GB2224743A - Glass cleaning preparation - Google Patents

Glass cleaning preparation Download PDF

Info

Publication number
GB2224743A
GB2224743A GB8826338A GB8826338A GB2224743A GB 2224743 A GB2224743 A GB 2224743A GB 8826338 A GB8826338 A GB 8826338A GB 8826338 A GB8826338 A GB 8826338A GB 2224743 A GB2224743 A GB 2224743A
Authority
GB
United Kingdom
Prior art keywords
preparation
glass cleaning
calcium carbonate
glass
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8826338A
Other versions
GB8826338D0 (en
GB2224743B (en
Inventor
Hermann Joseph Huber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Trico Ltd
Original Assignee
Trico Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Trico Ltd filed Critical Trico Ltd
Priority to GB8826338A priority Critical patent/GB2224743B/en
Publication of GB8826338D0 publication Critical patent/GB8826338D0/en
Priority to DE68921417T priority patent/DE68921417T2/en
Priority to ES89311337T priority patent/ES2071662T3/en
Priority to EP89311337A priority patent/EP0368559B1/en
Priority to AR89315386A priority patent/AR243927A1/en
Priority to JP1288945A priority patent/JP2701077B2/en
Priority to ZA898505A priority patent/ZA898505B/en
Priority to NZ231341A priority patent/NZ231341A/en
Priority to KR1019890016290A priority patent/KR900008028A/en
Priority to AU44603/89A priority patent/AU618148B2/en
Priority to BR898905766A priority patent/BR8905766A/en
Publication of GB2224743A publication Critical patent/GB2224743A/en
Application granted granted Critical
Publication of GB2224743B publication Critical patent/GB2224743B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013Liquid compositions with insoluble particles in suspension
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads

Description

1 GLASS CLEANING PREPARATION 2224743 This invention relates to a glass
cleaning preparation and more particularly to a preparation for cleaning the 5 windscreens of motor or like vehicles.
In motor vehicles, the ability to see clearly through the windscreen is critical not only for the safety of the driver and his passengers but also for the safety of other road users. For this reason, all motor vehicles travelling on public highways are fitted with windscreen wipers whose Job is to clear the windscreen of any rain thereon and, to a limited extent, with the help of washers, to remove mud and grime from the windscreen.
is However, for the windscreen wipers to work satisfactorily, it is essential that grease and other matter which sticks to the windscreen be removed at regular intervals as otherwise the wipe becomes streaky and visibility is impaired.
There are a number of glass cleaning preparations on the market with generally non specialised application.
0 However, they are far from satisfactory for a number of reasons. For example, many glass cleaning compositions are good at cleaning glass such as house windows, but they leave a surface coating on the glass which interferes with the correct operation of the windscreen wipers. Other preparations require to be washed off after use or dry in such a way as to leave smears on the glass.
This invention seeks to provide a glass cleaning preparation in which some or all of the above disadvantages are removed or substantially reduced and which is eminently suitable for cleaning the windscreens 1 2 of motor and like vehicles.
According to the invention, a glass cleaning preparation comprises a light abrasive, finely divided silica, water and alcohol in proportions suitable to produce a cream and a wetting agent.
The finely divided silica may be fumed, precipitated or in colloidal form.
Preferably, the light abrasive comprises calcium carbonate in precipitated form suitably in the form known commercially as "light calcium carbonate". The alcohol is preferably ethanol but may suitably include methanol and isopropanol. The wetting agent may be propylene glycol- ethylene glycol fatty alcohol polymer.
In a particular formulation of the glass cleaning preparation in accordance with the invention, the preparation comprises, by weight, 4 17% precipitated calcium carbonate, 1. 7 - 6% fumed silica, 47 - 77% water, 8 - 38% ethanol and 0.5 - 4% wetting agent.
The invention will now be described in greater detail by way of example.
In a particular example of a batch of glass cleaning preparation, the preparation comprised:- 100 Sm.
SM. 800 cc. 250 cc.
24 cc.
polymer calcium carbonate (light) fumed silica water ethanol propylene glycol- ethylene glycol fatty alcohol 3 To formulate the preparation, 50 Sm. fumed silica powder was placed in a mixing vessel to which 800 cc. water was then added. The contents of the mixing vessel were stirred to a smooth creamy consistency. Then the calcium carbonate powder was added to the mixing vessel and the contents were again stirred to a smooth creamy consistency.
At this point, 250 cc. ethanol and 24 cc. propylene 10 glycol-ethylene glycol fatty alcohol polymer were added as a mixture and the the final preparation was again stirred to a smooth consistency. The preparation was then ready for bottling.
The proportions used could suitably be varied in the ranges:- 50-200 Sm. calcium carbonate 20-70 gm, fumed silica 6 -48 cc. propylene glycol-ethylene glycol fatty alcohol polymer The amount of water and ethanol used would depend on the amount of powder present, the liquid being in sufficient quantities to provide a creamy smooth substance. While it is desirable that the ratio of ethanol to water should be of the order of 5: 16 parts by volume, this ratio could be varied over a wide range, e.g. between 1: 8 and 1: 1.
Other alcohols may be used instead of ethanol, for example methanol and isopropanol. The finely divided silica could be obtained by precipitation or used in colloidal form, Other forms of calcium carbonate, such as heavy chalk, could be used. Talc, Kaolin or other suitable light abrasives may be used instead of the 4 calcium carbonate. Other wetting agents could be used, but these should all be low foaming.
In use, the glass cleaning preparation above described 5 may suitably be dispensed directly onto the windscreen to be cleaned from a squeeze bottle. The preparation is rubbed into the glass with a tissue or soft cloth and allowed to dry. After a short time a residual dry powder is left and this can be removed by wiping with a soft dry cloth leaving a clean dry windscreen.
In the action of the material, the calcium carbonate and the fumed silica provide a light abrasive action. The fumed silica, which is a thixotropic material, acts to adhere the preparation to the glass and prevent it from running off before it has been rubbed in. The water and ethanol enable the ingredients to be emulsified into a smooth cream, the ratio of the two determining the drying time required after application.
The use of a 20 wetting agent ensures that no residue of the preparation is left adhered to the screen.
While the above preparation has been particularly formulated for windscreen cleaning, it will be understood that it is equally suitable for cleaning other glass surfaces.
f 1 1 f C L A i MES7 1. A glass cleaning preparation comprising a light abrasive, finely divided silica, water and alcohol in proportions suitable to produce a cream and a wetting agent.
2. A preparation as claimed in claim 1, wherein the finely divided silica is fumed.
3. A preparation as claimed in claim 1, finely divided silica is precipitated.
wherein the 4. A preparation as claimed in claim 1, wherein the 15 finely divided silica is in colloidal form.
5. A preparation as claimed in any one of clalms 1 to 4, wherein the light abrasive comprises calcium (:ar:),Dnate Jtated form.
in precip 6. A preparation ae claimed in claim 5, wherein tIhe calcium carbonate is in the form known commercially as "light calcium carbonate".
7. A preparation as claimed in any one of claims I to 6, wherein the alcohol is ethanol.
8. A preparation as claimed in any preceding claim, wherein the alcohol includes methanol and/or isopropanol.
9. A preparation as claimed in any preceding claim, wherein the wetting agent may be propylene glycolethylene glycol fatty alcohol polymer.
6 10. A preparation as claimed in claim 1, wherein the preparation comprises, by weight, 4 - 17% precipitated calcium carbonate, 1. 7 - 6% fumed silica, 4 7 - 7 7% water, 8 - 38% ethanol and 0.5 - 4% wetting agent.
11.. A preparation as claimed in claim 1, wherein the preparation has the following proportionate values:- gm. calcium carbonate (light) 10 50 gm. fumed silica 800 cc. water 250 cc. ethanol 24 cc. propylene glycol-ethylene glycol fatty alcohol polymer tion substantially as 12. A glass cleaning preparat described herein with reference to the examples.
Pubhshed 1990 atThe Patent Office, State House, 66,171 Hig Holborn, London WC1R4TP. Further copiesmaybe obtainedfrom The Patent OfficeSales Branch, St Mary Cray, Orpington, Kent BR5 3RD. Printed by Multiplex techniques ltd. St Mary Cray. Kent, Con- 1187
GB8826338A 1988-11-10 1988-11-10 Glass cleaning preparation Expired - Fee Related GB2224743B (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
GB8826338A GB2224743B (en) 1988-11-10 1988-11-10 Glass cleaning preparation
DE68921417T DE68921417T2 (en) 1988-11-10 1989-11-02 Glass cleaner.
ES89311337T ES2071662T3 (en) 1988-11-10 1989-11-02 PREPARED FOR GLASS CLEANING.
EP89311337A EP0368559B1 (en) 1988-11-10 1989-11-02 Glass cleaning preparation
AR89315386A AR243927A1 (en) 1988-11-10 1989-11-07 A preparation for cleaning vehicle windows.
ZA898505A ZA898505B (en) 1988-11-10 1989-11-08 Glass cleaning preparation
JP1288945A JP2701077B2 (en) 1988-11-10 1989-11-08 Glass cleaner
NZ231341A NZ231341A (en) 1988-11-10 1989-11-09 Glass cleaning preparation especially for motor vehicle windscreens
KR1019890016290A KR900008028A (en) 1988-11-10 1989-11-10 Glass cleaner
AU44603/89A AU618148B2 (en) 1988-11-10 1989-11-10 Glass cleaning preparation
BR898905766A BR8905766A (en) 1988-11-10 1989-11-10 PREPARATION FOR GLASS CLEANING

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8826338A GB2224743B (en) 1988-11-10 1988-11-10 Glass cleaning preparation

Publications (3)

Publication Number Publication Date
GB8826338D0 GB8826338D0 (en) 1988-12-14
GB2224743A true GB2224743A (en) 1990-05-16
GB2224743B GB2224743B (en) 1992-02-19

Family

ID=10646656

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8826338A Expired - Fee Related GB2224743B (en) 1988-11-10 1988-11-10 Glass cleaning preparation

Country Status (11)

Country Link
EP (1) EP0368559B1 (en)
JP (1) JP2701077B2 (en)
KR (1) KR900008028A (en)
AR (1) AR243927A1 (en)
AU (1) AU618148B2 (en)
BR (1) BR8905766A (en)
DE (1) DE68921417T2 (en)
ES (1) ES2071662T3 (en)
GB (1) GB2224743B (en)
NZ (1) NZ231341A (en)
ZA (1) ZA898505B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020041880A (en) * 2000-11-29 2002-06-05 이을규 Glass cleaning or etching composition and treatment method for alternative using hydrogen fluoride
DE10061897A1 (en) 2000-12-12 2002-06-13 Clariant Gmbh Washing or cleaning composition, useful for fabrics or hard surfaces, contains microdisperse, hydrophilic silicate particles that improve soil removal and prevent resoiling
FR2825272B1 (en) * 2001-05-31 2003-08-08 Oreal COSMETIC COMPOSITION COMPRISING SILICATE PARTICLES IN AN OIL-IN-WATER EMULSION TYPE SUPPORT
WO2014043669A1 (en) * 2012-09-17 2014-03-20 Richard Darrow White carbon black formulations and methods

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1370377A (en) * 1971-11-15 1974-10-16 Procter & Gamble Ltd Composition and method for cleaning hard surfaces
GB1459342A (en) * 1973-06-15 1976-12-22 Du Pont Cleaning composition
GB1511930A (en) * 1976-04-01 1978-05-24 Rialdi G Compositions for the treatment of glass surfaces
WO1983002624A1 (en) * 1982-01-22 1983-08-04 Western Electric Co Detergent cleaning composition
GB2153838A (en) * 1984-02-13 1985-08-29 Kao Corp Liquid abrasive detergent composition
GB2181738A (en) * 1985-10-16 1987-04-29 Kao Corp Liquid abrasive detergent composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1471278A (en) * 1973-07-06 1977-04-21 Colgate Palmolive Co Liquid abrasive compositions
EP0030986A1 (en) * 1979-12-24 1981-07-01 THE PROCTER & GAMBLE COMPANY Abrasive-containing, built liquid detergent composition
JPS6060197A (en) * 1983-09-12 1985-04-06 ジヨンソン株式会社 Oil film remover for glass surface
JPS60133100A (en) * 1983-12-22 1985-07-16 株式会社井上化学研究所 Detergent composition for automobile window glass

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1370377A (en) * 1971-11-15 1974-10-16 Procter & Gamble Ltd Composition and method for cleaning hard surfaces
GB1459342A (en) * 1973-06-15 1976-12-22 Du Pont Cleaning composition
GB1511930A (en) * 1976-04-01 1978-05-24 Rialdi G Compositions for the treatment of glass surfaces
WO1983002624A1 (en) * 1982-01-22 1983-08-04 Western Electric Co Detergent cleaning composition
GB2153838A (en) * 1984-02-13 1985-08-29 Kao Corp Liquid abrasive detergent composition
GB2181738A (en) * 1985-10-16 1987-04-29 Kao Corp Liquid abrasive detergent composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP60133100 A JP60060197 A *

Also Published As

Publication number Publication date
DE68921417D1 (en) 1995-04-06
AR243927A1 (en) 1993-09-30
EP0368559A2 (en) 1990-05-16
AU618148B2 (en) 1991-12-12
JPH02218799A (en) 1990-08-31
NZ231341A (en) 1992-01-29
KR900008028A (en) 1990-06-02
JP2701077B2 (en) 1998-01-21
EP0368559A3 (en) 1990-12-05
EP0368559B1 (en) 1995-03-01
ES2071662T3 (en) 1995-07-01
BR8905766A (en) 1990-06-05
GB8826338D0 (en) 1988-12-14
GB2224743B (en) 1992-02-19
AU4460389A (en) 1990-05-17
ZA898505B (en) 1990-11-28
DE68921417T2 (en) 1995-10-12

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20061110