬
化溶接管の製造方法。10. The age-hardenable copper alloy is Ni: 0.
3-4 wt%, Si: 0.02-1 wt%, Sn: 0.
003 to 1 wt%, Zn: 0.003 to 3 wt%, M
g: 0.0002 to 0.2 wt%, inevitable impurities, and Cu: balance composition, and the solution treatment is 600 to
The age hardening welded pipe according to claim 1 or 2, wherein the age hardening treatment is performed under conditions of 950 ° C x 0.05 to 30 minutes, and the age hardening treatment is performed under conditions of 250 to 550 ° C x 0.05 to 600 minutes. Manufacturing method.
05〜0.3wt%、P:0.003〜0.1wt%、
不可避不純物、およびCu:残部の組成を有し、前記溶
体化処理は500〜950℃×0.05〜30分の条件
で行い、前記時効硬化処理は250〜480℃×0.0
5〜600分の条件で行うことを特徴とする請求項1ま
たは2記載の時効硬化溶接管の製造方法。11. The age-hardenable copper alloy is Fe: 0.
05-0.3 wt%, P: 0.003-0.1 wt%,
Inevitable impurities, and Cu: The balance of composition, the solution treatment is performed under the conditions of 500 to 950 ° C. × 0.05 to 30 minutes, and the age hardening treatment is 250 to 480 ° C. × 0.0.
The age-hardened welded pipe manufacturing method according to claim 1 or 2, which is performed under the condition of 5 to 600 minutes.
5〜3wt%、P:0.003〜0.4wt%、Zn:
0.01〜0.5wt%、Mg:0.0002〜0.2
wt%、Ni:0.001〜0.2wt%、Sn:0.
001〜0.2wt%、不可避不純物、およびCu:残
部の組成を有し、前記溶体化処理は700〜980℃×
0.05〜30分の条件で行い、前記時効硬化処理は2
50〜680℃×0.05〜600分の条件で行うこと
を特徴とする請求項1または2記載の時効硬化溶接管の
製造方法。12. The age hardening copper alloy is Fe: 1.
5 to 3 wt%, P: 0.003 to 0.4 wt%, Zn:
0.01-0.5 wt%, Mg: 0.0002-0.2
wt%, Ni: 0.001-0.2 wt%, Sn: 0.
001 to 0.2 wt%, unavoidable impurities, and Cu: balance, and the solution treatment is 700 to 980 ° C.
It is performed for 0.05 to 30 minutes, and the age hardening treatment is 2
The method for producing an age-hardened welded pipe according to claim 1 or 2, which is carried out under the conditions of 50 to 680 ° C x 0.05 to 600 minutes.
03〜4wt%、Fe:0.002〜0.9wt%、M
g:0.0002〜0.2wt%、不可避不純物、およ
びCu:残部の組成を有し、前記溶体化処理は560〜
980℃×0.05〜30分の条件で行い、前記時効硬
化処理は250〜550℃×0.05〜600分の条件
で行うことを特徴とする請求項1または2記載の時効硬
化溶接管の製造方法。13. The age-hardenable copper alloy is Ti: 0.
03-4 wt%, Fe: 0.002-0.9 wt%, M
g: 0.0002 to 0.2 wt%, unavoidable impurities, and Cu: balance composition, and the solution treatment is 560 to
The age-hardened welded pipe according to claim 1 or 2, wherein the age-hardening treatment is performed under conditions of 980 ° C x 0.05-30 minutes, and the age hardening treatment is performed under conditions of 250-550 ° C x 0.05-600 minutes. Manufacturing method.
1〜0.9wt%、P:0.0002〜0.2wt%、
Sn:0.0002〜0.3wt%,Be:0.000
1〜0.3wt%、不可避不純物、およびCu:残部の
組成を有し、前記溶体化処理は550〜950℃×0.
05〜30分の条件で行い、前記時効硬化処理は250
〜500℃×0.05〜600分の条件で行うことを特
徴とする請求項1または2記載の時効硬化溶接管の製造
方法。14. The age hardening copper alloy is Mg: 0.
1 to 0.9 wt%, P: 0.0002 to 0.2 wt%,
Sn: 0.0002 to 0.3 wt%, Be: 0.000
1 to 0.3 wt%, inevitable impurities, and Cu: balance composition, and the solution treatment is 550 to 950 ° C. × 0.
It is performed under the condition of 05 to 30 minutes, and the age hardening treatment is 250
The process for producing an age-hardened welded pipe according to claim 1 or 2, wherein the process is carried out under conditions of ~ 500 ° C x 0.05-600 minutes.
02〜3wt%、P:0.0003〜0.2wt%、不
可避不純物、およびCu:残部の組成を有し、前記溶体
化処理は650〜980℃×0.05〜30分の条件で
行い、前記時効硬化処理は250〜600℃×0.05
〜600分の条件で行うことを特徴とする請求項1また
は2記載の時効硬化溶接管の製造方法。15. The age-hardenable copper alloy is Co: 0.
02 to 3 wt%, P: 0.0003 to 0.2 wt%, unavoidable impurities, and Cu: balance, and the solution treatment is performed under the condition of 650 to 980 ° C. × 0.05 to 30 minutes, The age hardening treatment is 250 to 600 ° C. × 0.05
The process for producing an age-hardened welded pipe according to claim 1 or 2, wherein the process is performed under conditions of about 600 minutes.
溶接管の製造方法により製造された時効硬化溶接管。16. An age hardening welded pipe manufactured by the method for manufacturing an age hardening welded pipe according to claim 1.
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Cited By (8)
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JP2007321240A (en) * | 2006-06-05 | 2007-12-13 | Yamaha Metanikusu Kk | Heat dissipation material and manufacturing method thereof |
EP1880776A1 (en) | 2006-07-19 | 2008-01-23 | Europa Metalli S.p.A. | Method for the production of tubes |
JP2008280567A (en) * | 2007-05-09 | 2008-11-20 | Furukawa Electric Co Ltd:The | Heat treatment method for age-precipitation type alloy strip |
EP2056056A1 (en) | 2007-10-23 | 2009-05-06 | Kobelco & Materials Copper Tube, Ltd. | Copper alloy tube for heat exchanger excellent in fracture strength |
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JP2014043622A (en) * | 2012-08-28 | 2014-03-13 | Kobe Steel Ltd | High-strength copper alloy tube |
JP2014173141A (en) * | 2013-03-08 | 2014-09-22 | Kobe Steel Ltd | High strength copper alloy |
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2002
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007321240A (en) * | 2006-06-05 | 2007-12-13 | Yamaha Metanikusu Kk | Heat dissipation material and manufacturing method thereof |
EP1880776A1 (en) | 2006-07-19 | 2008-01-23 | Europa Metalli S.p.A. | Method for the production of tubes |
JP2008280567A (en) * | 2007-05-09 | 2008-11-20 | Furukawa Electric Co Ltd:The | Heat treatment method for age-precipitation type alloy strip |
EP2056056A1 (en) | 2007-10-23 | 2009-05-06 | Kobelco & Materials Copper Tube, Ltd. | Copper alloy tube for heat exchanger excellent in fracture strength |
US9671182B2 (en) | 2007-10-23 | 2017-06-06 | Kobelco & Materials Copper Tube, Ltd. | Copper alloy tube for heat exchanger excellent in fracture strength |
CN103075111A (en) * | 2012-07-13 | 2013-05-01 | 宝鸡石油钢管有限责任公司 | Coiled tubing with different strength sections and manufacturing method thereof |
JP2014043622A (en) * | 2012-08-28 | 2014-03-13 | Kobe Steel Ltd | High-strength copper alloy tube |
JP2014173141A (en) * | 2013-03-08 | 2014-09-22 | Kobe Steel Ltd | High strength copper alloy |
JP2014189804A (en) * | 2013-03-26 | 2014-10-06 | Kobe Steel Ltd | High strength copper alloy tube and manufacturing method therefor |
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