GB1514466A - Preparation of bipyridilium compounds - Google Patents
Preparation of bipyridilium compoundsInfo
- Publication number
- GB1514466A GB1514466A GB27645/74A GB2764574A GB1514466A GB 1514466 A GB1514466 A GB 1514466A GB 27645/74 A GB27645/74 A GB 27645/74A GB 2764574 A GB2764574 A GB 2764574A GB 1514466 A GB1514466 A GB 1514466A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- bipyridilium
- preparation
- bipyridyl
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/22—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing two or more pyridine rings directly linked together, e.g. bipyridyl
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1503—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
Abstract
Compounds of the formula (I) below in which R are aromatic radicals and X<-> is an anion derived from an acid are prepared by reacting an N,N'-bis(2,4-dinitrophenyl)-4,4'-bipyridyl salt with a primary aromatic amine whose aromatic radical corresponds to the substituent R to be introduced into the bipyridyl ring. The resultant compounds are suitable for use in electrochromatic display devices. When an electric current is passed through a solution of the compound, the latter reacts reversibly to form an intensely coloured free-radical cation by reduction. <IMAGE>
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB27645/74A GB1514466A (en) | 1974-06-21 | 1974-06-21 | Preparation of bipyridilium compounds |
FR7519481A FR2275462A1 (en) | 1974-06-21 | 1975-06-20 | PROCESS FOR PREPARING BIPYRIDILIUM COMPOUNDS AND PRODUCTS OBTAINED |
CA229,830A CA1031346A (en) | 1974-06-21 | 1975-06-20 | Preparation of bipyridilium compounds |
IT24619/75A IT1039183B (en) | 1974-06-21 | 1975-06-20 | PREPARATION OF COMPOUNDS OF BIPI RIDILIO |
DE19752527638 DE2527638A1 (en) | 1974-06-21 | 1975-06-20 | PROCESS FOR PRODUCING DIPYRIDILIUM COMPOUNDS |
NL7507383A NL7507383A (en) | 1974-06-21 | 1975-06-20 | PROCESS FOR PREPARING BIPYRIDILIUM COMPOUNDS. |
CH807375A CH613447A5 (en) | 1974-06-21 | 1975-06-20 | Process for the preparation of a compound containing an N-substituted bipyridyl ring |
JP50076401A JPS5116675A (en) | 1974-06-21 | 1975-06-21 | |
HK25/79A HK2579A (en) | 1974-06-21 | 1979-01-11 | Preparation of bipyridilium compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB27645/74A GB1514466A (en) | 1974-06-21 | 1974-06-21 | Preparation of bipyridilium compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1514466A true GB1514466A (en) | 1978-06-14 |
Family
ID=10262960
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27645/74A Expired GB1514466A (en) | 1974-06-21 | 1974-06-21 | Preparation of bipyridilium compounds |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5116675A (en) |
CA (1) | CA1031346A (en) |
CH (1) | CH613447A5 (en) |
DE (1) | DE2527638A1 (en) |
FR (1) | FR2275462A1 (en) |
GB (1) | GB1514466A (en) |
HK (1) | HK2579A (en) |
IT (1) | IT1039183B (en) |
NL (1) | NL7507383A (en) |
Cited By (32)
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EP0787719A1 (en) * | 1994-10-22 | 1997-08-06 | Daikin Industries, Ltd. | Conjugated n-fluoropyridinium salt polymer and use thereof |
US7172633B2 (en) | 2003-06-16 | 2007-02-06 | L'ORéAL S.A. | Lightening dye composition comprising at least one cationic direct dye containing mixed chromophores |
US7201779B2 (en) | 2003-06-16 | 2007-04-10 | L'oreal S.A. | Dye composition comprising at least one direct dye containing mixed chromophores |
US7300471B2 (en) | 2004-02-27 | 2007-11-27 | L'oreal S.A. | Composition comprising at least one mixed dye based on at least one chromophore of azo or tri(hetero) arylmethane type, dyeing process and mixed dyes. |
EP2018847A1 (en) | 2007-07-24 | 2009-01-28 | L'Oreal | Hair composition comprising at least one direct disulfide dye and at least one alkali hydroxide agent and method of simultaneous styling and dyeing. |
US7488354B2 (en) | 2004-10-14 | 2009-02-10 | L'oreal S.A. | Dyeing composition comprising at least one disulphide dye and method of dyeing human keratin fibers using this dye |
EP2053094A2 (en) | 2007-09-24 | 2009-04-29 | L'Oréal | Composition for dyeing keratinous fibres comprising at least one direct dye with disulphur/thiol function and at least one polymer with thiol function and method using the composition |
US8038732B2 (en) | 2006-03-24 | 2011-10-18 | L'oreal S.A. | Fluorescent entity, dyeing composition containing at least one fluorescent entity, and method for lightening keratin materials using said at least one fluorescent entity |
US8038731B2 (en) | 2006-03-24 | 2011-10-18 | L'oreal S.A. | Method of dyeing and lightening keratin materials in the presence of a reducing agent comprising a fluorescent disulphide dye |
US8840684B2 (en) | 2010-12-15 | 2014-09-23 | L'oreal | Process for dyeing keratin fibres using a direct dye bearing a disulfide/thiol/protected thiol function and water vapour |
EP2848667A1 (en) * | 2013-09-17 | 2015-03-18 | ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) | Electrochromic single and two-core viologens and optical articles containing them |
US9044412B2 (en) | 2011-07-05 | 2015-06-02 | L'oreal | Dye composition using a long-chain ether of an alkoxylated fatty alcohol and a cationic polymer, processes and devices using the same |
US9060944B2 (en) | 2011-07-05 | 2015-06-23 | L'oreal | Cosmetic composition rich in fatty substances comprising a polyoxyalkylenated fatty alcohol ether and a direct dye and/or an oxidation dye, the dyeing method and the device |
US9066890B2 (en) | 2011-07-05 | 2015-06-30 | L'oreal | Dye composition comprising an alkoxylated fatty alcohol ether and a fatty alcohol |
US9265705B2 (en) | 2011-02-25 | 2016-02-23 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a nonionic surfactant, an amphoteric surfactant, an ethoxylated fatty alcohol, an alkaline agent and a reducing agent |
US9271915B2 (en) | 2011-02-25 | 2016-03-01 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a non-cellulose-based thickening polymer, an alkaline agent and a reducing agent |
US9345652B2 (en) | 2011-02-25 | 2016-05-24 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a sparingly or non-ethoxylated fatty alcohol, a cationic surfactant, an alkaline agent and a reducing agent |
US9522106B2 (en) | 2011-02-25 | 2016-12-20 | L'oreal | Composition for dyeing keratinous fibres comprising a direct dye having a disulphide/thiol functional group, a thickening polymer, an ethoxylated fatty alcohol and/or a nonionic surfactant, an alkaline agent and a reducing agent |
WO2017081314A1 (en) | 2015-11-12 | 2017-05-18 | L'oreal | Cationic direct dye comprising an aliphatic chain and bearing a disulfide/thiol/protected-thiol function for dyeing keratin fibres |
US9785030B2 (en) | 2013-09-17 | 2017-10-10 | Essilor International (Compagnie Generale D'optique) | Electrochromic composition |
US9827185B2 (en) | 2012-08-02 | 2017-11-28 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
US9841652B2 (en) | 2013-09-17 | 2017-12-12 | Essilor International (Compagnie Generale D'optique) | Electrochromic composition |
US10117811B2 (en) | 2013-12-23 | 2018-11-06 | L'oreal | Packaging article comprising an envelope and an anhydrous dye composition comprising an oxidation dye, use of the same and process for dyeing keratin fibres |
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US10179768B2 (en) | 2013-09-17 | 2019-01-15 | Essilor International | Electrochromic two-core viologen derivatives and optical articles containing them |
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US11911636B2 (en) | 2013-12-23 | 2024-02-27 | L'oreal | Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent |
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---|---|---|---|---|
JPH0196171A (en) * | 1987-10-09 | 1989-04-14 | Kootec Kk | Production of viologen derivative |
JPH0196170A (en) * | 1987-10-09 | 1989-04-14 | Kootec Kk | Viologen derivative |
US5998617A (en) * | 1997-04-02 | 1999-12-07 | Gentex Corporation | Electrochromic compounds |
WO2006095435A1 (en) * | 2005-03-10 | 2006-09-14 | Fujitsu Limited | Crosslinking ligand, metal complex and metal complex integrated structure |
FR2889954B1 (en) | 2005-08-26 | 2007-10-19 | Oreal | CATIONIC MIXED DYES COMPRISING ANTHRAQUINONE CHROMOPHORE AND THEIR USE IN CAPILLARY COLOR |
KR20090128379A (en) | 2007-03-05 | 2009-12-15 | 후지필름 가부시키가이샤 | Compound for photoresist, photoresist solution, and etching method using the photoresist solution |
CN101457138B (en) * | 2007-12-14 | 2011-11-30 | 宁波市金榜汽车电子有限公司 | Electrochromic component |
US8964278B2 (en) | 2010-08-09 | 2015-02-24 | Gentex Corporation | Electro-optic system configured to reduce a perceived color change |
US8228590B2 (en) | 2010-08-09 | 2012-07-24 | Gentex Corporation | Electro-optic system configured to reduce a perceived color change |
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EP2677996B1 (en) | 2011-02-25 | 2017-11-29 | L'Oréal | Composition for dyeing keratinous fibres comprising a direct dye having a disulphide/thiol functional group, a thickening polymer, an ethoxylated fatty alcohol and/or a nonionic surfactant, an alkaline agent and a reducing agent |
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FR3136972A1 (en) | 2022-06-22 | 2023-12-29 | L'oreal | Composition for lightening keratin fibers and process for lightening keratin fibers using this composition |
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-
1974
- 1974-06-21 GB GB27645/74A patent/GB1514466A/en not_active Expired
-
1975
- 1975-06-20 IT IT24619/75A patent/IT1039183B/en active
- 1975-06-20 CA CA229,830A patent/CA1031346A/en not_active Expired
- 1975-06-20 DE DE19752527638 patent/DE2527638A1/en not_active Withdrawn
- 1975-06-20 NL NL7507383A patent/NL7507383A/en not_active Application Discontinuation
- 1975-06-20 FR FR7519481A patent/FR2275462A1/en active Granted
- 1975-06-20 CH CH807375A patent/CH613447A5/en not_active IP Right Cessation
- 1975-06-21 JP JP50076401A patent/JPS5116675A/ja active Pending
-
1979
- 1979-01-11 HK HK25/79A patent/HK2579A/en unknown
Cited By (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0787719A1 (en) * | 1994-10-22 | 1997-08-06 | Daikin Industries, Ltd. | Conjugated n-fluoropyridinium salt polymer and use thereof |
EP0787719A4 (en) * | 1994-10-22 | 1998-01-07 | Daikin Ind Ltd | Conjugated n-fluoropyridinium salt polymer and use thereof |
US7172633B2 (en) | 2003-06-16 | 2007-02-06 | L'ORéAL S.A. | Lightening dye composition comprising at least one cationic direct dye containing mixed chromophores |
US7201779B2 (en) | 2003-06-16 | 2007-04-10 | L'oreal S.A. | Dye composition comprising at least one direct dye containing mixed chromophores |
US7300471B2 (en) | 2004-02-27 | 2007-11-27 | L'oreal S.A. | Composition comprising at least one mixed dye based on at least one chromophore of azo or tri(hetero) arylmethane type, dyeing process and mixed dyes. |
US7488354B2 (en) | 2004-10-14 | 2009-02-10 | L'oreal S.A. | Dyeing composition comprising at least one disulphide dye and method of dyeing human keratin fibers using this dye |
US8038732B2 (en) | 2006-03-24 | 2011-10-18 | L'oreal S.A. | Fluorescent entity, dyeing composition containing at least one fluorescent entity, and method for lightening keratin materials using said at least one fluorescent entity |
US8038731B2 (en) | 2006-03-24 | 2011-10-18 | L'oreal S.A. | Method of dyeing and lightening keratin materials in the presence of a reducing agent comprising a fluorescent disulphide dye |
US8562693B2 (en) | 2006-03-24 | 2013-10-22 | L'oreal | Method of dyeing and lightening keratin materials in the presence of a reducing agent comprising a fluorescent deisulphide dye |
US8685114B2 (en) | 2006-03-24 | 2014-04-01 | L'oreal | Composition for dyeing and lightening keratin materials comprising a fluorescent deisulphide dye compound |
EP2018847A1 (en) | 2007-07-24 | 2009-01-28 | L'Oreal | Hair composition comprising at least one direct disulfide dye and at least one alkali hydroxide agent and method of simultaneous styling and dyeing. |
EP2053094A2 (en) | 2007-09-24 | 2009-04-29 | L'Oréal | Composition for dyeing keratinous fibres comprising at least one direct dye with disulphur/thiol function and at least one polymer with thiol function and method using the composition |
US8840684B2 (en) | 2010-12-15 | 2014-09-23 | L'oreal | Process for dyeing keratin fibres using a direct dye bearing a disulfide/thiol/protected thiol function and water vapour |
US9265705B2 (en) | 2011-02-25 | 2016-02-23 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a nonionic surfactant, an amphoteric surfactant, an ethoxylated fatty alcohol, an alkaline agent and a reducing agent |
US9271915B2 (en) | 2011-02-25 | 2016-03-01 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a non-cellulose-based thickening polymer, an alkaline agent and a reducing agent |
US9345652B2 (en) | 2011-02-25 | 2016-05-24 | L'oreal | Composition for dyeing keratin fibres comprising a direct dye bearing a disulphide/thiol function, a sparingly or non-ethoxylated fatty alcohol, a cationic surfactant, an alkaline agent and a reducing agent |
US9522106B2 (en) | 2011-02-25 | 2016-12-20 | L'oreal | Composition for dyeing keratinous fibres comprising a direct dye having a disulphide/thiol functional group, a thickening polymer, an ethoxylated fatty alcohol and/or a nonionic surfactant, an alkaline agent and a reducing agent |
US9060944B2 (en) | 2011-07-05 | 2015-06-23 | L'oreal | Cosmetic composition rich in fatty substances comprising a polyoxyalkylenated fatty alcohol ether and a direct dye and/or an oxidation dye, the dyeing method and the device |
US9066890B2 (en) | 2011-07-05 | 2015-06-30 | L'oreal | Dye composition comprising an alkoxylated fatty alcohol ether and a fatty alcohol |
US9044412B2 (en) | 2011-07-05 | 2015-06-02 | L'oreal | Dye composition using a long-chain ether of an alkoxylated fatty alcohol and a cationic polymer, processes and devices using the same |
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US10130829B2 (en) | 2013-12-23 | 2018-11-20 | L'oreal | Packaging article comprising an envelope and an anhydrous dye composition comprising a direct dye, use of the same and process for dyeing keratin fibres |
US10117811B2 (en) | 2013-12-23 | 2018-11-06 | L'oreal | Packaging article comprising an envelope and an anhydrous dye composition comprising an oxidation dye, use of the same and process for dyeing keratin fibres |
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WO2017081314A1 (en) | 2015-11-12 | 2017-05-18 | L'oreal | Cationic direct dye comprising an aliphatic chain and bearing a disulfide/thiol/protected-thiol function for dyeing keratin fibres |
US11096880B2 (en) | 2017-06-16 | 2021-08-24 | L'oreal | Process for dyeing keratin fibres using at least one direct dye and at least one disulfide, thiol or protected-thiol fluorescent dye |
US11278482B2 (en) | 2017-06-16 | 2022-03-22 | L'oreal | Process for dyeing keratin materials using at least one blue, purple or green dye and at least one disulfide, thiol or protected thiol fluorescent dye |
US11672747B2 (en) | 2018-12-21 | 2023-06-13 | L'oreal | Process for dyeing keratin materials using a direct dye and an aliphatic ammonium salt, and composition comprising same |
Also Published As
Publication number | Publication date |
---|---|
CA1031346A (en) | 1978-05-16 |
IT1039183B (en) | 1979-12-10 |
FR2275462A1 (en) | 1976-01-16 |
JPS5116675A (en) | 1976-02-10 |
HK2579A (en) | 1979-01-19 |
CH613447A5 (en) | 1979-09-28 |
DE2527638A1 (en) | 1976-05-06 |
FR2275462B1 (en) | 1979-05-25 |
NL7507383A (en) | 1975-12-23 |
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PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |