GB865380A - Sizes for glass fibres - Google Patents
Sizes for glass fibresInfo
- Publication number
- GB865380A GB865380A GB14618/57A GB1461857A GB865380A GB 865380 A GB865380 A GB 865380A GB 14618/57 A GB14618/57 A GB 14618/57A GB 1461857 A GB1461857 A GB 1461857A GB 865380 A GB865380 A GB 865380A
- Authority
- GB
- United Kingdom
- Prior art keywords
- organic
- unsaturated
- water
- soluble
- reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
Abstract
An aqueous emulsion for sizing glass fibres to be used for reinforcing plastics comprises (1) an adhesive agent which is either a chromium compound containing unsaturated organic groups, e.g. methacrylato chromic chloride, or an organic silicon compound containing hydrolyzable groups and organic groups capable of reacting with the plastic to be reinforced, or a hydrolysis product of such an organic silicon compound, for increasing the adhesion between the glass fibres and the plastic to be reinforced, and (2) a binding and lubricating composition containing (a) at least one unsaturated organic compound capable of reacting with the plastic to be reinforced and (b) at least one water-soluble organic hydroxy compound capable of forming a continuous film while drying in air. The organic silicon compound may be vinyl-triethoxy silane or vinyl-trichloro-silane and the unsaturated organic compound may be an unsaturated polyester resin, e.g. an unsaturated alkyd made from maleic acid, phthalic acid and ethylene glycol and/or an unsaturated monomeric ester, e.g. diallyl phthalate. Suitable water-soluble film-forming organic hydroxy compounds are watersoluble cellulose derivatives, e.g. ethyl hydroxyethyl cellulose and carboxymethyl cellulose, dextrin and polyvinyl alcohol. When the composition contains water-soluble organic hydroxy compounds and water-insoluble unsaturated organic compounds, the ratio by weight of the former to the latter is preferably between 0,2 and 0,5. The composition preferably contains also (1) an aldehyde, e.g. glyoxal, in a proportion not more than 20% of the weight of the water-soluble organic hydroxy compounds, (2) a peroxide catalyst, e.g. benzoyl peroxide, (3) a weak organic acid, e.g. formic or acetic acid, to adjust the pH value below 7, and (4) an emulsifier, e.g. a polyoxyethylene derivative, an ester of sorbitol or similar sugar alcohol or ammonium oleate. Specification 760,798 is referred to.ALSO:Glass fibres to be used for reinforcing plastics are sized with an aqueous emulsion, intended to serve simultaneously as a lubricant and as a binder for the fibres, comprising (1) an adhesive agent which is either a chromium compound containing unsaturated organic groups, e.g. methacrylato chromic chloride, or an organic silicon compound containing hydrolyzable groups and organic groups capable of reacting with the plastic to be reinforced, or a hydrolysis product of such an organic silicon compound, for increasing the adhesion between the glass fibres and the plastic to be reinforced, and (2) a binding and lubricating composition containing (a) at least one unsaturated organic compound capable of reacting with the plastic to be reinforced and (b) at least one water-soluble organic hydroxy compound capable of forming a continuous film while drying in air. The organic silicon compound may be vinyl-triethoxy silane or vinyl trichloro-silane and the unsaturated organic compound may be an unsaturated polyester resin, e.g. an unsaturated alkyd made from maleic acid, phthalic acid and ethylene glycol and/or an unsaturated monomeric ester, e.g. diallyl phthalate. Suitable water-soluble film-forming organic hydroxy compounds are water-soluble cellulose derivatives, e.g. ethyl hydroxyethyl cellulose and carboxymethyl cellulose, dextrin and poly-vinyl alcohol. When the composition contains water-soluble organic hydroxy compounds and water-insoluble unsaturated organic compounds, the ratio by weight of the former to the latter is preferably between 0,2 and 0,5. The composition preferably contains also (1) an aldehyde, e.g. glyoxal, in a proportion not more than 20% of the weight of the water-soluble organic hydroxy compounds, (2) a peroxide catalyst, e.g. benzoyl peroxide, (3) a weak organic acid, e.g. formic or acetic acid, to adjust the pH value below 7, and (4) an emulsifier, e.g. a polyoxyethylene derivative, an ester of sorbitol or similar sugar alcohol or ammonium oleate. After sizing, the glass fibres are preferably heat-treated either after twisting or after weaving and are then made up into laminates with, for example, styrene-modified polyester resins. Specification 760,798 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE637056 | 1956-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB865380A true GB865380A (en) | 1961-04-19 |
Family
ID=20268502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14618/57A Expired GB865380A (en) | 1956-07-05 | 1957-05-08 | Sizes for glass fibres |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH400561A (en) |
ES (1) | ES236368A1 (en) |
GB (1) | GB865380A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011002730A1 (en) * | 2009-06-29 | 2011-01-06 | Owens Corning Intellectual Capital, Llc | Modified starch based binders |
US8864893B2 (en) | 2009-10-09 | 2014-10-21 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
US9718729B2 (en) | 2009-05-15 | 2017-08-01 | Owens Corning Intellectual Capital, Llc | Biocides for bio-based binders, fibrous insulation products and wash water systems |
US9957409B2 (en) | 2011-07-21 | 2018-05-01 | Owens Corning Intellectual Capital, Llc | Binder compositions with polyvalent phosphorus crosslinking agents |
US10000666B2 (en) | 2009-10-09 | 2018-06-19 | Owens Corning Intellectual Capital, Llc | Insulative products having bio-based binders |
US10047210B2 (en) | 2011-04-07 | 2018-08-14 | Owens Corning Intellectual Capital, Llc | Bio-based binders including carbohydrates and a pre-reacted product of an alcohol or polyol and a monomeric or polymeric polycarboxylic acid |
-
1957
- 1957-04-12 CH CH4495357A patent/CH400561A/en unknown
- 1957-05-08 GB GB14618/57A patent/GB865380A/en not_active Expired
- 1957-07-04 ES ES0236368A patent/ES236368A1/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9718729B2 (en) | 2009-05-15 | 2017-08-01 | Owens Corning Intellectual Capital, Llc | Biocides for bio-based binders, fibrous insulation products and wash water systems |
WO2011002730A1 (en) * | 2009-06-29 | 2011-01-06 | Owens Corning Intellectual Capital, Llc | Modified starch based binders |
US8864893B2 (en) | 2009-10-09 | 2014-10-21 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
US9290640B2 (en) | 2009-10-09 | 2016-03-22 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
US9546263B2 (en) | 2009-10-09 | 2017-01-17 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
US10000666B2 (en) | 2009-10-09 | 2018-06-19 | Owens Corning Intellectual Capital, Llc | Insulative products having bio-based binders |
US11286204B2 (en) | 2009-10-09 | 2022-03-29 | Owens Coming Intellectual Capital, LLC | Bio-based binders for insulation and non-woven mats |
US10047210B2 (en) | 2011-04-07 | 2018-08-14 | Owens Corning Intellectual Capital, Llc | Bio-based binders including carbohydrates and a pre-reacted product of an alcohol or polyol and a monomeric or polymeric polycarboxylic acid |
US11066535B2 (en) | 2011-04-07 | 2021-07-20 | Owens Corning Intellectual Capital, Llc | Bio-based binders including carbohydrates and a pre-reacted product of an alcohol or polyol and a monomeric or polymeric polycarboxylic acid |
US9957409B2 (en) | 2011-07-21 | 2018-05-01 | Owens Corning Intellectual Capital, Llc | Binder compositions with polyvalent phosphorus crosslinking agents |
Also Published As
Publication number | Publication date |
---|---|
ES236368A1 (en) | 1958-03-16 |
CH400561A (en) | 1965-10-15 |
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