GB509204A - A process for the production of nitrite esters of non-phenolic organic compounds - Google Patents

A process for the production of nitrite esters of non-phenolic organic compounds

Info

Publication number
GB509204A
GB509204A GB2619338A GB2619338A GB509204A GB 509204 A GB509204 A GB 509204A GB 2619338 A GB2619338 A GB 2619338A GB 2619338 A GB2619338 A GB 2619338A GB 509204 A GB509204 A GB 509204A
Authority
GB
United Kingdom
Prior art keywords
acid
suitable
polynitrites
erythritol
polyhydroxy compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2619338A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US509204XA priority Critical
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB509204A publication Critical patent/GB509204A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C203/00Esters of nitric or nitrous acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/04Preparation of esters of nitrous acid

Abstract

509,204. Polynitrites. NAAMLOOZE VENNOOTSCHAP DE BATAAFSCHE PETROLEUM MAATSCHAPPIJ. Sept. 7, 1938, No. 26193. Convention date, Sept. 17, 1937. [Class 2 (iii)] Monophenolic polynitrites are made by treating polyhydroxy compounds with nitrous acid in an aqueous medium, the products being removed from the medium as soon as they are formed. The solubility of the product may be diminished by adding a salt, or, if a higher nitrited product is desired, acetic acid may be added to increase the solubility of less nitrited esters. The nitrous acid may be made in the medium by adding an alkali or calcium nitrite and a mineral acid or acetic acid or nitrous anhydride may be introduced. Suitable polyhydroxy compounds are glycerol, alpha-, #- and dimethyl glycerols, pentaerythritol, methyl tricarbinol methane, erythritol and its monoacetate, monoethyl ether and monochlorhydrin, and hexyl erythritol, from all of which polynitrites containing a free hydroxy group may' be prepared ; and ethylene, propylene, trimethylene, isobutylene, #-butylene, alpha- and #- methyl trimethylene, diethylene and #-methylene trimethylene glycols, glycerol monoethyl ether and monoacetate, and erythritol dichlorhydrin; polyhydroxy compounds containing carboxyl groups are also suitable, such as monomethyl tartrate, dimethyl racemic acid and dihydroxy maleic acid.- Substances such as sucrose which contain many hydroxy groups are not suitable, but sucrose containing a hydrophobic group such as an alkyl group is suitable. An example describes the production of ethylene glycol dinitrite.
GB2619338A 1937-09-17 1938-09-07 A process for the production of nitrite esters of non-phenolic organic compounds Expired GB509204A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US509204XA true 1937-09-17 1937-09-17

Publications (1)

Publication Number Publication Date
GB509204A true GB509204A (en) 1939-07-12

Family

ID=21968319

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2619338A Expired GB509204A (en) 1937-09-17 1938-09-07 A process for the production of nitrite esters of non-phenolic organic compounds

Country Status (2)

Country Link
FR (1) FR843518A (en)
GB (1) GB509204A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3975425A (en) * 1972-10-14 1976-08-17 Stamicarbon B.V. Process for carrying out nitrosation reactions and diazotation reactions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3975425A (en) * 1972-10-14 1976-08-17 Stamicarbon B.V. Process for carrying out nitrosation reactions and diazotation reactions

Also Published As

Publication number Publication date
FR843518A (en) 1939-07-05

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