GB1357029A - Sizing composition and glass fibres treated therewith - Google Patents

Sizing composition and glass fibres treated therewith

Info

Publication number
GB1357029A
GB1357029A GB4519071A GB4519071A GB1357029A GB 1357029 A GB1357029 A GB 1357029A GB 4519071 A GB4519071 A GB 4519071A GB 4519071 A GB4519071 A GB 4519071A GB 1357029 A GB1357029 A GB 1357029A
Authority
GB
United Kingdom
Prior art keywords
resin
glass fibres
film
applying
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4519071A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning
Original Assignee
Owens Corning Fiberglas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp
Publication of GB1357029A publication Critical patent/GB1357029A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/16—Yarns or threads made from mineral substances
    • D02G3/18—Yarns or threads made from mineral substances from glass or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/003—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/36—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06—Unsaturated polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
    • B29K2309/08—Glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1357029 Laminated products OWENSCORNING FIBERGLAS CORP 28 Sept 1971 [15 Oct 1970] 45190/71 Heading B5N [Also in Divisions C3 B2 and D1] Glass fibres are coated with a sizing composition comprising an aqueous dispersion of (i) a water-solubilized epoxy resin, e.g. the reaction product of a bisphenol A diglycidyl ether, a dialkanolamine and a polyglycol monoester such as polyethylene glycol mono-oleate, (ii) vinyl acetate/N-methylol acrylamide copolymer, (iii) vinyl acetate/ethylene copolymer, (iv) an organosilane, e.g. gamma-methacryloxy propyl trimethoxy-silane, (v) a wax, (vi) a glass-fibre lubricant and (vii) a silicone emulsion. A sheet moulding material is formed by applying a resin or resin filler mixture containing an alkaline earth metal oxide and/or hydroxide, e.g. Ca(OH) 2 to a polyethylene film, applying to this a layer of chopped glass fibres coated as above, applying additional resin paste on top. and another film of protective polyethylene film, compressing and puncturing at least one layer of film and further compressing. The resin mixture may comprise a polyester prepared from maleic anhydride optionally together with phthalio anhydride, and propylene glycol, methyl methacrylate copolymer, dicumyl peroxide and 2,5- dimethylhexyl-2,5-di-(peroxybenzoate), as catalyst, zinc stearate and CaCO 3 or polyethylene as filler.
GB4519071A 1970-10-15 1971-09-28 Sizing composition and glass fibres treated therewith Expired GB1357029A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US8115770A 1970-10-15 1970-10-15

Publications (1)

Publication Number Publication Date
GB1357029A true GB1357029A (en) 1974-06-19

Family

ID=22162454

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4519071A Expired GB1357029A (en) 1970-10-15 1971-09-28 Sizing composition and glass fibres treated therewith

Country Status (9)

Country Link
AU (1) AU470937B2 (en)
BE (1) BE774039A (en)
CA (1) CA937830A (en)
DE (1) DE2150974A1 (en)
FR (1) FR2110469B1 (en)
GB (1) GB1357029A (en)
NL (1) NL170868C (en)
SE (1) SE397062B (en)
ZA (1) ZA716921B (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2433604A1 (en) * 1978-08-14 1980-03-14 Ppg Industries Inc GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE IN STORAGE
US4358501A (en) 1978-08-14 1982-11-09 Ppg Industries, Inc. Storage stable polyolefin compatible size for fiber glass strands
US4413085A (en) 1978-08-21 1983-11-01 Ppg Industries, Inc. Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
GB2261664A (en) * 1991-10-22 1993-05-26 Coates Brothers Plc Coating compositions
FR2864072A1 (en) * 2003-12-17 2005-06-24 Saint Gobain Vetrotex Glass fibre coated with a sizing composition containing polyvinyl acetate, ethylene-vinyl acetate copolymer and epoxy resin, used for production of resin-fibre composites by open-mould or closed-mould methods
WO2007032988A1 (en) * 2005-09-12 2007-03-22 Ocv Intellectual Capital, Llc Glass fiber bundles for mat applications and methods of making the same
WO2007075202A1 (en) * 2005-12-28 2007-07-05 Ocv Intellectual Capital, Llc Compression and injection molding applications utilizing glass fiber bundles
CN103435272A (en) * 2013-09-10 2013-12-11 西安友基复合材料有限公司 Method for preparing alkali-resistant glass fibre jet yarn impregnating compound
CN103435273A (en) * 2013-09-10 2013-12-11 西安友基复合材料有限公司 Alkali-resistant glass fibre jet yarn impregnating compound
WO2015127479A3 (en) * 2014-02-24 2015-10-29 Green Theme Technologies Llc Composition and process for applying hydrophobic coating to fibrous substrates
CN111853652A (en) * 2020-06-30 2020-10-30 圣晖系统集成集团股份有限公司 Emergency lamp and manufacturing method thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2398702A1 (en) * 1977-07-28 1979-02-23 Saint Gobain PREPARATION OF GLASS FIBERS FOR SMC PREIMREGNES
FR2421982A1 (en) * 1978-04-03 1979-11-02 Saint Gobain SIZING COMPOSITION AND GLASS FIBERS TREATED WITH THIS COMPOSITION

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2433604A1 (en) * 1978-08-14 1980-03-14 Ppg Industries Inc GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE IN STORAGE
US4358501A (en) 1978-08-14 1982-11-09 Ppg Industries, Inc. Storage stable polyolefin compatible size for fiber glass strands
US4413085A (en) 1978-08-21 1983-11-01 Ppg Industries, Inc. Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
GB2261664A (en) * 1991-10-22 1993-05-26 Coates Brothers Plc Coating compositions
FR2864072A1 (en) * 2003-12-17 2005-06-24 Saint Gobain Vetrotex Glass fibre coated with a sizing composition containing polyvinyl acetate, ethylene-vinyl acetate copolymer and epoxy resin, used for production of resin-fibre composites by open-mould or closed-mould methods
WO2005058770A2 (en) * 2003-12-17 2005-06-30 Saint-Gobain Vetrotex France S.A. Sized glass fibres which are intended to reinforce polymer materials, such as by means of moulding
WO2005058770A3 (en) * 2003-12-17 2006-03-23 Saint Gobain Vetrotex Sized glass fibres which are intended to reinforce polymer materials, such as by means of moulding
WO2007032988A1 (en) * 2005-09-12 2007-03-22 Ocv Intellectual Capital, Llc Glass fiber bundles for mat applications and methods of making the same
WO2007075202A1 (en) * 2005-12-28 2007-07-05 Ocv Intellectual Capital, Llc Compression and injection molding applications utilizing glass fiber bundles
CN103435272A (en) * 2013-09-10 2013-12-11 西安友基复合材料有限公司 Method for preparing alkali-resistant glass fibre jet yarn impregnating compound
CN103435273A (en) * 2013-09-10 2013-12-11 西安友基复合材料有限公司 Alkali-resistant glass fibre jet yarn impregnating compound
CN103435272B (en) * 2013-09-10 2015-08-19 西安友基复合材料有限公司 Alkali resistant glass fibre sprays the preparation method of roving sizing agent
CN103435273B (en) * 2013-09-10 2015-08-19 西安友基复合材料有限公司 Alkali resistant glass fibre sprays roving sizing agent
WO2015127479A3 (en) * 2014-02-24 2015-10-29 Green Theme Technologies Llc Composition and process for applying hydrophobic coating to fibrous substrates
CN106414838A (en) * 2014-02-24 2017-02-15 绿色主题技术有限责任公司 Composition and process for applying hydrophobic coating to fibrous substrates
CN106414838B (en) * 2014-02-24 2019-08-06 绿色主题技术有限责任公司 Composition and method for being administered to hydrophobic coating in fibrous substrate
US10655272B2 (en) 2014-02-24 2020-05-19 Green Theme Technologies Inc. Composition and process for applying hydrophobic coating to fibrous substrates
US10919647B2 (en) 2014-02-24 2021-02-16 Green Theme Technologies, Inc. Composition and process for applying hydrophobic coating to fibrous substrates
CN111853652A (en) * 2020-06-30 2020-10-30 圣晖系统集成集团股份有限公司 Emergency lamp and manufacturing method thereof

Also Published As

Publication number Publication date
AU3222971A (en) 1973-02-15
NL170868B (en) 1982-08-02
ZA716921B (en) 1972-09-27
AU470937B2 (en) 1976-04-01
FR2110469A1 (en) 1972-06-02
DE2150974A1 (en) 1972-04-20
NL7114041A (en) 1972-04-18
CA937830A (en) 1973-12-04
BE774039A (en) 1972-04-17
NL170868C (en) 1983-01-03
FR2110469B1 (en) 1975-07-18
SE397062B (en) 1977-10-17

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee