GB992136A - Process for the hydroformylation of olefinic compounds - Google Patents

Process for the hydroformylation of olefinic compounds

Info

Publication number
GB992136A
GB992136A GB2582762A GB2582762A GB992136A GB 992136 A GB992136 A GB 992136A GB 2582762 A GB2582762 A GB 2582762A GB 2582762 A GB2582762 A GB 2582762A GB 992136 A GB992136 A GB 992136A
Authority
GB
United Kingdom
Prior art keywords
pyridine
hydroformylated
olefins
catalyst
contacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2582762A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB992136A publication Critical patent/GB992136A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Olefins are hydroformylated by contacting with carbon monoxide and hydrogen, preferably at 500 to 5000 p.s.i. 100-300 DEG C., in the presence of a complex of chromium, molybdenum or tungsten and a substituted or unsubstituted pyridine, which includes polynuclear pyridines. Specified pyridines include 2-chloro pyridine, 3 picaline, ethyl nicotinate, quinoline 3-cyano pyridine, entidine and 3,5-dichloropyridine. Examples of products obtainable are 1-heptanal and 1-heptanol, 3-chloro 1-propanal and 3-chlorol propanol, 4-acetoxybutanol and 4-acetoxy butanyl, formyl cyclopentane and hydroxy methyl cyclopentane, diethyl formyl succinate and diethyl (hydroxy methyl) succinate, 4-phenyl butanal and 4-phenyl-1-butanol. In the detailed example wherein the catalyst is prepared in situ from pyridine and the hexacarbonyl of Mo, W, Cr, the effect of the metal on the isomer formed as product is given.ALSO:Macromolecular olefins, e.g. polybutadiene and styrene butadiene copolymer are stated to be hydroformylated by contacting with carbon monoxide and hydrogen and a catalyst which is a complex of Cr, W or Mo and a substituted or unsubstituted pyridine, which includes polynuclear pyridine derivatives especially at elevated pressures and temperatures.
GB2582762A 1961-07-07 1962-07-05 Process for the hydroformylation of olefinic compounds Expired GB992136A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12240761A 1961-07-07 1961-07-07

Publications (1)

Publication Number Publication Date
GB992136A true GB992136A (en) 1965-05-19

Family

ID=22402558

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2582762A Expired GB992136A (en) 1961-07-07 1962-07-05 Process for the hydroformylation of olefinic compounds

Country Status (4)

Country Link
DE (1) DE1214661B (en)
ES (1) ES278937A1 (en)
GB (1) GB992136A (en)
SE (1) SE301142B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5041685A (en) * 1988-03-22 1991-08-20 Neste Oy Procedure for producing alcohols and aldehydes from alkenes and synthesis gases

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE874301C (en) * 1951-05-03 1953-04-23 Basf Ag Process for the production of alcohols
DE921931C (en) * 1952-05-11 1955-01-07 Basf Ag Process for the production of alcohols and their esters
DE921932C (en) * 1952-09-05 1955-01-07 Basf Ag Process for the production of alcohols
US2811567A (en) * 1954-03-09 1957-10-29 Exxon Research Engineering Co Oxo preparation of high molecular weight alcohols

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5041685A (en) * 1988-03-22 1991-08-20 Neste Oy Procedure for producing alcohols and aldehydes from alkenes and synthesis gases

Also Published As

Publication number Publication date
SE301142B (en) 1968-05-27
DE1214661B (en) 1966-04-21
ES278937A1 (en) 1962-12-16

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