GB978488A - A process for the production of a layer of a semi-conducting ab compound by electrolytic deposition - Google Patents
A process for the production of a layer of a semi-conducting ab compound by electrolytic depositionInfo
- Publication number
- GB978488A GB978488A GB2663161A GB2663161A GB978488A GB 978488 A GB978488 A GB 978488A GB 2663161 A GB2663161 A GB 2663161A GB 2663161 A GB2663161 A GB 2663161A GB 978488 A GB978488 A GB 978488A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iii
- cathode
- electrolyte
- deposited
- deposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 230000008021 deposition Effects 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000151 deposition Methods 0.000 abstract 5
- 239000003792 electrolyte Substances 0.000 abstract 4
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- 229910017115 AlSb Inorganic materials 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910005542 GaSb Inorganic materials 0.000 abstract 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 abstract 1
- 239000001828 Gelatine Substances 0.000 abstract 1
- 229910000673 Indium arsenide Inorganic materials 0.000 abstract 1
- 229910021617 Indium monochloride Inorganic materials 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- 229940075397 calomel Drugs 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- WPYVAWXEWQSOGY-UHFFFAOYSA-N indium antimonide Chemical compound [Sb]#[In] WPYVAWXEWQSOGY-UHFFFAOYSA-N 0.000 abstract 1
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 abstract 1
- APHGZSBLRQFRCA-UHFFFAOYSA-M indium(1+);chloride Chemical compound [In]Cl APHGZSBLRQFRCA-UHFFFAOYSA-M 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 229910000859 α-Fe Inorganic materials 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/288—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/007—Preparing arsenides or antimonides, especially of the III-VI-compound type, e.g. aluminium or gallium arsenide
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/02549—Antimonides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/02623—Liquid deposition
- H01L21/02628—Liquid deposition using solutions
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
978,488. Electrolytically depositing semiconducting A<SP>III</SP> B<SP>V</SP> compounds. SIEMENSSCHUCKERTWERKE A.G. July 21, 1961 [July 21, 1960], No. 26631/61. Heading C7B. In a process for the production of a layer of a semi-conducting A<SP>III</SP>B<SP>V</SP> compound by electrolytic decomposition, where A<SP>III</SP> is an element in Group III of the Perodic Table and B<SP>V</SP> is an element in Group V, the compound is deposited from a solution containing the ions of the elements A<SP>III</SP> and B<SP>V</SP> together with a complex forming agent, the pH being such that the complex of the nobler element is more stable than that of the less noble element, the potentials at which the elements are deposited from the complexes are similar and the hydrogen separation at the cathode is small at the impressed potentials. An electrolyte for depositing InSb comprises InCl 3 , SbCl 3 , NH 4 Cl, tartaric acid as a complexing agent, and gelatine for improving the surface quality of the deposited layer. The pH is adjusted to about 2À5 with concentrated NH 3 solution and the electrolysis may be carried out at 3À5 volts. Other specified compounds which may be prepared similarly are InBi, InAs, GaSb, GaAs, AlSb and AlAs. A series of layers consisting of different A<SP>III</SP>B<SP>V</SP> compounds may be deposited. A doping can be carried out during the deposition. In apparatus for carrying out the process cathode 4 and anode 16 spaces are connected by an electrolyte bridge 12 having diaphragms 13 and 14. The cathode 4, which is held in a stopper 8, comprises a ferrite wafer and electrical contact is made with it through a graphite cushion 5 and a spring pressed copper contact 6. In measuring the cathode potential, a calomel electrode 10 is used. The cathode space contains the deposition electrolyte whereas the bridge and anode space contain an electrolyte such as KNO 3 solution. Alternatively, the whole apparatus may contain the deposition electrolye. The cell can be freed from dissolved H 2 by the introduction of N 2 before electrolysis is started. An admission pipe 17 and exhaust duct 18 are for this purpose. A magnetic stirrer is provided at 19.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DES69522A DE1121427B (en) | 1960-07-21 | 1960-07-21 | Process for the galvanic deposition of especially thin layers of semiconducting A B compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB978488A true GB978488A (en) | 1964-12-23 |
Family
ID=7501042
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2663161A Expired GB978488A (en) | 1960-07-21 | 1961-07-21 | A process for the production of a layer of a semi-conducting ab compound by electrolytic deposition |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE606242A (en) |
CH (1) | CH396216A (en) |
DE (1) | DE1121427B (en) |
GB (1) | GB978488A (en) |
NL (1) | NL267219A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2001102A (en) * | 1977-07-01 | 1979-01-24 | Oronzio De Nora Impianti | Monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL297836A (en) * | 1962-09-14 | |||
DE2810605C2 (en) * | 1978-03-11 | 1980-03-13 | Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Electrolytic deposition process for the production of large-area semiconductor components |
-
0
- NL NL267219D patent/NL267219A/xx unknown
-
1960
- 1960-07-21 DE DES69522A patent/DE1121427B/en active Pending
-
1961
- 1961-07-18 BE BE606242A patent/BE606242A/en unknown
- 1961-07-18 CH CH842161A patent/CH396216A/en unknown
- 1961-07-21 GB GB2663161A patent/GB978488A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2001102A (en) * | 1977-07-01 | 1979-01-24 | Oronzio De Nora Impianti | Monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
GB2001102B (en) * | 1977-07-01 | 1982-01-20 | Oronzio De Nora Impianti | Improvements relating to monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
Also Published As
Publication number | Publication date |
---|---|
BE606242A (en) | 1962-01-18 |
NL267219A (en) | |
CH396216A (en) | 1965-07-31 |
DE1121427B (en) | 1962-01-04 |
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