FR3105238B1 - MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF - Google Patents

MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF Download PDF

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Publication number
FR3105238B1
FR3105238B1 FR1915576A FR1915576A FR3105238B1 FR 3105238 B1 FR3105238 B1 FR 3105238B1 FR 1915576 A FR1915576 A FR 1915576A FR 1915576 A FR1915576 A FR 1915576A FR 3105238 B1 FR3105238 B1 FR 3105238B1
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FR
France
Prior art keywords
masterbatch
manufacturing
modified polymer
organophosphorus additive
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1915576A
Other languages
French (fr)
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FR3105238A1 (en
Inventor
Nathalie Coste
Adeline Jasselin
-Dit-Dominique François Jean-Baptiste
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Priority to FR1915576A priority Critical patent/FR3105238B1/en
Priority to PCT/FR2020/052419 priority patent/WO2021130430A1/en
Priority to CN202080090040.3A priority patent/CN114901728A/en
Priority to CA3160414A priority patent/CA3160414A1/en
Priority to BR112022011379A priority patent/BR112022011379A2/en
Publication of FR3105238A1 publication Critical patent/FR3105238A1/en
Application granted granted Critical
Publication of FR3105238B1 publication Critical patent/FR3105238B1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5397—Phosphine oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/26—Elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00—Characterised by the use of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00—Characterised by the use of unspecified polymers
    • C08J2400/26—Elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2407/00—Characterised by the use of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L’invention concerne un procédé de fabrication d’un mélange maître comprenant les étapes suivantes : mettre en contact au moins un polymère initial comportant au moins une insaturation carbone-carbone avec au moins un agent de greffage 1,3-dipolaire porteur d’au moins un dipôle oxyde de nitrile et d’au moins une fonction imidazolidinone N-substituée ou non-substituée en présence d’au moins un additif organophosphoré choisi dans le groupe constitué par les triesters d’acide phosphorique, les phosphonates, les phosphinates, les oxydes de phosphines et les mélange de ces composés, récupérer le mélange maître obtenu à l’étape précédente. L’invention concerne également un mélange maître, une composition comprenant un mélange maitre et un pneumatique comprenant ladite composition.The invention relates to a method for manufacturing a masterbatch comprising the following steps: contacting at least one initial polymer comprising at least one carbon-carbon unsaturation with at least one 1,3-dipolar grafting agent carrying at least least one nitrile oxide dipole and at least one N-substituted or unsubstituted imidazolidinone function in the presence of at least one organophosphorus additive chosen from the group consisting of phosphoric acid triesters, phosphonates, phosphinates, phosphine oxides and mixtures of these compounds, recover the masterbatch obtained in the previous step. The invention also relates to a masterbatch, a composition comprising a masterbatch and a tire comprising said composition.

FR1915576A 2019-12-24 2019-12-24 MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF Active FR3105238B1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1915576A FR3105238B1 (en) 2019-12-24 2019-12-24 MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF
PCT/FR2020/052419 WO2021130430A1 (en) 2019-12-24 2020-12-14 Masterbatch made from a modified polymer and an organophosphorus additive and method for producing same
CN202080090040.3A CN114901728A (en) 2019-12-24 2020-12-14 Master batch made of modified polymer and organophosphorus additive and preparation method thereof
CA3160414A CA3160414A1 (en) 2019-12-24 2020-12-14 Masterbatch made from a modified polymer and an organophosphorus additive and method for producing same
BR112022011379A BR112022011379A2 (en) 2019-12-24 2020-12-14 STANDARD MIXTURE BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND ITS MANUFACTURING PROCESS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1915576 2019-12-24
FR1915576A FR3105238B1 (en) 2019-12-24 2019-12-24 MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF

Publications (2)

Publication Number Publication Date
FR3105238A1 FR3105238A1 (en) 2021-06-25
FR3105238B1 true FR3105238B1 (en) 2022-12-23

Family

ID=70008817

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1915576A Active FR3105238B1 (en) 2019-12-24 2019-12-24 MASTERBATCH BASED ON A MODIFIED POLYMER AND AN ORGANOPHOSPHORUS ADDITIVE AND METHOD FOR MANUFACTURING THEREOF

Country Status (5)

Country Link
CN (1) CN114901728A (en)
BR (1) BR112022011379A2 (en)
CA (1) CA3160414A1 (en)
FR (1) FR3105238B1 (en)
WO (1) WO2021130430A1 (en)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2740778A1 (en) 1995-11-07 1997-05-09 Michelin & Cie SILICA-BASED RUBBER COMPOSITION AND FUNCTIONALIZED DIENE POLYMER HAVING TERMINAL SILANOL FUNCTION
CN1257211C (en) 2000-07-31 2006-05-24 米其林技术公司 Running tread for tyre
CA2457769C (en) 2001-08-13 2011-04-26 Rhodia Chimie Method of preparing silicas, silicas with specific pore-size and/or particle-size distribution and the use thereof, in particular for reinforcing polymers
DE60225300T2 (en) 2001-08-13 2009-02-26 Société de Technologie Michelin VEHICLE COMPOSITION FOR TIRES WITH A SPECIAL SILICONE AS REINFORCING FILLER
BRPI0705025A2 (en) 2007-12-14 2009-08-11 Petroflex Ind E Com S A 1,3-butadiene and styrene copolymer product functionalized at the ends of its polymeric chains and their preparation process
FR2962733B1 (en) 2010-07-13 2012-08-17 Michelin Soc Tech POLYMER GRAFTED BY NITROGEN ASSOCIATIVE MOLECULES.
FR2962737B1 (en) 2010-07-13 2012-08-17 Michelin Soc Tech RUBBER COMPOSITION CONTAINING MODIFIED ELASTOMER, PROCESS FOR PREPARING THE SAME AND PNEUMATIC CONTAINING THE SAME
FR3038607A1 (en) * 2015-07-10 2017-01-13 Michelin & Cie A 1,3-DIPOLAR COMPOUND HAVING A PHOSPHORUS GROUP AND A DIPOLE CONTAINING A NITROGEN ATOM.
FR3068694B1 (en) 2017-07-04 2019-07-26 Arkema France POLYAROMATIC MOLECULE WITH AN OXIDE FUNCTION OF NITRILE
FR3068703A1 (en) * 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin COMPOSITION BASED ON AT LEAST ONE PARTICULAR POLYAROMATIC COMPOUND

Also Published As

Publication number Publication date
FR3105238A1 (en) 2021-06-25
BR112022011379A2 (en) 2022-08-23
WO2021130430A1 (en) 2021-07-01
CN114901728A (en) 2022-08-12
CA3160414A1 (en) 2021-07-01

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