GB710105A - Detergent and/or bactericidal compositions - Google Patents

Detergent and/or bactericidal compositions

Info

Publication number
GB710105A
GB710105A GB1288451A GB1288451A GB710105A GB 710105 A GB710105 A GB 710105A GB 1288451 A GB1288451 A GB 1288451A GB 1288451 A GB1288451 A GB 1288451A GB 710105 A GB710105 A GB 710105A
Authority
GB
United Kingdom
Prior art keywords
di
n11
n5
n1
chlorophenyldiguanido
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1288451A
Inventor
George Edward Davies
John Francis
Eric Kay
Francis Leslie Rose
Geoffrey Swain
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1288451A priority Critical patent/GB710105A/en
Publication of GB710105A publication Critical patent/GB710105A/en
Application status is Expired legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/20Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylguanidines
    • C07C279/24Y being a hetero atom
    • C07C279/26X and Y being nitrogen atoms, i.e. biguanides

Abstract

A fungicidal and bactericidal composition having detergent properties comprises a bis-biguanide of the formula:- <FORM:0710105/III/1> wherein A and B stand for aromatic nuclei, the same or different and optionally substituted by one or more hydroxy, halogen, nitro, alkyl or alkoxy radicals, and X stands for a bridging group which is a hydrocarbon or a dialkoxybenzene radical of not more than 15 carbon atoms, preferably in the form of its salt, and for each 100 parts by weight of the bis-biguanide between 50 and 20,000 parts by weight of a substance of known wetting and/or detergent properties. Preferred bis-biguanides are those in whch A and B are identical and stand for a halogen substituted phenyl radical, and X stands for (CH2)n where n is an integer from 3 to 9. The composition may be in the form of an aqueous solution, preferably containing at least one part by weight of the bis-biguanide per 100,000 parts by weight of water. Bis-biguanides specified which may be used in the form of their dihydrochlorides or diacetates are:- 1 : 3 - di - (N1 : N11 - p - chlorophenyldiguanido - N5 : N51)-propane 1 : 4 - di - (N1 : N11 - p - chlorophenyldiguanido - N5 : N51)-butane 1 : 5 - di - (N1 : N11 - p - chlorophenyldiguanido - N5 : N51)-pentane 1 : 6 - di - (N1 : N11 - p - chlorophenyldiguanido - N5 : N51)-hexane and the corresponding p-tolyl, p-anisyl, m-chlorophenyl, 2 : 5-dichlorophenyl, 3 : 4-dichlorophenyl, m-nitrophenyl, phenyl, p-hydroxyphenyl, o-chlorophenyl and 2 : 4-dimethlphenyl compounds 1 : 7 - di - (N1 : N11 - p - chlorophenyldiguanido - N5 : N51)-heptane 1 : 10 - di - (N1 : N11 - p - chlorophenyldiguanido- N5 : N51)-decane 1 : 4 - di - (N1 : N11 - phenyldiguanido - N5 : N51)-benzene and the corresponding p-chlorophenyl compound, o : o 1 - di - (N1 : N11 - p - chlorophenyldiguanido-N5 : N51) - 1 : 4 - di - n - propoxybenzene, 4 : 41-di-(N1 : N11 - phenyldiguanido - N5 : N51) - diphenyl - methane and the corresponding p-chlorophenyl compound. The substances of known wetting and/or detergent properties include inorganic detergents, for example sodium hydroxide, sodium carbonate, borax and the sodium silicates and phosphates; anionic surface active substances, for example salts of long chain fatty acids, of long chain fatty alcohol sulphates, of the higher secondary alkyl sulphates and of the higher alkyl and aryl sulphonates; cationic surface active substances, for example dodecyltetra-decyl- and hexadecyl-pyridinium bromides and chlorides and dodecyl-, tetradecyl- and hexadecyltrimethyl-ammonium bromides and chlorides and long chain alkyldimethylbenzyl-ammonium bromides and chlorides; and non-ionic surface active substances, for example, condensation products of ethylene oxide with alkylphenols, long-chain fatty alcohols, and long-chain fatty acids or their amides. Specification 705,838, [Group IV (b)], is referred to.ALSO:A fungicidal and bactericidal composition having detergent properties comprises a bis-biguanide of the formula: <FORM:0710105/VI/1> wherein A and B stand for aromatic nuclei, the same or different and optionally substituted by one or more hydroxy, halogen, nitro, alkyl or alkoxy radicals, and X stands for a bridging group which is a hydrocarbon or a dialkoxy benzene radical of not more than 15 carbon atoms, preferably in the form of its salt, and for each 100 parts by weight of the bis-biguanide between 50 and 20,000 parts by weight of a substance of known wetting and/or detergent properties. Preferred bis-biguanides are those in which A and B are identical and stand for a halogen substituted phenyl radical, and X stands for (CH2)n where n is an integer from 3 to 9. The composition may be in the form of an aqueous solution, preferably containing at least 1 part by weight of the bis-biguanide per 100,000 parts by weight of water. Bis-biguanides specified which may be used in the form of their dihydrochlorides or diacetates are: 1:3 - di - (N1:N11 - p - chlorophenyldiguanido - N5:N15) - propane; 1:4-di-(N1:N11-p-chlorophenyldiguanido - N5: N15)-butane; 1:5 - di - (N1:N11 - p-chlorophenyldiguanido-N5:N15)-pentane; 1:6-di-(N1: N11-p-chlorophenyldiguanido - N5:N15) - hexane; and the corresponding p-tolyl, p-anisyl, m-chlorophenyl, 2:5-dichlorophenyl, 3:4-dichlorophenyl, m-nitrophenyl, phenyl, p-hydroxyphenyl, o-chlorophenyl and 2:4 dimethylhenyl compounds 1:7-di-(N1:N11-p-chlorophenyldiguanido - N5:N15) - heptane; 1:10 - di - (N1:N11-p-chlorophenyldiguanido -N5:N15) - decane; 1:4 - di - (N1: N11 - phenyldiguanido-N5:N15)-benzene and the corresponding p-chlorophenyl compound, di-(N1:N11 - p-chlorophenyldiguanido-N5: N15)-1:4-di-n-propoxybenzene, 4:41-di-(N1:N11-phenyldiguanido -N5:N15)- diphenylmethane and the corresponding p-chlorophenyl compound. The substances of known wetting and/or detergent properties include inorganic detergents, for example sodium hydroxide, sodium carbonate, borax and the sodium silicates and phosphates; anionic surface active substances, for example salts of long chain fatty acids, of long chain fatty alcohol sulphates, of the higher secondary alkyl sulphates and of the higher alkyl and aryl sulphonates; cationic surface active substances, for example dodecyl-tetra-decyl- and hexadecyl-pyridiumium bromides and chlorides and dodecyl-, tetradecyl- and hexadecyl-trimethyl - ammonium bromide and chlorides and long chain alkyldimethyl-benzyl-ammonium bromides and chlorides; and non-ionic surface active substances for example, condensation products of ethylene oxide with alkylphenols long-chain fatty alcohols, and long-chain fatty acids or their amides. Specification 705,838, [Group IV(b)], is referred to.
GB1288451A 1951-05-31 1951-05-31 Detergent and/or bactericidal compositions Expired GB710105A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1288451A GB710105A (en) 1951-05-31 1951-05-31 Detergent and/or bactericidal compositions

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
BE511801D BE511801A (en) 1951-05-31
GB1288451A GB710105A (en) 1951-05-31 1951-05-31 Detergent and/or bactericidal compositions
FR1057595D FR1057595A (en) 1951-05-31 1952-05-31 detergent compositions and (or) bactericides

Publications (1)

Publication Number Publication Date
GB710105A true GB710105A (en) 1954-06-09

Family

ID=10012893

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1288451A Expired GB710105A (en) 1951-05-31 1951-05-31 Detergent and/or bactericidal compositions

Country Status (3)

Country Link
BE (1) BE511801A (en)
FR (1) FR1057595A (en)
GB (1) GB710105A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977893A (en) * 1973-10-03 1976-08-31 J. M. Huber Corporation Amorphous precipitated siliceous pigments and improved process for producing such pigments
FR2579979A1 (en) * 1985-04-05 1986-10-10 Pf Cosmetique

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5164107A (en) * 1991-04-25 1992-11-17 Becton, Dickinson And Company Chlorhexidine composition useful in a surgical scrub

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977893A (en) * 1973-10-03 1976-08-31 J. M. Huber Corporation Amorphous precipitated siliceous pigments and improved process for producing such pigments
FR2579979A1 (en) * 1985-04-05 1986-10-10 Pf Cosmetique
EP0200607A1 (en) * 1985-04-05 1986-11-05 Pierre Fabre Cosmetique Surfactant chlorhexidine salts and compositions

Also Published As

Publication number Publication date
FR1057595A (en) 1954-03-09
BE511801A (en)

Similar Documents

Publication Publication Date Title
GB1128411A (en) Detergent-bleach compositions
US2897187A (en) Solid, stable diazonium compound and a process of preparing the same
GB1023377A (en) Improvements in or relating to light-sensitive layers
GB1072655A (en) Surfactants
GB944053A (en) Detergent composition enclosed by a water-soluble film
EP0542677B1 (en) Storage-stable formulation of mixtures of optical brighteners
US4588514A (en) Liquid thickened bleaching composition
Shinoda The critical micelle concentrations in aqueous solutions of potassium alkyl malonates
GB1025791A (en) Detergent compositions
GB1219850A (en) Improvements in the preparation of aromatic compounds containing monoethylenically unsaturated radicals
GB738538A (en) Detergent compositions
GB1099776A (en) Bactericidal p.v.c. sheet
GB671358A (en) Cleansing compositions
SE7409654L (en)
GB1003950A (en) Process for the production of basic dibenzo-oxepin and dibenzo-thiepin derivatives
GB992860A (en) New surface-active amine oxides and compositions containing them
US2607738A (en) Bleaching, sterilizing, disinfecting, and deterging compositions
EP0263911B1 (en) Low-foam alkali-stable amphoteric surface active agents
IL22818A (en) 4-alkanoylphenoxy acetic acids and derivatives thereof,processes for their preparation and pharmaceutical compositions containing them
US6358900B1 (en) Hard surface cleaners comprising an ethoxylated quaternary ammonium compound and an anionic surfactant
GB855679A (en) Improvements in or relating to liquid detergent compositions
GB1087413A (en) Improvements in or relating to amines
GB641297A (en) Germicidal detergent compositions
GB672106A (en) Improvements in or relating to preparation of azo compounds
GB948396A (en) Liquid detergent composition