GB1269788A - N-substituted-1-hydroxy-2-naphthamides and their use as cyan couplers - Google Patents
N-substituted-1-hydroxy-2-naphthamides and their use as cyan couplersInfo
- Publication number
- GB1269788A GB1269788A GB51868/69A GB5186869A GB1269788A GB 1269788 A GB1269788 A GB 1269788A GB 51868/69 A GB51868/69 A GB 51868/69A GB 5186869 A GB5186869 A GB 5186869A GB 1269788 A GB1269788 A GB 1269788A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxy
- naphthamide
- substituted
- reacting
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/333—Coloured coupling substances, e.g. for the correction of the coloured image
- G03C7/3335—Coloured coupling substances, e.g. for the correction of the coloured image containing an azo chromophore
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/34—Couplers containing phenols
- G03C7/344—Naphtholic couplers
Abstract
1,269,788. N - Substituted - 1 - hydroxy - 2- naphthamides and their uses as cyan couplers. KONISHIROKU PHOTO INDUSTRY CO. Ltd. 22 Oct., 1969 [24 Oct., 1968], No. 51868/69. Heading C2C. [Also in Divisions C4 and G2] The -invention comprises the compounds of the general formula wherein R 1 is a hydrogen or a methyl group; R 2 is a hydrogen atom or an aliphatic hydrocarbon radical having 1-16 carbon atoms; R 3 is an aliphatic hydrocarbon radical having 1-18 carbon atoms; n is zero or 1; and X is a hydrogen atom, or a substituted or unsubstituted phenylazo group. These compounds may be prepared by reacting an amino acid with an appropriate naphthoic acid derivative and reacting the resulting intermediate as a potassium salt with an alkyl (of 1 to 18 carbon atoms) ester of an α-halogeno fatty acid. N-Dodecyloxycarbonyl - methoxycarbonylmethyl - 1 - hyhydroxy - 2 - naphthamide is prepared by the reaction of 1 - hydroxy - 2 - naphthoylglycine with dodecyl - α - chloroacetate at a temperature of 95-100 C. The intermediate 1-hydroxy-2- naphthoyl glycine is obtained by treating glycine withphenyl-1-hydroxy-2-naphthoate; while dodecyl-α-chloroacetate is obtained by reacting α-chloroacetic acid and dodecyl alcohol. As representative compounds of the above formula there may be mentioned N-[1-(dodecyloxycarbonylmethoxycarbonyl) - ethyl] - 1 - hydroxy - 2 - naphthamide; N - dodecyloxycarbonyl - methoxycarbonylmethyl - 1 - hydroxy-4- chloro - 2 - naphthamide; N - [1 - dodecylcarbonyl - methoxycarbonyl) - ethyl] - 1 - hydroxy - 4 - (2 - acetylphenylazo) - 2 - naphthamide; and N - [2 - (dodecyloxycarbonylmethoxycarbonyl) - ethyl] - 1 - hydroxy - 4 - (2- ethoxycarbonylphenylazo)-2-naphthamide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7703068 | 1968-10-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1269788A true GB1269788A (en) | 1972-04-06 |
Family
ID=13622336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB51868/69A Expired GB1269788A (en) | 1968-10-24 | 1969-10-22 | N-substituted-1-hydroxy-2-naphthamides and their use as cyan couplers |
Country Status (3)
Country | Link |
---|---|
US (1) | US3619196A (en) |
DE (1) | DE1953372A1 (en) |
GB (1) | GB1269788A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1182472A (en) * | 1981-03-02 | 1985-02-12 | Kazimir Sestanj | N-[(2-naphthalenyl)thioxomethyl]glycine derivatives |
EP0711804A3 (en) | 1994-11-14 | 1999-09-22 | Ciba SC Holding AG | Latent light stabilizers |
WO2000064926A1 (en) * | 1999-04-26 | 2000-11-02 | Ajinomoto Co., Inc. | Melanocyte-stimulating hormone inhibitors |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL58022C (en) * | 1940-03-13 | |||
US2474293A (en) * | 1947-09-10 | 1949-06-28 | Eastman Kodak Co | 1-naphthol-2-carboxylic acid amide couplers for color photography |
US2562528A (en) * | 1949-01-21 | 1951-07-31 | Du Pont | Color former acetals of polyvinyl alcohol and substituted carbalkoxyacetamidobenzaldehydes |
US3418129A (en) * | 1963-12-27 | 1968-12-24 | Fuji Shoshin Film Kabushiki Ka | Color photographic silver halide emulsion |
US3481741A (en) * | 1964-09-10 | 1969-12-02 | Fuji Photo Film Co Ltd | Photographic silver halide elements containing magenta-colored cyanforming couplers |
GB1111342A (en) * | 1965-02-03 | 1968-04-24 | Fuji Photo Film Co Ltd | Colour photographic materials |
GB1099418A (en) * | 1965-07-28 | 1968-01-17 | Agfa Gevaert Nv | Photographic light-sensitive silver halide material containing colour couplers for cyan dyestuffs |
-
1969
- 1969-10-22 US US868579A patent/US3619196A/en not_active Expired - Lifetime
- 1969-10-22 GB GB51868/69A patent/GB1269788A/en not_active Expired
- 1969-10-23 DE DE19691953372 patent/DE1953372A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
DE1953372A1 (en) | 1970-05-21 |
US3619196A (en) | 1971-11-09 |
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