GB1451608A - Process for reducing calcium sulphate scale formation - Google Patents
Process for reducing calcium sulphate scale formationInfo
- Publication number
- GB1451608A GB1451608A GB5145472A GB5145472A GB1451608A GB 1451608 A GB1451608 A GB 1451608A GB 5145472 A GB5145472 A GB 5145472A GB 5145472 A GB5145472 A GB 5145472A GB 1451608 A GB1451608 A GB 1451608A
- Authority
- GB
- United Kingdom
- Prior art keywords
- additive
- crystals
- calcium sulphate
- liquor
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 title abstract 10
- 235000011132 calcium sulphate Nutrition 0.000 title abstract 4
- 239000001175 calcium sulphate Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000000654 additive Substances 0.000 abstract 9
- 230000000996 additive effect Effects 0.000 abstract 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 6
- 239000013078 crystal Substances 0.000 abstract 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052925 anhydrite Inorganic materials 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 abstract 1
- 239000008394 flocculating agent Substances 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 235000019983 sodium metaphosphate Nutrition 0.000 abstract 1
- 229940048086 sodium pyrophosphate Drugs 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F15/00—Other methods of preventing corrosion or incrustation
- C23F15/005—Inhibiting incrustation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0288—Applications, solvents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
- C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
- C01B25/223—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen only one form of calcium sulfate being formed
- C01B25/2235—Anhydrite processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
- C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
- C01B25/223—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen only one form of calcium sulfate being formed
- C01B25/226—Hemihydrate process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Priority Applications (27)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5145472A GB1451608A (en) | 1972-11-08 | 1972-11-08 | Process for reducing calcium sulphate scale formation |
| ZA00738038A ZA738038B (en) | 1972-11-08 | 1973-10-16 | Washing of calcium sulphate hemihydrate crystals |
| AU62036/73A AU478108B2 (en) | 1972-11-08 | 1973-10-21 | Process for the reduction of calcium sulphate scale formation during the production of phosphoric acid |
| US05/409,366 US3972981A (en) | 1972-11-08 | 1973-10-25 | Method of preventing gypsum scale formation in phosphoric acid plant filters |
| BE137083A BE806533A (fr) | 1972-11-08 | 1973-10-25 | Procede pour empecher les incrustations |
| NL7314813A NL7314813A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1973-10-29 | |
| AT0911973A AT363910B (de) | 1972-11-08 | 1973-10-29 | Verfahren zum waschen von kalziumsulfathemihydratkristallen |
| CA184,624A CA1032731A (en) | 1972-11-08 | 1973-10-30 | Incorporation of anti-scaling additive to calcium sulphate mother liquors |
| IN2421/CAL/1973A IN141012B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1973-11-02 | |
| RO7376545A RO63885A (fr) | 1972-11-08 | 1973-11-06 | Procede pour empecher la formation du couche de sulfate de calcium |
| HUFI549A HU168213B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1973-11-06 | |
| SU731967924A SU695549A3 (ru) | 1972-11-08 | 1973-11-06 | Способ получени фосфорной кислоты |
| DD174483A DD111883A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1973-11-06 | |
| PL1973166379A PL102163B1 (pl) | 1972-11-08 | 1973-11-07 | A process of producing phosphoric acid |
| DE19732355607 DE2355607A1 (de) | 1972-11-08 | 1973-11-07 | Waschverfahren fuer insbesondere bei der phosphorsaeureherstellung anfallende kristalle von kalziumsulfatanhydrid und -hemihydrat |
| FR7339491A FR2205479B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1973-11-07 | |
| ES420313A ES420313A1 (es) | 1972-11-08 | 1973-11-07 | Un procedimiento para reducir la formacion de incrustacio- nes, principalmente, la formacion de incrustaciones de sul- fato de calcio durante la produccion de acido fosforico. |
| BR8671/73A BR7308671D0 (pt) | 1972-11-08 | 1973-11-07 | Um processo para a lavagem de cristais de cristais de anidrita de sulfato de acido e/ou hemihidrato de sulfato de calcio, processo para a producao de acido fosforico pelo processo a umido de bloco de valvula |
| SE7315123A SE389092B (sv) | 1972-11-08 | 1973-11-07 | Forfarande for tvettning av kristaller avkalciumsulfatanhydrit och/eller kalciumsulfathemihydrat |
| IT7331058A IT1012092B (it) | 1972-11-08 | 1973-11-08 | Procedimento per ridurre la forma zione di incrostazioni in partico lare durante la produzione di aci do fosforico |
| CS737666A CS200462B2 (en) | 1972-11-08 | 1973-11-08 | Method of producing phosphoric acid by wet process |
| JP48125040A JPS594379B2 (ja) | 1972-11-08 | 1973-11-08 | 硫酸カルシウムのスケ−ル形成を低減する方法 |
| OA55072A OA04514A (fr) | 1972-11-08 | 1973-11-28 | Procédé pour empêcher les incrustations. |
| SE7600174A SE414164B (sv) | 1972-11-08 | 1976-01-09 | Forfarande for framstellning av fosforsyra |
| IN1569/CAL/1976A IN141032B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-11-08 | 1976-08-25 | |
| US06/016,142 US4221769A (en) | 1972-11-08 | 1979-02-28 | Process for preventing the formation of calcium sulphate scale |
| JP58177201A JPS59152211A (ja) | 1972-11-08 | 1983-09-27 | 硫酸カルシウムのスケ−ル形成を低減する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5145472A GB1451608A (en) | 1972-11-08 | 1972-11-08 | Process for reducing calcium sulphate scale formation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1451608A true GB1451608A (en) | 1976-10-06 |
Family
ID=10460097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5145472A Expired GB1451608A (en) | 1972-11-08 | 1972-11-08 | Process for reducing calcium sulphate scale formation |
Country Status (22)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2169115C1 (ru) * | 2000-08-23 | 2001-06-20 | Открытое акционерное общество "Невинномысский Внештрейдинвест" | Способ получения фосфорной кислоты |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049774A (en) * | 1970-11-12 | 1977-09-20 | Fisons Limited | Process for reducing formation of gypsum scale durng the washing of calcium sulphate hemihydrate crystals |
| US4221769A (en) * | 1972-11-08 | 1980-09-09 | Fisons Limited | Process for preventing the formation of calcium sulphate scale |
| DE2427122B2 (de) * | 1974-06-05 | 1976-12-30 | Gebr. Knauf Westdeutsche Gipswerke, 8715 Iphofen | Verfahren zur stabilisierung des bei der herstellung nasser phosphorsaeure anfallenden alpha-calciumsulfat-halbhydrat |
| US4332779A (en) * | 1980-11-24 | 1982-06-01 | American Cyanamid Company | Phosphoric acid filtration process |
| JPS63144107A (ja) * | 1986-12-08 | 1988-06-16 | Mitsui Toatsu Chem Inc | 高濃度燐酸−半水石こうスラリ−の濾過方法 |
| US20090294372A1 (en) * | 2008-05-30 | 2009-12-03 | Gill Jasbir S | Inhibition of water formed scale in acid conditions |
| US20090294373A1 (en) * | 2008-05-30 | 2009-12-03 | Gill Jasbir S | Inhibition of water formed scale in acid conditions |
| US9242863B2 (en) * | 2009-09-25 | 2016-01-26 | Cytec Technology Corp. | Process and reagents for the inhibition or reduction of scale formation during phosphoric acid production |
| AP3403A (en) * | 2009-09-25 | 2015-08-31 | Cytec Tech Corp | Preventing or reducing scale in wet-process phosphoric acid production |
| WO2011038108A1 (en) * | 2009-09-25 | 2011-03-31 | Cytec Technology Corp. | Process and reagents for the inhibition or reduction of scale formation during phosphoric acid production |
| US8900539B2 (en) | 2011-03-22 | 2014-12-02 | Cytec Technology Corp. | Preventing or reducing scale in wet-process phosphoric acid production |
| MA39205B1 (fr) | 2014-02-11 | 2018-11-30 | Cytec Ind Inc | Polymères contenant des amines primaires utiles en tant qu'inhibiteurs de tartre |
| LT3256420T (lt) | 2015-02-11 | 2025-07-25 | Cytec Industries Inc. | Modifikuotų aminų kaip nuovirų inhibitorių panaudojimas fosforo rūgšties gamyboje drėgnuoju būdu |
| US10759662B2 (en) * | 2018-03-12 | 2020-09-01 | Solenis Technologies, L.P. | Systems and methods for reducing formation of scale in phosphoric acid production |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2448218A (en) * | 1942-12-17 | 1948-08-31 | British Plaster Board Ltd | Manufacture of plaster of paris |
| US2968528A (en) * | 1957-07-01 | 1961-01-17 | Int Minerals & Chem Corp | Process for producing clarified phosphoric acid |
| GB1011163A (en) * | 1961-04-26 | 1965-11-24 | Dorr Oliver Inc | Manufacture of phosphoric acid |
| US3238142A (en) * | 1963-10-16 | 1966-03-01 | American Cyanamid Co | Antifoaming composition |
| GB1113922A (en) * | 1964-08-19 | 1968-05-15 | Fisons Ltd | Clarifying phosphoric acid |
| DE1238374B (de) * | 1965-04-24 | 1967-04-06 | Giulini Ges Mit Beschraenkter | Verfahren zur Herstellung von alpha-Calciumsulfat-Halbhydrat |
| US3397956A (en) * | 1966-07-28 | 1968-08-20 | Nalco Chemical Co | Process for manufacturing phosphoric acid |
| US3594123A (en) * | 1967-08-10 | 1971-07-20 | Arizona Chem | Enhancement of gypsum crystal growth in wet-process phosphoric acid |
| US3598755A (en) * | 1968-07-05 | 1971-08-10 | Continental Oil Co | Foam control agents |
| CA880214A (en) * | 1968-07-10 | 1971-09-07 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of National Defence Of Her Majesty's Canadian Government | Recovering phosphoric acid |
| US3645677A (en) * | 1968-09-24 | 1972-02-29 | Taki Fertilizer Mfg Co Ltd | Production of gypsum |
| US3554694A (en) * | 1969-06-02 | 1971-01-12 | Cities Service Co | Process for producing fluosilicates |
| DE2035505C3 (de) * | 1970-07-17 | 1974-06-12 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung reiner Alkaliphosphatlösungen |
| US3714330A (en) * | 1970-08-14 | 1973-01-30 | Cities Service Co | Treatment of phosphoric acid to recover alkali metal fluosilicates |
| US3796790A (en) * | 1972-04-25 | 1974-03-12 | Canadian Patents Dev | Process for recovering concentrated phosphoric acid |
-
1972
- 1972-11-08 GB GB5145472A patent/GB1451608A/en not_active Expired
-
1973
- 1973-10-16 ZA ZA00738038A patent/ZA738038B/xx unknown
- 1973-10-25 US US05/409,366 patent/US3972981A/en not_active Expired - Lifetime
- 1973-10-25 BE BE137083A patent/BE806533A/xx not_active IP Right Cessation
- 1973-10-29 NL NL7314813A patent/NL7314813A/xx not_active Application Discontinuation
- 1973-10-29 AT AT0911973A patent/AT363910B/de not_active IP Right Cessation
- 1973-10-30 CA CA184,624A patent/CA1032731A/en not_active Expired
- 1973-11-02 IN IN2421/CAL/1973A patent/IN141012B/en unknown
- 1973-11-06 DD DD174483A patent/DD111883A5/xx unknown
- 1973-11-06 SU SU731967924A patent/SU695549A3/ru active
- 1973-11-06 HU HUFI549A patent/HU168213B/hu unknown
- 1973-11-06 RO RO7376545A patent/RO63885A/ro unknown
- 1973-11-07 BR BR8671/73A patent/BR7308671D0/pt unknown
- 1973-11-07 FR FR7339491A patent/FR2205479B1/fr not_active Expired
- 1973-11-07 DE DE19732355607 patent/DE2355607A1/de not_active Withdrawn
- 1973-11-07 SE SE7315123A patent/SE389092B/xx unknown
- 1973-11-07 PL PL1973166379A patent/PL102163B1/pl unknown
- 1973-11-07 ES ES420313A patent/ES420313A1/es not_active Expired
- 1973-11-08 IT IT7331058A patent/IT1012092B/it active
- 1973-11-08 CS CS737666A patent/CS200462B2/cs unknown
- 1973-11-08 JP JP48125040A patent/JPS594379B2/ja not_active Expired
- 1973-11-28 OA OA55072A patent/OA04514A/xx unknown
-
1976
- 1976-01-09 SE SE7600174A patent/SE414164B/xx unknown
-
1983
- 1983-09-27 JP JP58177201A patent/JPS59152211A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2169115C1 (ru) * | 2000-08-23 | 2001-06-20 | Открытое акционерное общество "Невинномысский Внештрейдинвест" | Способ получения фосфорной кислоты |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |