GB847528A - Improvements relating to the treatment of clay - Google Patents
Improvements relating to the treatment of clayInfo
- Publication number
- GB847528A GB847528A GB19581/57A GB1958157A GB847528A GB 847528 A GB847528 A GB 847528A GB 19581/57 A GB19581/57 A GB 19581/57A GB 1958157 A GB1958157 A GB 1958157A GB 847528 A GB847528 A GB 847528A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cations
- clay
- cation
- final
- exchange resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/06—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic exchangers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/40—Clays
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/40—Clays
- C01B33/405—Clays not containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
- H01B3/10—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances metallic oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The replacement of exchangeable cations in a clay of the expanding lattice type, for example a bentonite or hectorite, is effected by first replacing the exchangeable cations by treatment with a cation exchange resin charged with intermediate cations, which are then eliminated as a gas by contacting the treated clay with a solution containing the final cations. The final cations are usually those of an organic base, and are preferably derived from an amine of high molecular weight and boiling point, for example diethylene triamine, triethanolamine, pentamethylene hexamine, para-diisobutyl phenoxy ethoxy ethyl dimethyl benzyl ammonium chloride, or dimethyl octadecylamine; they are advantageously polymerizable, such as the reaction product of a polyamine and a polycarboxylic acid, for example diethylene triamine and phthalic anhydride; or they may be metallic cations, for example lead, larger than the original cations, such as may be derived from lead acrylate, in which case the product will contain some polymerizable material. The final cations are preferably larger than the initial cations, which are normally sodium or calcium. The intermediate cations are preferably ammonium ions, but may also be substituted ammonium ions derived from compounds of low molecular weight, for example methylamine and dimethylamine. This treatment reduces the swelling properties of the clay in water, and is suitable for use as a dielectric film, having improved dielectric properties. The cation exchange resin may be a sulphonated phenol-formaldehyde resin or a sulphonated cross-linked polystyrene resin. The intermediate cation may either be eliminated as a gas by ensuring that it is a weaker base than the final cation, or by carrying out the final replacement at above the temperature at which the cation is evolved as a gas from the clay. Low molecular weight silicates, sulphates, and chlorides may be removed from the p initial clay suspension by treating with a strongly basic anion-exchange resin, either before or after the introduction of the intermediate cations, or by employing a mixed bed of the resins, simultaneously. In one example, an aqueous hectorite suspension was treated with a cation exchange resin in the ammonium form, and was then spread out as a film on glass plates and dried. This film was then treated with a solution of diethylene triamine and phthalic anhydride in water, dried, and the organic cation polymerized by heating.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US360979XA | 1956-06-27 | 1956-06-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB847528A true GB847528A (en) | 1960-09-07 |
Family
ID=21886606
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19581/57A Expired GB847528A (en) | 1956-06-27 | 1957-06-21 | Improvements relating to the treatment of clay |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH360979A (en) |
DE (1) | DE1048887B (en) |
GB (1) | GB847528A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0312988A2 (en) * | 1987-10-19 | 1989-04-26 | Rheox International, Inc. | Improved organophilic clay gellant and processes for preparing organophilic clay gellants |
EP3498673A1 (en) * | 2017-12-18 | 2019-06-19 | Imertech Sas | Mineral treatment process |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2407425A1 (en) * | 2010-07-12 | 2012-01-18 | Bayer Technology Services GmbH | Method for producing extremely pure, organically modified layer silicates |
-
1957
- 1957-06-21 GB GB19581/57A patent/GB847528A/en not_active Expired
- 1957-06-26 DE DEA27412A patent/DE1048887B/en active Pending
- 1957-06-27 CH CH360979D patent/CH360979A/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0312988A2 (en) * | 1987-10-19 | 1989-04-26 | Rheox International, Inc. | Improved organophilic clay gellant and processes for preparing organophilic clay gellants |
EP0312988A3 (en) * | 1987-10-19 | 1991-08-28 | Rheox International, Inc. | Improved organophilic clay gellant and processes for preparing organophilic clay gellants |
EP3498673A1 (en) * | 2017-12-18 | 2019-06-19 | Imertech Sas | Mineral treatment process |
Also Published As
Publication number | Publication date |
---|---|
DE1048887B (en) | 1959-01-22 |
CH360979A (en) | 1962-03-31 |
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