GB1098659A - Improvements relating to the production of motor fuels and jet fuels - Google Patents
Improvements relating to the production of motor fuels and jet fuelsInfo
- Publication number
- GB1098659A GB1098659A GB28877/66A GB2887766A GB1098659A GB 1098659 A GB1098659 A GB 1098659A GB 28877/66 A GB28877/66 A GB 28877/66A GB 2887766 A GB2887766 A GB 2887766A GB 1098659 A GB1098659 A GB 1098659A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silica
- production
- catalyst
- sulphur
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000446 fuel Substances 0.000 title abstract 11
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 239000005864 Sulphur Substances 0.000 abstract 3
- 238000009835 boiling Methods 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A flexible method for the production of motor fuels and jet fuels from a hydrocarbon liquid fraction boiling between 400 DEG and 900 DEG F. by contacting the hydrocarbon in the presence of hydrogen under hydrocracking conditions with a hydrocracking catalyst comprising a hydrogenating component selected from the group consisting of metals and oxides of metals of Group VI or VIII, comprises recovering from the reaction product a motor fuel having an end point of about 400 DEG F., recycling to the hydrocracking zone a reaction product fraction boiling above the motor fuel range when less than 60% of the metallic hydrogenation components of the catalyst are sulphided, and recovering from the reaction product a fraction boiling through the jet fuel range when more than 60% of solid components of the catalyst are sulphided, addition of sulphur being controlled in dependence on the fuel which is to be produced, sulphur being removed from the feed to the hydrocracking zone as the production of motor fuel is to be promoted, and sulphur being added to or allowed to remain in the feed to the hydrocracking zone when the production of jet fuel is to be promoted. Sulphur compounds may be added to the hydrogen or the charge stock or may be those naturally present in the charge stock. To produce motor fuel over a prolonged period the charge stock must first be desulphurized. The catalyst may be chromium, tungsten, cobalt, nickel, platinum, palladium, osmium or rhodium on a base of silica-alumina, silica-magnesia, silica-titania, silica-zirconia or a clay; the base may be treated with HF. The base may also be a molecular sieve.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US468932A US3395095A (en) | 1965-07-01 | 1965-07-01 | Hydrocracking of hydrocarbons with the constant addition of sulfur to the reaction zone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1098659A true GB1098659A (en) | 1968-01-10 |
Family
ID=23861812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28877/66A Expired GB1098659A (en) | 1965-07-01 | 1966-06-28 | Improvements relating to the production of motor fuels and jet fuels |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3395095A (en) |
| DE (1) | DE1275236B (en) |
| GB (1) | GB1098659A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3501545A (en) * | 1968-12-27 | 1970-03-17 | Union Carbide Corp | Process for recovering the aromatic value of sulfur-containing still bottoms formed during the refining of styrene |
| US4831207A (en) * | 1987-03-05 | 1989-05-16 | Uop | Chemical processing with an operational step sensitive to a feedstream component |
| US4831208A (en) * | 1987-03-05 | 1989-05-16 | Uop | Chemical processing with an operational step sensitive to a feedstream component |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB541067A (en) * | 1939-04-03 | 1941-11-12 | Standard Oil Dev Co | Improvements relating to the catalytic treatment of hydrocarbons |
| US3099617A (en) * | 1960-08-04 | 1963-07-30 | Union Oil Co | Pretreatment of catalyst employed in the hydrocracking of hydrocarbons |
| US3132090A (en) * | 1962-01-23 | 1964-05-05 | Union Oil Co | Hydrocracking process with regulation of the aromatic content of the product |
| NL298382A (en) * | 1962-09-25 |
-
1965
- 1965-07-01 US US468932A patent/US3395095A/en not_active Expired - Lifetime
-
1966
- 1966-06-28 GB GB28877/66A patent/GB1098659A/en not_active Expired
- 1966-06-30 DE DET31496A patent/DE1275236B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE1275236B (en) | 1968-08-14 |
| US3395095A (en) | 1968-07-30 |
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