JP2003113063A - Deodorizing composition and cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a deodorizing composition having excellent deodorizing effect on the ill odor of an inorganic ultraviolet scattering agent. SOLUTION: The deodorizing composition for a 10-15C aliphatic aldehyde generating from a cosmetic formulated with an inorganic ultraviolet scattering agent contains one or more kinds of perfumery components selected from p- hydroxy-phenylbutanone, 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl- naphthalene, decahydro-3a,6,6,9a-tetramethylnaphtho(2.1-b)furan, 4-hydroxy-3- methoxy-benzaldehyde, 4-undecanolide, 4-tricyclodecylidene butanol, 4-(2,6,6- trimethyl-2-cyclohexen-1-yl)-3-methyl-3-buten-2-one, styrax resinoid, etc.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a deodorant composition and a cosmetic, and more particularly to improvement of the deodorizing effect thereof.

[0002]

2. Description of the Related Art In recent years, as the environment surrounding solar ultraviolet rays has deteriorated and the adverse effects of ultraviolet rays on the skin have become clear, the ultraviolet ray protective ability has become very important as the performance required of cosmetics. UV protectors used in cosmetics can be divided into organic UV absorbers and inorganic UV scatterers, which are stable to light and have little effect on the human body. Is the mainstream.

[0003]

However, the cosmetics containing the above-mentioned inorganic ultraviolet scattering agent and fatty acid may cause an unpleasant odor after application on the skin, which is a problem. Was there. The present invention has been made in view of the above-mentioned conventional problems, and an object thereof is to provide a deodorant composition having an excellent deodorizing effect against the odor of cosmetics containing an inorganic ultraviolet scattering agent. To do.

[0004]

Means for Solving the Problems In view of the above problems, as a result of intensive studies by the present inventors, this odor is caused by light irradiation, and is particularly remarkable in cosmetics containing fatty acids. The inventors have found that an excellent deodorizing effect can be obtained by using the above or in combination, and completed the present invention.

The first subject of the present invention is to say that the number of carbon atoms generated from cosmetics containing an inorganic UV-scattering agent is 10-15.
In the deodorant composition for aliphatic aldehydes of
-Hydroxy-phenylbutanone, 7-acetyl-1,
2,3,4,5,6,7,8-octahydro-1,1,
6,7-Tetramethyl-naphthalene, decahydro-3
a, 6,6,9a-Tetramethylnaphtho (2.1-b)
Furan, 4-hydroxy-3-methoxy-benzaldehyde, 4-undecanolide, 4-tricyclodecylidenebutanol, 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-methyl-3- Butene-2
-One, methyl dihydrojasmonate, 4 (3)-
(4-Hydroxy-4-methylphenyl) -3-cyclohexene-1-carboxalaldehyde, p-tert-butyl-α-methylhydrocinnamic aldehyde, 3-methyl-2- (cis-2-pentene-1- Yl) -2-Cyclopenten-1-one, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-butene-2
-One, 2- (2,4-dimethyl-3-cyclohexenyl) -5-methyl-5- (1-methylpropyl) -1,
A deodorant composition comprising one or two or more fragrances selected from the group consisting of 3-dioxane, methyl 3,6-dimethyl-β-resorcylate, and styrax resininoid. In the deodorant composition, the blending amount of the fragrance is preferably 0.001 to 100% by mass.

A second subject of the invention is p-hydroxy-
Phenylbutanone, 7-acetyl-1,2,3,4
5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene, decahydro-3a, 6,6,9
a-Tetramethylnaphtho (2.1-b) furan, 4-hydroxy-3-methoxy-benzaldehyde, 4-undecanolide, 4-tricyclodecylidenebutanol, 4
-(2,6,6-Trimethyl-2-cyclohexene-1
-Yl) -3-methyl-3-buten-2-one, methyldihydrojasmonate, 4 (3)-(4-hydroxy-4-methylphenyl) -3-cyclohexene-1-carboxalaldehyde, p- tert-butyl-α-methylhydrocinnamic aldehyde, 3-methyl-2- (cis
-2-Penten-1-yl) -2-cyclopentene-1
-One, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one, 2-
From the group consisting of (2,4-dimethyl-3-cyclohexenyl) -5-methyl-5- (1-methylpropyl) -1,3-dioxane, methyl 3,6-dimethyl-β-resorsylate, styrac resininoid. A cosmetic comprising one or more selected fragrances and an inorganic ultraviolet scattering agent that generates an aliphatic aldehyde having 10 to 15 carbon atoms.

In the cosmetic, it is preferable that the blending amount of the fragrance is 0.01 to 20% by mass. In the cosmetic, the inorganic ultraviolet scattering agent is preferably titanium oxide or zinc oxide whose surface is coated with one or more selected from the group consisting of fatty acid soap, fatty acid, and fatty acid ester. The cosmetic preferably contains one or more selected from the group consisting of fatty acid soaps, fatty acids, and fatty acid esters, and titanium oxide or zinc oxide.

[0008]

BEST MODE FOR CARRYING OUT THE INVENTION Preferred embodiments of the present invention will be described below. Inorganic UV-scattering agents have excellent UV protection, are stable to light, and have little effect on the human body. Therefore, they are widely used in cosmetics and the like that require UV protection. However, the above cosmetics sometimes feel unpleasant odor within 30 minutes to 1 hour after application. With regard to this strange odor, the cause has not been clarified, and there has been no sufficient improvement measure.

Therefore, the present inventors conducted various tests in order to investigate the cause of this strange odor, and this unpleasant odor had 1 carbon atom.
Inorganic UV scattering agents which have a metallic or fishy odor due to an aliphatic aldehyde of 0 to 15 and generate such unpleasant odors include fatty acid soaps such as aluminum stearate and zinc palmitate, stearic acid, myristic acid, palmitic acid. It was confirmed that this occurs when the surface coating is carried out with a fatty acid such as the above, a fatty acid ester such as dextrin palmitate or the like, or when the inorganic ultraviolet scattering agent and the fatty acid coexist in the formulation.

The inorganic ultraviolet scattering agent scatters ultraviolet rays due to its high refractive index, and therefore is a material having a very excellent ultraviolet protection ability, and a particle diameter of 0.02 to give a transparent feeling.
Mainly fine particle powder of about 0.07 μm. However, when the fine particle powder is blended into the cosmetic composition as it is, there is a problem that aggregation easily occurs and it is difficult to disperse, and various surface treatment methods for improving dispersibility have been studied, and fatty acid soap, fatty acid, fatty acid ester. Surface coating with a material such as the above has been performed more often than before.

A process in which a cosmetic containing an inorganic ultraviolet scattering agent coated with a fatty acid soap, a fatty acid, a fatty acid ester, or the like, or a cosmetic in which an inorganic ultraviolet scattering agent and a fatty acid coexist in the formulation cause a change in odor. , And the substance to be generated were not clear, but it was confirmed by a headspace gas chromatograph that it was an aldehyde having 10 to 15 carbon atoms. This odor is considered to be caused by the reaction of the surface coating agent on the skin by light irradiation after applying the cosmetic.

The inorganic ultraviolet scattering agent according to the present invention is one that is usually used and is not particularly limited, and examples thereof include titanium oxide and zinc oxide.

In order to eliminate this odor, in the present invention, p-hydroxy-phenylbutanone, 7-acetyl-1,2,3,4,5,6,7,8-octahydro-
1,1,6,7-tetramethyl-naphthalene, decahydro-3a, 6,6,9a-tetramethylnaphtho (2.1
-B) Furan, 4-hydroxy-3-methoxy-benzaldehyde, 4-undecanolide, 4-tricyclodecylidenebutanol, 4- (2,6,6-trimethyl-2).
-Cyclohexen-1-yl) -3-methyl-3-buten-2-one, methyldihydrojasmonate, 4
(3)-(4-hydroxy-4-methylphenyl) -3
-Cyclohexene-1-carboxalaldehyde, p-
tert-butyl-α-methylhydrocinnamic aldehyde, 3-methyl-2- (cis-2-penten-1-yl) -2-cyclopenten-1-one, 4- (2,6,
6-trimethyl-1-cyclohexen-1-yl) -3
-Buten-2-one, 2- (2,4-dimethyl-3-cyclohexenyl) -5-methyl-5- (1-methylpropyl) -1,3-dioxane, methyl 3,6-dimethyl-β- There is provided a deodorant composition comprising one or more flavors selected from the group consisting of resorcylate and styrax resininoid.

By applying the deodorant composition of the present invention to the skin, it is possible to deodorize the odor of the cosmetics containing an inorganic ultraviolet scattering agent that has already been applied to the skin.

In the present invention, "deodorant" means a masking effect and / or a harmony effect for the odor of an inorganic ultraviolet scattering agent. In the present invention, the masking effect means an effect that antagonizes the odor and makes it difficult to sense the odor, and the harmony effect means an effect that is well harmonized with the odor and does not cause discomfort.

The fragrance contained in the deodorant composition of the present invention is
It may be composed of only the above-mentioned fragrance, or may contain other fragrance as long as the deodorizing effect is not impaired. Further, the content of the fragrance in the total deodorant composition is 0.
It is preferably 001 to 100% by mass, particularly 0.01 to 100% by mass. If it is 0.001% by mass or less, the effect of the present invention may not be sufficiently exhibited.

The fragrance according to the present invention can be used in combination with an inorganic ultraviolet scattering agent in cosmetics. The cosmetics that can be blended are not particularly limited, and can be used in general cosmetics that incorporate an inorganic ultraviolet scattering agent. For example, it can be used by blending with sunscreen cream, oil-based foundation, water-based foundation, emulsion-type foundation, powder-type foundation and the like.

The amount of the fragrance compounded is 0.1% based on the total cosmetic composition.
It is preferably from 0 to 20% by mass, particularly from 0.01 to 5% by mass. If it is 0.01% by mass or less, the effect of the present invention may not be sufficiently exhibited, and if it is 20% by mass or more, the odor may be too strong and may be unpleasant.

In the deodorant composition or cosmetic of the present invention, in addition to the above-mentioned fragrance and / or inorganic ultraviolet scattering agent, the deodorant composition and cosmetics are usually added within a range not impairing the effects of the present invention. Ingredients used, such as moisturizers, antioxidants, oily ingredients, emulsifiers, surfactants, thickeners, alcohols, powder ingredients, coloring materials, aqueous ingredients, water, various skin nutritional agents, etc. It can be blended appropriately.

Further, sequestering agents such as disodium edetate, trisodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, malic acid, caffeine, tannin, verapamil, tranexamic acid, and the like. Derivatives, licorice extract, glabridin, hot water extract of karin fruit, various crude drugs, drugs such as tocophenol acetate, glycyrrhizinic acid and its derivatives or salts thereof, retinoic acid, retinol, retinol acetate, retinol pyroionate, palmitic acid Drugs such as retinol and its derivatives or salts thereof, whitening agents such as vitamin C, magnesium ascorbyl phosphate, ascorbyl glucoside, arbutin and kojic acid, fructose, mannose, erythritol, trehalose, xylitol, etc. Sugars, arginine, amino acids such as lysine, and can be blended as appropriate also amino acids such as derivatives or salts thereof, such as trimethyl glycine.

Further, the deodorant composition and cosmetics of the present invention can be widely applied to cosmetics applied to the outer skin, pharmaceuticals, and quasi drugs. The dosage form can be any drug formulation, including solution systems, solubilization systems, emulsification systems, powder dispersion systems, water-oil two-layer systems, water-oil-powder three-layer systems, gels, aerosols, It can be provided in any form such as a mist and a capsule.

The form of use is also arbitrary, and examples include sunscreens, foundations, emulsions, creams,
Any form can be used as long as it is conventionally used for deodorants and cosmetics, such as lotion, lotion, spray, mousse, gel, hair shampoo, hair rinse, hair treatment, and lipstick.

[0023]

EXAMPLES Next, the present invention will be described in more detail by way of examples, but the technical scope of the present invention is not limited by these examples. In addition, all compounding amounts are mass%. (1) Relationship Between Kind of Inorganic UV Protective Agent and Smell Odor Among cosmetics containing an inorganic UV scatterer, some odors may occur and some may not. Therefore, the present inventors produced cosmetics by changing the type of the inorganic UV protection agent, respectively, in order to investigate in which case the odor occurs and what is the causative substance thereof. Various tests were conducted. Sunscreens containing various inorganic UV protectors were prepared and applied to the skin in a room at a room temperature of 30 to 35 ° C., a humidity of 58 to 72% and a light irradiation amount of 750 KJ / m ² . The dispersibility of the inorganic ultraviolet protective agent in the base material, the transparency of the sunscreen coating film, and the presence or absence of odor (4 hours after application) were evaluated according to the following criteria. The results are shown in Table 1.

<Evaluation criteria>Base dispersibility ◯: It is easy to disperse without aggregation. Δ: Aggregates easily, but can be dispersed. X: Agglomerated and cannot be dispersed.transparency ◯: Excellent transparency and no whitening. Δ: Poor in transparency and slightly whitened. X: There is no transparency and whitening occurs.Odor ○: None ×: Yes

[0025]

[Table 1] Test Example 1 Test Example 2 Test Example 3 Test Example 4 Palmitin Acid Dextrin-treated fine particles Zinc oxide (0.05 μm)                                5.0 ―― ―― ―― Fine particle zinc oxide (0.05 μm) ―― 5.0 ―― 5.0 Zinc oxide (0.5 μm) ―― ―― 5.0 ――Permitin Acid ―― ―― ―― 5.0 1,3-butylene glycol 5.0 5.0 5.0 5.0 Polyoxyethylene / methylpolysiloxane Copolymer 2.0 2.0 2.0 2.0 Dimethyldistearyl ammonium hectorite        0.5 0.5 0.5 0.5 Cyclomethyl silicone                     32 32 32 32 Methyl polysiloxane                     5.0 5.0 5.0 5.0 Octyl methoxycinnamate                  7.0 7.0 7.0 7.0 Spherical polyethylene 5.0 5.0 5.0 5.0 Paraben                          Right amount Right amount Right amount Right amount EDTA / 3Na / 2H₂O 0.05 0.05 0.05 0.05Ion-exchanged water Residual Residual Residual Transparency ○ ○ × ○ Base dispersibility ○ × △ △Odor × ○ ○ ×

From Table 1, the sunscreen using fine zinc oxide particles treated with dextrin palmitate is superior in transparency and dispersibility to the base material as compared with other sunscreens, but odor is generated by light irradiation. It was confirmed. In addition, the odor also occurred in the sunscreen using fine particle zinc oxide and fatty acid. Therefore, it was found that this odor was derived from the presence or absence of fatty acids. It was also confirmed by headspace gas chromatography that the causative substance of the offensive odor was an aliphatic aldehyde having 10 to 15 carbon atoms (Fig. 1). It is not clear how the cosmetic containing the surface-coated inorganic UV scattering agent changes its odor, but after application, the surface-coating agent reacts on the skin with light irradiation to generate an aliphatic aldehyde having 10 to 15 carbon atoms. It is thought to be to do. Therefore, a fragrance having a deodorizing effect against the base odor was examined.

(2) Type of fragrance and deodorizing effect Room temperature 30 to 35 ° C., humidity 58 to 72%, light irradiation amount 750
In a KJ / m ² room, a sunscreen containing 0.005% by mass of each fragrance was applied to the skin of each panelist. Before the application, 1 hour after the application, and 2 hours after the application, the scent masking effect and the harmony effect were comprehensively evaluated. The odorants that were evaluated were p-methoxybenzaldehyde (sweet odor) and 2-ethylhexanol (greenish pungent odor), which were sensory-evaluated according to the following criteria. The results are shown in Table 2.

<Evaluation Criteria> ⊚: Very effective. ○: The effect is recognized. Δ: Not very effective X: No effect is observed.

[0029]

[Table 2]                                     Test example4 5 6 7 8 9 10 p-Hydroxy-phenylbutanone 0.005 − − − − − − Lemon oil             − 0.02 − − − − − Mandarin oil          − − 0.02 − − − − Orange oil           − − − 0.02 − − − Grapefruit oil      − − − − 0.02 − − Rose oil            − − − − − 0.02 −Geranium oil − − − − − − 0.02 Palmitin Acid Dextrin-treated fine particles Zinc oxide (0.05 μm)                  0.5 0.5 0.5 0.5 0.5 0.5 0.5 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Polyoxyethylene / methylpolysiloxane Copolymer                  2.0 2.0 2.0 2.0 2.0 2.0 2.0 Dimethyldistearyl ammonium hectorite                    0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Cyclomethyl silicone       32 32 32 32 32 32 32 Methyl polysiloxane       5.0 5.0 5.0 5.0 5.0 5.0 5.0 Octyl methoxycinnamate    7.0 7.0 7.0 7.0 7.0 7.0 7.0 Spherical polyethylene 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Paraben           Right amount Right amount Right amount Right amount Right amount Right amount Right amount EDTA / 3Na / 2H₂O 0.05 0.05 0.05 0.05 0.05 0.05 0.05Ion-exchanged water Residual Residual Residual Residual Residual Residual Musking Effect ◎ × × × × × ×Harmony effect ◎ × × × × × × ×                                     Test example11 12 13 14 15 16 17 Peppermint oil     0.005 − − − − − − 1- (2,6,6-trimethyl-2-cyclohexenyl) -2-buten-1-one                  − 0.005 − − − − − 5-methyl-2-isopropylcyclohexanol                  − − 0.005 − − − − Belugamot oil       − − − 0.02 − − − Ylang Ylang Oil         − − − − 0.005 − − n-decyl aldect − − − − − − 0.005 −Allyl isoamyloxyacetate − − − − − − 0.005 Palmitin Acid Dextrin-treated fine particles Zinc oxide (0.05 μm)                  0.5 0.5 0.5 0.5 0.5 0.5 0.5 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Polyoxyethylene / methylpolysiloxane Copolymer                  2.0 2.0 2.0 2.0 2.0 2.0 2.0 Dimethyldistearyl ammonium hectorite                    0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Cyclomethyl silicone       32 32 32 32 32 32 32 Methyl polysiloxane       5.0 5.0 5.0 5.0 5.0 5.0 5.0 Octyl methoxycinnamate    7.0 7.0 7.0 7.0 7.0 7.0 7.0 Spherical polyethylene 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Paraben           Right amount Right amount Right amount Right amount Right amount Right amount Right amount EDTA / 3Na / 2H₂O 0.05 0.05 0.05 0.05 0.05 0.05 0.05Ion-exchanged water Residual Residual Residual Residual Residual Residual Musking Effect × △ × × × × ×Harmony effect × × × × × × × ×

From Table 2, it can be seen that the fragrances generally used in cosmetics have no masking effect and harmony effect against the odor of cosmetics containing an inorganic ultraviolet scattering agent, whereas the present invention It was confirmed that the p-hydroxy-phenylbutanone according to Example 1 has excellent masking effect and harmony effect. In addition, the present inventors have discovered a specific fragrance having a masking effect and a harmony effect. It shows in Table 3.

[0031]

[Table 3]

P-Hydroxy-phenylbutanone, 7-
Acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene, decahydro-3a, 6,6,9a-tetramethylnaphtho (2.1 -B) Furan and 4-hydroxy-3-methoxy-benzaldehyde have a particularly excellent masking effect and harmony effect, and 4-undecanolide, 4-
Tricyclodecylidene butanol, 4- (2,6,6-
Trimethyl-2-cyclohexen-1-yl) -3-methyl-3-buten-2-one, methyldihydrojasmonate, 4 (3)-(4-hydroxy-4-methylphenyl) -3-cyclohexene-1 -Carboxalaldehyde, p-tert-butyl-α-methylhydrocinnamic aldehyde, 3-methyl-2- (cis-2-pentene-
1-yl) -2-cyclopenten-1-one, 4-
(2,6,6-trimethyl-1-cyclohexene-1-
Yl) -3-buten-2-one, 2- (2,4-dimethyl-3-cyclohexenyl) -5-methyl-5- (1-
Methylpropyl) -1,3-dioxane, methyl 3,6
It was shown that -dimethyl-β-resorcylate and styrax resininoid have a masking effect and a harmonizing effect according to them.

The following are examples of formulation of deodorant compositions and cosmetics suitable for carrying out the present invention, but the technical scope of the present invention is not limited by these examples.

[0034]Example 1 Sunscreen (cosmetics) <Prescription>   Oil phase; Titanium Dioxide Treated with Dextrin Palmitate 8.0 4-tert-butyl-4'-methoxybenzoylmethane 8.0 Tetra-2-ethylhexyl acid pentaerythritol 3.0 2-hydroxy-4-methoxybenzophenone 3.0 Squalane 20.0 Polyoxyethylene / methylpolysiloxane copolymer 3.0 Organic modified montmorillonite 1.5 Silicon powder 5.0 Paraben 0.2 Perfume of Table 4 0.1 γ-Oryzanol 0.1   Water phase; Dynamite glycerin 3.0 Trisodium edetate 0.2 Ion-exchanged water residue

<Manufacturing Method> The aqueous phase was heated to 70 ° C. and dissolved. In the oil phase portion, components other than titanium dioxide and silicon powder were heated and dissolved, and then titanium dioxide and silicon powder were sufficiently dispersed. The water phase part was added to the oil phase part while performing the homogenizer treatment, and the emulsion was cooled using a heat exchanger to obtain a sunscreen.

[0036]

[Table 4] Fragrance name Mixing amount 4- (2,6,6-Trimethyl-2-cyclohexen-1-yl) -3-methyl-3-buten-2-one 100-methyl dihydroxylogosmonate                                          100 4- (2,6,6-Trimethyl-1-cyclohexen-1-yl) -3-buten-2-one 5 decahydro -3a, 6,6,9a-Tetramethylnaphtho (2.1-b) furan 5 4-Hydroxy-3-methoxybenzyl aldehit 1% 5 4-Undecanol 10% 2 3-Methyl-2- (cis-2-penten-1-yl) -2-cyclopenten-1-one 10% 5 1- (2,6,6-trimethyl-2-cyclohexenyl) -2-buten-1-one 10% 2 p-Human ethoxyphenylbutanone 5 allyl isoamyloxyacetate 10% 2 7-Acetyl-1,2,3,4,5,6,7,8-octahitro-1,1,6,7-tetramethyl-naphthalene 30 bergamot oil                                                100 4 (3)-(4-Humanoxy-4-methylpentyl) -3-cyclohexene-1-carboxalaldehit 100 p-tert-Butyl-α-methyl human "Grosinamic Aldehito" 30 grape fruit oil                                              100 orange oil                                                     50 Hexyl Synthetic Aldehit                                            60 Oxacyclohexadecene -2-on 50 cis-3-hexenol 2 benzyl acetate                                                  25 phenyl ethyl alcohol                                                 Fifty 3,7-Dimethyl-6-octene-1-ol 20 indole 10% 2 3- (3,4-Methylenedioxyphenyl) -2-methylpropanol 8 cis-3-Hexenylmethyl carbonylate 10% 5 3-Methyl-5- (2,2,3-trimethylpent-3-en-1-yl) -pentan-2-ol-5allylcyclohexyloxyacetate 10% 1 4-Tricyclodesilidin butanol 10% 1Jewel Prolong Recall 130       Total 1000

[0037]Example 2 Makeup mist (deodorant composition) <Prescription>     Ethyl alcohol 10.0     Dipropylene glycol 2.0     1,3-butylene glycol 5.0     Polyethylene glycol 1500 3.0     Polyoxyethylene (60) hydrogenated castor oil 1.0     Diglyceryl diisostearate 0.5     Glyceryl tri-2-ethylhexanoate 0.5     Nylon 1.0     Glycerin 2.0     Dye suitable amount     pH buffering agent     Preservative Suitable amount     Antioxidant Appropriate amount     Perfume according to the present invention     Ion-exchanged water 73.0

[0038]Example 3 Powdery Foundation <Prescription>     Fatty acid metal soap treatment (aluminum stearate treatment) titanium oxide                                                 10.0     Talc 20.0     Mica 35.0     Kaolin 5.0     Mica titanium 10.0     Bengal 1.0     Yellow iron oxide 3.0     Black iron oxide 0.2     Nylon powder 10.0     Squalane 6.0     Lanolin acetate 1.0     Octyldodecyl myristate 2.0     Neopentyl glycol diisooctanoate 2.0     Sorbitan monooleate 0.5     Octyl methoxycinnamate 2.0     Preservative Suitable amount     Antioxidant Appropriate amount     Perfume according to the present invention

[0039]

As described above, according to the present invention,
By using the specific fragrance alone or in combination, it is possible to provide a deodorant composition having an excellent deodorizing effect against the odor of the inorganic ultraviolet scattering agent.

[Brief description of drawings]

FIG. 1 is a headspace gas chromatograph showing a change in odor of an inorganic ultraviolet scattering agent-containing cosmetic composition of the present invention.

   ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Ryushi Hotta             2-2-1 Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa               Shiseido Research Center Co., Ltd.             Beach) (72) Inventor Masanori Yoshimura             2-2-1 Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa               Shiseido Research Center Co., Ltd.             Beach) F-term (reference) 4C083 AA121 AA122 AB211 AB232                       AB241 AB242 AB432 AB442                       AC022 AC071 AC082 AC102                       AC122 AC152 AC211 AC212                       AC241 AC331 AC332 AC341                       AC342 AC351 AC352 AC392                       AC422 AC432 AC442 AC482                       AC532 AC841 AC842 AC852                       AD042 AD072 AD152 AD162                       AD512 AD531 AD532 BB41                       BB46 CC12 CC17 CC19 DD08                       DD17 EE18

Claims (6)

[Claims] 1. A deodorant composition for an aliphatic aldehyde having 10 to 15 carbon atoms generated from a cosmetic composition containing an inorganic ultraviolet scattering agent, which comprises p-hydroxy-phenylbutanone and 7-acetyl-1,2,3. , 4, 5, 6, 7, 8-
Octahydro-1,1,6,7-tetramethyl-naphthalene, decahydro-3a, 6,6,9a-tetramethylnaphtho (2.1-b) furan, 4-hydroxy-3-methoxy-benzaldehyde, 4-undecanolide , 4-
Tricyclodecylidene butanol, 4- (2,6,6-
Trimethyl-2-cyclohexen-1-yl) -3-methyl-3-buten-2-one, methyldihydrojasmonate, 4 (3)-(4-hydroxy-4-methylphenyl) -3-cyclohexene-1 -Carboxalaldehyde, p-tert-butyl-α-methylhydrocinnamic aldehyde, 3-methyl-2- (cis-2-pentene-
1-yl) -2-cyclopenten-1-one, 4-
(2,6,6-trimethyl-1-cyclohexene-1-
Yl) -3-buten-2-one, 2- (2,4-dimethyl-3-cyclohexenyl) -5-methyl-5- (1-
Methylpropyl) -1,3-dioxane, methyl 3,6
-A deodorant composition comprising one or more fragrances selected from the group consisting of dimethyl-β-resorcylate and styrax resininoid. 2. The deodorant composition according to claim 1, wherein the amount of the fragrance compounded is 0.001 to 100% by mass. 3. p-Hydroxy-phenylbutanone, 7
-Acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene,
Decahydro-3a, 6,6,9a-tetramethylnaphtho (2.1-b) furan, 4-hydroxy-3-methoxy-benzaldehyde, 4-undecanolide, 4-tricyclodecylidenebutanol, 4- (2,6). , 6-Trimethyl-2-cyclohexen-1-yl) -3-methyl-
3-buten-2-one, methyldihydrojasmonate, 4 (3)-(4-hydroxy-4-methylphenyl) -3-cyclohexene-1-carboxalaldehyde, p-tert-butyl-α-methylhydro Cinamic aldehyde, 3-methyl-2- (cis-2-pentene-1
-Yl) -2-cyclopenten-1-one, 4- (2,
6,6-Trimethyl-1-cyclohexen-1-yl)
-3-Buten-2-one, 2- (2,4-dimethyl-3
-Cyclohexenyl) -5-methyl-5- (1-methylpropyl) -1,3-dioxane, methyl 3,6-dimethyl-β-resorsylate, and one or two species selected from the group consisting of styracus resinoids A cosmetic comprising the above fragrance and an inorganic ultraviolet scattering agent that generates an aliphatic aldehyde having 10 to 15 carbon atoms. 4. The cosmetic according to claim 3, wherein the blending amount of the fragrance is 0.01 to 20% by mass. 5. The oxidation product according to claim 3 or 4, wherein the inorganic ultraviolet scattering agent is surface-coated with one or more selected from the group consisting of fatty acid soaps, fatty acids and fatty acid esters. A cosmetic material comprising titanium or zinc oxide. 6. The cosmetic composition according to claim 3 or 4, comprising one or more kinds selected from the group consisting of fatty acid soaps, fatty acids, and fatty acid esters, and titanium oxide or zinc oxide. And cosmetics.