GB935802A - Production of alcohols - Google Patents
Production of alcoholsInfo
- Publication number
- GB935802A GB935802A GB11844/62A GB1184462A GB935802A GB 935802 A GB935802 A GB 935802A GB 11844/62 A GB11844/62 A GB 11844/62A GB 1184462 A GB1184462 A GB 1184462A GB 935802 A GB935802 A GB 935802A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- alkyl
- olefins
- trialkyl
- oxidising
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
Abstract
Alcohols are produced by oxidising a feedmixture of alpha-olefins and trialkyl aluminium with an oxygen-containing gas to produce partially oxidised aluminium alkyl in which up to 70% of the alkyl substituents are converted to alkoxy groups, separating, by stripping, the a -olefin from the partially oxidised aluminium alkyl, and oxidising with an oxygen-containing gas the separated partially-oxidised aluminium alkyl to produce trialkoxy-aluminium which is then hydrolysed to the corresponding alcohol. The process is suitable for treating the mixture of a -olefins and trialkyl aluminium obtained by treating aluminium triethyl with ethylene. The solvent used for this reaction may be retained in the mixture of alpha-olefins and trialkyl aluminium used as starting material and is stripped off with the a -olefine after the first oxidation step. In general the alkyl groups of the trialkyl aluminium each contain 4-30 carbon atoms.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9948561A | 1961-03-30 | 1961-03-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB935802A true GB935802A (en) | 1963-09-04 |
Family
ID=22275233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11844/62A Expired GB935802A (en) | 1961-03-30 | 1962-03-28 | Production of alcohols |
Country Status (2)
Country | Link |
---|---|
CH (1) | CH411874A (en) |
GB (1) | GB935802A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475501A (en) * | 1967-11-21 | 1969-10-28 | Ethyl Corp | Alcohol production |
-
1962
- 1962-03-21 CH CH335562A patent/CH411874A/en unknown
- 1962-03-28 GB GB11844/62A patent/GB935802A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475501A (en) * | 1967-11-21 | 1969-10-28 | Ethyl Corp | Alcohol production |
Also Published As
Publication number | Publication date |
---|---|
CH411874A (en) | 1966-04-30 |
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