GB731934A - Method for the production of modified esters of polyglycerol or glycerol, with polymerized and/or oxidized fatty acids - Google Patents
Method for the production of modified esters of polyglycerol or glycerol, with polymerized and/or oxidized fatty acidsInfo
- Publication number
- GB731934A GB731934A GB10898/52A GB1089852A GB731934A GB 731934 A GB731934 A GB 731934A GB 10898/52 A GB10898/52 A GB 10898/52A GB 1089852 A GB1089852 A GB 1089852A GB 731934 A GB731934 A GB 731934A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fatty acids
- polymerized
- glycerol
- esters
- polyglycerol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/02—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Edible Oils And Fats (AREA)
- Fats And Perfumes (AREA)
Abstract
Modified esters of polyglycerol or glycerol and polymerized fatty acids with 8 or more carbon atoms in the molecule are made by esterifying glycerol or polyglycerol with a hydroxy carboxylic acid with 2-4 C atoms in the molecule, and esterifying or re-esterifying the product with one or more polymerized fatty acids or esters thereof, the total number of fatty acid groups introduced into the molecule being less than the total number of hydroxyl groups belonging to glycerol or polyglycerol radicles. The esters are also obtained when partial esters of glycerol or polyglycerol with polymerized fatty acids or a mixture of such esters (which may include polymerized triglyceride) with glycerol or polyglycerol are esterified with a hydroxy carboxylic acid of 2-4 C atoms in the molecule. As a modification of both processes polymerizable fatty acids or esters thereof may be used in place of the polymerized fatty acids or their esters and the fatty acid groups polymerized by heating with or without oxidation after final ester production. The unsaturated fatty acids may be synthetic or derived from natural sources. Fats or fatty acids specified are soy, mustard seed, sunflower seed, castor, ground nut, sesame, cotton seed, whale, and herring oils and partly hydrogenated whale or herring oils and their fatty acids. Glycollic, lactic and hydroxybutyric are specified hydroxyacids. In an example glycerol is polymerized to give a product varying from pentato octa-glycerol, esterified with about 10 per cent of lactic acid in the presence of a catalyst and the product (10 parts) re-esterified with a polymerized triglyceride (100 parts). The products are used in the preparation of emulsions especially for use in the baking industry (see Group III).ALSO:Emulsifying agents which are modified esters of polyglycerol or glycerol and polymerized fatty acids with 8 or more carbon atoms in the molecule are made by esterifying glycerol or polyglycerol with a hydroxycarboxylic acid with 2-4 C atoms in the molecule, and esterifying or re-esterifying the product with one or more polymerized fatty acids or esters thereof, the total number of fatty acid groups introduced into the molecule being less than the total number of hydroxyl groups belonging to glycerol or polyglycerol radicles. The agents are also obtained when partial esters of glycerol or polyglycerol with polymerized fatty acids or a mixture of such esters (which may include polymerized triglyceride) with glycerol or polyglycerol are esterified with a hydroxycarboxylic acid of 2-4 C atoms in the molecule. As a modification of both processes polymerizable fatty acids or esters thereof may be used in place of the polymerized fatty acids or their esters and the fatty acid groups polymerized by heating with or without oxidation after final ester production. The unsaturated fatty acids may be synthetic or derived from natural sources. Fats or fatty acids specified are soy, mustard seed, sunflower seed, castor, ground nut, sesame, cotton seed, whale and herring oils and partly hydrogenated whale or herring oils and their fatty acids. Glycollic, lactic and hydroxybutyric are specified hydroxyacids. In an example glycerol is polymerized to give a product ranging from pentto octa-glycerol, esterified with about 10 per cent of lactic acid in the presence of a catalyst and the product (10 parts) re-esterified with a polymerized triglyceride (100 parts). The ester products are used in the preparation of water-in-oil type emulsions, particularly for bakery purposes. Thus the esters are used in the production of a plastic emulsion for kneading or rolling into a dough, or a liquid emulsion for spraying or greasing baking-tins or an emulsion for preventing loaves sticking together during baking.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK731934X | 1951-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB731934A true GB731934A (en) | 1955-06-15 |
Family
ID=8152542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10898/52A Expired GB731934A (en) | 1951-05-18 | 1952-04-30 | Method for the production of modified esters of polyglycerol or glycerol, with polymerized and/or oxidized fatty acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB731934A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3966632A (en) | 1974-06-06 | 1976-06-29 | G. D. Searle & Co. | Vegetable oil emulsion |
-
1952
- 1952-04-30 GB GB10898/52A patent/GB731934A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3966632A (en) | 1974-06-06 | 1976-06-29 | G. D. Searle & Co. | Vegetable oil emulsion |
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