GB1253924A - Compounds having peroxy and aliphatic azo groups and methods using these as initiators - Google Patents

Compounds having peroxy and aliphatic azo groups and methods using these as initiators

Info

Publication number
GB1253924A
GB1253924A GB549569A GB549569A GB1253924A GB 1253924 A GB1253924 A GB 1253924A GB 549569 A GB549569 A GB 549569A GB 549569 A GB549569 A GB 549569A GB 1253924 A GB1253924 A GB 1253924A
Authority
GB
United Kingdom
Prior art keywords
aliphatic
radical
compounds
azo
peroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB549569A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Filter Wallace and Tiernan Inc
Original Assignee
Wallace and Tiernan Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wallace and Tiernan Inc filed Critical Wallace and Tiernan Inc
Publication of GB1253924A publication Critical patent/GB1253924A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/40—Peroxy compounds containing nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D273/00—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00
    • C07D273/08—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00 having two nitrogen atoms and more than one oxygen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,253,924. Azo-peroxy compounds. WALLACE & TIERNAN Inc. 31 Jan., 1969 [6 Feb., 1968], No. 5495/69. Heading C2C. [Also in Division C3] Novel azo-peroxy compounds of the general formula wherein m is 1 or 2, n is 1 to 20, R<SP>1</SP> is a radical of the formula or X is a peroxy containing radical selected from CO.OO.R 3 , OCO.OO.R 3 , C(R 1 )R 1 .OO.R 3 , -CO.OO.CO-, -OOH, -O.CO.OO.CO.O, and -CO.OO.C(R 1 ) 2 .R 5 .C(R 1 ) 2 .OO.CO-; Y is -CO.O- or -O.CO-; R 1 is an aliphatic radical having 1 to 10 carbon atoms, R 2 is R 1 OCO, H 2 NCO-, R 1 - , R 1 -O-, R 1 O.CO-, R 1 CO.O-, ArO-, ArCO.O-, NC-, N 3 -, Cl- or Br, where Ar is an aromatic radical of 6 to 12 C atoms; R 3 is C 4-10 tertiary aliphatic radical; R 5 is C 1-10 aliphatic diradical; R 6 is C 1-10 aliphatic diradical or C 6-12 aromatic diradical; R 1 and R 5 together with the tertiary carbon atom in R<SP>1</SP> may form a cycloaliphatic triradical and R is a tertiary aliphatic radical having 4 to 10 C atoms, R<SP>1</SP>-X or R<SP>1</SP> when m is 1, and X is a diradical are prepared by one of the following methods:- (a) the peroxidation of suitable substituted aliphatic azo compounds; (b) the coupling of peroxides and aliphatic azo compounds each containing functional groups that will interact to link the azo to the peroxide, for example esterification, etherification, and carbonate formation.
GB549569A 1968-02-06 1969-01-31 Compounds having peroxy and aliphatic azo groups and methods using these as initiators Expired GB1253924A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70324168A 1968-02-06 1968-02-06

Publications (1)

Publication Number Publication Date
GB1253924A true GB1253924A (en) 1971-11-17

Family

ID=24824609

Family Applications (1)

Application Number Title Priority Date Filing Date
GB549569A Expired GB1253924A (en) 1968-02-06 1969-01-31 Compounds having peroxy and aliphatic azo groups and methods using these as initiators

Country Status (4)

Country Link
DE (1) DE1905915A1 (en)
FR (1) FR2001422A1 (en)
GB (1) GB1253924A (en)
NL (1) NL6901772A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2483412A1 (en) * 1980-06-03 1981-12-04 Syrov Anatoly Bis-(carboxy- or hydroxymethylene) azo-bis- cyano-butyl peroxy derivs. - useful as initiators for free radical polymerisation

Also Published As

Publication number Publication date
FR2001422A1 (en) 1969-09-26
NL6901772A (en) 1969-08-08
DE1905915A1 (en) 1969-09-11

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