GB2195175A - Oxygen enriched burner flame - Google Patents

Oxygen enriched burner flame Download PDF

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Publication number
GB2195175A
GB2195175A GB08706525A GB8706525A GB2195175A GB 2195175 A GB2195175 A GB 2195175A GB 08706525 A GB08706525 A GB 08706525A GB 8706525 A GB8706525 A GB 8706525A GB 2195175 A GB2195175 A GB 2195175A
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United Kingdom
Prior art keywords
gaseous fuel
stream
streams
improved method
oxygen
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Granted
Application number
GB08706525A
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GB2195175B (en
GB8706525D0 (en
Inventor
William P Coppin
Richard A Campos
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Maxon Corp
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Maxon Corp
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Publication of GB2195175A publication Critical patent/GB2195175A/en
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Publication of GB2195175B publication Critical patent/GB2195175B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/32Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid using a mixture of gaseous fuel and pure oxygen or oxygen-enriched air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Abstract

A centrally disposed stream of gaseous fuel is provided at a pressure sufficient to direct the flame in a longitudinal direction, and a multiplicity of streams of oxygen- enriched air (or oxygen) in preferably a substantially stoichiometric amount are disposed about the stream of fuel and at a radial angle selected from approximately +20 DEG to -20 DEG , diverging from or converging towards, the longitudinal axis of the gaseous fuel stream. Next, the streams of gaseous fuel and oxygen enriched air are mixed. Finally, the mixture is combusted to form a sustainable flame having a zone of reduced temperature surrounding the flame to burn the gaseous fuel efficiently and to form relatively low levels of noxious combustion products therefrom. The oxygen- enriched air may contain up to 35% oxygen, and is fed through angled apertures 22 in an orifice plate 12 surrounding a fuel nozzle 16. <IMAGE>

Description

1 GB2195175A 1
SPECIFICATION
Improved method of providing oxygen enriched flame 1 BACKGROUND OF THE INVENTION
The present invention is directed to methods of providing heat, and more particularly to im proved methods of providing efficient heating and at reduced costs by means of the direct burning of a gaseous fuel by means of oxygen enriched air streams.
The prior art has provided various types of burners of the most usually efficient heating of air for direct transfer of heat such as in an oven, and for the heating of liquids, such as may be contained within a boiler for indirect transfer of such heat. Some of such prior art heating mechanisms have used stoichiometric mixtures of various fuels, including for example gaseous fuels, with ambient air. However, some such burner mechanisms have had excessive flame temperatures, and flame shapes which have resulted in shock to the most generally necessary refractory block, which block has served as a sleeve for containing such flame in order to maintain the flame as a sustainable entity. Usually, a more durable material could not be used as and for the block because of the high temperatures of such prior art flame containing structures.
Also some of such prior art burner mechanisms further have been relatively inefficient in burning the gaseous fuel and have created excessively high combustion products including NO and NO, (hereinafter sometimes designated as NO.).
In view of the deficiencies and disadvantages of prior art burners, it is an object of the.
improved methods of the present invention to provide improved methods which do not require the use of a refractory block, but instead may utilize a metal sleeve in order to avoid contamina tion of the flame, and thereby the material being heated, and also in order to resist fracture from inadvertent impact.
It is a further object of the improved methods of the present invention to provide for levels of from at least approximately 35% oxygen to 100% oxygen enrichment, which levels yield a more efficient flame and at substantially lower combustion product levels.
It is yet further an object of the improved methods of the present invention to provide oxygen enrichment of the air stream and to do so by twisting the air stream at a velocity, pressure, 30 angle of convergence or divergence, and at an angle of twist sufficient to shape a flame to create a zone of reduced temperature within the block, which in turn materially reduces block shock, but while maintaining efficient burning and substantially reduced combustion products.
It is also an object of the improved methods of the present invention to maintain the same isotherms within a burner structure as may be present with the utilization of ambient air, but to do so at a reduction of the gaseous fuel of approximately 15%, while at the same time maintaining reduced NO,, emissions.
The presently improved methods are especially adaptable in plants utilized for the production of aluminum, which facilities produce 35% oxygen enriched air as a by product of such alumi num production. The improved methods of the present invention also may find special applica- 40 tion in circumstances wherein an exceedingly clean flame is necessary, such as in the heating of glass and other similar applications.
These and other objects of the improved methods of the present invention will become apparent to those of ordinary skill in the art upon review of the following summary of the invention, brief description of the drawing, detailed description of the preferred embodiments, 45 including exemplary embodiments, appended claims, and accompanying drawing.
SUMMARY OF THE INVENTION
The improved methods of the present invention of providing efficient and reduced cost heating are accomplished by means of burning a preferably gaseous fuel directly, and doing so in the 50 environment of oxygen enriched air. Specifically, a centrally disposed stream of such gaseous fuel, having a longitudinal axis and delivered at a pressure sufficient to direct the gaseous fuel in the longitudinal direction, is provided. A multiplicity of streams of oxygen enriched air preferably in stoichiometric amount is provided, and such streams are disposed, in transverse cross section, in a circular array about the stream of gaseous fuel. Such gaseous streams are disposed 55 for flowing in streams which are radially angled at approximately from + 200 to -20' in divergence from or convergence towards the longitudinal axis of the gaseous fuel stream.
In the next step of the methods hereof, the stream of gaseous fuel and oxygen enriched air are mixed. Finally, the mixture is combusted to produce a sustainable flame, and within a block of shielding the flame, such flame having a zone of reduced temperature surrounding the flame, 60 thereby to burn the fuel efficiently and to maintain relatively low levels of combustion products.
The improved methods of the present invention will be better understood with regard to the following drawings.
6 5 BRIEF DESCRIPTION OF THE DRAWINGS
2 GB2195175A 2 The improved methods of providing combustion of a gaseous fuel in an oxygen enriched environment may be carried out by means of the exemplary apparatus shown in the Figs., and in which:
Figure 1 is a partially cut away cross-sectional and fragmented side view of a burner for carrying out the methods of the present invention, such burner including an orifice plate having for example an angle A of divergence from the longitudinal axis of the gaseous stream, a nozzle, an ignitor spark shield, a back plate with a gasket separating the back plate from the nozzle body, further having a spark ignitor subassembly disposed at the back portion of the nozzle body, and with the truncated and cross-sectional block assembly held by block holding frame means disposed at the front portion of such nozzle body; Figure 2 is a front view of one preferred embodiment of an orifice plate, as shown in Fig. 1, and showing an illustrative angle of twist at angle B thereof with the plurality of orifices disposed radially in spaced array about the centrally disposed gaseous fuel conduit means, and being suitable for stoichiometric burning in ambient air containing 20.8% oxygen; Figure 3 is a front view of an alternative embodiment of an orifice plate suitable for carrying 15 out certain other embodiments of the improved methods of the present invention, and showing such angled and diverging orifices being one-half the diameter of those shown in the embodi ment of Fig. 2, and suitable for use with oxygen enriched air streams containing 22.8% oxygen; and Figure 4 is a front view of a further alternative embodiment of an orifice plate suitable for 20 carrying out further embodiments of the improved methods of the present invention, and show ing the angled and diverging orifices at approximately one-quarter the diameter of those of the embodiment of Fig. 2, and suitable for use with oxygen enriched air streams containing approxi mately 35% oxygen.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The improved methods of the present invention are directed towards providing efficient and reduced cost heating by means of direct burning of fuels including gaseous fuel in preferred embodiments, and in a stream of oxygen enriched air, which may have varying amounts of oxygen ranging from ambient air with approximately 20.8% oxygen air streams, to 35% oxygen 30 air streams, and further to 100% oxygen streams. Specifically, such improved methods of the present invention include the initial step of providing a centrally disposed stream of gaseous fuel which has a longitudinal axis and is delivered at a pressure sufficient to direct the gaseous fuel in such longitudinal direction. A multiplicity of streams of oxygen enriched air are provided, and are disposed in transverse cross-section in a preferably circular spaced array about the stream of 35 gaseous fuel, and flowing in streams which are radially angled in divergence or convergence at approximately +200 to -20' with respect to and respectively away from or towards the longitudinal axis of the gaseous fuel stream. The result is to direct the streams of oxygen enriched air in a plurality of paths around the centrally disposed stream of gaseous fuel. Such respective streams of fuel and oxygen enriched air are mixed, and are combusted to provide a 40 sustainable flame having a zone of reduced temperature surrounding the flame, thereby to burn such gaseous fuel efficiently and to form relatively low levels of noxious combustion products therefrom, including reduced levels of NO, In some preferred embodiments, the improved methods of the present invention include oxygen enrichment of up to approximately 35% oxygen. In yet further preferred embodiments, 45 pure oxygen may be used, in which case orifice openings having approximately one-fifth the diameter of those useable with ambient air may be provided.
Various delivery pressures of the stream of gaseous fuel may be utilized, and are determinable by those of ordinary skill in the art without the necessity for undue experimentation, and as taught by the examples of specification hereof. The same is true with respect to the required delivery pressure of the streams of air utilizable therewith, and as are further set forth in the examples illustrating preferred and alternative embodiments, supra.
The stream of gaseous fuel may preferably be generally circular in transverse cross-section.
The streams of oxygen enriched air surrounding the longitudinal axis of the gaseous fuel stream may be twisted. Such twisting may comprise the disposing of the streams of oxygen enriched 55 air at an angle of approximately 0 to 40' with respect to the longitudinal axis of the stream of gaseous fuel. Such twistings of the streams of oxygen enriched air may form a plurality of spiral streams in preferred embodiments disposed about the centrally disposed gaseous fuel stream.
The cross-sectional diameter of the streams of gaseous fuel and the respective diameters of the plurality of surrounding streams of oxygen enriched air may be selected to render the combus- 60 tion thereof substantially stoichiometric, according to standards known to those having ordinary skill in the art, and as are set forth in the following examples of preferred and alternative embodiments.
The respective pressures and respective diameters of the gaseous fuel stream and the multipli city of streams of oxygen enriched air are selected in preferred embodiments to maintain 65 3 GB2195175A 3 substantially constant isotherms using the oxygen enriched air streams, as compared to isoth erms in a burner apparatus in utilizing ambient air in such a burner for combustion of the gaseous fuel.
The improved methods of the present invention may further comprise radially confining the sustainable flame. Such radial confining may preferably be accomplished by means which are free 5 of refractory materials to prevent particles of any such refractory material from contaminating the sustainable flame, and/or thereby the material being heated by such flame. Such radial confining means may comprise a metallic sleeve. Also, in other preferred embodiments, the radial confin ing may be accomplished by means of a refractory material sleeve where the heating purpose is indirect and/or other means are present for reducing contamination of the item to be heated.
In some of the improved methods of the present invention as set forth in illustrative examples hereof, the temperature of the sustainable flame in some embodiments thereof may be reduced as as compared to combustion within ambient air.
Referring now to the drawing, and to Fig. 1 in particular, the improved methods of providing combustion of the gaseous fuel in an oxygen enriched environment may be carried out by means 15 of the exemplary apparatus shown in the Figs., although other apparatus for carrying out such inventive methods may be devised by those skilled in the art.
Fig. 1 depicts in partially cross-sectional and fragmented side view a burner generally 10 for carrying out the present invention. Burner 10 includes an orifice plate generally 12 disposed at the front portion 14 of nozzle 16. Nozzle 16 is disposed within a nozzle body 18 containing an 20 oxidizing gas conduit portion 20 for transmittal of oxidizing gas from an external source and preferably through an adjustable orifice cock (not shown). Also referring to Fig. 2, such oxidizing gas is transmitted through orifice 22 in orifice plate 12 in a diverging stream shown as angle A in Fig. 1, into the central bore 24 of refractory block 26. Such refractory block 26 is supported by means of block frame 28 held by nozzle body flange 30. Such nozzle body 18 may further 25 include an inlet flange 31 attached to nozzle body 18 by means of suitable bolts 32 and sealed thereto by means of gasket 34. Similarly, a nozzle body back plate 36 is sealingly attached by means of gasket 38 and bolts 40 to nozzle body 18. Disposed onto back plate 36 is a spark ignitor assembly 42. A sight glass 44 may also be provided for viewing the interior of nozzle 16. Also, a hollow pipe plug 46 may be provided for access in to nozzle body 18.
Referring now to Fig. 2 in particular, which depicts a front view of the embodiment of orifice plate 12 as shown in Fig. 1, for use with ambient air, an angle B of twist of the plurality of orifices 22 is illustrated. Such orifices 22 are disposed radially in spaced array about a centrally disposed gaseous fuel conduit 48. The surface 50 of orifice plate 12 may preferably be planar, as shown, although other arrangements are contemplated.
Fig. 3 illustrates an embodiment of an orifice plate 112 suitable for carrying out certain other embodiments of the improved methods of the present invention, and showing such orifices 122 being approximately one-half the diameter of those shown in the embodiment of Fig. 2, and suitable for use with plus 2% oxygen enriched air streams. Centrally disposed gaseous fuel conduit 148 is shown. The plate surface 150 is likewise preferably planar, and such orifices 122 40 are likewise diverging at angle A and twisted at angle B. Similarly, Fig. 4 illustrates a front view of a further embodiment of an orifice plate 212 suitable for carrying out a further embodiment of the improved methods of the present invention. Orifice plate 212 likewise includes a centrally disposed gaseous fuel conduit 248, and further includes angled and diverging orifices 222 at approximately one-quarter the diameter of those of the embodiment of Fig. 2 for ambient air. Such embodiment of orifice plate 212 of Fig. 4 is suitable for use with an approximately 35% oxygen enriched air stream.
As referred to in Exhibit 1, six different loci of temperature measurement were selected for inclusion in the following examples of illustrative embodiments of the methods of the present invention, are are designated respectively as T, T2, T3, T, T5, and T6. The location of these loci 50 of temperature are identified, as follows:
T,-On the top outside surface of refractory block 26 near the exit end, which is opposite flange 30; T2-near T, on the side/top outside surface of refractory block 26 and approximately 45' 55 degrees from the vertical; T3-on the outside surface of refractory block 26 near T2 and approximately 90 degrees from the vertical; T4-buried approximately 1/4" in the front face of refractory block 26 at the top center portion of such face; T5-buried approximately 1/4" in the front face of refractory block 26 at the bottom center portion of such face; and T6-on the inside lateral surface of refractory block 26 near the exit end, which is opposite flange 30.
4 GB2195175A 4 Working examples of various embodiments of the improved methods of the present invention have been conducted and are set forth in columnar form in Exhibits I and 11, infra.
In preferred embodiments, the burner 10 may be a 1-1/2 inch burner, 2 inch burner, 3 inch burner, 4 inch burner, 6 inch burner or other sizes of burner. The material for refractory block 26 may preferably comprise a fuseable ceramic material having large temperature withstanding capacity and/or other materials. Where a ceramic block 26 is utilized, the initial diameter of central bore 24 thereof may vary from 3-1/4 to 5-1/2 inches for 1-1/2 to 4 inch burners respectively. Such a refractory block 26 may be at least 9-1/4 inches to 13 inches in length. These and other dimensions are not deemed to be critical and may be suitably varied.
The basic and novel characteristics of the improved methods of the present invention will be 10 readily understood from the foregoing disclosure by those skilled in the art. It will become readily apparent that various changes and modifications may be made in the conducting of the improved methods of the present invention as set forth hereinabove without departing from the spirit and scope of the invention. Accordingly, the preferred and alternative embodiments of the present invention set forth hereinabove are not intended to limit such spirit and scope in any way.
EXHIBIT 1 Flame Tests Using-2" KINEMAX" Burnerl llsinq Natural Gas Gas AIR G Percent Percent Block T2 T3 T4 T5 Exit Flamn Visible Flame Flame Firing Volume Pressure GAS 02 02 Temp. (F.) (F.) (F.) (F.) Port Temp. Flame Diam. Color Time Cubic (Water Pressure in in Tl T6 (F.) F.enqth (in (In Feet Inches e Rey 1 v Furnace (F.) (F.) (in Inches) Minutes) Per Hour Column) ("'a Inches) (Water Inches in C Column) FURN. 600 7 1.5 20.8 2 14 6 Blue 1000 6 4.0 35 2 36+ 4 Unite - OPEN 1000 22.5 3.6 20.8 - 98 123 112 363 351 595 3100 14 6 Blue is AIR 1000 7.5 4.0 35. - 132 159 164 508 437 770 2650 24 6 White 15 1000 22.5 3.6 20.8 - 120 162 152 401 375 628 3150 14 6 Blue 30 1000 7.5 4.0 35 - 232 246 267 557 480 765 2650 42 6 white 30 1000 22.5 3.6 20.8 - 139 188 185 422 390 643 3150 14 6 Blue 60 1000 6.5 4.0 35 - 247 262 285 568 486 760 2650 42 6 White 60 600 8.0 1.5 20.8 - 165 234 240 644 478 1100 3100 24 5 Blue 10 600 4.0 1.5 35 - 260 271 298 572 506 755 2700 30 6 White 10 1.0.2 20.8 - 198 279 312 724 696 1275 2950 18 4 Blue 15 1.5.2 35 - 269 294 319 585 559 816 3150 1 4 White 15 100.5. 1 35 288 310 338 604 603 838 3200 18 4 81/Wh 5 0 3 5 300 320 340 540 540; '750 3200 r_ T; -r-1 131/qh 10 Trademark of Maxon Corporation; Muncie, Indiana.
M a) cj m m (n -j (n M CF):
EXHI13IT 11 AMBIENT AIR and 02 ENRICHED COMPARISON VISING W' KINEMAX' PtiRNr.R SERIE'S "G" (FURNACE 02 - 2%) _ IRV Gas Air Gas % MRV Ga s Air Gas % PSI FURNACE PRE Vo 1 ume Pressure Pressure 02 volume Pressure Pressure 02 02.05 Ine (Cubic (Inches (Inches BURNER (Cubic (Inches (Inches BURNER H.G. Water Cc Feet Water Water BODY Feet Water Water BODY TUBE Per Hour) Column) Column) Per Hour Column) Column) Piwr 200.1 1.004 20.8 PT I=. 200. 1.004 35.05 1INIMUM ON. 1.05 20.8 MINIMUM 800. 1. 1 35. 1 RATIO 1 1 500 1 1400.8.3 20.8: 1: 2400.8.6 35.2 2 1900 1.5.7 20.8 2 3800 1.5 1.8 35.6 3 2800 3.1 1.4 20.8 3 4900 3.1 3.4 35 1.
4 4000 6.2 1.6 20.8 4 6100 6.2 5.3 35 1.5 4900 9.5 3.4 20.8 5 8000 9.5 8.5 35 2.3 6 5800 13. 4.8 20.8 6 9300 13. 10. 35 3.2 7 6400 16. 6.1 20.8 7 10400 16. 12. 35 4.2 8 7150 20. 7.1 20.8 8 11600 20. 15. 35 5.1 9 7670 23. 7.7 20.8 9 12400 23. 22. 35 6.
8000 25. 8.1 20.8 10 13000 25. 25. 35 6.8 27. 8.5 20.8 MAXIMM 13500 26.4 26.4 35 8.
11 ' G) ca N C0 M M a) 7 GB2195175A 7

Claims (15)

1. An improved method of providing efficient and reduced cost heating by means of direct burning of a gaseous fuel, said improved method comprising the steps of:
providing a centrally disposed stream of gaseous fuel having a longitudinal axis and delivered at pressure sufficient to direct the gaseous fuel in a longitudinal direction; providing a multiplicity of streams of oxygen enriched air, disposed in transverse cross-section in a circular array about the stream of gaseous fuel, and flowing in streams radially angled approximately +200 to -20' with respect to the longitudinal axis of the gaseous fuel stream initially to direct the streams of oxygen enriched air in a plurality of paths around the centrally disposed stream of gaseous fuel; mixing the stream of gaseous fuel and oxygen enriched air; and combusting such mixture to provide a sustainable and shaped flame having a zone of reduced temperature surrounding the flame, to burn such gaseous fuel efficiently and to form reduced levels of noxious combustion products therefrom.
2. The improved method of claim 1 wherein the oxygen enrichment of the air stream is 15 elevated up to approximately 35% oxygen.
3. The improved method of claim 1 wherein the oxygen enrichment of the air stream is pure oxygen.
4. The improved method of claim 1 wherein the stream of gaseous fuel is generally circular in transverse cross-section.
5. The improved method of claim 1 further comprising twisting the streams of oxygen enriched air around the longitudinal axis of the gaseous fuel stream.
6. The improved method of claim 5 wherein said twising comprises disposing the streams of oxygen enriched air at an angle of approximately 0-400 with respect to the longitudinal axis of the stream of gaseous fuel.
7. The improved method of claim 5 wherein such twisted streams of oxygen enriched air form a plurality of spiral streams disposed about the centrally disposed gaseous fuel stream.
8. The improved method of claim 1 wherein the cross-sectional diameter of the streams of gaseous fuel and the respective diameters of the plurality of surrounding streams of oxygen enriched air are selected at a selected pressure to render the combustion thereof substantially 30 stoichiometric.
9. The improved method of claim 1 wherein the respective pressures and respective dia meters of the gaseous fuel stream and the multiplicity of streams of oxygen enriched air are selected to main substantially constant isotherms as compared to combustion of the gaseous fuel in ambient air.
10. The improved method of claim 1 further comprising radially confining the sustainable flame.
11. The improved method of claim 10 wherein such radial confining is accomplished by means free of refractory materials to prevent particles of refractory material from contamining the sustainable flame.
12. The improved method of claim 11 wherein the radial confining means comprises a metallic sleeve.
13. The improved method of claim 12 wherein such radial confining is accomplished by refractory material sleeve means.
14. The improved method of claim 1 wherein the temperature of the sustainable flame is 45 reduced as compared to combustion with ambient air.
15. A method of providing an oxygen enriched flame substantially as herein described.
Published 1988 at The Patent Office, State House, 66/71 High Holborn, London WC 1 R 4TP. Further copies may be obtained from The Patent Office, Sales Branch, St Mary Cray, Orpington, Kent BR5 3RD. Printed by Burgess & Son (Abingdon) Ltd. Con, 1/87.
GB8706525A 1986-09-22 1987-03-19 Improved method of providing oxygen enriched flame Expired - Lifetime GB2195175B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US90960886A 1986-09-22 1986-09-22

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GB8706525D0 GB8706525D0 (en) 1987-04-23
GB2195175A true GB2195175A (en) 1988-03-30
GB2195175B GB2195175B (en) 1990-08-01

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GB8706525A Expired - Lifetime GB2195175B (en) 1986-09-22 1987-03-19 Improved method of providing oxygen enriched flame

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FR (1) FR2604241A1 (en)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2325518A (en) * 1997-05-02 1998-11-25 Derek William Wild Gas burner
US7014458B2 (en) * 2001-03-28 2006-03-21 American Air Liquide, Inc. High velocity injection of enriched oxygen gas having low amount of oxygen enrichment
CN104006405A (en) * 2013-02-27 2014-08-27 唐山纳川节能设备制造有限公司 Ceramic kiln oxygen enrichment combustion supporting and energy saving device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2325518A (en) * 1997-05-02 1998-11-25 Derek William Wild Gas burner
US7014458B2 (en) * 2001-03-28 2006-03-21 American Air Liquide, Inc. High velocity injection of enriched oxygen gas having low amount of oxygen enrichment
CN104006405A (en) * 2013-02-27 2014-08-27 唐山纳川节能设备制造有限公司 Ceramic kiln oxygen enrichment combustion supporting and energy saving device

Also Published As

Publication number Publication date
FR2604241A1 (en) 1988-03-25
GB2195175B (en) 1990-08-01
GB8706525D0 (en) 1987-04-23
DE3730122A1 (en) 1988-03-31

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