GB693166A - Improvements relating to ion-exchange resins - Google Patents
Improvements relating to ion-exchange resinsInfo
- Publication number
- GB693166A GB693166A GB28100/49A GB2810049A GB693166A GB 693166 A GB693166 A GB 693166A GB 28100/49 A GB28100/49 A GB 28100/49A GB 2810049 A GB2810049 A GB 2810049A GB 693166 A GB693166 A GB 693166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resin
- water
- tubes
- ion
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Ion-exchange resins in the form of sheets, rods, discs or tubes are prepared by reacting appropriate compounds in the presence of that quantity of water necessary substantially to saturate the resulting resin gel and under conditions such that no water can escape from the reaction mass or resin gel. The resin may be prepared in a mould of appropriate shape, or a porous support may be impregnated with a resin in the liquid state and the resin gelled on the support. The quantity of water required is determined previously by experiment. In examples: (1) phenol, sodium metabisulphite, formaldehyde and sodium hydroxide were reacted under reflux in the presence of water which formed 50 per cent by weight of the mixture, to yield a viscous resin. This was placed in a long glass tube which after sealing was heated to cure the resin. After cooling, the tube was opened and the rod of resin immersed in water; (2) sulphonated phenol, formaldehyde and sodium hydroxide with sufficient water to form 50 per cent by weight of the whole mixture were heated under reflux to give a viscous resin. After cooling this was used to impregnate a filter paper which was placed in a closed glass tube containing an open ampoule of water. The resin was cured by heating, and the paper then removed and washed with water; (3) phenol, formaldehyde, tetraethylene-pentamine, and sodium hydroxide with sufficient water to form 48 per cent by weight of the mixture were reacted under reflux to yield a viscous resin. The resin was poured into a flat bottomed tube to form a thin layer which was then sealed and heated to cure the resin to a solid disc which was then removed and washed with water; (4) acetone, formaldehyde, guanidine nitrate and sodium hydroxide with sufficient water to form 46 per cent of the mixture were reacted under reflux to give a viscous resin. This was used to impregnate a sintered glass disc which was cured in a small pressure-vessel containing water. The cured disc was removed and washed with water. The Specification also refers to the production of the resins in rods and tubes by extrusion from a tube or from between two coaxial tubes into a heated closed space. The products may be used in electrodialysis, ion-exchange resin sheets being used as the partitions, for the separation of large ions from small ions and the measurement of ionic activities and mobilities. Impregnated filter papers may be used in paper chromatography.ALSO:The Specification states that filter papers impregnated with an ion-exchange resin made in such a manner that cracking of the final resin is prevented (see Group IV(a)), may be used in the separation and detection of ions by paper chromatography.ALSO:Ion exchange resins in the form of sheets, rods, discs or tubes are made by reacting the resin-forming compounds in the presence of sufficient water to ensure that the resultant gel is substantially saturated. The products do not crack. The reaction may be effected in a mould of the appropriate shape, e.g. a glass mould which is broken to release the hardened article. Long rods (or tubes) may be made by extruding the viscous resin mixture under slight pressure through a tube (or concentric tubes) heated to about 90 DEG C. and arranged in a space which is either entirely closed or has a reflux arrangement on it to prevent loss of water. The resin solidifies continuously and then passes into another space which is completely closed, the temperature being raised to that required to complete the polycondensation, e.g. 120 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB28100/49A GB693166A (en) | 1949-11-02 | 1949-11-02 | Improvements relating to ion-exchange resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB28100/49A GB693166A (en) | 1949-11-02 | 1949-11-02 | Improvements relating to ion-exchange resins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB693166A true GB693166A (en) | 1953-06-24 |
Family
ID=10270267
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28100/49A Expired GB693166A (en) | 1949-11-02 | 1949-11-02 | Improvements relating to ion-exchange resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB693166A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2736637A (en) * | 1952-07-24 | 1956-02-28 | Ionics | Water hardness measurement-method and apparatus |
DE1074008B (en) * | 1955-07-30 | 1960-01-28 | South African Council for Seien tific and Industrial Research Pretoria Transvaal (Südafrikanische Union) Y'ertr Dr Ing A v Krcisler Dr Ing K Schonwald Dipl Chem Dr phil H Siebeneicher und Dr Ing Th Me\er Pat Anwalte Köln 1 | Process for the production of cation-selective membranes containing sulfonic acid groups for electrodialysis |
DE1083230B (en) * | 1957-07-08 | 1960-06-15 | South African Council For Scie | Process for the production of anion-selective membranes for electrodialysis |
US2955067A (en) * | 1954-10-20 | 1960-10-04 | Rohm & Haas | Cellulosic paper containing ion exchange resin and process of making the same |
DE1104687B (en) * | 1956-01-16 | 1961-04-13 | Ionics | Process for the production of ion exchange membranes |
US6833238B2 (en) | 2002-01-04 | 2004-12-21 | Applera Corporation | Petal-array support for use with microplates |
-
1949
- 1949-11-02 GB GB28100/49A patent/GB693166A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2736637A (en) * | 1952-07-24 | 1956-02-28 | Ionics | Water hardness measurement-method and apparatus |
US2955067A (en) * | 1954-10-20 | 1960-10-04 | Rohm & Haas | Cellulosic paper containing ion exchange resin and process of making the same |
DE1113359B (en) * | 1954-10-20 | 1961-08-31 | Rohm & Haas | Process for the production of cellulose paper with ion-exchange properties |
DE1074008B (en) * | 1955-07-30 | 1960-01-28 | South African Council for Seien tific and Industrial Research Pretoria Transvaal (Südafrikanische Union) Y'ertr Dr Ing A v Krcisler Dr Ing K Schonwald Dipl Chem Dr phil H Siebeneicher und Dr Ing Th Me\er Pat Anwalte Köln 1 | Process for the production of cation-selective membranes containing sulfonic acid groups for electrodialysis |
DE1104687B (en) * | 1956-01-16 | 1961-04-13 | Ionics | Process for the production of ion exchange membranes |
DE1083230B (en) * | 1957-07-08 | 1960-06-15 | South African Council For Scie | Process for the production of anion-selective membranes for electrodialysis |
US6833238B2 (en) | 2002-01-04 | 2004-12-21 | Applera Corporation | Petal-array support for use with microplates |
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