GB2518525A - Treating of catalyst carrier, fischer - tropsch catalysts and method of preparation thereof - Google Patents
Treating of catalyst carrier, fischer - tropsch catalysts and method of preparation thereof Download PDFInfo
- Publication number
- GB2518525A GB2518525A GB1415360.5A GB201415360A GB2518525A GB 2518525 A GB2518525 A GB 2518525A GB 201415360 A GB201415360 A GB 201415360A GB 2518525 A GB2518525 A GB 2518525A
- Authority
- GB
- United Kingdom
- Prior art keywords
- support
- preparation
- catalyst
- treating
- fischer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 5
- 238000002360 preparation method Methods 0.000 title abstract 3
- 239000000463 material Substances 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8896—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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- B01J35/30—
-
- B01J35/40—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
Abstract
A method for the preparation of a modified catalyst support comprising: (a) treating a bare catalyst support material with an aqueous solution or dispersion of one or more titanium metal sources and one or more carboxylic acids; and (b) drying the treated support, and (c) optionally calcining the treated support. Also provided are catalyst support materials obtainable by the methods, and catalysts prepared from such supports. The method of preparation improves the stability of the modified catalyst support. The catalyst prepared with the treated support are also more active compare with catalyst having a support, which is not prepared according to the method of the application.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1201619.2A GB201201619D0 (en) | 2012-01-30 | 2012-01-30 | Treating of catalyst support |
PCT/GB2013/050193 WO2013114098A1 (en) | 2012-01-30 | 2013-01-29 | Treating of catalyst carrier, fischer - tropsch catalysts and method of preparation thereof |
Publications (3)
Publication Number | Publication Date |
---|---|
GB201415360D0 GB201415360D0 (en) | 2014-10-15 |
GB2518525A true GB2518525A (en) | 2015-03-25 |
GB2518525B GB2518525B (en) | 2018-09-26 |
Family
ID=45876376
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB1201619.2A Ceased GB201201619D0 (en) | 2011-02-07 | 2012-01-30 | Treating of catalyst support |
GB1415360.5A Active GB2518525B (en) | 2012-01-30 | 2013-01-29 | Treating of catalyst support |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB1201619.2A Ceased GB201201619D0 (en) | 2011-02-07 | 2012-01-30 | Treating of catalyst support |
Country Status (6)
Country | Link |
---|---|
US (1) | US9656247B2 (en) |
AU (1) | AU2013203123B2 (en) |
CA (1) | CA2862224C (en) |
DE (1) | DE112013000754T5 (en) |
GB (2) | GB201201619D0 (en) |
WO (1) | WO2013114098A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201214122D0 (en) * | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
EP2941409B1 (en) * | 2013-01-07 | 2023-03-08 | Nitto Denko Corporation | Method for forming an oxide coated substrate |
GB2544210B (en) * | 2014-07-16 | 2020-10-21 | Velocys Tech Ltd | Cobalt-containing fischer-tropsch catalysts, methods of making, and methods of conducting fischer-tropsch synthesis |
PE20171664A1 (en) | 2015-02-25 | 2017-11-15 | Sasol Tech (Pty) Limited | HYDROCARBON SYNTHESIS PROCESS |
CA3028590C (en) | 2016-08-11 | 2021-08-03 | Sasol South Africa Limited | A cobalt-containing catalyst composition |
KR101840378B1 (en) * | 2016-11-09 | 2018-03-21 | 한국화학연구원 | Catalyst for olefin metathesis and method for preparing thereof |
EP3551327B1 (en) | 2016-12-09 | 2022-02-16 | Velocys Technologies Limited | Process for operating a highly productive tubular reactor |
EP3513872A1 (en) | 2018-01-22 | 2019-07-24 | SASOL Germany GmbH | Catalyst support comprising homogeneously distributed titanium dioxide and method for production |
US11110438B2 (en) | 2018-07-31 | 2021-09-07 | Board Of Regents, The University Of Texas System | Methods for preparation and use of liquid synthesis catalysts |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5397806A (en) * | 1991-11-14 | 1995-03-14 | Exxon Research & Engineering Co. | Method for stabilizing titania supported cobalt catalyst (C-2715) |
WO2001083108A1 (en) * | 2000-05-04 | 2001-11-08 | Shell Internationale Research Maatschappij B.V. | A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst |
US20020098977A1 (en) * | 2000-11-28 | 2002-07-25 | Korea Research Institute Of Chemical Technology | Titania photocatalyst and its preparing method |
US20050026776A1 (en) * | 2003-07-29 | 2005-02-03 | Muneyoshi Yamada | Preparation method of catalysts for fischer-tropsch synthesis |
WO2007068731A1 (en) * | 2005-12-16 | 2007-06-21 | Shell Internationale Research Maatschappij B.V. | Process for preparing a hydrocarbon synthesis catalyst |
WO2009055013A2 (en) * | 2007-10-26 | 2009-04-30 | Exxonmobil Research And Engineering Company | Cobalt catalyst with improved activity maintenance |
JP2009219980A (en) * | 2008-03-14 | 2009-10-01 | Babcock Hitachi Kk | Catalyst for removing nitrogen oxide and its manufacturing method |
US20090293359A1 (en) * | 2008-04-09 | 2009-12-03 | Simmons Wayne W | Process for upgrading a carbonaceous material using microchannel process technology |
US20090305881A1 (en) * | 2005-12-21 | 2009-12-10 | Johnson Matthey Plc | Metal nitrate conversion method |
WO2010097754A2 (en) * | 2009-02-26 | 2010-09-02 | Sasol Technology (Proprietary) Limited | Catalysts |
US20110028575A1 (en) * | 2008-04-15 | 2011-02-03 | Sasol Technology (Proprietary) Limited | Catalysts |
WO2012107718A2 (en) * | 2011-02-07 | 2012-08-16 | Oxford Catalysts Limited | Catalysts |
Family Cites Families (9)
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US5863856A (en) * | 1997-04-22 | 1999-01-26 | Exxon Research And Engineering Company | Preparation of high activity catalysts the catalysts and their use |
GB0222240D0 (en) * | 2002-09-25 | 2002-10-30 | Ici Plc | Cobalt catalysts |
US7084180B2 (en) | 2004-01-28 | 2006-08-01 | Velocys, Inc. | Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
MY142111A (en) | 2004-04-16 | 2010-09-15 | Nippon Oil Corp | Catalyst for fischer-tropsch synthesis and process for producing hydrocarbons |
US7449423B2 (en) * | 2005-01-14 | 2008-11-11 | Headwaters Technology Innovation, Llc | Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method |
US7820725B2 (en) | 2006-09-05 | 2010-10-26 | Velocys, Inc. | Integrated microchannel synthesis and separation |
GB0704003D0 (en) | 2007-03-01 | 2007-04-11 | Oxford Catalysts | Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof |
CA2719382C (en) | 2008-04-09 | 2019-02-26 | Velocys Inc. | Process for upgrading a carbonaceous material using microchannel process technology |
US8668961B2 (en) | 2008-07-31 | 2014-03-11 | Guardian Industries Corp. | Titania coating and method of making same |
-
2012
- 2012-01-30 GB GBGB1201619.2A patent/GB201201619D0/en not_active Ceased
-
2013
- 2013-01-29 DE DE112013000754.1T patent/DE112013000754T5/en active Pending
- 2013-01-29 CA CA2862224A patent/CA2862224C/en active Active
- 2013-01-29 WO PCT/GB2013/050193 patent/WO2013114098A1/en active Application Filing
- 2013-01-29 GB GB1415360.5A patent/GB2518525B/en active Active
- 2013-01-29 AU AU2013203123A patent/AU2013203123B2/en not_active Ceased
- 2013-01-29 US US14/373,920 patent/US9656247B2/en active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
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US5397806A (en) * | 1991-11-14 | 1995-03-14 | Exxon Research & Engineering Co. | Method for stabilizing titania supported cobalt catalyst (C-2715) |
WO2001083108A1 (en) * | 2000-05-04 | 2001-11-08 | Shell Internationale Research Maatschappij B.V. | A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst |
US20020098977A1 (en) * | 2000-11-28 | 2002-07-25 | Korea Research Institute Of Chemical Technology | Titania photocatalyst and its preparing method |
US20050026776A1 (en) * | 2003-07-29 | 2005-02-03 | Muneyoshi Yamada | Preparation method of catalysts for fischer-tropsch synthesis |
WO2007068731A1 (en) * | 2005-12-16 | 2007-06-21 | Shell Internationale Research Maatschappij B.V. | Process for preparing a hydrocarbon synthesis catalyst |
US20090305881A1 (en) * | 2005-12-21 | 2009-12-10 | Johnson Matthey Plc | Metal nitrate conversion method |
WO2009055013A2 (en) * | 2007-10-26 | 2009-04-30 | Exxonmobil Research And Engineering Company | Cobalt catalyst with improved activity maintenance |
JP2009219980A (en) * | 2008-03-14 | 2009-10-01 | Babcock Hitachi Kk | Catalyst for removing nitrogen oxide and its manufacturing method |
US20090293359A1 (en) * | 2008-04-09 | 2009-12-03 | Simmons Wayne W | Process for upgrading a carbonaceous material using microchannel process technology |
US20110028575A1 (en) * | 2008-04-15 | 2011-02-03 | Sasol Technology (Proprietary) Limited | Catalysts |
WO2010097754A2 (en) * | 2009-02-26 | 2010-09-02 | Sasol Technology (Proprietary) Limited | Catalysts |
WO2012107718A2 (en) * | 2011-02-07 | 2012-08-16 | Oxford Catalysts Limited | Catalysts |
Non-Patent Citations (1)
Title |
---|
HINCHIRANAN ET AL: "TiO2 promoted Co/SiO2 catalysts for Fischer-Tropsch synthesis", FUEL PROCESSING TECHNOLOGY, ELSEVIER BV, NL, vol. 89, no. 4, 11 December 2007 (2007-12-11), pages 455-459, XP022540761, ISSN: 0378-3820, DOI: 10.1016/J.FUPROC.2007.11.007 * |
Also Published As
Publication number | Publication date |
---|---|
AU2013203123B2 (en) | 2015-12-17 |
CA2862224C (en) | 2021-01-05 |
CA2862224A1 (en) | 2013-08-08 |
GB201201619D0 (en) | 2012-03-14 |
WO2013114098A1 (en) | 2013-08-08 |
US20150018439A1 (en) | 2015-01-15 |
US9656247B2 (en) | 2017-05-23 |
GB2518525B (en) | 2018-09-26 |
DE112013000754T5 (en) | 2015-03-19 |
AU2013203123A1 (en) | 2013-08-15 |
GB201415360D0 (en) | 2014-10-15 |
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