GB2520833A - Catalyst And Method of Manufacture - Google Patents

Catalyst And Method of Manufacture Download PDF

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Publication number
GB2520833A
GB2520833A GB1419218.1A GB201419218A GB2520833A GB 2520833 A GB2520833 A GB 2520833A GB 201419218 A GB201419218 A GB 201419218A GB 2520833 A GB2520833 A GB 2520833A
Authority
GB
United Kingdom
Prior art keywords
suspension
liquid
copper oxide
solid particles
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB1419218.1A
Other versions
GB2520833B (en
GB201419218D0 (en
Inventor
Joachim Pohl
Aalbert Zwijnenburg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of GB201419218D0 publication Critical patent/GB201419218D0/en
Publication of GB2520833A publication Critical patent/GB2520833A/en
Application granted granted Critical
Publication of GB2520833B publication Critical patent/GB2520833B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B01J35/30—
    • B01J35/40—
    • B01J35/615—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • C11C3/126—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation using catalysts based principally on other metals or derivates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention concerns a method for making a solid material which is useful as a heterogeneous catalyst comprising the steps of: forming at least one copper oxide suspension comprising solid particles of copper oxide in a liquid; forming at least one carrier suspension comprising solid particles of a carrier material in a liquid; combining the copper oxide suspension and the carrier suspension; subjecting the combined suspensions to mechanical energy; separating the suspension liquid from the solid particles in the combined suspension; and subjecting the solid material to a thermal decomposition step. A catalyst made by the method has a BET surface area greater than 150 m2/g, a particle size distribution in which D50 is in the range from 25 35 μm, and wherein the D50 after 60 minutes ultrasound treatment is at least 30% of the original value.
GB1419218.1A 2012-03-30 2013-03-28 Catalyst And Method of Manufacture Active GB2520833B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1205764.2A GB201205764D0 (en) 2012-03-30 2012-03-30 Catalyst and method of manufacture
PCT/GB2013/050839 WO2013144650A1 (en) 2012-03-30 2013-03-28 Catalyst and method of manufacture

Publications (3)

Publication Number Publication Date
GB201419218D0 GB201419218D0 (en) 2014-12-10
GB2520833A true GB2520833A (en) 2015-06-03
GB2520833B GB2520833B (en) 2018-09-12

Family

ID=46160098

Family Applications (2)

Application Number Title Priority Date Filing Date
GBGB1205764.2A Ceased GB201205764D0 (en) 2012-03-30 2012-03-30 Catalyst and method of manufacture
GB1419218.1A Active GB2520833B (en) 2012-03-30 2013-03-28 Catalyst And Method of Manufacture

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GBGB1205764.2A Ceased GB201205764D0 (en) 2012-03-30 2012-03-30 Catalyst and method of manufacture

Country Status (7)

Country Link
US (1) US9895678B2 (en)
EP (1) EP2834334B8 (en)
CN (2) CN110237842A (en)
GB (2) GB201205764D0 (en)
MY (1) MY173727A (en)
RU (1) RU2630698C2 (en)
WO (1) WO2013144650A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0145094A2 (en) * 1983-12-06 1985-06-19 Unilever N.V. Process for preparing a transition metal-silicate catalyst
DE4308120A1 (en) * 1992-03-21 1993-09-23 Erwin Dr Oser Oxidn. hydrogenation or hardening catalyst obtd. from metal oxide mixt. - contains catalytic crystallites of varying size, esp. for hydrogenating oil, fat or fatty acid
DE19611132A1 (en) * 1996-03-21 1997-09-25 Joachim Dr Pohl Heterogeneous catalyst, its preparation and its use
EP2586528A1 (en) * 2010-06-24 2013-05-01 Tianjin University Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3906586A1 (en) 1989-03-02 1990-09-13 Henkel Kgaa METHOD FOR PRODUCING HETEROGENIC CATALYSTS BASED ON NANOCRISTALLINE ALLOYS, USE OF SUCH CATALYSTS FOR DIFFERENT REACTIONS, AND CORRESPONDING CATALYSTS
DE19818096A1 (en) * 1998-04-23 1999-10-28 Basf Ag Hexandiol production by hydrogenation of dialkyl adipate
US6306795B1 (en) * 1999-09-07 2001-10-23 Cytec Technology Corp. Stable highly active supported copper based catalysts
KR100455665B1 (en) 2002-03-23 2004-11-06 한국화학연구원 Preparation of copper-silica catalyst from acidic waste solution containing copper, which is useful for hydrogenation or dehydrogenation
CN1202912C (en) * 2003-06-02 2005-05-25 厦门中坤化学有限公司 Method for preparing load-type catalyst of modified cupric oxide
JP2008518750A (en) * 2004-11-03 2008-06-05 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Abrasion-resistant granular catalyst
DE102005004429A1 (en) * 2005-01-31 2006-08-10 Süd-Chemie AG Process for the preparation of a catalyst for the desulfurization of hydrocarbon streams
EP1963010B1 (en) * 2005-12-21 2011-09-28 Johnson Matthey PLC Metal nitrate conversion method
CN101489671B (en) * 2006-07-17 2011-08-03 巴斯夫欧洲公司 Process for hydrogenating unsaturated hydrocarbons over catalysts comprising copper and zinc
CN101138726A (en) * 2006-09-05 2008-03-12 中国石油天然气股份有限公司 Catalyzer for industrial production of 1,6-hexamethylene glycol and method of preparing the same
JP5490129B2 (en) * 2008-11-05 2014-05-14 ビーエーエスエフ ソシエタス・ヨーロピア Process for producing N, N-substituted-3-aminopropan-1-ol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0145094A2 (en) * 1983-12-06 1985-06-19 Unilever N.V. Process for preparing a transition metal-silicate catalyst
DE4308120A1 (en) * 1992-03-21 1993-09-23 Erwin Dr Oser Oxidn. hydrogenation or hardening catalyst obtd. from metal oxide mixt. - contains catalytic crystallites of varying size, esp. for hydrogenating oil, fat or fatty acid
DE19611132A1 (en) * 1996-03-21 1997-09-25 Joachim Dr Pohl Heterogeneous catalyst, its preparation and its use
EP2586528A1 (en) * 2010-06-24 2013-05-01 Tianjin University Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof

Also Published As

Publication number Publication date
WO2013144650A1 (en) 2013-10-03
RU2630698C2 (en) 2017-09-12
GB2520833B (en) 2018-09-12
GB201205764D0 (en) 2012-05-16
EP2834334B1 (en) 2022-05-18
EP2834334B8 (en) 2022-08-03
GB201419218D0 (en) 2014-12-10
US9895678B2 (en) 2018-02-20
RU2014143806A (en) 2016-05-27
EP2834334A1 (en) 2015-02-11
CN110237842A (en) 2019-09-17
CN104271721A (en) 2015-01-07
US20150094499A1 (en) 2015-04-02
MY173727A (en) 2020-02-18

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