GB973835A - Improvements in or relating to the production of phenoplast foam materials - Google Patents
Improvements in or relating to the production of phenoplast foam materialsInfo
- Publication number
- GB973835A GB973835A GB14704/62A GB1470462A GB973835A GB 973835 A GB973835 A GB 973835A GB 14704/62 A GB14704/62 A GB 14704/62A GB 1470462 A GB1470462 A GB 1470462A GB 973835 A GB973835 A GB 973835A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenoplast
- boron
- mixture
- mono
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0047—Use of organic additives containing boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A method of producing a difficulty inflammable phenoplast foam material suitable as a heat-insulating material comprises incorporating in a liquid or solid phenoplast a foaming agent and a hardening agent and, in addition, one or more boron compounds in a total quantity of from 5 to 40% by weight, calculated as boric acid based on the phenoplast, the boron compound(s) being incorporated in the phenoplast before foaming or curing has commenced. Suitable boron compounds are boric acid, boron trioxide, an ester or salt of boric acid, sodium tetraborate, or organic compounds for example mono- and diphenyl borates. The phenoplast can be derived from mono- and polyvalent phenols, phenolic tar fractions and low-temperature carbonization oils. In example (1) a cresol/formaldehyde condensate (viscosity 2500 cP.) is mixed with a pentane fraction and there are added powdered orthoboric acid, concentrated hydrochloric acid and alcohol. The mixture is heated in a mould at 60 DEG C. to give a foamed product. In other examples the reactants used are (2) finely powdered and mixed novolak and hexa, to which ammonium carbonate dissolved in mixed mono- and diphenyl borates is added. The mixture is plasticized at 105 DEG -115 DEG C. on heated rollers, cooled, and broken to give a granulate, which is foamed at 160 DEG C.; (3) phenol resol, petroleum ether, sodium tetra borate and a mixture of glycerol and hydrochloric acid as hardener are used; (4) resorcinol/ formaldehyde condensate (4000 cP), pentane, paraformaldehyde and boron trioxide are used as reactants.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED35870A DE1230557B (en) | 1961-04-18 | 1961-04-18 | Flame retardant phenolic resin foams |
Publications (1)
Publication Number | Publication Date |
---|---|
GB973835A true GB973835A (en) | 1964-10-28 |
Family
ID=7042837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14704/62A Expired GB973835A (en) | 1961-04-18 | 1962-04-16 | Improvements in or relating to the production of phenoplast foam materials |
Country Status (8)
Country | Link |
---|---|
AT (1) | AT244599B (en) |
BE (1) | BE616587A (en) |
CH (1) | CH410396A (en) |
DE (1) | DE1230557B (en) |
FR (1) | FR1319889A (en) |
GB (1) | GB973835A (en) |
NL (1) | NL130445C (en) |
OA (1) | OA01653A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2343181A (en) * | 1998-10-30 | 2000-05-03 | Kingspan Ind Insulation Limite | A phenolic foam |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2220366B1 (en) * | 1973-03-05 | 1976-05-21 | Saint Gobain | |
US4071481A (en) * | 1974-02-25 | 1978-01-31 | Saint-Gobain Industries | Manufacture of phenolic foam |
DE102020005288A1 (en) | 2020-08-28 | 2022-03-03 | Hexion GmbH | foam resin composition |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE537367C (en) * | 1928-12-14 | 1931-11-02 | Erich Asser Dr | Process for increasing the melting point of novolaks and the oil-soluble compounds prepared from them with natural resin acids |
BE506553A (en) * | 1950-10-21 | |||
GB818574A (en) * | 1957-04-12 | 1959-08-19 | British Plimber Ltd | Method of producing chip-boards or -panels, and chip-boards or -panels produced by the method |
-
1961
- 1961-04-17 FR FR894782A patent/FR1319889A/en not_active Expired
- 1961-04-18 DE DED35870A patent/DE1230557B/en active Pending
-
1962
- 1962-03-30 CH CH387462A patent/CH410396A/en unknown
- 1962-04-02 AT AT266662A patent/AT244599B/en active
- 1962-04-16 GB GB14704/62A patent/GB973835A/en not_active Expired
- 1962-04-16 NL NL277281A patent/NL130445C/en active
- 1962-04-18 BE BE616587A patent/BE616587A/en unknown
-
1964
- 1964-12-31 OA OA51885A patent/OA01653A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2343181A (en) * | 1998-10-30 | 2000-05-03 | Kingspan Ind Insulation Limite | A phenolic foam |
Also Published As
Publication number | Publication date |
---|---|
BE616587A (en) | 1962-08-16 |
NL277281A (en) | 1964-10-26 |
DE1230557B (en) | 1966-12-15 |
NL130445C (en) | 1971-01-15 |
AT244599B (en) | 1966-01-10 |
FR1319889A (en) | 1963-03-01 |
CH410396A (en) | 1966-03-31 |
OA01653A (en) | 1969-09-20 |
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