GB2460818A - Composition for treating a concrete surface comprising a metal silicate and a metal siliconate - Google Patents
Composition for treating a concrete surface comprising a metal silicate and a metal siliconate Download PDFInfo
- Publication number
- GB2460818A GB2460818A GB0808141A GB0808141A GB2460818A GB 2460818 A GB2460818 A GB 2460818A GB 0808141 A GB0808141 A GB 0808141A GB 0808141 A GB0808141 A GB 0808141A GB 2460818 A GB2460818 A GB 2460818A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- composition according
- siliconate
- concrete
- silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 239000004567 concrete Substances 0.000 title claims abstract description 50
- 125000005625 siliconate group Chemical group 0.000 title claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 10
- 239000002184 metal Substances 0.000 title claims abstract description 10
- 229910052914 metal silicate Inorganic materials 0.000 title claims abstract description 5
- 239000002562 thickening agent Substances 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims abstract description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- 239000004111 Potassium silicate Substances 0.000 claims description 5
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 5
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical group [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 5
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000011343 solid material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 19
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 238000006253 efflorescence Methods 0.000 abstract description 5
- 206010037844 rash Diseases 0.000 abstract description 5
- 241000195493 Cryptophyta Species 0.000 abstract description 3
- 150000001340 alkali metals Chemical class 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 238000010186 staining Methods 0.000 abstract description 2
- 239000000725 suspension Substances 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- -1 alkali metal salt Chemical class 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000013201 Stress fracture Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
- C04B41/5089—Silica sols, alkyl, ammonium or alkali metal silicate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
- C04B41/4938—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane containing silicon bound to hydroxy groups, e.g. trimethyl silanol
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/65—Coating or impregnation with inorganic materials
- C04B41/68—Silicic acid; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/21—Efflorescence resistance
Abstract
The composition comprises a soluble metal silicate, a metal siliconate and a thickening agent. In addition a pigment can be included, for example as a solid in suspension. Examples of said pigment are titanium dioxide or iron(III) oxide. The metal silicate can be selected from an alkali metal silicate and be present in an amount from 20-30% w/w of the composition. The siliconate can similarly be that of an alkali metal and be present up to 5% w/w of the mass of the dried coating. The siliconate, when the composition is dried aids water repellency of the coating. Thickening agents, present from 2-5% w/w of the composition are added to aid even spreading and retention on a surface. The composition when applied to the surface of concrete and reduces efflorescence, maintains concrete strength and reduces staining and growth of algae or lichen.
Description
A COMPOSITION FOR THE TREATMENT OF CONCRETE
Field of the Invention
The present invention is concerned with a composition for use in the treatment of concrete. In particular, the composition disclosed are intended to be spreadable, for example by a brush, roller or the like.
Background to the Invention
The prevalence of concrete products is easy to discern. The reasons for this overall presence are due to the relatively low cost of concrete, its inherent strength and its capacity to be cast into virtually any shape required. Concrete is therefore used in paving, walls and as a support medium for buildings, particularly where strengthened by steel strengthenrng members.
Concrete does however have a number of disadvantages both of a technical nature and an aesthetic nature. Firstly, concrete suffers from a problem commonly known as efflorescence. Efflorescence is discernible on the surface of concrete as a powdery deposit, sometime slightly lighter in colour than the main body of concrete. The problem arises due to water penetration into the concrete through faults in the structure, which water then dissolves soluble salts such as calcium sulphate from the concrete.
As the water and the salts then seep onto the surface of the concrete, the water evaporates leaving the salt behind on the surface. The efflorescence is not only unsightly in itself, but continual removal of the salts from the concrete can lead to weakening of the concrete, with replacement being eventually required.
Secondly, concrete is easily stained by, that is absorbs fairly readily into its surface layers, oil-based products. Two applications where this is especially undesirable are firstly where the concrete is likely to come into contact with such materials: for example on a garage forecourt or on a driveway used to park a vehicle. Oil from vehicles, with time causes a dark stain to become evident, which stain can only be removed with difficulties. Also, the writing of graffiti on the side of a building is often carried out usmg oil-based paints and this makes satisfactory removal of the graffiti problematic: especially without causing damage to the wall or removing an upper layer.
A third disadvantage lies in the aesthetics associated with concrete colour which, if not altered in any way is a grey colour of darker or lighter hue. Coloured concretes are available, in which a colouring agent is mixed in with the liquid pre-concrete mix.
However, the colours applied are themselves not usually especially appealing, being designed to disguise the concrete as a different type of stone.
As is also well known, concrete can also suffer relatively easily from discolouration due to organic growth such as algae or lichen. This problem is particularly acute for concrete paths. A part of the problem lies in the inherent hydrophilicity of the silicates in the concrete which result in a layer of water being bound to the concrete's surface for a longer time than would otherwise be the case. This, together with salts within the concrete leaching to the surface, provides an environment for organic growth causing the well known green discolouration, which is difficult to remove fully.
The prior art discloses a number of ways to address certain of the above problems.
For example stains are provided which penetrate the upper layers of the concrete providing a degree of colour. However, partially in order to provide the colour partially to assist the staining process and also to prevent organic growth, the stains are often relatively acidic or contain salts of toxic heavy metals. These render the stains unsuitable for many applications as the acids or metals can be easily leached into the surrounding area.
It is an object of the current invention to address the above problems and provide a composition which can be easily applied to a concrete surface to protect and to enhance the appearance.
Summaryof the Invention
According to a first aspect of the invention, there is provided a liquid composition for the treatment of a concrete surface, the composition comprising: a soluble metal silicate; a metal siliconate; and a thickening agent.
The composition thus provided enables a coating to be applied to the surface of a concrete object, which coating is hydrophobic and so resists water building up on or penetration into the concrete. Damage to the concrete is thereby reduced.
Optionally, the composition includes a pigment enabling concrete objects to be rendered more aesthetically pleasing and also covering up surface markings on the concrete. The pigment is further optionally a solid material, suspended in the composition Yet further optionally, the pigment is selected from titanium dioxide or iron (III) oxide. Still yet further optionally, the pigment is present in an amount of from 5 -l5%w/w of the composition The silicate is preferably present in an amount from 20 -30%w/w of the composition Particularly preferably, the silicate is an alkali metal silicate to facilitate dissolution of the silicate in the composition Especially preferably, the silicate is potassium silicate, and conveniently Ki 20 or K66. The former of these has a mean weight ratio of Si02:K20 of 1.43, a mean K20 content of 21.6%w/w and Si02 content of 30.8%w/w. The latter has a mean weight ratio of Si02:K20 of 1.33, a mean K20 content of 11.4%w/w and a mean Si02 content of 23.3&w/w.
The metal siliconate is optionally present up to a level of 5%wlw to provide sufficient hydrophobicity in the dried coating. The metal siliconate is further optionally an alkali metal siliconate to facilitate dissolution of the siliconate in the composition.
Still yet further optionally the cation is potassium.
Preferably, the thickener is an inverse emulsion thickener, and is further preferably present in an amount of from 2 -5%w/w of the chosen composition. The thickener is particularly preferably Decal' 1200.
Detailed Description of the Invention
The compositions as herein described are aqueous based liquids and have in general a viscosity greater than that of water which enables the compositions to be spread evenly across a surface. It is also envisaged that the compositions have a degree of thixotropy to retain them in position during the drying process.
Preparation of the compositions is by means of known methodology, to form emulsions and suspensions. Care must be taken during the preparation that hydration and dissolution of the soluble constituents is carried out correctly and that too rapid hydration of the outer regions of particles does not take place leaving a core of relatively dry material.
In order to improve the aesthetic appearance of concrete the compositions can include a colouring agent, distributed evenly throughout its volume. The colouring agent can be dissolved in the aqueous phase of the composition, which allows the colouring agent to be readily evenly distributed and which is unlikely to settle during storage.
Alternatively, colouring agent present in solid form can be employed. For example white titanium dioxide can be used or red iron(ffi) oxide. When using a solid material, the correct particle size needs to be selected to facilitate composition make up and stability. Typically the colouring agent is present in an amount from 5 - 15%w/w of the composition.
One important aspect of the compositions disclosed herein is the property of preventing water penetration into the body of the concrete and also from remaining on the surface for too long a time. The former property prevents serious damage being done to concrete through the presence of water in the interior. Water on the inside can cause a number of problems. Firstly, during cold weather, the water can freeze and in so doing expands, causing stress fractures within the concrete. Secondly, the water can dissolve certain soluble components from the concrete, which can be carried out of the concrete as the water seeps back out. This seepage not only leads to deposits of the salts on the surface of the concrete, known as efflorescence, but can also lead to weakening and ultimately catastrophic failure of the mechanical properties of the concrete.
In order to prevent the entry of water therefore, the composition includes a hydrophobic component. On drying, following application of the composition, the hydrophobic component repels water and prevents it from entering the concrete.
Additionally, water does not spread out so easily across a hydrophobic surface and so water build up is reduced. The drier conditions on the surface of the concrete prevent or slow down the growth of algae, lichen or other organisms on the concrete, which organisms can cause unsightly markings on the concrete and which can be slippery when wet.
In the present compositions the hydrophobic component is a siliconate, preferably an alkali metal salt or mixture of alkali metal salts of the siliconate. The use of an alkali metal salt at least simplifies the dissolution of the hydrophobic siliconate in the aqueous compositions. Of the alkali metals, the potassium salt is preferred as it is more hydrophobic than the sodium salt. Levels of up to 5%w/w of potassium siliconate have been found to be effective.
In order to enable the compositions to have the correct flow characteristics, a thickening agent is included. The compositions need firstly to be sufficiently viscous so that they can be spread easily across a surface to yield a good coat. Secondly, the compositions are advantageously thixotropic to minimise their flow once they have been applied. This is especially of advantage when the coating is on a vertical surface. The thickening agent can be an inverse emulsion thickener such as Decal 1200, available from Devine Chemicals. Levels of from 2 -5%w/w of the composition have been found to be effective.
Silicate is included in the compositions to adjust the pH of the compositions and also because of the compatibility of silicates with concrete. The silicate also acts to an extent as a viscosity moderator, raising the viscosity above that of water. Silicates are therefore added in an amount of from 20 -30 %w/w of the composition. In order to enable sufficient silicate to be used, the silicate is selected to be an alkali metal silicate and preferably potassium silicate. As examples of silicates which are suitable are those marketed under the designations K120 and 1(66.
It will of course be understood that the invention is not limited to the specific details described herein, which are given by way of example only, and that various modifications and alterations are possible within the scope of the invention.
Claims (9)
- CLAIMS1. A liquid composition for the treatment of a concrete surface, the composition comprising: a soluble metal silicate; a metal siliconate; and a thickening agent.
- 2. A composition according to Claim 1, wherein the composition includes a pigment.
- 3. A composition according to Claim 2 wherein the pigment is a solid material, suspended in the composition
- 4. A composition according to Claim 2 or Claim 3, wherein the pigment is selected from titanium dioxide or iron (III) oxide.
- 5. A composition according to Claim 2-4 wherein the pigment is present in an amount of from 5 -I 5%w/w of the composition.
- 6. A composition according to any preceding claim, wherein the silicate is present in an amount from 20-30%w/w of the composition.
- 7. A composition according to any preceding claim, wherein the silicate is an alkali metal silicate.
- 8. A composition according to Claim 7, wherein the silicate is potassium silicate.
- 9. A composition according to Claim 8, wherein the potassium silicate has a * mean weight ratio of Si02:K20 of 1.43, a mean K20 content of 21.6%w/w and Si02 content of 30.8%w/w. *S*. * S *S.S10. A composition according to Claim 8, wherein the potassium silicate has a **.: 35 mean weight ratio of Si02:K20 of 1.33, a mean K20 content of 11.4%w/w and ameanSiO2 content of 23.3%w/w. *. * * S * a a.11. A composition according to any preceding claim, wherein the metal siliconate is present up to a level of 5%w/w.12. A composition according to any preceding metal siliconate is a claim, wherein the metal siliconate is an alkali metal siliconate.13. A composition according to Claim 12, wherein the siliconate is a potassium siliconate.14. A composition according to any preceding claim, wherein the thickener is an inverse emulsion thickener.15. A composition according to Claim 14, wherein the thickener is present in an amount of from 2 -5%wlw of the chosen composition.16. A composition according to Claim 15, wherein the thickener is Decal 1200.17. A composition substantially as herein described. * .* * * * * S. * S * S..S. S 35 * * S * S. * ***.SS * S 5 * S* S *S
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0808141A GB2460818A (en) | 2008-05-06 | 2008-05-06 | Composition for treating a concrete surface comprising a metal silicate and a metal siliconate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0808141A GB2460818A (en) | 2008-05-06 | 2008-05-06 | Composition for treating a concrete surface comprising a metal silicate and a metal siliconate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB0808141D0 GB0808141D0 (en) | 2008-06-11 |
| GB2460818A true GB2460818A (en) | 2009-12-16 |
Family
ID=39537284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB0808141A Withdrawn GB2460818A (en) | 2008-05-06 | 2008-05-06 | Composition for treating a concrete surface comprising a metal silicate and a metal siliconate |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2460818A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1424101A (en) * | 1972-05-23 | 1976-02-11 | Wacker Chemie Gmbh | Rendering surfaces hydrophobic |
| GB1493478A (en) * | 1974-10-09 | 1977-11-30 | Chollet J | Silicate-containing flame-resistant adhesive composition |
| US20020034650A1 (en) * | 2000-07-19 | 2002-03-21 | Neely James E. | Curable coating compositions |
| WO2005118726A1 (en) * | 2004-06-04 | 2005-12-15 | Sto Ag | Coating composition |
| DE102005040965A1 (en) * | 2005-08-25 | 2007-03-08 | Reinhardt Beton Gmbh | Surface treatment of mineral substance e.g. for private and public traffic area, highway, building exterior or safety floor uses 2-stage treatment with substances forming silicic acid in pores and on surface and added mineral particles |
-
2008
- 2008-05-06 GB GB0808141A patent/GB2460818A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1424101A (en) * | 1972-05-23 | 1976-02-11 | Wacker Chemie Gmbh | Rendering surfaces hydrophobic |
| GB1493478A (en) * | 1974-10-09 | 1977-11-30 | Chollet J | Silicate-containing flame-resistant adhesive composition |
| US20020034650A1 (en) * | 2000-07-19 | 2002-03-21 | Neely James E. | Curable coating compositions |
| WO2005118726A1 (en) * | 2004-06-04 | 2005-12-15 | Sto Ag | Coating composition |
| DE102005040965A1 (en) * | 2005-08-25 | 2007-03-08 | Reinhardt Beton Gmbh | Surface treatment of mineral substance e.g. for private and public traffic area, highway, building exterior or safety floor uses 2-stage treatment with substances forming silicic acid in pores and on surface and added mineral particles |
Also Published As
| Publication number | Publication date |
|---|---|
| GB0808141D0 (en) | 2008-06-11 |
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