GB2212261A - Water contaminant meter - Google Patents

Water contaminant meter Download PDF

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Publication number
GB2212261A
GB2212261A GB8726085A GB8726085A GB2212261A GB 2212261 A GB2212261 A GB 2212261A GB 8726085 A GB8726085 A GB 8726085A GB 8726085 A GB8726085 A GB 8726085A GB 2212261 A GB2212261 A GB 2212261A
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GB
United Kingdom
Prior art keywords
light
contaminant
cell
water
meter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8726085A
Other versions
GB8726085D0 (en
GB2212261B (en
Inventor
Peter George Hale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STC PLC
Original Assignee
STC PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by STC PLC filed Critical STC PLC
Priority to GB8726085A priority Critical patent/GB2212261B/en
Publication of GB8726085D0 publication Critical patent/GB8726085D0/en
Publication of GB2212261A publication Critical patent/GB2212261A/en
Application granted granted Critical
Publication of GB2212261B publication Critical patent/GB2212261B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/47Scattering, i.e. diffuse reflection
    • G01N21/49Scattering, i.e. diffuse reflection within a body or fluid
    • G01N21/53Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke
    • G01N21/532Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke with measurement of scattering and transmission
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N2021/3129Determining multicomponents by multiwavelength light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/08Optical fibres; light guides
    • G01N2201/084Fibres for remote transmission

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

In a water contaminant meter, e.g. for oil in water measurement, light signals transmitted through the water and light signals scattered by the contaminant are multiplexed on to a single optical path 21 for transmission to a detector/analyser 22. A light source 14 generates a plurality of different wavelengths simultaneously or sequentially. Optical filters 16, 17 are associated respectively with the transmitted and scattered light. In a modification, the filters 16, 17 and separate optical fibres 18, 19 are replaced by a graded index optical filter, a transparent body, and a reflector. <IMAGE>

Description

WATER CONTAMINATION METEr This invention relates to instruments for the detection and measurement of contamination -n water.
Our published UK specification No. i556029 (G.D. Pitt - H.J. Smith 19-4).describes and claims on oil in water detector arrangement, including a cell in through which the water is allowed to flow, a semiconductor laser operable in the inf ra-red region of the spectrum and coupled to one side of the cell, and one or more photodetectors arranged at an angle to the laser beam so as to detect the laser light scattered from oil droplets in the water.
The present invention Is concerned with the optical arrangement associated with the instrument test cell.
According to the invention there is provi ec a meter for measuring contamination in liquid, the meter including a test cell through which contaminate liquid may be directed, means for directing light into the cell whereby light is transmitted through the cell and scattered from the contaminant, wavelength selective means for receiving light signals transmitted through the cell and scattered at one or more predetermined angles, means for multiplexing the received light signals on a common optical path, and means for determining from said multiplexed signals the level of contaminatlon in the liauid.
According to the invention there is further provided a water contaminant meter, including 2 test cell through wnich water contaminated may be directed, means for directing light signals of first and second wavelengths into said cells whereby light is transmitted through the cell or is scattered by the contaminant, first optical filter means having a pass band corresponding to the first wavelength and so disposed as to receive light transmitted through the cell, second optical filter means having a pass band corresponding to the second wavelength and so disposed as to receive light scattered at a predetermined angle by the contaminant, means for multiplexing light signals fro the first and second filters on to a common optical path, an means for determining from said multiplexe signals the level of contamination in the water.
Embodiments of the invention will now be described witn reference to the accompanying drawings in which:- Figure 1 is a schematic aiagrar. cf contaminant measurement arrangement; and figure 2 shows an alternative test cell construction for use with the arrangement of Figure 1.
Referring to Figure 1 the measurement arrangement includes a cell 11 through which contaminated water is directed via an inlet and outlet (not shown). Light signals generated by light wave 14 are carried into the cell 11 via optical fibre 15. The light source 14 may be adapted to generate light signals of discrete wavelengths or in some applications, a range of wavelengths. The light source may comprise a number of lasers or light emitting diodes, or it may comprise a single laser which is current modulated to provide a plurality of output wavelengths. The different wavelengths may be generated simultaneousl- or secuentially.
Within the cell, some light is scattered by the contaminant within the water whilst the remainder in general the major portion, is transmitted across the cell. The reduction of the transmitted light intensity in comparison with clean water, and the intensity of scattered light, together give an accurate measre of the level of oil contamination in the water.
The light signals output from the cell are received by wavelength selective filters 1E and 17 arranged respectively in line with the inp light signal so as to receive transmitted light ano at angle to the input light signal so as to receive scattered light. In some applications one c more further wavelength selective filters may also be provided to receive light at different scattering angles.
The filters 16 and 1, are coupled -o respective optical fibres 18 and 19 which are in turn coupled by 2 beam combiner 20 to a common optical fibre 21. The light signals thus multiplexed are transmitted vi fibre 21 t z detector 22. At the detector the ligE,t-s.gnais are demultiplexed and analysed to a given measu-e of r the level of contamination within the cell. A method of calculating contaminant level from the direct and scattered light intensities is described in our published specification No. 2166234 (S.I.N. Gregorig 5-1).
The arrangement allows the return signals from the cell to be carried via a single fibre rather than the plurality of fibres required in previous arrangements. This simplifies installation and also improves accuracy as all the returned signals transverse the same optical path.
The arrangement is particularly adapted to the measurement of oil contamination in water either in marine or land-based installations. It wlll be appreciated however that the arrangement is not limited to the measurement of oil contamination but may also be used e.g. in the detection and measurement of suspended solid particles.
Figure 2 shows an alternative test cell construction. In this arrangement an arc of the inner surface of the cell comprises a grade optical filter 31. The filter 31 is contacted with an arcuate transparent, e.c. glass, body 32 the outer surface 33 of whlcn is silvered to provide a reflectIng surface. The transparent body 32 provIdes an optlca collection unction whereby light signals received fr various portions of the filter 31 are multiplexed and launched into optical fibre 34.
It will be appreciated that the contaminant measurement arrangement described herein may either be provided as a new installation or as a retrofit replacement in existing installations.

Claims (5)

CLAIMS:
1. A. meter for measuring contamination in liquid, the meter including a test cell through which contaminated liquid may be directed, means for directing light into the cell whereby light is transmitted through the cell and scattered from the contaminant, wavelength selective means for receiving light signals transinitted through the cell and scattered at one or more predetermined angles, means for multiplexing the received light signals on a common optical path, and means for determining from said multiplexed signals the level of oil contamination in the licuid.
2. A water contaminant meter, including Ç test cell through which water contaminated may be directed, means for directing light signals of first and second wavelengths into said cells whereby light is transinltted through the cell or is scattered by the contaminant, first optical filter means having a pass band corresponding to the first wavelength and so disposed as to receive light transmitted through the cell, second optical filter means having a pass band corresponding to the second wavelength and so disposed as to receIve light scattered at a predetermined angle by the contaminant, means for multiplexing light signals from the first and second filters on to a common optical path, and means for determining fro said multiplexed signals the level of contamination in the water.
3. A water contaminant meter as claimed in Claim 2, wherein the light detecting means comprises one or more semiconductor lasers.
4. A water contaminant meter as claimed in Claims 2 or 3, wherein said first and second optical filter means are provided by a graded index optical filter.
5. A water contaminant meter substantially as described herein with reference to and as shown in Figure 1 or Figures 1 and 2 of the accoFpanyina drawings.
GB8726085A 1987-11-06 1987-11-06 Liquid contamination meter Expired - Fee Related GB2212261B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB8726085A GB2212261B (en) 1987-11-06 1987-11-06 Liquid contamination meter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8726085A GB2212261B (en) 1987-11-06 1987-11-06 Liquid contamination meter

Publications (3)

Publication Number Publication Date
GB8726085D0 GB8726085D0 (en) 1987-12-09
GB2212261A true GB2212261A (en) 1989-07-19
GB2212261B GB2212261B (en) 1991-06-26

Family

ID=10626573

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8726085A Expired - Fee Related GB2212261B (en) 1987-11-06 1987-11-06 Liquid contamination meter

Country Status (1)

Country Link
GB (1) GB2212261B (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0422442A2 (en) * 1989-09-27 1991-04-17 Hughes Aircraft Company Collimated light optrode
GB2228314B (en) * 1989-02-16 1992-11-18 Hamamatsu Photonics Kk Examination apparatus
GB2256043A (en) * 1991-03-19 1992-11-25 Welsh Water Enterprises Ltd Organic pollutant monitor
US5350922A (en) * 1993-03-22 1994-09-27 Robert Bartz Underwater light scattering sensor
GB2282880A (en) * 1993-10-18 1995-04-19 Welsh Water Enterprises Ltd Apparatus for measuring characteristics of a liquid
US5420432A (en) * 1991-03-19 1995-05-30 Welsh Water Enterprises Limited Organic pollutant monitor
WO2004010119A1 (en) * 2002-07-20 2004-01-29 Council For The Central Laboratory Of The Research Councils Optical apparatus for measuring absorption and fluorescence or scattering properties of a sample
DE10360563A1 (en) * 2003-12-22 2005-07-14 BSH Bosch und Siemens Hausgeräte GmbH Fluid contamination measurement procedure records selectively filtered transmitted and scatter light in visible, UV and IR regions as function of contamination level
WO2005088270A2 (en) * 2004-03-15 2005-09-22 Evanesco Ltd Fluid monitoring apparatus and methods
WO2006026766A2 (en) * 2004-09-01 2006-03-09 Honeywell International Inc. Frequency-multiplexed detection of multiple wavelength light for flow cytometry
WO2006041303A1 (en) * 2004-09-24 2006-04-20 Tomra Systems Asa A device and a method for detection of characteristic features of a medium
EP1710556A3 (en) * 1995-04-06 2006-11-29 DeLaval Holding AB Method and apparatus for quantitative particle determination in fluids
DE102006030854A1 (en) * 2006-07-04 2008-01-10 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for determining oil content of cleaning fluid, involves analyzing of measuring volume of cleaning fluid with optical radiation, and intensity of optical radiation part is measured in trans-illuminating direction by measuring volume
ITAN20120140A1 (en) * 2012-10-24 2014-04-25 Tognella S P A Flli DEVICE AND PROCEDURE TO MEASURE THE CONCENTRATION OF AT LEAST ONE CONTAMINANT IN A FLUID

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2228314B (en) * 1989-02-16 1992-11-18 Hamamatsu Photonics Kk Examination apparatus
EP0422442A3 (en) * 1989-09-27 1991-10-23 Hughes Aircraft Company Collimated light optrode
EP0422442A2 (en) * 1989-09-27 1991-04-17 Hughes Aircraft Company Collimated light optrode
GB2256043A (en) * 1991-03-19 1992-11-25 Welsh Water Enterprises Ltd Organic pollutant monitor
GB2256043B (en) * 1991-03-19 1995-01-04 Welsh Water Enterprises Ltd Organic pollutant monitor
US5420432A (en) * 1991-03-19 1995-05-30 Welsh Water Enterprises Limited Organic pollutant monitor
US5350922A (en) * 1993-03-22 1994-09-27 Robert Bartz Underwater light scattering sensor
GB2282880A (en) * 1993-10-18 1995-04-19 Welsh Water Enterprises Ltd Apparatus for measuring characteristics of a liquid
GB2282880B (en) * 1993-10-18 1997-07-23 Welsh Water Enterprises Ltd Apparatus for measuring characteristics of a liquid
US5864140A (en) * 1993-10-18 1999-01-26 Acer Consultants Limited Apparatus for measuring characteristics of a liquid
EP1710556A3 (en) * 1995-04-06 2006-11-29 DeLaval Holding AB Method and apparatus for quantitative particle determination in fluids
WO2004010119A1 (en) * 2002-07-20 2004-01-29 Council For The Central Laboratory Of The Research Councils Optical apparatus for measuring absorption and fluorescence or scattering properties of a sample
DE10360563A1 (en) * 2003-12-22 2005-07-14 BSH Bosch und Siemens Hausgeräte GmbH Fluid contamination measurement procedure records selectively filtered transmitted and scatter light in visible, UV and IR regions as function of contamination level
WO2005088270A2 (en) * 2004-03-15 2005-09-22 Evanesco Ltd Fluid monitoring apparatus and methods
WO2005088270A3 (en) * 2004-03-15 2007-02-22 Evanesco Ltd Fluid monitoring apparatus and methods
WO2006026766A2 (en) * 2004-09-01 2006-03-09 Honeywell International Inc. Frequency-multiplexed detection of multiple wavelength light for flow cytometry
WO2006026766A3 (en) * 2004-09-01 2006-06-01 Honeywell Int Inc Frequency-multiplexed detection of multiple wavelength light for flow cytometry
US7612871B2 (en) 2004-09-01 2009-11-03 Honeywell International Inc Frequency-multiplexed detection of multiple wavelength light for flow cytometry
WO2006041303A1 (en) * 2004-09-24 2006-04-20 Tomra Systems Asa A device and a method for detection of characteristic features of a medium
US7633614B2 (en) 2004-09-24 2009-12-15 Tomra Systems Asa Device and a method for detection of characteristic features of a medium
DE102006030854A1 (en) * 2006-07-04 2008-01-10 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for determining oil content of cleaning fluid, involves analyzing of measuring volume of cleaning fluid with optical radiation, and intensity of optical radiation part is measured in trans-illuminating direction by measuring volume
ITAN20120140A1 (en) * 2012-10-24 2014-04-25 Tognella S P A Flli DEVICE AND PROCEDURE TO MEASURE THE CONCENTRATION OF AT LEAST ONE CONTAMINANT IN A FLUID

Also Published As

Publication number Publication date
GB8726085D0 (en) 1987-12-09
GB2212261B (en) 1991-06-26

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 19921106