GB1319191A - Process for reforming hydrocarbons - Google Patents

Process for reforming hydrocarbons

Info

Publication number
GB1319191A
GB1319191A GB983371*[A GB983371A GB1319191A GB 1319191 A GB1319191 A GB 1319191A GB 983371 A GB983371 A GB 983371A GB 1319191 A GB1319191 A GB 1319191A
Authority
GB
United Kingdom
Prior art keywords
nickel
rhenium
oxide
catalyst
alumina
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB983371*[A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1319191A publication Critical patent/GB1319191A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1319191 Hydrocarbon steam reformation catalysts E I DU PONT DE NEMOURS & CO 19 April 1971 [20 April 1970 1 March 1971] 9833/71 Heading B1E [Also in Division C5] Catalyst for use in steam reforming hydrocarbons comprises nickel oxide in combination with from 0.01 to 20 weight per cent, based on the amount of nickel, of rhenium which may be present in elemental form or in combined form, for example in the form of material selected from rhenium oxide, nickel perrhenate and nickel rhenate. The catalyst may contain, per part by weight of nickel, up to 100 parts by weight of a stabiliser or promoter, for example nickel chromite or an oxide of magnesium, calcium, strontium, barium, aluminium, silicon, titanium, zirconium, thorium, niobium, tantalum, chromium, molybdenum, tungsten, uranium, manganese, cerium, lanthenum, praseodymium or other individual or mixed rare earth metal(s) A preferred catalyst contains from 0.1 to 10 weight per cent of manganese oxide and from 0.05 to 5 weight per cent of rhenium. The catalyst also may comprise support material, for example a refractory oxide melting above 1500‹C, a ceramic, a metal or an alloy; exemplified support materials are magnesia (for example in the form of periclase), spinel, alumina, silica, silica-alumina, sillimanite, mullite, zirconia, thoria, chromia, lanthena, ceria, steel, stainless steel, nickel and alloys of nickel with aluminium, thorium, chromium or iron. The nickel oxide, rhenium and, if present, the stabiliser or promoter preferably constitute from 0.1 to 25 weight per cent of catalyst which comprises support material. The catalyst may be prepared by generally conventional procedures which may involve the use of an adhesive, for example alumina gel, colloidal boehmite, colloidal silica sol or nickel nitrate, or the use of a cement, for example selected from Sorel cement, calcium aluminate, alumina gel and colloidal alumina. Exemplified sources of nickel are nickel oxide, nitrate, sulphate, chloride, formate and acetate; exemplified sources of rhenium are rhenium oxide, perrhenic acid, sodium perrhenate, potassium perrhenate, ammonium perrhenate, rhenium oxytetrachloride, rhenium hexachloride and rhenium hexabromide; exemplified sources of the stabiliser or promoter are niobium tetrachloride, tantalum tetrachloride, ammonium molybdate, ammonium tungstate and the nitrates of magnesium, aluminium, thorium, uranium, mangenese and lenthenum. Examples relate to the preparation of catalyst from nickel nitrate, perrhenic acid, optionally manganese nitrate, and alpha-alumina particles having specified size, surface area, apparent density, pore size and pore volume (Examples 1 and 3) and from nickel nitrate, perrhenic acid and stainless steel wire in the form of loosely compacted pillows (Example 2).
GB983371*[A 1970-04-20 1971-04-19 Process for reforming hydrocarbons Expired GB1319191A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3025870A 1970-04-20 1970-04-20
US11981771A 1971-03-01 1971-03-01

Publications (1)

Publication Number Publication Date
GB1319191A true GB1319191A (en) 1973-06-06

Family

ID=26705833

Family Applications (1)

Application Number Title Priority Date Filing Date
GB983371*[A Expired GB1319191A (en) 1970-04-20 1971-04-19 Process for reforming hydrocarbons

Country Status (4)

Country Link
BE (1) BE765482A (en)
DE (1) DE2118907A1 (en)
GB (1) GB1319191A (en)
LU (1) LU62992A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0021736A2 (en) * 1979-06-27 1981-01-07 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
US4581157A (en) * 1981-12-21 1986-04-08 Imperial Chemical Industries Plc Catalyst and steam reforming process
EP1059262A1 (en) * 1999-06-08 2000-12-13 Matsushita Electric Industrial Co., Ltd. Fuel reforming apparatus
WO2001066247A2 (en) * 2000-03-03 2001-09-13 Union Carbide Chemicals & Plastics Technology Corporation A nickel-rhenium catalyst for use in reductive amination processes
EP2208529A3 (en) * 2008-12-30 2010-11-24 Samsung Electronics Co., Ltd. Hydrocarbon reforming catalyst, method of preparing the same and fuel cell including the hydrocarbon reforming catalyst
EP2298447A1 (en) * 2008-07-04 2011-03-23 JGC Corporation Catalyst for catalytic partial oxidation of hydrocarbon and process for producing synthesis gas

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4123462A (en) * 1976-01-07 1978-10-31 Union Carbide Corporation Amination process using nickel-rhenium catalysts
DE3915522A1 (en) * 1989-05-11 1990-11-15 Siemens Ag DRIVE DEVICE FOR A VACUUM SWITCH TUBE WITH A CONTACT SPRING
ES2342814B1 (en) * 2009-01-13 2011-05-23 Hynergreen Technologies, S.A CATALYST FOR A PROCESS FOR THE OBTAINING OF HYDROGEN BY REFORMED HYDROCARBONS WITH WATER VAPOR, PROCESS OF PREPARATION OF THE CATALYST AND USE OF THE SAME IN THE PROCESS.

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0021736A2 (en) * 1979-06-27 1981-01-07 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
EP0021736B1 (en) * 1979-06-27 1985-12-04 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
US4581157A (en) * 1981-12-21 1986-04-08 Imperial Chemical Industries Plc Catalyst and steam reforming process
US6534441B1 (en) 1999-03-06 2003-03-18 Union Carbide Chemicals & Plastics Technology Corporation Nickel-rhenium catalyst for use in reductive amination processes
EP1059262A1 (en) * 1999-06-08 2000-12-13 Matsushita Electric Industrial Co., Ltd. Fuel reforming apparatus
WO2001066247A2 (en) * 2000-03-03 2001-09-13 Union Carbide Chemicals & Plastics Technology Corporation A nickel-rhenium catalyst for use in reductive amination processes
WO2001066247A3 (en) * 2000-03-03 2002-04-11 Union Carbide Chem Plastic A nickel-rhenium catalyst for use in reductive amination processes
EP2298447A1 (en) * 2008-07-04 2011-03-23 JGC Corporation Catalyst for catalytic partial oxidation of hydrocarbon and process for producing synthesis gas
EP2298447A4 (en) * 2008-07-04 2014-07-09 Jgc Corp Catalyst for catalytic partial oxidation of hydrocarbon and process for producing synthesis gas
EP2208529A3 (en) * 2008-12-30 2010-11-24 Samsung Electronics Co., Ltd. Hydrocarbon reforming catalyst, method of preparing the same and fuel cell including the hydrocarbon reforming catalyst
US8633132B2 (en) 2008-12-30 2014-01-21 Samsung Electronics Co., Ltd. Hydrocarbon reforming catalyst, method of preparing the same and fuel cell including the hydrocarbon reforming catalyst

Also Published As

Publication number Publication date
LU62992A1 (en) 1971-08-26
DE2118907A1 (en) 1971-11-04
BE765482A (en) 1971-08-30

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee