GB2201802A - Photographic production of images - Google Patents
Photographic production of images Download PDFInfo
- Publication number
- GB2201802A GB2201802A GB08704965A GB8704965A GB2201802A GB 2201802 A GB2201802 A GB 2201802A GB 08704965 A GB08704965 A GB 08704965A GB 8704965 A GB8704965 A GB 8704965A GB 2201802 A GB2201802 A GB 2201802A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- layer
- pigment
- image
- photosensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 33
- 230000000903 blocking effect Effects 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 10
- 206010073306 Exposure to radiation Diseases 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 229920003176 water-insoluble polymer Polymers 0.000 claims description 3
- 229920003169 water-soluble polymer Polymers 0.000 claims description 3
- 239000000758 substrate Substances 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 89
- 239000000203 mixture Substances 0.000 description 21
- 239000006185 dispersion Substances 0.000 description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 description 15
- 239000000975 dye Substances 0.000 description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 description 9
- 229920002689 polyvinyl acetate Polymers 0.000 description 9
- 239000011118 polyvinyl acetate Substances 0.000 description 9
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000000976 ink Substances 0.000 description 5
- 230000000740 bleeding effect Effects 0.000 description 4
- 239000002981 blocking agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical group [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000012831 Printan Substances 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- LOBCDGHHHHGHFA-LBPRGKRZSA-N (S)-monastrol Chemical compound CCOC(=O)C1=C(C)NC(=S)N[C@H]1C1=CC=CC(O)=C1 LOBCDGHHHHGHFA-LBPRGKRZSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 1
- KJSGODDTWRXQRH-UHFFFAOYSA-N 2-(dimethylamino)ethyl benzoate Chemical compound CN(C)CCOC(=O)C1=CC=CC=C1 KJSGODDTWRXQRH-UHFFFAOYSA-N 0.000 description 1
- YSJWNEDBIWZWOI-UHFFFAOYSA-N 2-hydroxy-3,4-dimethylbenzoic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1C YSJWNEDBIWZWOI-UHFFFAOYSA-N 0.000 description 1
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000002895 emetic Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F3/00—Colour separation; Correction of tonal value
- G03F3/10—Checking the colour or tonal value of separation negatives or positives
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Abstract
In the photographic production of multi-colour images on a substrate, a first pigmented photosensitive layer is applied to the substrate, imagewise exposed and developed with water to wash out the non-exposed material from the exposed first pigmented layer, the layer is then dried and a second pigmented photosensitive layer of a different colour is applied. This second layer is then imagewise exposed, developed and dried as before. According to the present invention, when either the pigment of the first or second pigmented layer is a pigment which bleeds, there is used a blocking layer comprising an immobilising agent for the dye of the pigment which prevents movement of the dye from one layer to contaminate the other. <IMAGE>
Description
PHOTOGRAPHIC PRODUCTION OF IMAGES
This invention relates to the photographic production of multi-colour images.
It is known to produce multi-colour images on a substrate by applying a first pigmented photosensitive layer to the substrate, imagewise exposing and developing with water to wash out the non-exposed material from the exposed first pigmented layer. The layer is then dried and a second pigmented photosensitive layer of a different colour is applied. This second layer is then imagewise exposed, developed and dried as before. The process can be repeated with further differently coloured pigmented photosensitive layers to build up the final multi-colour image.
Variations within this general process are known.
For example, although it is generally more convenient to provide the pigmented photosensitive layers in a single layer, it is also known to use two sub layers, one, which may or may not be photosensitive, containing the pigmented material and the other an unpigmented photosensitive material. It is also known to provide adhesive within each, or at least the top, photosensitive layer so that the final multi-coloured image is transferable from its substrate to a receptor surface as required.
Alternatively adhesive may be applied as a separate overlayer to render the image transferable. Additionally our European Patent Application No: 86308448.9 describes the use of a separate opacifying layer comprising a water-soluble polymer, water-insoluble polymer and a, preferably white, pigment in photographically produced colour images. The use of this opacifying layer behind the photographically produced coloured layer serves to increase the colour intensity of the image.
It has been found that, when there is used a pigment, which bleeds in water, in at least one of the photosensitive layers, there is a tendency for the pigment colour to bleed out of its layer into other layers of the image product. The bleeding of the pigments in this way causes considerable problems in the production of multi-coloured images. Thus the colour from one layer bleeds through into another layer causing colour contamination and resulting in poor colour matches and poor colour consistency.
According to the present invention there is provided a method of producing an image which method comprises
imagewise exposing photosensitive material, the photosensitive material comprising a carrier sheet which has thereon a first water-removable photosensitive layer containing a first pigment of a first colour, which first photosensitive layer material is rendered non-water-removable on exposure to radiation, and, optionally, over the first water-removable photosensitive layer, a blocking layer,
developing the image thereby obtained with water to remove the first photosensitive layer material and any overlying blocking layer material in the non-image areas and drying the product thereby obtained,
if the photosensitive material does not comprise a blocking layer, applying over the imaged material at least in the image area or areas a blocking layer,
applying over the composite obtained a second water-removable photosensitive layer containing a second pigment of a second colour, which second photosensitive layer material is rendered non-water-removable on exposure to radiation,
imagewise exposing the second photosensitive layer,
developing the image thereby obtained with water to remove the second photosensitive layer material in the non-image areas and drying the product thereby obtained;
at least one of the first and second pigments being a pigment which bleeds in water and the blocking layer comprising an immobilising agent which prevents passage through the layer of dye from the pigment, which bleeds in water, or at least one of the pigments, which bleed in water.
It has been found that the use of an immobilising agent in a blocking layer separate from that containing the pigment, which bleeds in water, effectively prevents movement of the colour from the pigment and the colour does not pass through the blocking layer. Thus the provision of a blocking layer between the bleeding pigment-containing layer and a subsequent (or preceding) coloured layer prevents the colour of the subsequent (or preceding) layer being contaminated due to bleeding through of colour from the pigment layer. It should be appreciated in the multi-coloured images method according to the invention there may be used both layers which contain pigments which bleed in water and layers which contain pigments which do not bleed in water.In this case the number and positioning of the blocking agents used should be such that for each layer used containing a pigment, which bleeds in water, there is provided an associated blocking layer, to prevent the dye moving to the adjacent pigment layer. If succeeding pigment layers both contain pigments, which bleed, there is provided between them an immobilising agent preventing movement of the colour of both pigments. If one immobilising agent acts for both pigments, then of course a single blocking layer between the pigment layers will prevent each being contaminated by the other. If different immobilising agents are required then these can be in the same blocking layer or in different ones.
The immobilising agent may be provided as a continuous layer over the entire imaged product surface.
Alternatively, and preferably, the immobilising agent-containing blocking layer may be provided only over the image areas. Most preferably the blocking agent layer is a water washout layer; that is a layer which, when applied as a continuous layer, may be subjected to water washout to leave blocking agent layer material in register with the image areas and to remove the blocking agent material from the non-image areas.
The immobilising agent may be included with any layer of the imaged product other than that containing the pigment to provide the blocking layer. For example it may be included in an opacifying layer as described in
European Patent Application No: 86308448.9.
According to a preferred embodiment of the invention, there is provided a method of producing a multi-coloured image which method comprises
imagewise-exposing photosensitive material, the photosensitive material comprising a carrier sheet having a release surface which has thereon the first water-removable photosensitive layer containing the first pigment,
developing the image thereby obtained with water to remove t first photosensitive layer material in the non-image areas and drying the product thereby obtained,
applying over the image material obtained an opacifying layer comprising a water-soluble polymer, a water-insoluble polymer and a, preferably white, pigment
applying over the opacifying layer a blocking layer,
treating the product obtained with water and drying,
applying over the composite obtained the second water-removable photosensitive layer containing the second pigment,
imagewise exposing the second photosensitive layer,
developing the image thereby obtained with water;
at least one of the first and second pigments being a pigment which bleeds in water and the blocking layer comprising an immobilising agent which prevents passage through the layer of dye from the pigment which bleeds in water, or from at least one of the pigments, which bleed in water.
The presence of the immobilising agent-containing blocking layer prevents bleeding through of the colour of the first layer to contaminate the second layer (or vice versa).
According to this preferred embodiment there is applied over the first image layer an opacifying layer and subsequently an immobilising agent-containing blocking layer. When this material is contacted with water, that in the non-image areas, i.e. in contact with the release surface of the carrier sheet, is removed. However in the image areas, the opacifying layer (and immobilising agent-containing overlayer) is retained on the image layer.
The immobilising agent used in the blocking layer according to the invention may precipitate, absorb, adsorb or otherwise prevent the passage of the dye through the layer to prevent contamination of the adjacent pigment-containing layer. The immobilising agent may be organic or inorganic, molecular or polymeric, water-insoluble or water-soluble. Of course when a water-soluble agent is used it is necessary for it to be used in combination with a water-insoluble binder to prevent it being leach out during water development.
A particularly convenient class of immobilising agents for use according to the invention are laking agents. The term "laking agent" is one which is well known but used slightly differently in different industries. Generally speaking they are agents used to provide water-insoluble pigments of enhanced perceived colour. For example The Printing Ink Manual (3rd Edn
Northwood Books, London 1979 pages 137 and 304) refers to the reduction of water-solubility of alcohol based inks using laking agents. Laking agents take different forms and act in different ways. They may be water-soluble or water-insoluble. The most commonly used laking agents are water-soluble laking agents which react with dyes to form water-insoluble, dye-containing precipitate and water-insoluble laking agents which adsorb water-soluble dye from solution.
It has been found that use of the laking agent in the same layer as a pigment, which bleeds in water, does not overcome the problem with which the present application is concerned. That is it does not prevent the migration of colour from that layer to contaminate adjacent colour layers. Surprisingly however when the laking agent is placed in a separate layer, it does act to prevent colour migration. The reason why laking agent should be ineffective in restricting colour mobility when placed in the pigment-containing layer while being effective when in a separate layer, is not fully understood. It may perhaps be due to the pigment maintaining an equilibrium between a dye solution in the water and the pigment or derived dye adsorbed by the laking agent.This equilibrium may then require an impractically high level of laking agent effectively to shift the equilibrium and stop the colour migration.
The laking agent used as immobilising agent according to the invention may be organic or inorganic, monomer or polymeric, water-insoluble or water-soluble.
Most suitable according to the present invention as laking agent is phenol formaldehyde resin. Other suitable laking agents include silicates, barium and manganese salts. Also tannic acid may be used though it is not preferred because of its toxic qualities. Also there may be used shellac, phenol-sulphur condensates, dimethyl salicylic acid and tartar emetic.
According to the present invention, there is used, for at least one of the colour pigments a pigment which bleeds in water. Amongst such pigments are pigments derived from water-soluble dyes, e.g. water-soluble basic dyestuffs. Particularly troublesome are toned pigments obtained from the precipitation of basic dyestuffs with acid. For example benefits are obtained using toners derived from precipitation with phosphotungstomolybdic acid (PTMA). Pigments, which bleed in water, can also be obtained when acidic dyes and their derived toners are used.
Other pigments which bleed in water include laked pigments in which the laking agent used insufficiently insolubilises the dye component of the pigment. In this case the laking agent used as immobilising agent in the blocking layer may be the same as that used in the pigment. Alternatively it may be different. Indeed the laking agent of the blocking layer need not necessarily be a recognised laking agent for the particular water-soluble dye involved.
If it is desired that the multi-coloured image is transferable from the carrier sheet, the image is preferably-provided with an adhesive at least in or over its top layer. Thus for example a pressure-sensitive adhesive may be included in the second photosensitive layer. Alternatively a pressure-sensitive adhesive layer may be provided over that second layer after development and drying.
The invention is further illustrated by way of
Example in the following Example. In this Example parts and percentages are by weight unless otherwise indicated.
EXAMPLE
A silicone release coating composition was prepared according to the following formulation
Parts
Silicone polymer containing
catalyst (Syl-off 7046 ex
Dow Corning) 20.5
Crosslinker (Syl-off 7048
ex Dow Corning) 0.102
Adhesion modifier (Syl-off
Q2-7089 ex Dow Corning) 0.92
Hydrocarbon solvent (Exsol
145/160 ex Esso) 14.24
Methyl ethyl ketone 14.24
This composition was coated onto polyethylene terephthalate (542 Melinex ex I.C.I.) using a no. 72 Meyer bar, and cured at 120 C for 5 minutes.
There were prepared the following starting mixtures:
A 33% polyvinyl alcohol solution in water was prepared using Gohsenol GL03 (ex Nippon Gohsei).
A dispersion of 30% silica (Neosyl GP ex Crossfield
Limited) in a 10% solution of polyvinyl alcohol (Gelvatol 4020 ex Monsanto Limited) was prepared by the simple addition of the silica to the solution with mixing.
A mixture of surface active agents was made by adding
Tween 80 (62%) to Span 80 (38%) (both ex Honeywell and
Stein) and mixing the two solutions to homogeneity.
A solution of the initiator isopropyl thioxanthone (Quantacure ITX ex Ward Blenkinsop) in the amine 2-(dimethyl amino) ethyl benzoate (Quantacure DMB ex Ward
Blenkinsop) in the ratio 1:2 was made by mixing the initiator into the amine heated to about 50 C.
A 10% solution of the surface active agent Aerosol OT (ex Hopkin and Williams) was made in water.
A dispersion of titanium dioxide (Tiona 472 ex
Laport) in a 10% solution of polyvinyl alcohol (Gelvatol 4020) was manufactured by ball milling in 60 parts pigment in 40 parts solution for 24 hours.
A dispersion of Monastral Blue BG in 10% polyvinyl alcohol solution (Gelvatol 4020) was made by adding 30 parts of the pigment to 70 parts of the solution and ball milling for 48 hours.
A clear precoat composition was prepared using the following formulation; the ingredients of which were mixed in an even dispersion using high shear stirring.
Parts
Polyvinyl alcohol solution
(33% Gohsenol in water) 12.0
Acrylate monomer (AM 548 ex Synthes BV) 19.2
Silicone acrylate monomer
(Ebecryl 350 ex UCB BV) 4.1
Polyvinyl acetate copolymer
emulsion (Vinnapas MV70H
ex Wacker Chemie) 16.0
Polyvinyl acetate copolymer
emulsion (Vinnapas EP 11 ex
Wacker Chemie) 8.8
Polyvinyl acetate homopolymer
(Mowilith DHL ex Harco) 28.7
10% solution of Aerosol OT 21.2
Surface active agent mixture 1.1
Initiator mixture 1.25
This clear "pre coat" composition was coated on the silicone release coating using a no. 8 Meyer bar.
The following ink formulation was mixed to give an even dispersion using high shear stirring
Parts
Polyvinyl alcohol solution
(33% Gohensol in water) 8.21
Acrylate monomer (Setalin AM
548 ex UCB) 14.75
Parts
Silicone acrylate monomer
(Ebecryl 350) 0.75
Polyvinyl acetate copolymer
emulsion (Vinnapas MV70H) 20.0
Polyvinyl acetate copolymer
emulsion (Vinnapas EP 11) 6.05
Polyvinyl acetate homopolymer
(Mowilith DHL) 11.1
10% Aerosol OT solution 9.2
Surface active agent mixture 1.93
Silicone surface active agent
(L77 ex Union Carbide) 0.3
Silica dispersion 4.13
Polyvinyl acetate copolymer
dispersion (Emultex AC43 ex Harco) 15.02
10% polyvinyl alcohol solution
in water (Gelvatol 4020) 12.0
Initiator mixture 2.8
Monastral Blue BG dispersion 4.2
Titanium dioxide dispersion 17.7
This formulation was coated onto the precoated carrier using a no. 20 Meyer bar.
After drying, the sheet was exposed to ultraviolet light and developed by water wash-out.
An opaquing formulation was prepared as follows:
Parts
Polyvinyl alcohol solution solution of Gohsenol GL03) 193
Acrylate (AM548) 15
Silicone acrylate monomer
(Ebecryl 350) 4.7
Silica dispersion 15
Surface active agent mixture 7
Polyvinyl acetate copolymer
dispersion (Emultex AC43) 87
Parts
Polyvinyl acetate copolymer
dispersion (Vinnapas MV70H) 82
10% Aerosol OT solution 170
Surface active agent
(Silwett 7001 ex Union Carbide) 14.6
Titanium dioxide dispersion 223
This opaquing dispersion was applied over the blue image with a no. 20 Meyer bar and dried.
A laking agent-containing composition was prepared by reducing a phenol formaldehyde resin (Printan G ex
Ciba-Geigy) on a coffee grinder and then dispersing in 15% polyvinyl pyrrolidone (Luviscol K 30 ex BASF) in water.
This dispersion was applied over the opaquing composition with a no. 20 Meyer bar and again dried.
The whole sheet was then washed out with water to remove the opaquing composition and subsequent coating in the non-image areas.
A second precoat composition as described above was applied over the imaged sheet. There was then applied a second ink formulation of the same composition as above except that in place of the 4.2 parts of Monastrol Blue BG dispersion there were used 11.0 parts of a dispersion of
Irgalite magenta TCB in water made by milling 40% of the pigment in 60% of a 10% solution of polyvinyl alcohol solution (Gelvatol 4020) in water.
The sheet was then imaged to a negative carrying the magenta image and developed with water.
There was obtained a final product containing clear blue and magenta transferable images.
A similar sheet made without the Printan G dispersion coating showed the blue images stained purple from the magenta ink having bled in.
Claims (5)
1. A method of producing an image which method comprises
imagewise exposing photosensitive material, the photosensitive material comprising a carrier sheet which has thereon a first water-removable photosensitive layer containing a first pigment of a first colour, which first photosensitive layer material is rendered non-water-removable on exposure to radiation, and, optionally, over the first water-removable photosensitive layer, a blocking layer,
developing the image thereby obtained with water to remove the first photosensitive layer material and any overlying blocking layer material in the non-image areas and drying the product thereby obtained,
if the photosensitive material does not comprise a blocking layer, applying over the imaged material at least in the image area or areas a blocking layer,
applying over the composite obtained a second water-removable photosensitive layer containing a second pigment of a second colour, which second photosensitive layer material is rendered non-water-removable on exposure to radiation,
imagewise exposing the second photosensitive layer,
developing the image thereby obtained with water to remove the second photosensitive layer material in the non-image areas and drying the product thereby obtained;
at least one of the first and second pigments being a pigment, which bleeds in water, and the blocking layer comprising an immobilising agent which prevents passage through the layer of dye from the pigment, which bleeds in water, or at least one of the pigments, which bleed in water.
2. A method of producing a multi-coloured image which method comprises
imagewise exposing photosensitive material, the photosensitive material comprising a carrier sheet having a release surface which has thereon the first water-removable photosensitive layer containing the first pigment,
developing the image thereby obtained with water to remove the first photosensitive layer material in the non-image areas and drying the product thereby obtained,
applying over the image material obtained an opacifying layer comprising a water-soluble polymer, a water-insoluble polymer and a pigment
applying over the opacifying layer a blocking layer,
treating the product obtained with water and drying,
applying over the composite obtained the second water-removable photosensitive layer containing the second pigment,
imagewise exposing the second photosensitive layer,
developing the image thereby obtained with water;
at least one of the first and second pigments being a pigment which bleeds in water and the blocking layer comprising an immobilising agent which prevents passage through the layer of dye from the pigment which bleeds in water, or from at least one of the pigments, which bleed in water.
3. A method according to claim 1 or 2 wherein the immobilising agent used is a laking agent.
4. A method according to claim 1 substantially as described in the Example.
5. An image produced by the method claimed in any one of claims 1 to 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08704965A GB2201802A (en) | 1987-03-03 | 1987-03-03 | Photographic production of images |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08704965A GB2201802A (en) | 1987-03-03 | 1987-03-03 | Photographic production of images |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB8704965D0 GB8704965D0 (en) | 1987-04-08 |
| GB2201802A true GB2201802A (en) | 1988-09-07 |
Family
ID=10613256
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08704965A Withdrawn GB2201802A (en) | 1987-03-03 | 1987-03-03 | Photographic production of images |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2201802A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0443802A3 (en) * | 1990-02-20 | 1992-11-25 | Truproof Limited | Production of pre-press colour proofs |
-
1987
- 1987-03-03 GB GB08704965A patent/GB2201802A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0443802A3 (en) * | 1990-02-20 | 1992-11-25 | Truproof Limited | Production of pre-press colour proofs |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8704965D0 (en) | 1987-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |