GB1204863A - Dimerization process - Google Patents

Dimerization process

Info

Publication number
GB1204863A
GB1204863A GB5497767A GB5497767A GB1204863A GB 1204863 A GB1204863 A GB 1204863A GB 5497767 A GB5497767 A GB 5497767A GB 5497767 A GB5497767 A GB 5497767A GB 1204863 A GB1204863 A GB 1204863A
Authority
GB
United Kingdom
Prior art keywords
propylene
ethylene
nix
pentene
dimers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5497767A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of GB1204863A publication Critical patent/GB1204863A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,204,863. Dimers and co-dimers. PHILLIPS PETROLEUM CO. 4 Dec., 1967 [5 Dec., 1966; 9 Oct., 1967], No. 54977/67. Heading C5E. Olefin dimers or codimers are made by contacting a cyclic monolefin having up to 12 C per mol. or an acyclic olefin having 2 to 12 C atoms and no branching nearer the double bond than the 3-position or a mixture of two such olefins with a catalyst composition formed on mixing (1) a nickel complex of formula (R 3 P) 2 NiY 2 , (R 3 PO) 2 NiX 2 , (R 3 AsO) 2 NiX 2 , or a complex of NiX 2 with where R represents a C 1-20 hydrocarbon radical, Y is a halogen or a radical as defined for R, X is halogen, n is 0 or 1 to 4, R<SP>11</SP> is hydrogen, CH 3 or C 2 H 5 and (2) an aluminium compound of formula R x AlX y , where R and X are as defined above and x and y are integers such that x+y=3, R and X in components (1) and (2) being the same or different. Specified monolefins are ethylene, propylene, butenes-1 and -2, pentenes-1 -2 and cyclo-, cyclohexene, 3: 4: 5- trimethylcyclohexene, 3-methylbutene-1, cycloheptene, hexene-2, heptene-1, cyclo-octene, 4: 4-dimethylheptene-2, decene-1, dodecene-1 and mixtures thereof. Examples describe the dimerization of ethylene, propylene, butene-1, pentene-1 and pentene-2, and the co-dimerization of ethylene and propylene, propylene and pentene-1, and ethylene and cyclopentene (to 1- ethylcyclopentene).
GB5497767A 1966-12-05 1967-12-04 Dimerization process Expired GB1204863A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59897566A 1966-12-05 1966-12-05
US67400467A 1967-10-09 1967-10-09

Publications (1)

Publication Number Publication Date
GB1204863A true GB1204863A (en) 1970-09-09

Family

ID=27083204

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5497767A Expired GB1204863A (en) 1966-12-05 1967-12-04 Dimerization process

Country Status (7)

Country Link
JP (1) JPS4939643B1 (en)
BE (1) BE707477A (en)
CA (1) CA1004235A (en)
DE (1) DE1667228A1 (en)
ES (1) ES347915A1 (en)
FR (1) FR1577248A (en)
GB (1) GB1204863A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009070858A1 (en) * 2007-12-05 2009-06-11 Braskem S. A. Integrated process for the production of ethylene-butylene copolymer, an ethylene-butylene copolymer and the use of ethylene and 1-butylene, as comonomer, sourced from renewable natural raw materials

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2709883C3 (en) * 1977-03-07 1981-07-16 Institut Neftechimiceskogo Sinteza Imeni A.V. Topcieva Akademii Nauk Sssr, Moskva Process for the dimerization or codimerization of olefins
DE2709885C3 (en) * 1977-03-07 1981-06-19 Institut neftechimi&ccaron;eskogo sinteza imeni A.V. Top&ccaron;ieva Akademii Nauk SSSR, Moskva Process for the dimerization of olefins
DE2709884C3 (en) * 1977-03-07 1981-07-23 Institut Neftechimiceskogo Sinteza Imeni A.V. Topcieva Akademii Nauk Sssr, Moskva Process for the dimerization or codimerization of olefins
JPS61187504U (en) * 1985-05-16 1986-11-22
JPS6346101A (en) * 1986-04-09 1988-02-27 アキレス株式会社 Antistatic shoes
FR2995893B1 (en) * 2012-09-21 2014-09-05 Axens PROCESS FOR THE PRODUCTION OF 1,3-BUTADIENE IMPLEMENTING THE ETHYLENE DIMERISATION AND THE DEHYDROGENATION OF THE BUTENES OBTAINED

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009070858A1 (en) * 2007-12-05 2009-06-11 Braskem S. A. Integrated process for the production of ethylene-butylene copolymer, an ethylene-butylene copolymer and the use of ethylene and 1-butylene, as comonomer, sourced from renewable natural raw materials
US8222354B2 (en) 2007-12-05 2012-07-17 Braskem S.A. Integrated process for the production of ethylene-butylene copolymer, an ethylene-butylene copolymer and the use of ethylene and 1-butylene, as comonomer, sourced from renewable natural raw materials

Also Published As

Publication number Publication date
DE1667228A1 (en) 1972-03-30
ES347915A1 (en) 1969-06-01
CA1004235A (en) 1977-01-25
JPS4939643B1 (en) 1974-10-28
BE707477A (en) 1968-06-04
FR1577248A (en) 1969-08-08

Similar Documents

Publication Publication Date Title
US3485881A (en) Dimerization of olefins
US3641189A (en) Disproportionation of olefines
GB1204863A (en) Dimerization process
GB1131146A (en) Oligomerisation process
US3483268A (en) Dimerisation process
GB1125529A (en) Olefin metathesis
GB1357632A (en) Process for the manufacture of higher olefins
GB1240025A (en) Dimerization of olefin hydrocarbons
US3689588A (en) Process for dimerization of olefins
GB1295673A (en)
GB1089486A (en) Process for the production of vulcanisable copolymers
GB1194857A (en) Dimerization of Olefins and Novel Catalyst therefor
GB832475A (en) Preparation of isoprene
GB1211973A (en) Polymerization with zeolitic catalysts
GB1453535A (en) Cracking feedstock containing c4 olefins
GB1298186A (en) PROCESS FOR THE CATALYTIC MIXED OLIGOMERIZATION OF 1,3-DIOLEFINS WITH alpha-UNSATURATED ORGANIC COMPOUNDS
GB1295476A (en)
GB1155003A (en) Oligomerisation of Olefines
ES356199A1 (en) Process for the production of c5-c8 olefines
GB1295913A (en)
GB876680A (en) Improvements in and relating to the dimerisation of olefines
KR960700206A (en) MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES
FR1604541A (en) Catalyst compsn. for use in (co)dimerisation of C2-4 alpha-alkenes, and ethylene with vinylcyclohexane consists of a complex of (I) bisacrolein-Ni, bisacrylonit
GB1158211A (en) Process for Oligomerizing alpha-Olefins.
GB912821A (en) Improvements in or relating to the polymerisation of unsaturated hydrocarbons

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee