GB755514A - Improvements in or relating to the preparation of silica suitable for use as a refractory and refractory bricks, shapes, and blocks made therefrom - Google Patents
Improvements in or relating to the preparation of silica suitable for use as a refractory and refractory bricks, shapes, and blocks made therefromInfo
- Publication number
- GB755514A GB755514A GB1771853A GB1771853A GB755514A GB 755514 A GB755514 A GB 755514A GB 1771853 A GB1771853 A GB 1771853A GB 1771853 A GB1771853 A GB 1771853A GB 755514 A GB755514 A GB 755514A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per hour
- flint
- temperature
- per cent
- maintained
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
Abstract
Silica for use in refractories is prepared by calcining flint containing on analysis after ignition at least 98.5 per cent silica, preferably more than 99 per cent, at a rate of temperature rise of 40 DEG -80 DEG C. per hour maintained within limits of \sB5 DEG C., until a temperature of 700-950 DEG C., preferably 800 DEG C., is reached, which temperature is maintained within limits of \sB25 DEG C. until at least three-quarters of the combined water has been removed. As a modification when grey flint is calcined, the maintained temperature may be 500-700 DEG C., preferably 600 DEG C. The rate of temperature rise for grey flint is 60-80 DEG C. and for black flint 40-60 DEG C. The calcining may be effected as a continuous moving bed in a bogie type kiln. The calcined material is crushed, ground and screened. Coarse grain (3.5-0.5 mm.), medium grain (0.5 mm. and less), and fine flour (at least 70 per cent 0.1 mm. size) of the calcined flint is kneaded with lime (hydrated, putty, or milk) and sulphite lye temporary binder, and moulded into bricks. The bricks are fired on the following schedule:-Up to 500 DEG C., 10-15 DEG C. per hour; 500-650 DEG C., 5-7 DEG C. per hour; 650-1000 DEG C; 10-15 DEG C. per hour; 1000-1100 DEG C.; 5-7 1/2 DEG C. per hour; 1100-1310 to 1330 DEG C., 3-5 DEG C. per hour; and soak for some time at the maximum temperature to effect complete conversion to cristobalite. A metal oxide, e.g. 0.6 per cent Fe2O3, may be added to the kneaded material to increase the strength, or preferably an oxide may be precipitated by the lime by adding a metal salt solution, e.g. ferrous sulphate, as described in Specification 755,515.ALSO:Silica for use in refractories is prepared by calcining flint containing on analysis after ignition at least 98.5 per cent silica, preferably more than 99 per cent, at a rate of temperature rise of 40 DEG -80 DEG C. per hour maintained with limits of \sB5 DEG C., until a temperature of 700 DEG -950 DEG C., preferably 800 DEG C., is reached, which temperature is maintained with limits of \sB25 DEG C. until at least three-quarters of the combined water has been removed. As a modification, when grey flint is calcined the maintained temperature may be 500 DEG -700 DEG C., preferably 600 DEG C. The rate of temperature rise for grey flint is 60 DEG -80 DEG C. and for black flint 40 DEG -60 DEG C. The calcining may be effected as a continuous moving bed in a bogie-type kiln. The calcined material is crushed, ground and screened. Coarse grain (3.5-0.5 mm.) medium grain (0.5 mm. and less), and fine flour (at least 70 per cent 0.1 mm. size) of the calcined flint is kneaded with lime (hydrated, putty, or milk) and sulphite lye temporary binder, and moulded into bricks. The bricks are fired on the following schedule: Up to 500 DEG C., 10 DEG -15 DEG C. per hour; 500 DEG -650 DEG C., 5 DEG -7 DEG C. per hour; 650 DEG -1000 DEG C., 10 DEG -15 DEG C. per hour; 1000 DEG -1100 DEG C., 5 DEG -7 1/2 DEG C. per hour; 1100 DEG -1310 DEG C. to 1330 DEG C., 3 DEG -5 DEG C. per hour; and soak for some time at the maximum temperature to effect complete conversion to cristobalite. A metal oxide, e.g. 0.6 per cent Fe2O3, may be added to the kneaded material to increase the strength, or preferably an oxide may be precipitated by the lime by adding a metal salt solution, e.g. ferrous sulphate, as described in p Specification 755,515.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1771853A GB755514A (en) | 1953-06-26 | 1953-06-26 | Improvements in or relating to the preparation of silica suitable for use as a refractory and refractory bricks, shapes, and blocks made therefrom |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1771853A GB755514A (en) | 1953-06-26 | 1953-06-26 | Improvements in or relating to the preparation of silica suitable for use as a refractory and refractory bricks, shapes, and blocks made therefrom |
Publications (1)
Publication Number | Publication Date |
---|---|
GB755514A true GB755514A (en) | 1956-08-22 |
Family
ID=10100012
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1771853A Expired GB755514A (en) | 1953-06-26 | 1953-06-26 | Improvements in or relating to the preparation of silica suitable for use as a refractory and refractory bricks, shapes, and blocks made therefrom |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB755514A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2883853A1 (en) * | 2013-12-10 | 2015-06-17 | Refratechnik Holding GmbH | Coarse ceramic fire resistant product and method for its manufacture and its use |
-
1953
- 1953-06-26 GB GB1771853A patent/GB755514A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2883853A1 (en) * | 2013-12-10 | 2015-06-17 | Refratechnik Holding GmbH | Coarse ceramic fire resistant product and method for its manufacture and its use |
WO2015086204A1 (en) * | 2013-12-10 | 2015-06-18 | Refratechnik Holding Gmbh | Refractory coarse ceramic product and method for producing the same and its use |
EP3159320A1 (en) * | 2013-12-10 | 2017-04-26 | Refratechnik Holding GmbH | Coarse ceramic fire resistant product and method for its manufacture and its use |
US9809498B2 (en) | 2013-12-10 | 2017-11-07 | Refratechnik Holding Gmbh | Refractory coarse ceramic product and method for producing the same and its use |
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