GB2519712A - Electrochemical humidity and optional temperature measurement - Google Patents

Electrochemical humidity and optional temperature measurement Download PDF

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Publication number
GB2519712A
GB2519712A GB201503275A GB201503275A GB2519712A GB 2519712 A GB2519712 A GB 2519712A GB 201503275 A GB201503275 A GB 201503275A GB 201503275 A GB201503275 A GB 201503275A GB 2519712 A GB2519712 A GB 2519712A
Authority
GB
United Kingdom
Prior art keywords
humidity
electrochemical
multiferrocene
determining
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB201503275A
Other versions
GB201503275D0 (en
Inventor
Richard Compton
Linhongjia Xiong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxford University Innovation Ltd
Original Assignee
Oxford University Innovation Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxford University Innovation Ltd filed Critical Oxford University Innovation Ltd
Publication of GB201503275D0 publication Critical patent/GB201503275D0/en
Publication of GB2519712A publication Critical patent/GB2519712A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K7/00Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
    • G01K7/16Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements
    • G01K7/26Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements the element being an electrolyte
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416Systems
    • G01N27/48Systems using polarography, i.e. measuring changes in current under a slowly-varying voltage
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0006Calibrating gas analysers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036Specially adapted to detect a particular component
    • G01N33/0059Specially adapted to detect a particular component avoiding interference of a gas with the gas to be measured
    • G01N33/006Specially adapted to detect a particular component avoiding interference of a gas with the gas to be measured avoiding interference of water vapour with the gas to be measured

Abstract

Voltammetric method for measuring humidity of the mixture of a ferrocene compound containing a single iron atom and a multiferrocene compound, the method comprising • determining, at a humidity of interest, a first peak potential at which a first electrochemical reaction of the mixture of a ferrocene compound containing a single iron atom and a multiferrocene compound occurs; • determining, at the humidity of interest, a second peak potential at which a second electrochemical reaction of that mixture occurs; • determining the difference between the first and second peak potentials; • converting the difference between the first and second peak potentials to a value of humidity. • Also provided is an electrochemical method for measuring both temperature and humidity simultaneously. Also further provided is a humidity sensor for carrying out these methods, and a voltammetric sensor for sensing a species, the sensor comprising a ferrocene compound containing a single iron atom, a multiferrocene compound and an ionic liquid.
GB201503275A 2012-08-02 2013-08-01 Electrochemical humidity and optional temperature measurement Withdrawn GB2519712A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1213772.5A GB201213772D0 (en) 2012-08-02 2012-08-02 Electrochemical humidity and optional temperature measurement
PCT/GB2013/052060 WO2014020347A1 (en) 2012-08-02 2013-08-01 Electrochemical humidity and optional temperature measurement

Publications (2)

Publication Number Publication Date
GB201503275D0 GB201503275D0 (en) 2015-04-15
GB2519712A true GB2519712A (en) 2015-04-29

Family

ID=46881565

Family Applications (2)

Application Number Title Priority Date Filing Date
GBGB1213772.5A Ceased GB201213772D0 (en) 2012-08-02 2012-08-02 Electrochemical humidity and optional temperature measurement
GB201503275A Withdrawn GB2519712A (en) 2012-08-02 2013-08-01 Electrochemical humidity and optional temperature measurement

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GBGB1213772.5A Ceased GB201213772D0 (en) 2012-08-02 2012-08-02 Electrochemical humidity and optional temperature measurement

Country Status (2)

Country Link
GB (2) GB201213772D0 (en)
WO (1) WO2014020347A1 (en)

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
TORRIERO ET AL: "Ionic liquid effects on the redox potential of ferrocene", ELECTROCHEMISTRY COMMUNICATIONS, vol. 16, no. 1, 2011, pages 84-87 *
XIONG ET AL: "A simultaneous voltammetric temperature and humidity sensor", THE ANALYST, vol. 137, no. 21, 2012, pages 4951-4957 *
XIONG ET AL: "An electrochemical thermometer: voltammetric measurement of temperature and its application to amperometric gas sensing", THE ANALYST, vol. 137, no. 11, 2012, pages 2567-2573 *
XIONG ET AL: "Tuning solute redox potentials by varying the anion component of room temperature ionic liquids", CHEMICAL COMMUNICATIONS, vol. 48, no. 46, 2012, pages 5784-5786 *
ZHANG ET AL: "A hydrogel modified electrode for application as a voltammetric temperature sensor and its use in oxygen detection", ANALYTICAL METHODS, vol. 5, no. 14, 2013, page 3473 *

Also Published As

Publication number Publication date
GB201503275D0 (en) 2015-04-15
WO2014020347A1 (en) 2014-02-06
GB201213772D0 (en) 2012-09-12

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Legal Events

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)