GB1472735A - Process for producing metal salts from organosulphonic acids - Google Patents
Process for producing metal salts from organosulphonic acidsInfo
- Publication number
- GB1472735A GB1472735A GB66176A GB66176A GB1472735A GB 1472735 A GB1472735 A GB 1472735A GB 66176 A GB66176 A GB 66176A GB 66176 A GB66176 A GB 66176A GB 1472735 A GB1472735 A GB 1472735A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- sulphonic acid
- organosulphonic
- sulphonic
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 9
- 150000007513 acids Chemical class 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- 239000011133 lead Substances 0.000 abstract 2
- 238000006386 neutralization reaction Methods 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 abstract 1
- IILMIAKZFKOMTK-UHFFFAOYSA-N 2,3-didodecylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CCCCCCCCCCCC)C(CCCCCCCCCCCC)=CC2=C1 IILMIAKZFKOMTK-UHFFFAOYSA-N 0.000 abstract 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- XWNWPUWXRCLVEG-UHFFFAOYSA-N 4,5-di(nonyl)naphthalene-1,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(CCCCCCCCC)=C2C(CCCCCCCCC)=CC=C(S(O)(=O)=O)C2=C1 XWNWPUWXRCLVEG-UHFFFAOYSA-N 0.000 abstract 1
- ANYJSVKEVRJWRW-UHFFFAOYSA-N 4,5-di(nonyl)naphthalene-2-sulfonic acid Chemical compound OS(=O)(=O)C1=CC(CCCCCCCCC)=C2C(CCCCCCCCC)=CC=CC2=C1 ANYJSVKEVRJWRW-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910000003 Lead carbonate Inorganic materials 0.000 abstract 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- SSILHZFTFWOUJR-UHFFFAOYSA-N hexadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCS(O)(=O)=O SSILHZFTFWOUJR-UHFFFAOYSA-N 0.000 abstract 1
- FYAQQULBLMNGAH-UHFFFAOYSA-N hexane-1-sulfonic acid Chemical compound CCCCCCS(O)(=O)=O FYAQQULBLMNGAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
- 239000011667 zinc carbonate Substances 0.000 abstract 1
- 229910000010 zinc carbonate Inorganic materials 0.000 abstract 1
- 235000004416 zinc carbonate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
- C10M135/10—Sulfonic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1472735 Metal salts of organosulphonic acids KING INDUSTRIES Inc 8 Jan 1976 [8 Jan 1975] 00661/76 Heading C2C An alkali metal, alkaline earth metal, lead or zinc salt of an organosulphonic acid is obtained by reacting an organosulphonic acid, in free acid form, with at least a 1% molar excess, relative to the sulphonic acid groups therein, of an alkali metal, alkaline earth metal, lead or zinc carbonate, in the presence of "free" water, continuing the reaction until a carbonate/acid equilibrium is established, and thereafter completing the neutralization of the sulphonie acid groups by adding to the equilibrium mixture a small amount of a strong base which has a base strength greater than that of the bicarbonate ion. Specified organosulphonic acids are dinonyl naphthalene sulphonic acid and disulphonic acid, mono-, di- and poly-dodecylbenzene sulphonic acid, didodecylnaphthalene sulphonic acid, hexane sulphonic acid, hexadecane sulphonic acid, petroleum sulphonic acids and the sulphonic acid of white mineral oil. An inert solvent may be added to the reaction mixture before or after the establishment of the equilibrium. Preferably, a combination of a volatile inert solvent and hydrocarbon oil is used so that after neutralization the water and volatile solvent can be stripped off to leave the sulphonate salt in solution in the hydrocarbon oil.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53959575A | 1975-01-08 | 1975-01-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1472735A true GB1472735A (en) | 1977-05-04 |
Family
ID=24151887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB66176A Expired GB1472735A (en) | 1975-01-08 | 1976-01-08 | Process for producing metal salts from organosulphonic acids |
Country Status (4)
| Country | Link |
|---|---|
| CA (1) | CA1051455A (en) |
| DE (1) | DE2600179C2 (en) |
| FR (1) | FR2297210A1 (en) |
| GB (1) | GB1472735A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0433816A1 (en) * | 1989-12-18 | 1991-06-26 | Riedel-De Haen Aktiengesellschaft | Process and device for the preparation of a solution of a non-ferrous metal sulphonate |
| WO1996026919A2 (en) * | 1995-02-28 | 1996-09-06 | Exxon Chemical Patents Inc. | Low base number sulphonates |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1075801B (en) * | 1976-04-27 | 1985-04-22 | Witco Chemical Corp | PREPARATION OF NEUTRAL SYNTHETIC CALCIUM SULPHONATE-BASED COMPOSITIONS |
| DE3827262A1 (en) * | 1988-08-11 | 1990-02-22 | Bayer Ag | Process for the preparation of crystalline, anhydrous, flowable lithium dodecylbenzenesulphonate |
-
1976
- 1976-01-05 DE DE2600179A patent/DE2600179C2/en not_active Expired
- 1976-01-06 CA CA243,019A patent/CA1051455A/en not_active Expired
- 1976-01-07 FR FR7600269A patent/FR2297210A1/en active Granted
- 1976-01-08 GB GB66176A patent/GB1472735A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0433816A1 (en) * | 1989-12-18 | 1991-06-26 | Riedel-De Haen Aktiengesellschaft | Process and device for the preparation of a solution of a non-ferrous metal sulphonate |
| WO1996026919A2 (en) * | 1995-02-28 | 1996-09-06 | Exxon Chemical Patents Inc. | Low base number sulphonates |
| WO1996026919A3 (en) * | 1995-02-28 | 1996-11-07 | Exxon Chemical Patents Inc | Low base number sulphonates |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2297210A1 (en) | 1976-08-06 |
| CA1051455A (en) | 1979-03-27 |
| DE2600179A1 (en) | 1976-07-15 |
| FR2297210B1 (en) | 1980-03-21 |
| DE2600179C2 (en) | 1983-06-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19960107 |