GB888503A - Improvements in and relating to interpolymers - Google Patents

Improvements in and relating to interpolymers

Info

Publication number
GB888503A
GB888503A GB3127560A GB3127560A GB888503A GB 888503 A GB888503 A GB 888503A GB 3127560 A GB3127560 A GB 3127560A GB 3127560 A GB3127560 A GB 3127560A GB 888503 A GB888503 A GB 888503A
Authority
GB
United Kingdom
Prior art keywords
methylol
vinyl
weight per
per cent
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3127560A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Publication of GB888503A publication Critical patent/GB888503A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)

Abstract

Interpolymers of 50 to 99,8 weight per cent of a conjugated diene, 0 to 49,8 weight per cent of a monoalkenyl monomer copolymerizable with said diene, 0,1 to 10 weight per cent of an N-alkylol amide of an alpha, beta-olefinically unsaturated carboxylic acid, and 0,1 to 10 weight per cent of an alpha, beta-olefinically unsaturated carboxylic acid or anhydride thereof may be prepared by polymerizing a mixture of the monomers in aqueous dispersion at -30 DEG to 100 DEG C. to from 90 to 100% conversion. Specified dienes are butadiene, isoprene, piperylene, 1,3-dimethyl butadiene, 2-ethyl butadiene, hexadiene-1,3, 4-methyl-1,3-pentadiene, chloroprene, bromoprene and fluoroprene. Specified monoalkenyl compounds are styrene, vinyl toluenes and their alpha-methyl derivatives; vinyl xylenes; acrylic, methacrylic and ethacrylic acid esters and nitriles; vinylidene cyanide; vinyl and vinylidene halides; and vinyl and isopropenyl esters. Specified amides are N-methylol acrylamide, N-ethanol acrylamide, N-propanol acrylamide, N-methylol methacrylamide, N-ethanol methacrylamide, N-methylol maleimide, N-methylol maleamide, N-methylol maleamic acid, N-methylol maleamic acid esters and the N-methylol amides of vinyl aromatic acids such as N-methylol p-vinyl benzamide. Specified acids are acrylic, methacrylic, ethacrylic, alphachloracrylic, maleic, fumaric, citraconic and sorbic acids and anhydrides. Polymerization may be effected in the presence of emulsifiers, e.g. alkali metal hydrocarbon sulphates and sulphonates, alkali metal sulphonates of dicarboxylic acid esters and amides, quaternary ammonium salts, polyether alcohols, fatty alkylolamine condensates and diglycol esters of fatty acids; catalysts, e.g. hydrogen peroxide, acyl peroxides, hydrocarbon hydroperoxides, peresters and alkali metal persulphates, optionally together with conventional redox activators, e.g. polyhydroxy phenols, sodium sulphite or bisulphite, dimethylaminopropionitrile, reducing sugars and heavy metal ions; modifiers, e.g. mercaptans; buffers; electrolyte salts and carbon black. The polymerization may be terminated by the addition of hydroquinone or phenyl-beta-naphthylamine. The latex obtained may be coagulated, or thickened, e.g. with casein, carboxymethylcellulose, methylcellulose or polyacrylic acid. The latices may be employed in finishing leather; binding, impregnating and coating textiles and paper; and in adhesive compositions, printing pastes and paints. The polymers are useful in the preparation of gloves, gaskets, foams, tyres, hose, shock absorbers, footwear and flooring.
GB3127560A 1959-09-14 1960-09-12 Improvements in and relating to interpolymers Expired GB888503A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US83955459A 1959-09-14 1959-09-14

Publications (1)

Publication Number Publication Date
GB888503A true GB888503A (en) 1962-01-31

Family

ID=25280044

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3127560A Expired GB888503A (en) 1959-09-14 1960-09-12 Improvements in and relating to interpolymers

Country Status (5)

Country Link
BE (1) BE594773A (en)
DE (1) DE1128144B (en)
GB (1) GB888503A (en)
LU (1) LU39171A1 (en)
NL (2) NL127450C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3392048A (en) * 1965-01-08 1968-07-09 Gen Tire & Rubber Co Pigment-coated paper products having a binder of protein and a conjugated diene polymer that can form a reversible colloidal solution
US4272426A (en) 1979-03-07 1981-06-09 The International Synthetic Rubber Company Ltd. Preparation of latices
US4831078A (en) * 1984-08-31 1989-05-16 Nippon Zeon Co., Ltd. Process for producing copolymer latex

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1349586A (en) * 1970-12-11 1974-04-03 Polysar Ltd Latex composition and process for producing the same
US3882070A (en) * 1973-05-23 1975-05-06 Arco Polymers Inc Persulfate stabilized latices
DE2418419C3 (en) * 1974-04-17 1987-07-09 Bayer Ag, 5090 Leverkusen Process for the preparation of latexes containing carboxyl groups
DE2429817C2 (en) * 1974-06-21 1982-09-23 Bayer Ag, 5090 Leverkusen Production of heat-sensitized rubber latices

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816050A (en) * 1953-12-18 1957-12-10 Ibm Method of forming monocrystals

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3392048A (en) * 1965-01-08 1968-07-09 Gen Tire & Rubber Co Pigment-coated paper products having a binder of protein and a conjugated diene polymer that can form a reversible colloidal solution
US4272426A (en) 1979-03-07 1981-06-09 The International Synthetic Rubber Company Ltd. Preparation of latices
US4831078A (en) * 1984-08-31 1989-05-16 Nippon Zeon Co., Ltd. Process for producing copolymer latex

Also Published As

Publication number Publication date
DE1128144B (en) 1962-04-19
NL127450C (en)
BE594773A (en)
LU39171A1 (en) 1960-11-14
NL255496A (en)

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