GB729122A - Process of decorating textile materials - Google Patents

Process of decorating textile materials

Info

Publication number
GB729122A
GB729122A GB24881/51A GB2488151A GB729122A GB 729122 A GB729122 A GB 729122A GB 24881/51 A GB24881/51 A GB 24881/51A GB 2488151 A GB2488151 A GB 2488151A GB 729122 A GB729122 A GB 729122A
Authority
GB
United Kingdom
Prior art keywords
basic
copolymer
triazine
hexahydro
triacrylyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24881/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB729122A publication Critical patent/GB729122A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen

Abstract

Fabrics are printed or padded with a vinyl or divinyl polymer or copolymer emulsion which contains also a high molecular basic compound which, as such or as a salt, is soluble or emulsifiable in water, and there is caused to react therewith, on the fabric, a compound containing two or more reactive groups capable of forming cross-linkages with the basic compound; but when the high molecular basic compound is capable of forming cross-linkages with itself, the use of a separate cross-linking agent is not necessary. The invention comprises also a printing paste comprising an aqueous vinyl polymer emulsion, a high molecular basic compound which, as such or as a salt, is soluble or emulsifiable in water, and a compound containing two or more reactive groups capable of reacting with the basic groups of the high molecular basic compound. Many high molecular basic compounds are specified including basic polyureas, basic polyamides, basic polyesters, basic polyurethanes, basic polystyrene, basic polyacrylonitrile, polyacrylates charged with basic groups by aminolyzing with di- or poly-amines, basic polymers obtained by hydrogenation of polymers containing nitro or nitrile groups, polyacrylonitriles converted to basic derivatives by boiling with polyamines, polyvinylamines obtained by saponifying polyvinyl succinimide or phthalimide by means of hydrazine hydrate, polyimines, cross-linked polyamines, basic polysaccharides, addition products of ethylene imine and hydroxyethyl cellulose or polyvinyl alcohol, and aminolysates of proteins. Cross-linking agents containing two or more reactive groups include hexahydro - 1,3,5 - triacrylyl - s - triazine, acrylic amides of polyvalent amines, acrylic acid esters of polyvalent alcohols, polyesters of polyvalent unsaturated acids, addition products of a diisocyanate with a 1,3-diketone or 1,3-ketone ester, polyisocyanate-bisulphite addition products, polyfunctional acids or esters, condensation products of phenoxyacetic acid with formaldehyde, polyfunctional aldehydes, and formaldehyde or its polymers. In the following examples, textiles are printed with printing pastes which, in addition to the pigments, thickeners and dispersing agents, contain (1) vinylidene chloride-butyl acrylate copolymer, the acetate of a basic polyurea prepared from diethylene triamine, g ,g 1-diamino-dipropylmethyl amine and hexane diisocyanate, and hexahydro - 1,3,5 - triacrylyl - s - triazine; (2) acrylonitrile - vinylidene chloride - butyl acrylate copolymer, a basic polyurea acetate and hexahydro - 1,3,5 - triacrylyl - s - triazine; (3) butyl acrylate - vinylidene chloride copolymer, gasoline, basic polyurea acetate and hexahydro - 1,3,5 - triacrylyl - s - triazine; (4) butyl acrylate - vinylidene chloride - vinyl chloride copolymer, turpentine, a basic thiourea acetate and hexahydro - 1,3,5 - triacrylyl - s-triazine; (5) copolymer as in (1), gasoline, basic polyamide acetate obtained from undecane - and dodecane - dicarboxylic acids and g ,g 1 - diaminodipropylmethyl amine, and hexahydro - 1,3,5 - triacrylyl - s - triazine; (6) the copolymer of (1), the acetate of the reaction product of butyl polyacrylate and methylpropyl diamine, and hexahydro - 1,3,5 - triacrylyl - s-triazine; (7) the copolymer as in (2), a basic polyurea acetate and hexahydro-1,3,5-triacrylyl-s-triazine, which is printed on to Naphtholated goods which are subsequently dyed with Variamine Blue Salt; (8) copolymer as in (2), basic polyurea acetate and hexahydro-1,3,5-triacrylyl-s-triazine, which is printed on to Naphtholated goods which are subsequently treated with a dyeing salt; (9) the copolymer of (1), basic polyurea acetate, and hexahydro - 1,3,5 - triacrylyl - s - triazine, which is printed on to white goods which are subsequently padded with aniline black solution; (10) copolymer as in (3), basic polyoxamide acetate prepared from a polyimine and ethyl oxalate, and hexahydro-1,3,5 - triacrylyl - s - triazine; (11) copolymer as in (1), basic polyurea acetate, and formaldehyde; (12) copolymer as in (2), basic polyester prepared from adipic acid, trimethylolpropane and acrylochloride with subsequent addition of butylamine to the double bonds, and hexahydro - 1,3,5 - triacrylyl - s - triazine; (13) copolymer as in (1), the reaction product of butyl polyacrylate and methylpropylenediamine, and hexahydro - 1,3,5 - triacrylyl - s - triazine; (14) the copolymer of (1), polyethyleneimine acetate and hexahydro - 1,3,5 - triacryl - s-triazine or hexane diisocyanate-bisulphite addition product; (15) copolymer as in (1), acrylonitrile-ethylenediamine reaction product, and hexahydro - 1,3,5 - triacrylyl - s - triazine; (16) copolymer as in (2), basic polystyrene prepared by reacting methyl propylenediamine with the copolymer of styrene and acrylofluoride, and hexahydro - 1,3,5 - triacrylyl - s - triazine; and (17) copolymer as in (2), and a basic polyurea. (18) Textiles are p impregnated with a resistant comprising the copolymer as in (1), the reaction product of butyl polyacrylate and methyl propylenediamine, and hexahydro - 1,3,5 - triacrylyl - s - triazine. (19) Fabrics are printed with a pigmented emulsion which comprises copolymer as in (1), basic polyurea acetate, hexahydro - 1,3,5 - triacrylyl - s - triazine and gasoline. In each of these examples the finished material is fixed by heating. Specifications 706,717, 723,767 and 727,650, [Group IV (a)] are referred to.ALSO:Fabrics are printed or padded with a vinyl or divinyl polymer or copolymer emulsion which contains also a high molecular basic compound which, as such or as a salt, is soluble or emulsifiable in water, and there is caused to react therewith, on the fabric, a compound containing two or more reactive groups capable of formng cross-linkages with the basic compound; but when the high molecular basic compound is capable of forming cross-linkages with itself, the use of a separate cross-linking agent is not necessary. The invention comprises also a printing paste comprising an aqueous vinyl polymer emulsion, a high molecular basic compound which, as such or as a salt, is soluble or emulsifiable in water, and a compound containing two or more reactive groups capable of reacting with the basic groups of the high molecular basic compound. Many high molecular basic compounds are specified including basic polyureas, basic polyamides, basic polyesters, basic polyurethanes, basic polystyrene, basic polyacrylonitrile, polyacrylates charged with basic groups by aminolyzing with di- or poly-amines, basic polymers obtained by hydrogenation of polymers containing nitro or nitrile groups, polyacrylonitriles converted to basic derivatives by boiling with polyamines, polyvinylamines obtained by saponifying polyvinyl succinimide or phthalimide by means of hydrazine hydrate, polyimines, cross-linked polyamines, basic polysaccharides, addition products of ethylene imine and hydroxyethyl cellulose or polyvinyl alcohol, and aminolysates of proteins. Cross-linking agents containing two or more reactive groups include hexahydro-1,3,5-triacrylyl-s-triazine, acrylic amides of polyvalent amines, acrylic acid esters of polyvalent alcohols, polyesters of polyvalent unsaturated acids, addition products of a diisocyanate with a 1,3 - diketone or 1,3 - ketone ester, polyisocyanate-bisulphite addition products, polyfunctional acids or esters, condensation products of phenoxyacetic acid with formaldehyde, polyfunctional aldehydes, and formaldehyde or its polymers. In the following examples, textiles are printed with printing pastes which, in addition to the pigments, thickeners and dispersing agents, contain (1) vinylidene chloridebutyl acrylate copolymer, the acetate of a basic polyurea prepared from diethylene triamine, g ,g 1-diaminodipropylmethyl amine and hexane diisocyanate, and hexahydro-1,3,5-triacrylyl-s-triazine; (2) acrylonitrile-vinylidene chloridebutyl acrylate copolymer, a basic polyurea acetate and hexahydro - 1,3,5 - triacrylyl - s - triazine, (3) butyl acrylate-vinylidene chloride copolymer, gasoline, basic polyurea acetate and hexahydro - 1,3,5 - triacrylyl - s - triazine, (4) butyl acrylate-vinylidene chloride-vinyl chloride copolymer, turpentine, a basic thiourea acetate and hexahydro-1,3,5-triacrylyl-s-triazine, (5) copolymer as in (1), gasoline, basic polyamide acetate obtained from undecane- and dodecanedicarboxylic acids and g ,g 1-diaminodipropylmethyl amine, and hexahydro-1,3,5-triacrylyl-s-triazine, (6) the copolymer of (1), the acetate of the reaction product of butyl polyacrylate and methylpropyl diamine, and hexahydro-1,3,5-triacrylyl-s-triazine, (7) the copolymer as in (2), a basic polyurea acetate and hexahydro-1,3,5-triacrylyl-s-triazine, which is printed on to naphtholated goods which are subsequently dyed with Variamine Blue Salt, (8) copolymer as in (2), basic polyurea acetate and hexahydro-1,3,5-triacrylyl-s-triazine, which is printed on to Naphtholated goods which are subsequently treated with a dyeing salt, (9) the copolymer of (1) basic polyurea acetate, and hexahydro-1,3,5-triacrylyl-s-triazine, which is printed on to white goods which are subsequently padded with aniline black solution, (10) copolymer as in (3), basic polyoxamide acetate prepared from a polyamine and ethyl oxalate, and hexahydro-1,3,5-triacrylyl-s-triazine, (11) copolymer as in (1), basic polyurea acetate, and formaldehyde, (12) copolymer as in (2), basic polyester prepared from adipic acid, trimethylolpropane and acrylochloride with subsequent addition of butylamine to the double bonds, and hexahydro-1,3,5-triacrylyl-s-triazine, (13) copolymer as in (1), the reaction product of butyl polyacrylate and methyl propylenediamine, and hexahydro-1,3,5-triacrylyl-s-triazine, (14) the copolymer of (1), polyethyleneimine acetate and hexahydro-1,3,5 - triacrylyl - s - triazine or hexane diisocyanate-bisulphite addition product, (15
GB24881/51A 1950-10-30 1951-10-24 Process of decorating textile materials Expired GB729122A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE304367X 1950-10-30

Publications (1)

Publication Number Publication Date
GB729122A true GB729122A (en) 1955-05-04

Family

ID=6117153

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24881/51A Expired GB729122A (en) 1950-10-30 1951-10-24 Process of decorating textile materials

Country Status (5)

Country Link
BE (1) BE506611A (en)
CH (1) CH304367A (en)
FR (1) FR1061686A (en)
GB (1) GB729122A (en)
NL (1) NL83472C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1704878A3 (en) * 1995-12-18 2007-04-25 AngioDevice International GmbH Crosslinked polymer compositions and methods for their use
US8377466B2 (en) 1995-12-18 2013-02-19 Angiotech Pharmaceuticals (Us), Inc. Adhesive tissue repair patch

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1704878A3 (en) * 1995-12-18 2007-04-25 AngioDevice International GmbH Crosslinked polymer compositions and methods for their use
US8377466B2 (en) 1995-12-18 2013-02-19 Angiotech Pharmaceuticals (Us), Inc. Adhesive tissue repair patch
US8617584B2 (en) 1995-12-18 2013-12-31 Angiodevice International Gmbh Adhesive tissue repair patch and collagen sheets

Also Published As

Publication number Publication date
FR1061686A (en) 1954-04-14
CH304367A (en) 1955-01-15
NL83472C (en)
BE506611A (en)

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