GB1047068A - Improvements relating to self-curing polymers - Google Patents

Improvements relating to self-curing polymers

Info

Publication number
GB1047068A
GB1047068A GB3001064A GB3001064A GB1047068A GB 1047068 A GB1047068 A GB 1047068A GB 3001064 A GB3001064 A GB 3001064A GB 3001064 A GB3001064 A GB 3001064A GB 1047068 A GB1047068 A GB 1047068A
Authority
GB
United Kingdom
Prior art keywords
butadiene
sodium
latices
polymerization
interpolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3001064A
Inventor
Clifford Maynard Thomas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Geon Ltd
Original Assignee
British Geon Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Geon Ltd filed Critical British Geon Ltd
Priority to GB3001064A priority Critical patent/GB1047068A/en
Priority to NL6509310A priority patent/NL6509310A/xx
Priority to FR26373A priority patent/FR1481042A/en
Publication of GB1047068A publication Critical patent/GB1047068A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Interpolymers are derived from polymerizable mixtures comprising (1) less than 50% but not less than 5% of a conjugated diene, (2) 94.8% to 49.8% of a monoalkenyl monomer copolymerizable with said diene, (3) 0.1 to 10% of an N-alkylolamide of an a ,b -olefinically unsaturated carboxylic acid and (4) 0.1 to 10% of an a ,b -olefinically unsaturated acid. The preferred polymer is prepared from butadiene, n-butyl acrylate, N-methylol acrylamide and methacrylic acid. Polymerization may be in an aqueous medium, e.g. emulsion polymerization. Specified emulsifiers are sodium lauryl sulphate, the alkali metal salts of sulphonated petroleum or paraffin oils, the sodium salt of naphthalene sulphonic acid, sodium dodecyl benzene sulphonate, sodium dioctyl sulphosuccinate, sodium N-octadecyl sulphosuccinimate, organic phosphate esters or their alkali metal salts, lauryl amine hydrochloride, dodecyl trimethyl ammonium bromide, polyether alcohols, fatty alkylolamine condensates and diglycol esters of lauric, oleic and stearic acids. The polymerization pH is preferably 7 to 9. Catalysts specified are hydrogen, benzoyl and caprylyl peroxides, cumene hydroperoxide and sodium, potassium and ammonium persulphates. Inorganic salts and antioxidants, e.g. hindered phenols may be present during polymerization. Post-polymerization emulsifiers may be added to the interpolymer latices produced and the latices may be mixed with latices of polyvinylchloride and vinyl chloride copolymers, butadiene-styrene and butadieneacrylonitrile copolymers, polyethylacrylate or thermosetting resins, e.g. melamine-formaldehyde resins. In Examples (1) and (2) interpolymer latices of the previously specified monomers are produced.ALSO:An aqueous latex of an interpolymer of 5% to less than 50% of a conjugated diene, 94.8% to 49.8% of a monoalkenyl monomer, 0.1 to 10% of an N-alkylolamide of an a ,b -olefinically unsaturated carboxylic acid and 0.1 to 10% of an a ,b -olefinically unsaturated carboxylic acid is used as a saturant for non-woven fabrics. The preferred interpolymer is of butadiene, n-butyl acrylate, N-methylol acrylamide and methacrylic acid. The latex may be admixed with latices or dispersions of other rubber or plastic materials e.g. polyvinyl chloride and vinyl chloride copolymers, butadiene-styrene or butadiene-acrylonitrile copolymers, polyethyl acrylate or melamine-formaldehyde resins.
GB3001064A 1964-07-28 1964-07-28 Improvements relating to self-curing polymers Expired GB1047068A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB3001064A GB1047068A (en) 1964-07-28 1964-07-28 Improvements relating to self-curing polymers
NL6509310A NL6509310A (en) 1964-07-28 1965-07-19
FR26373A FR1481042A (en) 1964-07-28 1965-07-28 Improved self-hardening polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3001064A GB1047068A (en) 1964-07-28 1964-07-28 Improvements relating to self-curing polymers

Publications (1)

Publication Number Publication Date
GB1047068A true GB1047068A (en) 1966-11-02

Family

ID=10300806

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3001064A Expired GB1047068A (en) 1964-07-28 1964-07-28 Improvements relating to self-curing polymers

Country Status (2)

Country Link
GB (1) GB1047068A (en)
NL (1) NL6509310A (en)

Also Published As

Publication number Publication date
NL6509310A (en) 1966-01-31

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