GB1063822A - Process for producing backing materials - Google Patents

Process for producing backing materials

Info

Publication number
GB1063822A
GB1063822A GB13193/64A GB1319364A GB1063822A GB 1063822 A GB1063822 A GB 1063822A GB 13193/64 A GB13193/64 A GB 13193/64A GB 1319364 A GB1319364 A GB 1319364A GB 1063822 A GB1063822 A GB 1063822A
Authority
GB
United Kingdom
Prior art keywords
vinyl
chloride
acetate
solution
polyvinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13193/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Deutsche Gold und Silber Scheideanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Deutsche Gold und Silber Scheideanstalt filed Critical Degussa GmbH
Publication of GB1063822A publication Critical patent/GB1063822A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0042—Conductive or insulating layers; Antistatic layers; Flame-proof layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride

Abstract

Coating compositions comprise (a) 35 to 90 parts by weight of a paste composed of a vinyl chloride polymer and a platicizer, (b) 65 to 10 parts by weight of a paste of electrically conductive carbon black and just sufficient plasticizer to form a paste, and (c) 2 to 12 parts of a 15 to 40 weight per cent solution of polymers in organic solvents. The vinyl chloride polymer may be polyvinyl chloride or a copolymer of vinyl chloride with vinylacetate, vinyl propionate, vinylidene chloride, acrylic, methacrylic or maleic acids and the esters thereof or vinyl isobutyl ether. Specified carbon blacks are acetylene, furnace and channel blacks. Specified plasticizers are dioctyl phthalate, butyl benzyl phthalate dioctyl adipate, dioctyl sebacate, dioctyl azelate, glycol phthalate and glycol adipate, which may be used together with extenders, e.g. high fatty alcohols, fatty acid esters and chlorinated hydrocarbons. The polymer solution may be a solution of a copolymer of vinyl chloride with vinyl acetate, styrene, vinylidene chloride, fumaric acid or maleic acid in esters, ketones or ethers, e.g. ethyl acetate, butyl acetate, methyl glycol acetate, acetone methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, tetrahydrofuran, dioxane, diisopropyl ether and mixtures thereof. The compositions may also comprise fillers, e.g. chalk, silica, talc, heavy spar and graphite; dyestuffs and pigments; stabilizers and ultra-violet light absorbents; adherence promoters; lubricants; blowing agents cross-linking agents and flame retardants, e.g. antimony trioxide and magnesium carbonate; and may be used for coating wood, metals, wires, plastic foils, knitted and woven fabrics, fleeces, felts and paper to give artificial leathers and antistatic materials, e.g. for mine ducts. Examples describe compositions comprising (1) (a) polyvinyl chloride, antimony oxide, dibutyl tin dilaurate, dioctyl phthalate, fatty acid ester and polyoxyethylene sorbitan monolaurate, (b) carbon black, dioctyl phthalate and dioctyl adipate, and (c) a solution of a vinyl chloride/vinyl acetate/dicarboxylic acid copolymer in ethyl acetate and tetrahydrofuran; (2) a polyvinyl chloride, graphite, dibutyl tin dilaurate, dioctyl phthalate, fatty acid ester and polyoxyethylene sorbitan monolaurate, (b) and (1)(b), and (c) a solution of a vinyl chloride/vinyl acetate/dicarboxylic acid copolymer and an epichlorhydrin - Bisphenol A condensate in methyl isobutyl ketone and methyl glycol acetate, to which an ethyl acetate solution of a condensate of toluylene-2,4-diisocyanate and a polyalcohol is added; (3)(a) as (2)(a), (b) as 1(b), and (c) a solution of a vinyl chloride/vinyl acetate/dicarboxylic acid copolymer in methyl isobutyl ketone; (4)(a) as (1)(a), (b) as 1(b), and (c) a solution of a vinyl chloride/vinyl acetate/dicarboxylic acid copolymer and an epichlorhydrin-Bisphenol A condensate in ethyl acetate and methyl isobutyl ketone, and graphite; (5)(a) polyvinyl chloride, graphite, dibutyltin dilaurate, dioctyl phthalate, fatty acid ester, polyoxyethylene sorbitan monolaurate and an azo dicarboxylic acid amide, (b) as (1)(b), and (c) as (1)(c), which is applied to grey cotton cloth and cured to give a foamed coating.ALSO:Impermeable and porous substrates are provided with antistatic or electrically conductive coatings by applying thereto and thermally treating pasty compositions comprising (a) 35 to 90 parts by weight of an initial paste composed of polyvinyl chloride and/or vinyle chloride copolymers and a plasticiser therefor, (b) 65 to 10 parts by weight of a carbon black paste prepared from electrically conductive carbon black with an amount of a plasticiser for vinyl chloride polymers just sufficient to form a paste, and (c) 2 to 12 parts by weight of a 15 to 40 weight percent solution of polymers in organic solvents. Specified substrates are paper, wood, metals, wires, plastic foils, woven or knitted fabrics, fleeces and felts. The coating compositions may also comprise adherence promoters, stabilisers, cross-linking or expanding agents, extenders, dye-stuffs and fillers. The compositions may be applied by spreading or dipping, and any excess material removed by doctor blades, squeeze rolls or air stripping. Several coats may be applied. In examples substrates formed by laminating polyvinyl chloride foils to polyester fabrics are coated using a doctor blade with compositions comprising 1 (a) polyvinyl chloride, antimony oxide, dibutyl tin dilaurate, dioctyl phthalate, fatty acid ester and polyoxyethylene sorbitan monolaurate, 1 (b) carbon black, dioctyl phthalate and dioctyl adipate and 1 (c) a vinyl chloride / vinyl acetate / dicarboxylic acid terpolymer, ethyl acetate and tetrahydrofuran; 3 (a) polyvinyl chloride, graphite, dibutyl tin dilaurate, dioctyl phthalate, fatty acid ester and polyoxyethylene sorbitan monolaurate, 3(b) as 1(b) and 3(c) a vinyl chloride/vinyl acetate/dicarboxylic acid terpolymer and methyl isobutyl ketone; and 4(a) as 1(a), 4(b) as 1(b) and 4(c) a vinyl chloride/vinyl acetate/dicarboxylic acid terpolymer, an epichlorohydrin/bis phenol A condensate, graphite, ethyl acetate and methyl isobutyl ketone; two coats being applied to the fabric side and one to the foil side: a nylon fabric substrate is coated on both sides by dipping and again by means of a doctor blade with compositions comprising 2(a) as 3(a), 2(b) as 1(b) and 2(c) the above terpolymer, an epichlorohydrin/bis phenol. A condensate, a toluylene diisocyanate/polyol condensate, methyl isobuty ketone and methyl glycol acetate: grey cotton cloth is coated with the composition of Example 1 and subsequently with a composition comprising polyvinyl chloride, graphite, dibutyl tin dilaurate, dioctyl phthalate, fatty acid ester, polyoxyethylene sorbitan monolaurate and an azodicarboxylic acid amide and the paste of 1b and solution of 1c, which layer is expanded by heating: and polyester net fabric is dip coated with a composition comprising polyvinyl chloride, dioctyl phthalate, dioctyl adipate, an alkyl epoxy stearate, polypropylene glycol adipate, trichlorethyl phosphate, triethylene glycol dicaprylate, antimony oxide, dibutyl tin dilaurate and carbon black, and subsequently with a composition as in Example 1.
GB13193/64A 1963-03-29 1964-03-31 Process for producing backing materials Expired GB1063822A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DED41247A DE1253665B (en) 1963-03-29 1963-03-29 Process for the production of synthetic leather-like laminates
DED41248A DE1286669B (en) 1963-03-29 1963-03-29 Process for the production of a spreadable paste from polyvinyl chloride, carbon black and plasticizer for the production of antistatic to electrically conductive coatings or layers

Publications (1)

Publication Number Publication Date
GB1063822A true GB1063822A (en) 1967-03-30

Family

ID=25971606

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13193/64A Expired GB1063822A (en) 1963-03-29 1964-03-31 Process for producing backing materials

Country Status (5)

Country Link
BE (1) BE645717A (en)
CH (1) CH432452A (en)
DE (2) DE1286669B (en)
GB (1) GB1063822A (en)
NL (1) NL6403204A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2245195A (en) * 1990-06-04 1992-01-02 Tomoegawa Paper Co Ltd Conductive substrate comprising carbon black
WO2005026246A1 (en) * 2003-09-16 2005-03-24 Isca Uk Limited Fire retardant coating
EP2275499A3 (en) * 2007-11-01 2011-04-27 E.M.A.T. Technologies Ltd. Polymer-based fire-retarding formulations
US20120308806A1 (en) * 2009-06-03 2012-12-06 Gerald Leto Material for use with a capacitive touch screen
CN103255675A (en) * 2013-04-08 2013-08-21 上海东升新材料有限公司 Water-soluble lubricant for papermaking

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL207952A (en) * 1955-06-13
BE555889A (en) * 1956-03-23
AT188907B (en) * 1958-11-05 1957-03-25 Semperit Ag Flooring
GB889651A (en) * 1958-11-28 1962-02-21 Kaybar Inc Articles having a textured surface of leather-like character and method for their production

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2245195A (en) * 1990-06-04 1992-01-02 Tomoegawa Paper Co Ltd Conductive substrate comprising carbon black
GB2245195B (en) * 1990-06-04 1994-11-30 Tomoegawa Paper Co Ltd Conductive substrate
US5384190A (en) * 1990-06-04 1995-01-24 Tomoegawa Paper Co., Ltd. Conductive substrate comprising carbon black and inorganic powders
WO2005026246A1 (en) * 2003-09-16 2005-03-24 Isca Uk Limited Fire retardant coating
EP2275499A3 (en) * 2007-11-01 2011-04-27 E.M.A.T. Technologies Ltd. Polymer-based fire-retarding formulations
US20120308806A1 (en) * 2009-06-03 2012-12-06 Gerald Leto Material for use with a capacitive touch screen
US9051621B2 (en) * 2009-06-03 2015-06-09 Glt Technovations, Llc Material for use with a capacitive touch screen
US20160015100A1 (en) * 2009-06-03 2016-01-21 Glt Technovations, Llc Material for use with a capacitive touch screen
CN103255675A (en) * 2013-04-08 2013-08-21 上海东升新材料有限公司 Water-soluble lubricant for papermaking
CN103255675B (en) * 2013-04-08 2015-07-29 上海东升新材料有限公司 Paper grade (stock) soluble oil

Also Published As

Publication number Publication date
DE1253665B (en) 1967-11-09
BE645717A (en) 1964-07-16
CH432452A (en) 1967-03-31
DE1286669B (en) 1969-01-09
NL6403204A (en) 1964-09-30

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