GB935802A - Production of alcohols - Google Patents

Production of alcohols

Info

Publication number
GB935802A
GB935802A GB11844/62A GB1184462A GB935802A GB 935802 A GB935802 A GB 935802A GB 11844/62 A GB11844/62 A GB 11844/62A GB 1184462 A GB1184462 A GB 1184462A GB 935802 A GB935802 A GB 935802A
Authority
GB
United Kingdom
Prior art keywords
aluminium
alkyl
olefins
trialkyl
oxidising
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11844/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Oil Co filed Critical Continental Oil Co
Publication of GB935802A publication Critical patent/GB935802A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • C07C31/125Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms

Abstract

Alcohols are produced by oxidising a feedmixture of alpha-olefins and trialkyl aluminium with an oxygen-containing gas to produce partially oxidised aluminium alkyl in which up to 70% of the alkyl substituents are converted to alkoxy groups, separating, by stripping, the a -olefin from the partially oxidised aluminium alkyl, and oxidising with an oxygen-containing gas the separated partially-oxidised aluminium alkyl to produce trialkoxy-aluminium which is then hydrolysed to the corresponding alcohol. The process is suitable for treating the mixture of a -olefins and trialkyl aluminium obtained by treating aluminium triethyl with ethylene. The solvent used for this reaction may be retained in the mixture of alpha-olefins and trialkyl aluminium used as starting material and is stripped off with the a -olefine after the first oxidation step. In general the alkyl groups of the trialkyl aluminium each contain 4-30 carbon atoms.
GB11844/62A 1961-03-30 1962-03-28 Production of alcohols Expired GB935802A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9948561A 1961-03-30 1961-03-30

Publications (1)

Publication Number Publication Date
GB935802A true GB935802A (en) 1963-09-04

Family

ID=22275233

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11844/62A Expired GB935802A (en) 1961-03-30 1962-03-28 Production of alcohols

Country Status (2)

Country Link
CH (1) CH411874A (en)
GB (1) GB935802A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3475501A (en) * 1967-11-21 1969-10-28 Ethyl Corp Alcohol production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3475501A (en) * 1967-11-21 1969-10-28 Ethyl Corp Alcohol production

Also Published As

Publication number Publication date
CH411874A (en) 1966-04-30

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