JP2001091354A - Pyroelectric infrared thin-film element - Google Patents

Pyroelectric infrared thin-film element

Info

Publication number
JP2001091354A
JP2001091354A JP26766299A JP26766299A JP2001091354A JP 2001091354 A JP2001091354 A JP 2001091354A JP 26766299 A JP26766299 A JP 26766299A JP 26766299 A JP26766299 A JP 26766299A JP 2001091354 A JP2001091354 A JP 2001091354A
Authority
JP
Japan
Prior art keywords
thin film
pyroelectric
pyroelectric infrared
infrared
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26766299A
Other languages
Japanese (ja)
Inventor
Koji Tominaga
浩二 富永
Kazutaka Okamoto
一隆 岡本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Horiba Ltd
Original Assignee
Horiba Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Horiba Ltd filed Critical Horiba Ltd
Priority to JP26766299A priority Critical patent/JP2001091354A/en
Publication of JP2001091354A publication Critical patent/JP2001091354A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a pyroelectric infrared thin-film element by which infrared rays can be measured with stable accuracy without being influenced by an ambient temperature even when the ambient temperature is changed. SOLUTION: In this pyroelectric infrared thin-film element, an upper-part electrode 4 and a lower-part electrode 5 are formed respectively on the surface and the rear surface of a pyroelectric thin film 3, and an infrared detection part 6 is formed. A heater 9 is installed at the infrared detection part 6, the heater 9 is electrified, and the temperature of the pyroelectric thin film 3 is adjusted.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、焦電体薄膜の上
面および下面にそれぞれ上部電極および下部電極を設け
て赤外線検出部を形成した焦電型赤外線薄膜素子に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pyroelectric infrared thin-film element in which an infrared detector is formed by providing an upper electrode and a lower electrode on the upper and lower surfaces of a pyroelectric thin film, respectively.

【0002】[0002]

【従来の技術】上記焦電型赤外線薄膜素子として、例え
ば特開平9−318454号公報に記載されたものがあ
る。図5は、この公報に記載された焦電型赤外線薄膜素
子を概略的に示すもので、この図において、1はMgO
(酸化マグネシウム)よりなる単結晶基板で、2はこの
基板1の表層部にエッチングによって形成される微小な
凹部である。3は焦電体薄膜で、例えばPZT強誘電体
薄膜またはPLZT強誘電体薄膜からなる。この焦電体
薄膜3の上下両面には、それぞれ例えばPt(白金)よ
りなる上部電極4と下部電極5とが互いに対応するよう
に設けられている。なお、矢印A方向に見て、上部電極
4、下部電極5および焦電体薄膜3が互いに重なり合う
部分を赤外線検出部6というものとする。
2. Description of the Related Art As the above-mentioned pyroelectric infrared thin film element, for example, there is one described in Japanese Patent Application Laid-Open No. 9-318454. FIG. 5 schematically shows a pyroelectric infrared thin film element described in this publication, where 1 is MgO.
A single crystal substrate made of (magnesium oxide) 2 is a minute concave portion formed by etching in the surface layer of the substrate 1. Reference numeral 3 denotes a pyroelectric thin film, for example, a PZT ferroelectric thin film or a PLZT ferroelectric thin film. On the upper and lower surfaces of the pyroelectric thin film 3, an upper electrode 4 and a lower electrode 5 made of, for example, Pt (platinum) are provided so as to correspond to each other. When viewed in the direction of arrow A, a portion where the upper electrode 4, the lower electrode 5, and the pyroelectric thin film 3 overlap each other is referred to as an infrared detector 6.

【0003】7は赤外線検出部6の周辺に形成され、赤
外線検出部6を基板1に対して保持させる絶縁性薄膜
で、例えばポリイミド系樹脂薄膜のような有機絶縁性薄
膜またはSiO2 薄膜やSi3 4 のような無機絶縁性
薄膜よりなる。8は上部電極4の上面を被覆するように
設けられる赤外線吸収膜で、フォトリソグラフが可能な
感光性有機薄膜にカーボンブラックのような赤外線吸収
材料を適宜混入してなるものである。
An insulating thin film 7 is formed around the infrared detecting section 6 and holds the infrared detecting section 6 with respect to the substrate 1. The insulating thin film 7 is, for example, an organic insulating thin film such as a polyimide resin thin film, a SiO 2 thin film or a Si thin film. an inorganic insulating film such as 3 N 4. Reference numeral 8 denotes an infrared absorbing film provided so as to cover the upper surface of the upper electrode 4, which is formed by appropriately mixing an infrared absorbing material such as carbon black into a photosensitive organic thin film capable of photolithography.

【0004】上記焦電型赤外線検出器においては、赤外
線検出部6の上面に赤外線吸収膜8を形成しているの
で、感度が良好で応答速度に優れるといった利点があ
る。
In the above-described pyroelectric infrared detector, since the infrared absorption film 8 is formed on the upper surface of the infrared detector 6, there is an advantage that the sensitivity is good and the response speed is excellent.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、一般
に、焦電型赤外線検出器は、上記構成の焦電型赤外線薄
膜素子を赤外線透過窓を形成した容器内に組み込んだ焦
電型赤外線検出器においても、一般的には、感度に対し
て温度係数を持っている。図6は、例えば3つの焦電型
赤外線検出器について、周囲温度を変化させたときにお
ける出力の状況をプロットした(図中の●、□、△で示
す)もので、周囲温度が20℃のときの感度を100%
としている。
However, in general, the pyroelectric infrared detector is also applicable to a pyroelectric infrared detector in which the pyroelectric infrared thin-film element having the above structure is incorporated in a container having an infrared transmission window. , Generally, has a temperature coefficient for sensitivity. FIG. 6 is a plot of the output status when the ambient temperature is changed for three pyroelectric infrared detectors (indicated by ●, □, and Δ in the figure). 100% sensitivity
And

【0006】したがって、上述のような感度に対する温
度係数を持つ焦電型赤外線検出器を、例えばガス分析計
に複数個用いる場合、それらの温度係数が互いにほぼ等
しいものを用いることが望ましく、これらを温度調節さ
れた金属ブロックに固定するようにしている。
Therefore, when a plurality of pyroelectric infrared detectors having a temperature coefficient for sensitivity as described above are used in, for example, a gas analyzer, it is desirable to use ones whose temperature coefficients are substantially equal to each other. It is fixed to a temperature-controlled metal block.

【0007】そして、上記複数の焦電型赤外線検出器を
用いたガス分析計において、その測定精度を上げるた
め、焦電型赤外線検出器の温度係数をほぼ等しくするた
めに、温度係数を測定することが好ましいが、この測定
にはかなりに時間や労力を必要とする。また、前記金属
ブロックの温度調節を行う場合、これを一定温度にする
まで暖機時間を必要とする。これは、金属ブロックの熱
容量が大きいためであるが、金属ブロックの熱容量を小
さくしてしまうと、金属ブロックの温度が周囲温度によ
って左右されるといった不都合がある。さらに、大きな
熱容量を有する金属ブロックの温度調節を行うには、か
なり大容量の温度調節用ヒータが必要になるが、それだ
け消費電力が大きくなり、ランニングコストなどコスト
アップを招来する。
In the gas analyzer using the plurality of pyroelectric infrared detectors, the temperature coefficient is measured to improve the measurement accuracy and to make the temperature coefficient of the pyroelectric infrared detector substantially equal. However, this measurement requires considerable time and effort. In addition, when the temperature of the metal block is adjusted, a warm-up time is required until the temperature is adjusted to a constant temperature. This is because the heat capacity of the metal block is large. However, if the heat capacity of the metal block is reduced, there is a disadvantage that the temperature of the metal block depends on the ambient temperature. Further, in order to control the temperature of the metal block having a large heat capacity, a considerably large-capacity temperature control heater is required. However, the power consumption is correspondingly increased, which leads to an increase in running costs and other costs.

【0008】この発明は、上述の事柄に留意してなされ
たもので、周囲温度の影響が変化してもその影響を受け
ず、安定した精度で測定が可能な焦電型赤外線薄膜素子
を提供することを目的としている。
The present invention has been made in consideration of the above-mentioned circumstances, and provides a pyroelectric infrared thin-film element which can be measured with stable accuracy without being affected by the influence of the ambient temperature. It is intended to be.

【0009】[0009]

【課題を解決するための手段】上記目的を達成するた
め、この発明では、焦電体薄膜の上面および下面にそれ
ぞれ上部電極および下部電極を設けて赤外線検出部を形
成した焦電型赤外線薄膜素子において、前記赤外線検出
部にヒータを設け、このヒータに通電を行うことによ
り、焦電体薄膜の温度調節を行うようにしている。
In order to achieve the above object, the present invention provides a pyroelectric infrared thin film element in which an infrared detector is formed by providing an upper electrode and a lower electrode on the upper and lower surfaces of a pyroelectric thin film, respectively. In the above, a heater is provided in the infrared detection section, and the heater is energized to control the temperature of the pyroelectric thin film.

【0010】上記構成の焦電型赤外線薄膜素子において
は、焦電体薄膜の熱容量が小さく、したがって、これを
含む赤外線検出部をヒータによって加熱しても、温度が
安定するまでに僅か数秒といった極めて短い時間しか必
要としない。また、温度調節のためのブロックなどを必
要としないため、構成が簡略化される。
In the pyroelectric infrared thin film element having the above-mentioned structure, the heat capacity of the pyroelectric thin film is small. Therefore, even if the infrared detecting section including the thin film is heated by the heater, it takes only a few seconds until the temperature is stabilized. Requires only a short time. Further, since a block for adjusting the temperature is not required, the configuration is simplified.

【0011】[0011]

【発明の実施の形態】この発明の実施の形態を、図面を
参照しながら説明する。図1は、この発明の焦電型赤外
線薄膜素子の一例を示すもので、この図に示す焦電型赤
外線薄膜素子が、上記図5に示したものと大きく異なる
点は、焦電体薄膜、上部電極および下部電極を含む赤外
線検出部にヒータを設け、このヒータに通電を行うこと
により、焦電体薄膜の温度調節を行うようにしたことで
ある。
Embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows an example of a pyroelectric infrared thin-film element of the present invention. The pyroelectric infrared thin-film element shown in FIG. 1 is significantly different from that shown in FIG. A heater is provided in the infrared detecting section including the upper electrode and the lower electrode, and the heater is energized to control the temperature of the pyroelectric thin film.

【0012】すなわち、図1において、9は赤外線検出
部6に設けられるヒータで、例えばPt、Ni、NiC
lなどの金属からなり、より詳しくは、赤外線検出部6
を基板1に対して保持させる絶縁性薄膜7の上面に設け
られている。そして、10はこのヒータ9を覆うように
して設けられる絶縁性薄膜で、この絶縁性薄膜10は赤
外線検出部6を基板1に対して保持させる絶縁性薄膜7
と同様に、例えばポリイミド系樹脂薄膜のような有機絶
縁性薄膜またはSiO2 薄膜やSi3 4 のような無機
絶縁性薄膜よりなる。そして、この絶縁性薄膜10の上
面に赤外線吸収膜8が設けられている。
That is, in FIG. 1, reference numeral 9 denotes a heater provided in the infrared detecting unit 6, for example, Pt, Ni, NiC.
1 and more specifically, the infrared detecting unit 6
Is provided on the upper surface of the insulating thin film 7 for holding the substrate 1 against the substrate 1. Reference numeral 10 denotes an insulating thin film provided so as to cover the heater 9. The insulating thin film 10 is an insulating thin film 7 for holding the infrared detecting unit 6 with respect to the substrate 1.
Similarly to the above, for example, it is composed of an organic insulating thin film such as a polyimide resin thin film or an inorganic insulating thin film such as a SiO 2 thin film or Si 3 N 4 . The infrared absorbing film 8 is provided on the upper surface of the insulating thin film 10.

【0013】上記構成の焦電型赤外線薄膜素子は、赤外
線透過窓を形成した容器内に組み込んで焦電型赤外線検
出器として形成される。図2は、この焦電型赤外線検出
器の電気的構成を概略的に示す図で、この図において、
11は赤外線検出部6の検出信号を増幅する回路、12
はヒータ9を温度調節する回路である。
The pyroelectric infrared thin-film element having the above-described structure is incorporated as a pyroelectric infrared detector in a container having an infrared transmission window. FIG. 2 is a diagram schematically showing an electrical configuration of the pyroelectric infrared detector. In FIG.
11 is a circuit for amplifying the detection signal of the infrared detection unit 6, 12
Is a circuit for adjusting the temperature of the heater 9.

【0014】図3は、上記焦電型赤外線薄膜素子を組み
込んだ焦電型赤外線検出器の感度を調べるための構成を
概略的に示すもので、この図において、13は焦電型赤
外線検出器で、温度測定対象である黒体炉14と対向配
置されている。15は焦電型赤外線検出器13と黒体炉
14との間に介装されるチョッパで、図外のモータによ
って回転駆動される。16は焦電型赤外線検出器13の
駆動用電源、17は測定器である。
FIG. 3 schematically shows a configuration for examining the sensitivity of a pyroelectric infrared detector incorporating the above-described pyroelectric infrared thin film element. In FIG. 3, reference numeral 13 denotes a pyroelectric infrared detector. , And is arranged to face the black body furnace 14 whose temperature is to be measured. A chopper 15 is interposed between the pyroelectric infrared detector 13 and the black body furnace 14, and is driven to rotate by a motor (not shown). Reference numeral 16 denotes a power supply for driving the pyroelectric infrared detector 13, and reference numeral 17 denotes a measuring device.

【0015】そして、上記図3において、温度調節回路
12によって、焦電型赤外線検出器13内に組み込まれ
た焦電型赤外線薄膜素子における赤外線検出部6に設け
られたヒータ9に通電する電流を制御して、赤外線検出
部6の焦電体薄膜3の温度を、常に、例えば60℃とな
るようにして、焦電型赤外線検出器13の周囲温度の温
度を変化させたときの出力を測定したところ、図4に示
すような結果が得られた。
In FIG. 3, the current flowing through the heater 9 provided in the infrared detector 6 of the pyroelectric infrared thin-film element incorporated in the pyroelectric infrared detector 13 is controlled by the temperature control circuit 12. By controlling the temperature of the pyroelectric thin film 3 of the infrared detecting section 6 to be always 60 ° C., for example, and measuring the output when the ambient temperature of the pyroelectric infrared detector 13 is changed. As a result, the result as shown in FIG. 4 was obtained.

【0016】この図4においては、周囲温度が20℃の
ときの感度を100%としているが、この発明の焦電型
赤外線薄膜素子においては、焦電体薄膜3、上部電極4
および下部電極5を含む赤外線検出部6にヒータ9を設
け、このヒータ9に通電を行うことにより、焦電体薄膜
3の温度調節が常に一定(例えば60℃)になるように
しているので、周囲温度が変化しても、これによる影響
をキャンセルすることができ、常に100%の出力が得
られ、安定した精度で測定を行える。
In FIG. 4, the sensitivity when the ambient temperature is 20 ° C. is set to 100%. In the pyroelectric infrared thin film element of the present invention, the pyroelectric thin film 3 and the upper electrode 4 are used.
The heater 9 is provided in the infrared detecting section 6 including the lower electrode 5 and the lower electrode 5, and the heater 9 is energized so that the temperature adjustment of the pyroelectric thin film 3 is always constant (for example, 60 ° C.). Even if the ambient temperature changes, the influence of the change can be canceled, an output of 100% is always obtained, and the measurement can be performed with stable accuracy.

【0017】以上説明したように、そして、この発明の
焦電型赤外線薄膜素子においては、焦電体薄膜3の熱容
量が小さく、したがって、これを含む赤外線検出部6を
ヒータ9によって加熱しても、温度が安定するまでに僅
か数秒といった極めて短い時間しか必要とせず、消費電
力も少なくて済むとともに、短時間で所望の測定を行え
る状態になる。また、温度調節のためのブロックなどを
必要としないため、構成が簡略化され、小型コンパクト
な装置が得られる。
As described above, in the pyroelectric infrared thin film element of the present invention, the heat capacity of the pyroelectric thin film 3 is small. Only a very short time, such as a few seconds, is required for the temperature to stabilize, the power consumption is reduced, and the desired measurement can be performed in a short time. In addition, since a block for temperature control is not required, the configuration is simplified, and a small and compact device can be obtained.

【0018】[0018]

【発明の効果】この発明の焦電型赤外線薄膜素子は、以
上のように構成されているので、周囲温度の影響が変化
してもその影響を受けず、安定した精度で測定を行うこ
とができ、電源オン後、短時間で所望の測定を行うこと
ができる。また、構成が簡略化され、コンパクトな焦電
型赤外線検出器を得ることができる。
As described above, the pyroelectric infrared thin film element of the present invention is constructed as described above, so that even if the influence of the ambient temperature changes, the measurement can be performed with stable accuracy. The desired measurement can be performed in a short time after the power is turned on. Further, the configuration is simplified, and a compact pyroelectric infrared detector can be obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の焦電型赤外線薄膜素子の一例を概略
的に示す縦断面図である。
FIG. 1 is a longitudinal sectional view schematically showing an example of a pyroelectric infrared thin film element of the present invention.

【図2】前記焦電型赤外線薄膜素子を組み込んだ焦電型
赤外線検出器の電気的構成を概略的に示す図である。
FIG. 2 is a view schematically showing an electrical configuration of a pyroelectric infrared detector incorporating the pyroelectric infrared thin film element.

【図3】前記焦電型赤外線検出器を出力を測定するため
の装置の概略構成図である。
FIG. 3 is a schematic configuration diagram of an apparatus for measuring an output of the pyroelectric infrared detector.

【図4】前記焦電型赤外線検出器の感度の温度依存性を
示す図である。
FIG. 4 is a diagram showing the temperature dependence of the sensitivity of the pyroelectric infrared detector.

【図5】従来の焦電型赤外線薄膜素子を概略的に示す縦
断面図である。
FIG. 5 is a longitudinal sectional view schematically showing a conventional pyroelectric infrared thin film element.

【図6】従来の焦電型赤外線薄膜素子を組み込んだ焦電
型赤外線検出器の感度の温度依存性を示す図である。
FIG. 6 is a diagram showing the temperature dependence of sensitivity of a conventional pyroelectric infrared detector incorporating a pyroelectric infrared thin film element.

【符号の説明】[Explanation of symbols]

3…焦電体薄膜、4…上部電極、5…下部電極、6…赤
外線検出部、9…ヒータ。
3 ... pyroelectric thin film, 4 ... upper electrode, 5 ... lower electrode, 6 ... infrared detector, 9 ... heater.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 焦電体薄膜の上面および下面にそれぞれ
上部電極および下部電極を設けて赤外線検出部を形成し
た焦電型赤外線薄膜素子において、前記赤外線検出部に
ヒータを設け、このヒータに通電を行うことにより、焦
電体薄膜の温度調節を行うようにしたことを特徴とする
焦電型赤外線薄膜素子。
1. A pyroelectric infrared thin-film element having an infrared detector formed by providing an upper electrode and a lower electrode respectively on an upper surface and a lower electrode of a pyroelectric thin film, wherein the infrared detector is provided with a heater, and the heater is energized. The pyroelectric infrared thin film element is characterized in that the temperature of the pyroelectric thin film is adjusted by performing the following.
JP26766299A 1999-09-21 1999-09-21 Pyroelectric infrared thin-film element Pending JP2001091354A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26766299A JP2001091354A (en) 1999-09-21 1999-09-21 Pyroelectric infrared thin-film element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26766299A JP2001091354A (en) 1999-09-21 1999-09-21 Pyroelectric infrared thin-film element

Publications (1)

Publication Number Publication Date
JP2001091354A true JP2001091354A (en) 2001-04-06

Family

ID=17447802

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26766299A Pending JP2001091354A (en) 1999-09-21 1999-09-21 Pyroelectric infrared thin-film element

Country Status (1)

Country Link
JP (1) JP2001091354A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2446414A (en) * 2007-02-06 2008-08-13 Thorn Security A Detector

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2446414A (en) * 2007-02-06 2008-08-13 Thorn Security A Detector

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