FR2864779A1 - Composition for washing keratinic materials, especially hair, comprises an aqueous medium, an amine-functional silicone, an anionic, nonionic or amphoteric surfactant and a stringy polymer - Google Patents

Abstract

Composition for washing keratinic materials comprises an aqueous medium, an amine-functional silicone, an anionic, nonionic or amphoteric surfactant and a stringy polymer with a string length of more than 5 cm.

Description

2864779 1

  DETERGENT COSMETIC COMPOSITIONS COMPRISING A

  AMINO SILICONE AND A THREAD POLYMER AND USE THEREOF

LATEST

  The present invention relates to novel cosmetic compositions with improved properties intended simultaneously for the cleaning, conditioning and styling of keratin materials, in particular the hair, and comprising, in a cosmetically acceptable support, a washing base consisting of detergent surfactants in which amino silicones are also present in combination with particular high molecular weight polymers. The invention also relates to the use of said compositions in the aforementioned cosmetic application.

  For cleaning and / or washing the hair, the use of detergent hair compositions (or shampoos) essentially based on conventional surfactants such as anionic, nonionic and / or amphosteric surfactants, but more particularly of the type anionic, is common. These compositions are applied to wet hair and the foam generated by massage or friction with the hands allows, after rinsing with water, the elimination of various soils initially present on the hair.

  Although these basic compositions have a good washing power, the intrinsic cosmetic properties attached to them remain rather weak, in particular because the relatively aggressive nature of such a cleaning treatment can lead in the long run to the fiber. capillary more or less marked damage related in particular to the progressive elimination of lipids or proteins contained in or on the surface of the latter.

  Also, to improve the cosmetic properties of the above detergent compositions, and more particularly those which are to be applied to hair sensitized (ie hair which is damaged or weakened especially under the chemical action of atmospheric agents and / or hair treatments such as permanent dyes or discolorations), it is now customary to introduce in the latter additional cosmetic agents known as conditioning agents intended mainly to repair or limit the adverse or undesirable effects induced by the various treatments or aggressions that undergo more or less repeated, the hair fibers. These conditioning agents can of course also improve the cosmetic behavior of natural hair.

  The most commonly used conditioning agents in shampoos today are the cationic polymers, which in effect give the washed, dry or wet hair a much greater ease of demixing, smoothness and smoothness compared to what can be obtained. with the corresponding cleaning compositions which are free of it.

  Moreover, for some time now, it has been sought to obtain conditioning shampoos that are capable of providing the washed hair with not only the cosmetic properties mentioned above but also, to a greater or lesser degree, styling and volume properties. , shaping and holding. The latter cleansing shampoos with improved general cosmetic properties are often called, for simplicity, "shampoos with styling effects", an expression that will be repeated later in the presentation.

  However, and despite recent progress in the field of shampoos styling effects, they are not really completely satisfactory, so that a strong need still exists now to have new products with, at the level of the one or more of the cosmetic properties mentioned above, better performance. In particular, it is most often necessary to use a styling product after the shampoo to give a shape to the hair and to fix the hairstyle.

  The present invention aims to satisfy such a need.

  Thus, following important research conducted on the subject, it has now been found by the Applicant, in a totally unexpected and surprising manner, that by combining amino silicones, as defined below, with certain polymers. Having a particular spinning power in detergent compositions, it is possible to significantly and significantly improve the styling and holding properties, and this while maintaining their intrinsic good washing power and their cosmetic properties.

  In particular, these compositions make it possible to obtain a very good maintenance and a certain volume of the hair, that is to say a styling effect similar to that obtained with a fixing styling gel used after shampooing. It is also noted that the keratinous fibers are reinforced (hardened).

  All these discoveries are at the basis of the present invention.

  Thus, according to the present invention, it is now proposed new compositions for washing keratinous substances, in particular hair comprising, in a cosmetically acceptable aqueous medium, at least one aminosilicone, at least one anionic, nonionic or amphoteric detergent surfactant. and at least one polymer having a spinning power greater than 5 cm.

  The subject of the invention is also the use in cosmetics of the above compositions for cleaning, conditioning, care and styling of keratin materials, in particular the hair and the eyelashes.

  Another subject of the invention consists of a process for the cosmetic treatment of keratinous materials, in particular keratinous fibers using the composition according to the invention and more particularly the hair and the eyelashes.

  The invention also relates to a use of the composition according to the invention as a shampoo.

  However, other features, aspects and advantages of the invention will emerge even more clearly on reading the description which follows, as well as concrete but not limiting examples intended to illustrate it.

  The spinning power of a polymer corresponds to the length of the polymer yarn obtained at the breaking of said yarn according to the procedure defined below.

  ethylene oxide 12.5% Cocoamidopropylbetaine 2.5% Polymer to be tested 1% Water qs 100%.

  The measurement of the spinning power is done using a texture analyzer TATX2 (Rhéo / stable Micro Systems) The measurement is done after compression of the product: Displacement of the disc (cylinder 35 mm in aluminum) with the speed of 2, 5 mm / s and detection of the compressive strength Penetration in the product at the same speed to a depth of 10 mm - Removal of the probe at a speed of 2.5 mm / s Measurement of the displacement of the probe and detection of According to the present invention, the polymers having a spinning power greater than 5 cm will also be referred to as spinning polymers.

  The polymers having a spinning power greater than 5 cm are in particular either (a1) a dispersion of particles of a water-soluble polymer. The spin-power of the polymers that can be used according to the invention is that which is measured for a composition containing (% by weight) : 2.2 mole oxyethylenated sodium lauryl ether sulphate having a weight average molecular weight of greater than 10 6 in an aqueous salt solution, obtained by heterogeneous radical polymerization of water-soluble monomers with precipitation of the polymer formed, at least one of the monomers being cationic or (a2) an aqueous solution of a water soluble polymer having a weight average molecular weight greater than 106, obtained by heterogeneous radical polymerization of water-soluble monomers with precipitation of the polymer formed, at least one of the monomers being cationic.

  The water-soluble polymer of high molecular weight is a cationic or amphoteric polyelectrolyte, that is to say a polyelectrolyte polymerized from at least one cationic monomer of formula (I).

  As indicated above, the synthesis of the high molecular weight water-soluble polymers used in the present invention is by heterogeneous radical polymerization of water-soluble monomers having at least one ethylenic unsaturation. The polymerization is carried out in an aqueous solution of a mineral electrolyte (salt) having an ionic strength sufficient to cause the precipitation of the formed polymer as soon as it reaches a certain molecular weight. This polymerization technique thus makes it possible, thanks to the well-known salt-salting-out phenomenon, to produce aqueous saline dispersions of water-soluble polymer particles. The polymers thus synthesized are distinguished by a high weight average molecular weight, generally greater than 106.

  The heterogeneous radical polymerization technique in an aqueous medium with precipitation of the polymer formed is described, for example, in US Pat. No. 4,929,655, in the patent application EP 0,943,628 or in the international application WO 02/34796.

  To ensure the stability of the dispersions of polymer particles during synthesis and during storage, it is generally essential to perform the polymerization in the presence of a dispersing agent. This dispersing agent is preferably a polyelectrolyte which, in contrast to the high molecular weight polymer used in the invention, is soluble in the aqueous medium of high ionic strength polymerization.

  This dispersing polyelectrolyte preferably has a charge identical to that of the synthesized polymer, in other words for the synthesis of cationic polyelectrolytes, a cationic dispersing polyelectrolyte is generally used.

  As preferred dispersing agents, mention may be made of cationic polyelectrolytes obtained by polymerization of from 50 to 100 mol% of at least one cationic monomer chosen from the salts, preferably the hydrochlorides or sulphates, of dimethylaminoethyl (meth) acrylate. , N-dimethylaminopropyl (meth) acrylamide or di (meth) allylamine, (meth) acryloyloxyethyltrimethylammonium chloride, (meth) acrylamidopropyltrimethylammonium chloride and dimethyldiallylammonium chloride, and from 50 to 0 mol% of acrylamide. It is also possible to use a polyamine such as a polyalkyleneamine.

  The dispersing agent is preferably used in a proportion of 1 to 10% by weight, based on the total weight of the monomers to be polymerized.

  The aqueous saline solution which serves as a synthesis and dispersion medium for the water-soluble polymer of high molecular weight is a solution of one or more mineral salts preferably chosen from divalent anionic salts.

  As anionic salts, mention may be made, for example, of ammonium sulphate, ammonium hydrogen sulphate, sodium sulphate, sodium hydrogen sulphate, magnesium sulphate, magnesium hydrogen sulphate and aluminum sulphate. and aluminum hydrogen sulfate. Ammonium sulfate and sodium sulfate are particularly preferred.

  The concentration of this salt (s) should preferably be sufficient to induce the precipitation of the water-soluble polymer formed in the polymerization medium. To obtain such a precipitation, the salt concentration is preferably at least 15% by weight and can go up to the saturation concentration of each salt. The aqueous salt solution may further contain monovalent salts such as sodium chloride and ammonium chloride.

  Heterogeneous radical polymerization in an aqueous medium as described above is most often accompanied by a significant increase in the viscosity of the reaction medium, which results in stirring difficulties, a lack of homogeneity of the medium. reaction and enlargement of the particle size of the polymer particles formed. To prevent such an increase in viscosity, it has been proposed in European Patent Application EP 0 943 628 to add to the polymerization medium at least one agent preventing the increase of the viscosity of the reaction medium during polymerization. .

  The water-soluble, high molecular weight polymers used in the present invention are preferably prepared in the presence of such an agent to prevent the increase in viscosity.

  These agents preventing the increase in the viscosity of the reaction medium are chosen for example from (1) polycarboxylic acids and their salts, (2) polyphenols, (3) cyclic compounds containing a hydroxy group and a carboxy group, or their salts, (4) gluconic acid or its salts, (5) the reaction products obtained by reaction of a methoxyhydroquinone and / or (meth) acrylic cationic monomer with a compound which generates radicals under an atmosphere oxidizing, (6) reaction products obtained by reaction of a (meth) acrylic cationic polymer with a compound which generates radicals, under an oxidizing atmosphere, (7) the reaction products obtained by reaction of a cationic polymer (meth) acrylic with an oxidizing agent, and mixtures thereof.

  The addition of at least one viscosity-increasing agent as described above makes it possible to carry out the polymerization of the water-soluble monomers described above with a low-power stirrer while avoiding the formation of coarse particles. The agents preventing the increase of the viscosity are preferably soluble in the aqueous reaction medium.

  Examples of compounds (A) include oxalic acid, adipic acid, tartaric acid, malic acid, phthalic acid and their salts.

  Examples of compounds (B) include resorcinol and pyrogallol.

  Examples of compounds (C) include mhydroxybenzoic acid, p-hydroxybenzoic acid, salicylic acid, gallic acid, tannic acid and salts thereof.

  As examples of compounds (D), mention may be made of sodium gluconate, potassium gluconate, ammonium gluconate and various amino salts of gluconic acid.

  Examples of compounds (E) include those obtained by reacting a radical generating compound under a stream of oxygen gas in a solution containing methoxyhydroquinone and / or (meth) acrylic cationic monomer. The compound that generates radicals may be an initiator commonly used for radical polymerization. Mention may be made, for example, of water-soluble azo initiators such as 2,2'-azo-bis (2-amidinopropane) hydrochloride sold, for example, under the name V-50 by the company Wako Chemical Industries, or the hydrochloride of 2.2 '-azo-bis [2- (2-imidazolin-2-yl) propane] sold for example under the trade name VA-044 by the company Wako Chemical Industries, or an initiator of the group of water-soluble redox reductors such as the persulfate combination ammonium / sodium hydrogen sulfite.

  An agent preventing the increase of the viscosity (F) can be obtained by reacting a radical initiator, under an oxygenated atmosphere, with a dispersing agent according to the invention. The polymerization initiator may be a water-soluble azo initiator or a water-soluble redox as described above.

  The compounds (G) can be obtained in the form of low molecular weight oxidized polymers by oxidation of a cationic dispersing agent according to the invention obtained by polymerization of a (meth) acrylic cationic monomer, using as oxidizing agent hydrogen peroxide or halogen.

  As cationic (meth) acrylic monomers used for the preparation of the agents preventing the increase in viscosity (E), (F) and (G), mention may be made, for example, of the hydrochloride or the (meth) acrylate sulfate of 2864779 9 dimethylaminoethyl chloride, (meth) acryloyloxyethyltrimethylammonium chloride, (meth) acryloyloxyethyldimethylbenzylammonium chloride, N-dimethylaminopropyl (meth) -acrylamide hydrochloride or sulfate, (meth) acrylamidopropyltrimethylammonium chloride, sodium chloride or dimethylaminohydroxypropyl (meth) acrylate, (meth) acryloyloxyhydroxypropyltrimethylammonium chloride, (meth) acryloyloxyhydroxypropyldimethylbenzylammonium chloride.

  These agents preventing the increase of the viscosity (A) to (G) may be used alone or in a mixture, in an amount preferably between 10 ppm and 10,000 ppm relative to the total weight of the reaction solution.

  The water-soluble monomers polymerized by heterogeneous radical polymerization to obtain water-soluble polymers of high molecular weight are monomers comprising at least one ethylenic double bond, for example a vinyl, acrylic or allyl double bond. They may be cationic, anionic or nonionic, at least one of them being cationic and used in a mixture.

  Examples of water-soluble anionic monomers include acrylic acid, methacrylic acid, 2-acrylamido-2-methylpropanesulfonic acid and itaconic acid. These anionic monomers are at least partially neutralized in the form of a salt of an alkali metal, an alkaline earth metal, ammonium or an organic amine such as an alkanolamine, in particular ethanolamine.

  Non-ionic, water-soluble monomers include acrylamide, methacrylamide, N-vinylformamide, N-vinylacetonamide, hydroxypropyl acrylate and hydroxypropyl methacrylate.

  The water-soluble cationic monomers are preferably chosen from di (C 1-4 alkyl) diallylammonium salts and compounds of formula (I) ## STR1 ## wherein R 1 represents a hydrogen atom or a methyl group, R2 and R3, which may be identical or different, each represent a hydrogen atom or a linear or branched C1-C4 alkyl group, R4 represents a hydrogen atom, a linear or branched C1-C4 alkyl group or an aryl group, D represents the following unit -Yn CA i- wherein Y represents an amide function (-CO-NH-), ester (-O-CO- or CO-O-), urethane (-O-CO-NH-) or urea (-NH-CO-NH-), A represents a linear, branched or cyclic C1-C18 alkylene group which may be substituted or interrupted by a divalent aromatic or heteroaromatic ring, or which may be interrupted by a heteroatom selected from O, N, S and P, and which may comprise a ketone, amide, ester, urethane or urea function, n is 0 or 1, and X- represents an anionic counterion such as a chloride or sulfate ion.

  Examples of water-soluble cationic monomers that may be mentioned include dimethylaminoethyl (meth) acrylate hydrochloride or sulfate, (meth) acryloyloxyethyltrimethylammonium chloride, (meth) acryloyloxyethyldimethylbenzylammonium chloride, hydrochloride or N dimethylaminopropyl (meth) acrylamide, (meth) acrylamidopropyltrimethylammonium chloride, (meth) acrylamidopropyldimethylbenzylammonium chloride, dimethylaminohydroxypropyl (meth) acrylate hydrochloride or sulfate, (meth) acryloyloxyhydroxypropyltrimethylammonium chloride, (meth) chloride acryloyloxyhydroxypropyldimethylbenzylammonium and dimethyldiallylammonium chloride.

  In a preferred embodiment of the present invention, the high molecular weight water-soluble polymer is obtained by heterogeneous radical polymerization of a monomer mixture comprising from 0 to 30 mol% of acrylic acid, from 0 to 95.5% in moles of acrylamide and from 0.5 to 100 mol% of at least one cationic monomer of formula (I).

  According to a particularly preferred embodiment, the water-soluble polymers are obtained by polymerization of a mixture of monomers consisting of acrylic acid and a cationic monomer of formula (I), in which the number of moles of cationic monomer of formula (I) is greater than the number of moles of acrylic acid.

  Particularly preferred water-soluble polyelectrolytes are, for example, those polymerized from monomer mixtures consisting respectively of 10% by mole of acryloyloxyethyldimethylbenzyl-ammonium chloride and 90% by mole of acrylamide.

  2. 30 mol% of acryloyloxytrimethylammonium chloride, 50 mol% of acryloyloxyethyldimethylbenzylammonium chloride and 20 mol% of acrylamide.

  3. 10 mol% acryloyloxyethyltrimethylammonium chloride and 90 mol% acrylamide.

  4. 30 mol% diallyldimethylammonium chloride and 70 mol% acrylamide.

  The spinning polymers used in the present invention preferably have a weight average molecular weight greater than 1,000,000, preferably between 1,000,000 and 50,000,000. This weight average molecular weight is determined by the RSV method (Reduced Specific Viscosity) as defined in Principles of Polymer Chemistry, Cornell University Press, Ithaca, NY, 1953, Chapter VII entitled Determination of Molecular Weight, pages 266,316.

  The concentration of the dispersion or solution of water-soluble high molecular weight polymer is preferably selected so that the concentration of the water-soluble polymer is between 0.01 and 10% by weight, preferably between 0.05 and 5%. % by weight relative to the total weight of the final composition.

  The concentration of the spinning polymer according to the invention is preferably between 0.01 and 10% by weight, preferably between 0.05 and 5% by weight relative to the total weight of the final composition.

  The detergent surfactant (s) are chosen, alone or as mixtures, from anionic, amphoteric, nonionic and zwitterionic surfactants.

  Thus, according to the invention, the detergent surfactants may represent from 4% to 50% by weight, preferably from 6% to 30% by weight, and still more preferably from 8% to 25% by weight, of the total weight of the final composition.

  The surfactants that are suitable for the implementation of the present invention are notably the following: (i) Anionic surfactant (s): Their nature is not, in the context of the present invention, of a truly critical nature.

  Thus, by way of example of anionic surfactants which may be used, alone or mixtures, in the context of the present invention, mention may be made in particular (non-limiting list) of the salts (in particular alkaline salts, in particular sodium salts, sodium salts, ammonium, amine salts, aminoalcohol salts or magnesium salts) of the following compounds: alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkyl aryl polyether sulphates, monoglyceride sulphates; alkylsulfonates, alkylphosphates, alkylamidesulfonates, alkylarylsulfonates, α-olefin-sulfonates, paraffin-sulfonates; alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates; alkylsulfosuccinamates; alkylsulfoacetates; alkyl ether phosphates; acylsarcosinates; acylisethionates and N-acyltaurates, the alkyl or acyl radical of all these different compounds preferably comprising from 12 to 20 carbon atoms, and the aryl radical preferably denoting a phenyl or benzyl group. Among the anionic surfactants that can still be used, mention may also be made of fatty acid salts such as the salts of oleic, ricinoleic, palmitic and stearic acids, coconut oil acid or hydrogenated coconut oil acid; acyl lactylates whose acyl radical has 8 to 20 carbon atoms. It is also possible to use weakly anionic surfactants, such as alkyl D galactoside uronic acids and their salts, as well as polyoxyalkylenated carboxylic ether acids and their salts, in particular those containing from 2 to 50 ethylene oxide groups, and mixtures thereof. The anionic surfactants of the polyoxyalkylenated acid or polyoxyalkylenated ether carboxylic acid type are, in particular, those which have the following formula (1): ## STR2 ## in which: R 1 denotes an alkylamido or alkaryl alkyl group; and n is an integer or decimal number (average value) which may vary from 2 to 24 and preferably from 3 to 10, the alkyl radical having from 6 to 20 carbon atoms, and aryl preferably denoting phenyl, A denotes H , ammonium, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue Mixtures of compounds of formula (1) can also be used, in particular mixtures in which the groups R 1 are different.

  Compounds of formula (1) are sold for example by CHEM Y under the names AKYPO (NP40, NP70, OP40, OP80, RLM25, RLM38, RLMQ 38 NV, RLM 45, RLM 45 NV, RLM 100, RLM 100 NV , RO 20, RO 90, RCS 60, RS 60, RS 100, RO 50) or by SANDOZ under the names SANDOPAN (DTC Acid, DTC).

  (ii) Nonionic surfactant (s): Nonionic surfactants are also well-known compounds per se (see in particular in this connection "Handbook of Surfactants" by M.R.

  PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178) and their nature is not critical in the context of the present invention. Thus, they can be chosen in particular from (non-limiting list) polyethoxylated, polypropoxylated or polyglycerolated fatty alcohols, polyethoxylated, polypropoxylated or polyglycerolated fatty alpha-diols, polyethoxylated, polypropoxylated or polyglycerolated fatty alkylphenols and polyethoxylated, polypropoxylated fatty acids. or polyglycerolated, all having a fatty chain comprising, for example, 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups possibly ranging from 2 to 50 and the number of glycerol groups that can range in particular from 2 to 30. Mention may also be made of copolymers of ethylene oxide and propylene oxide, condensates of ethylene oxide and of propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and in particular 1.5 to 4; oxyethylenated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; sucrose fatty acid esters, polyethylene glycol fatty acid esters, alkylpolyglycosides, N-alkylglucosamine derivatives, amine oxides such as (C10-C14) alkyl oxides or oxides N-acylaminopropylmorpholine. It will be noted that the alkylpolyglycosides constitute nonionic surfactants that fall particularly well within the scope of the present invention.

  (iii) amphoteric (s) or zwitterionic (s) surfactant (s): Amphoteric or zwitterionic surfactants, the nature of which does not fall within the scope of the present invention of a critical nature, may especially be (non-limiting list) derivatives of aliphatic secondary or tertiary amines, in which the aliphatic radical is a linear or branched chain having 8 to 18 carbon atoms and containing at least one water-soluble anionic group (for example carboxylate, sulphonate, sulphate, phosphate or phosphonate); mention may also be made of (C 8 -C 20) alkyl betaines, sulfobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkyl betaines or (C 8 -C 20) alkylamido (C 1 -C 6) alkyl sulfobetaines.

  Among the amine derivatives, mention may be made of the products sold under the name MIRANOL, as described in US Pat. No. 2,528,378 and US Pat. No. 2,286,479 and US Pat. No. 4,781,354 and filed in the CTFA dictionary, 3rd edition, 1982, under the names Amphocarboxyglycinates and Amphocarboxypropionates of respective structures: R2 -CONHCH2CH2 N + (R3) (R4) (CH2OOO-) (2) in which: R2 denotes an alkyl radical of a R2-COOH acid present in the hydrolysed coconut oil, a heptyl, nonyl or undecyl radical, R3 denotes a beta-hydroxyethyl group and R4 a carboxymethyl group and R2'-CONHCH2CH2-N (B) (C) (3) in which: B represents - CH2CH2OX ', C represents - (CH2 z = Y ', where z = 1 or 2, X' denotes the group -CH2CH2-COOH or a hydrogen atom Y 'denotes -COOH or the radical -CH2-CHOH-SO3H R2' denotes an alkyl radical an R 9 -COOH acid present in coconut oil or in hydrolysed linseed oil, an alkyl radical, in particular a C 7, C 6, C 11 or C13, a C17 alkyl radical and its iso form, an unsaturated C17 radical.

  By way of example, mention may be made of the cocoamphocarboxyglycinate sold under the trade name MIRANOL C2M concentrated by MIRANOL.

  In the compositions according to the invention, it is possible to use mixtures of surfactants and in particular mixtures of anionic surfactants, mixtures of anionic surfactants and amphoteric, cationic or nonionic surfactants, mixtures of cationic surfactants with nonionic or amphoteric surfactants. A particularly preferred mixture is a mixture comprising at least one anionic surfactant and at least one amphoteric surfactant.

  The amount of anionic surfactants is preferably from 3% to 40% by weight, based on the total weight of the cosmetic composition. It is preferably between 5% and 35% by weight and more preferably between 8% and 25% by weight.

  The amount of amphoteric and / or nonionic surfactants, when present, is preferably between 0.5 and 20%, and in particular between 1 and 15%, based on the total weight of the composition.

  According to the invention, aminosilicone refers to any silicone comprising at least one primary, secondary or tertiary amine or a quaternary ammonium group. It is possible to cite: (a) the polysiloxanes designated in the CTFA dictionary "amodimethicone" and corresponding to the formula: CH 3 Si O CH 3 x '

HO

O

H

OH

  If (CH 2) 3 NH 1 (CH 2) 2 NH 2 (VIII) y 'wherein x' and y 'are integers dependent on molecular weight, generally such that said weight average molecular weight is between 5,000 and 500,000 about; (b) amino silicones corresponding to the formula: R'aG3_a-Si (OSiG2) n (OSiGbR'2_b) m O-SiG3_a-R'a (IX) in which: 2864779 17 G is a hydrogen atom, or a phenyl, OH or C 1 -C 8 alkyl group, for example methyl, a denotes the number 0 or an integer from 1 to 3, in particular 0, b denotes 0 or 1, and in particular 1, m and n are numbers such that the sum (n + m) may vary in particular from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149 and m being able to designate a number of From 1 to 2,000, and especially from 1 to 10; R 'is a monovalent radical of the formula -CqH2qL wherein q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the groups: NR "-CH2-CH2-N' (R") 2 -N (R ") 2 - Ns (R") 3 A - NH (R ") 2 A - NH 2 (R") A - N (R ") - CH 2 -CH 2 -NsR" H 2 A-, in which R "may denote hydrogen, phenyl, benzyl, or a monovalent saturated hydrocarbon radical, for example an alkyl radical having from 1 to 20 carbon atoms and A 'represents a halide ion such as, for example, fluoride, chloride, bromide or iodide.

  A product corresponding to this definition is the silicone called "trimethylsilylamodimethicone", corresponding to the formula: ## STR2 ## in which n and m have the meanings given. above (see formula Such polymers are described for example in the patent application EP-A-95238.

  (c) amino silicones corresponding to the formula: ## STR5 ## wherein: R 5 represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C 1 -C 18 alkyl or C 2 -C 18 alkenyl radical, for example methyl; R6 represents a divalent hydrocarbon radical, especially a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, for example C1-C8 linked to Si by an SiC bond; Q- is an anion such as a halide ion, in particular chloride or an organic acid salt (acetate, etc.); r represents an average statistical value of 2 to 20 and in particular 2 to 8; s represents an average statistical value of 20 to 200 and in particular of 20 to 50.

  Such amino silicones are described more particularly in US Pat. No. 4,185,087.

  A silicone in this class is the silicone marketed by Union Carbide under the name Ucar Silicone ALE 56.

  (R5) 3As-Si O Si O Si O Si (R5) 3 R5 R5 d) the quaternary ammonium silicones of formula: R7 R7 R7 Si O Si R6 CH2 CHOH-CH2-N R7 R7 R7 R7 r R7, which may be identical or different, represent a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a ring comprising 5 or 6 carbon atoms, for example methyl; R6 represents a divalent hydrocarbon radical, especially a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, for example C1-C8 linked to Si by an SiC bond; R8, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical, a radical-R6- NHCOR7; X - is an anion such as a halide ion, especially chloride or an organic acid salt (acetate, etc.); r represents an average statistical value of 2 to 200 and in particular 5 to 100. These silicones are for example described in application EP-A-0530974.

  Silicones falling within this class are the silicones marketed by GOLDSCHMIDT under the names ABIL QUAT 3270, ABIL QUAT 3272 and ABIL QUAT 3474.

  e) the amino silicones of formula (X111): ## STR2 ## R 1 R 3 SiO SiO Si R 5 (XIII) (CnH 2n) 2 R 2

NH

  (C H 2 H) NH 2 in which: R 1, R 2, R 3 and R 4, which may be identical or different, denote a C 1 -C 4 alkyl radical or a phenyl group; R 5 denotes a C 1 -C 4 alkyl radical or a hydroxyl group; n is an integer ranging from 1 to 5, - m is an integer ranging from 1 to 5, and wherein x is chosen such that the amine value is between 0.01 and 1 meglg.

  According to the invention, the amino silicones can be in the form of an oil, aqueous solutions, alcoholic or aqueous-alcoholic, in the form of dispersion or emulsion.

  A particularly interesting embodiment is their use as emulsions, particularly in the form of microemulsions or nanoemulsions.

  For example, the product sold under the name "Cationic Emulsion DC 929" can be used by the Dow Corning Company, which comprises, in addition to amodimethicone, a cationic surface-active agent derived from tallow fatty acids called Tallowtrimonium (CTFA), in combination with a nonionic surfactant known as "Nonoxynol 10".

  It is also possible to use, for example, the product marketed under the name "Cationic Emulsion DC 939" by the Dow Corning Company, which comprises, in addition to amodimethicone, a cationic surfactant, trimethyl cetyl ammonium chloride in combination with a surfactant. nonionic surface trideceth-12.

  Another commercial product that can be used according to the invention is the product sold under the name "Dow Corning Q2 7224" by the Dow Corning Company comprising in combination trimethylsilylamodimethicone of formula (X), a nonionic surfactant of formula: C8H17-C6H4 (OCH2CH2) n-OH where n = 40 further denominated octoxynol-40, another nonionic surfactant of formula: C12H25- (OCH2-CH2) n-OH where n = 6 still called isolaureth-6, and glycol.

  According to the invention, all the silicones can also be used in the form of emulsions or microemulsions.

  Particularly preferred silicones according to the invention are: polysiloxanes containing amine groups such as amodimethicones or trimethylsilylamodimethicones (CTFA 4th edition 1997); According to the invention, the at least one amino silicone may represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight and more particularly from 0.1% to 3% by weight relative to the total weight. of the final composition.

  According to a preferred embodiment of the invention, the compositions may further comprise at least one cationic polymer different from the spinning polymer according to the invention.

  The cationic polymers that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair, namely in particular those described in the patent application EP-A-0 337 354 and in the patent applications FR-A-2,270,846, 2,383,660, 2,598,611, 2,470,596 and 2,519,863 and having a suitable cationic charge density.

  In a more general sense, for the purposes of the present invention, the term "cationic polymer" denotes any polymer containing cationic groups and / or ionizable groups in cationic groups.

  The preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that may either be part of the main polymer chain or may be carried by a lateral substituent directly connected thereto.

  The cationic polymers used generally have an average molecular weight in number or in weight of between about 500 and 5 × 10 6, and preferably between about 103 and 3 × 10 6.

  Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products.

  The polymers of the polyamine, polyamidoamide or quaternary polyammonium type which can be used in accordance with the present invention, which may be mentioned in particular, are those described in French patents Nos. 2,505,348 or 2,542,997. Among these polymers, mention may be made of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formula: R 3 CH 2 Cl 0 = C

AT

R3 CH C

AT

  Wherein R 3, which may be identical or different, denotes a hydrogen atom or a CH 3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms; R1 and R2, which may be identical or different, represent hydrogen or an alkyl group having 1 to 6 carbon atoms and preferably methyl or ethyl; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide.

  The copolymers of the family (1) may further contain one or more units derived from comonomers which may be selected from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1). -C4), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.

  Thus, among these copolymers of the family (1), mention may be made of: the copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company Hercules, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium methosulphate sold under the name RETEN by the company HERCULES, vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers quaternized or otherwise. These polymers are described in detail in French Patents 2,077,143 and 2,393,573, dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers.

  and the quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymers.

  (2) cationic polysaccharides, in particular cationic celluloses and cationic galactomannan gums. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives containing quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.

  The cellulose ether derivatives containing quaternary ammonium groups described in French Patent 1,492,597. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted with a trimethylammonium group.

  Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in US Pat. No. 4 131 576, such as hydroxyalkyl celluloses, such as hydroxymethyl, hydroxyethyl or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyltrimethylammonium, methacrylmidopropyltrimethylammonium, dimethyldiallylammonium.

  The cationic galactomannan gums are described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, in particular guar gums containing cationic trialkylammonium groups. For example, guar gums modified with a salt (eg chloride) of 2,3-epoxypropyltrimethylammonium are used.

  (3) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are in particular described in French Patents 2,162,025 and 2,280,361; (4) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bisunsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide or a oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polymaoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functional groups, quaternized. Such polymers are described in particular in French Patents 2,252,840 and 2,368,508; (5) polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid-diacoylaminohydroxyalkyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Such polymers are described in particular in French Patent 1,583,363.

  Among these derivatives, mention may be made more particularly of the adipiqueldimethylaminohydroxypropyl / diethylene triamine acid polymers sold under the name "CARTARETINE F, F4 or F8" by SANDOZ.

  (6) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1; the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in the patents US 3,227,615 and 2,961,347.

  Polymers of this type are in particular marketed under the name "HERCOSETT 57" by the company Hercules Inc. by the company HERCULES in the case of the adipic acid / epoxypropyl / diethylenetriamine copolymer.

  (7) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium such as homopolymers or copolymers comprising, as the main constituent of the chain, units corresponding to formulas (I) or (I '): / (CH 1) k - (CH 2) t-CR 12 C (R 12) -CH 2 -H 2 Cl 2 / CH 2 (I) N + Y-R 1 / R 11 (CH 2) k - (CH 2) t-CR 12 C (R 12) -CH 2 -CH 2 CH 2

N Rio

  formulas in which k and t are 0 or 1, the sum k + t being equal to 1; R12 denotes a hydrogen atom or a methyl radical; R10 and R11, independently of each other, denote an alkyl group having 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1 -C4) or R10 and R11 may designate, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French Patent 2,080,759 and in its certificate of addition 2,190,406.

  R10 and R11, independently of one another, preferably denote an alkyl group having 1 to 4 carbon atoms.

  Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name Merquat 100 by the company Nalco (and its homologues of low average molecular weight) and the copolymers of diallyldimethylammonium chloride and acrylamide.

  (8) quaternary diammonium polymers containing recurring units corresponding to the formula: ## STR5 ## in which: R 13, R 14, R 15 and R 16, which may be identical or different, represent aliphatic radicals; , alicyclic, or arylaliphatic containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or R13, R14, R15 and R16, together or separately, together with the nitrogen atoms to which they are attached, constitute heterocycles optionally containing a second heteroatom other than nitrogen or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile, ester, acyl, amide group or -CO-O-R17-D or -CO- NH-R17-D wherein R17 is alkylene and D is a quaternary ammonium group; Al and B1 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- denotes an anion derived from a mineral or organic acid; Al, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, BI may also denote a (CH 2) n -CO-D-OC- (CH 2) n- group in which D denotes: 2864779 29 a) a glycol residue of formula: -OZ-O-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: - (CH2-CH2-O) x-CH2-CH2- [CH2- CH (CH 3) -O] y -CH 2 -CH (CH 3) - where x and y denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number of 1 to 4 representing a degree of polymerization way; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or alternatively the divalent radical -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula: -NH-CO-NH-; Preferably, X- is an anion such as chloride or bromide.

  These polymers have a number-average molecular weight generally between 1000 and 100,000.

  Polymers of this type are described in French patents 2,320,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and US Patents 2,273,780, 2,375,853, 2,388,614 and 2,454,547. , 3.206.462, 2.261.002, 2.271. 378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 4,027,020.

  It is more particularly possible to use polymers which consist of repeating units corresponding to the formula: ## STR1 ## in which R 1, R 2, R 3 and R 4 , identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p 2864779 are integers ranging from 2 to about 20 and, X- is an anion derived from a mineral acid or organic.

  A particularly preferred compound of formula (a) is that for which R1, R2, R3 and R4 represent a methyl radical and n = 3, p = 6 and X = CI, referred to as Hexadimethrine chloride according to the INCI nomenclature (CTFA).

  (9) quaternary polyammonium polymers comprising units of formula (III): ## STR1 ## wherein R 1 is a radical of formula (III): ## STR5 ## R19 (III) X-R21 wherein R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, (3-15 hydroxypropyl or CH2CH2 ( OCH2CH2) pOH, where p is 0 or an integer between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, r and s, which are identical or different, are integers between 1 and 6, q is 0 or an integer from 1 to 34, X- is an anion such as a halide, A is a radical of a dihalide or is preferably CH 2 -CH 2 -O-CH 2 -CH 2.

  Such compounds are described in particular in patent application EP-A-122 324.

  These include, for example, the products "Mirapol A 15", "Mirapol AD1", "Mirapol AZ1" and "Mirapol 175" sold by the company Miranol.

  (10) The quaternary vinylpyrrolidone and vinylimidazole polymers such as, for example, the products sold under the names Luviquat FC 905, FC 550 and FC 370 by the company B.A.S.F.

  (11) Crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts such as polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by the methyl chloride, homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide.

  Other cationic polymers which may be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives, especially chitosans or their salts; the salts which can be used are, in particular, chitosan acetate, lactate, glutamate, gluconate or pyrrolidonecarboxylate.

  Among these compounds, mention may be made of chitosan having a degree of deacetylation of 90% by weight, the chitosan pyrrolidonecarboxylate sold under the name KYTAMER PC by the company AM ERCHOL.

  Among all the cationic polymers that may be used in the context of the present invention, it is preferred to use cationic cyclopolymers, in particular homopolymers or copolymers of dimethyldiallylammonium chloride, sold under the names MERQUAT 100, MERQUAT 550 and MERQUAT S by NALCO, quaternary vinylpyrrolidone and vinylimidazole polymers, homopolymers or crosslinked copolymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts, chitosan pyrrolidone carboxylate and mixtures thereof.

  The amphoteric polymers that may be used in accordance with the present invention may be chosen from polymers comprising K and M units statistically distributed in the polymer chain, where K denotes a unit derived from a monomer comprising at least one basic nitrogen atom and M denotes a unit derived from an acidic monomer having one or more carboxylic or sulfonic groups, or K and M may denote groups derived from zwitterionic monomers of carboxybetaines or sulfobetaines; K and M may also denote a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic or sulphonic group connected via a hydrocarbon radical, or K and M form part of a chain of an ethylene α, β-dicarboxylic polymer having one of the carboxylic groups reacted with a polyamine having one or more primary or secondary amine groups.

  The amphoteric polymers as defined above, more particularly preferred, are chosen from the following polymers: (1) The polymers resulting from the copolymerization of a monomer derived from a vinyl compound carrying a carboxylic group such as, more particularly, the acrylic acid, methacrylic acid, maleic acid, alpha-chloro acrylic acid, and a basic monomer derived from a substituted vinyl compound containing at least one basic atom such as, more particularly, dialkylaminoalkyl methacrylate and acrylate, dialkylaminoalkylmethacrylamide and acrylamide. Such compounds are described in US Pat. No. 3,836,537. Mention may also be made of the sodium acrylate / acrylamidopropyltrimethylammonium chloride copolymer sold under the name Polyquart KE 3033 by the company Cognis.

  The vinyl compound may also be a dialkyldiallylammonium salt such as dimethyldiallylammonium salt (e.g. chloride). The copolymers of acrylic acid and of the latter monomer are sold under the names MERQUAT 280 and MERQUAT 295 by the company NALCO.

  (2) polymers comprising units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen with an alkyl radical, b) with at least one acidic comonomer containing one or more carboxylic groups reagents, and c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituent esters of acrylic and methacrylic acids and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.

  The N-substituted acrylamides or methacrylamides which are more particularly preferred according to the invention are the groups in which the alkyl radicals contain from 2 to 12 carbon atoms and more particularly the N-ethylacrylamide, the N-tert-butyl-acrylamide, the N-tert-octyl-acrylamide, the N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides.

  The acidic comonomers are chosen more particularly from acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids as well as alkyl monoesters having 1 to 4 carbon atoms of maleic or fumaric acids or anhydrides.

  Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl, and N-tert-butyl-aminoethyl methacrylates.

  The copolymers whose CTFA name (4th Ed., 1991) is octylacrylamidecrylateslbutylaminoethylmethacrylate copolymer are particularly used.

  (3) The polyamino amides crosslinked and alkylated partially or completely derived from polyamino amides of the general formula: ## STR3 ## wherein R 4 represents a divalent radical derived from a saturated dicarboxylic acid, an acid ethylenically double bonded mono or dicarboxylic aliphatic agent, an ester of a lower alkanol having 1 to 6 carbon atoms of these acids or a radical derived from the addition of any of said acids with a primary bis amine or secondary bis, and Z denotes a radical of a bis-primary, mono or bis-secondary polyalkylene polyamine and preferably represents: a) in the proportions of 60 to 100 mole%, the radical NH - [- (CH 2 ), - NH (V) where x = 2 and p = 2 or 3, or x = 3 and p = 2 this radical derived from diethylene triamine, triethylene tetraamine or dipropylene triamine; b) in the proportions of 0 to 40 mol%, the radical (V) above, in which x = 2 and p = 1 and which is derived from ethylenediamine, or the radical derived from piperazine: / \ NN \ c) in the proportions of 0 to 20 mole%, the -NH- (CH 2) 6 -NH radical derived from hexamethylenediamine, these polyaminoamines being crosslinked by addition of a bifunctional crosslinking agent chosen from epihalohydrins, diepoxides and dianhydrides; the bis unsaturated derivatives, by means of 0.025 to 0.35 mole of crosslinking agent per amine group of the polyaminoamide and alkylated by the action of acrylic acid, chloroacetic acid or an alkane sultone or of their salts.

  The saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms such as adipic acid, trimethyl-2,2,4-adipic acid and trimethyl-2,4,4-adipic acid, terephthalic acid, acids with ethylenic double bond such as acrylic acid, methacrylic acid, itaconic acid.

  The alkanesultones used in the alkylation are preferably propane or butane sultone, the salts of the alkylating agents are preferably the sodium or potassium salts.

  Polymers comprising zwitterionic units of formula: wherein R5 denotes a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group, y and z represent an integer of 1 to 3, R 6 and R 7 represent a hydrogen, methyl, ethyl or propyl, R8 and R8 represent a hydrogen atom or an alkyl radical such that the sum of the carbon atoms in R8 and R8 does not exceed 10.

  Polymers comprising such units may also comprise units derived from non-zwitterionic monomers such as dimethyl or diethylaminoethyl acrylate or methacrylate or alkyl acrylates or methacrylates, acrylamides or methacrylamides or vinyl acetate.

  By way of example, mention may be made of the butyl methacrylate / dimethylcarboxymethylammonioethyl methacrylate copolymer.

  (5) polymers derived from chitosan having monomer units corresponding to the following formulas (VII), (VIII) and (IX): ## STR2 ##

J

  Wherein the unit (VII) is present in proportions of between 0 and 30%, the unit (VIII) in proportions of between 5 and 50% and the unit (IX) in proportions of between 30 and 90%, it being understood that in this unit (IX), Rio represents a radical of formula: (4) I + o R5 CN (CH2) z CO

Y R7 R9 CH2OH

  Wherein R 1, R 11, R 12 and R 13, which are identical or different, each represents a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine residue; or a dialkylamine residue optionally interrupted by one or more nitrogen atoms and / or optionally substituted by one or more amine, hydroxyl, carboxyl, alkylthio or sulphonic groups, an alkylthio radical whose alkyl group carries an amino residue, one of less radicals R11, R12 and R13 being in this case a hydrogen atom; or if q = 1, R 11, R 12 and R 13 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids.

  (6) Polymers derived from the N-carboxyalkylation of chitosan such as N-carboxymethyl chitosan or N-carboxybutyl chitosan.

  (7) The polymers corresponding to the general formula (X) such as those described, for example, in the French patent 1,400,366: (CH CH2) (X)

COOHCO r

  in which R14 represents a hydrogen atom, a radical CH3O, CH3CH2O, phenyl, R15 denotes hydrogen or a lower alkyl radical such as methyl, ethyl, R16 denotes hydrogen or a lower alkyl radical such as methyl, ethyl, R17 denotes a lower alkyl radical such as methyl, ethyl or a radical corresponding to the formula: R18-N (R16) 2, R18 representing a group -CH2-CH2-, -CH2CH2-CH2-, -CH2-CH ( CH3) -, R16 having the meanings mentioned above, as well as the higher homologues of these radicals and containing up to 6 carbon atoms.

  (8) Amphoteric polymers of the -DXDX- type chosen from: a) the polymers obtained by the action of chloroacetic acid or sodium chloroacetate on compounds comprising at least one unit of formula: -DXDXD- (XI) where D denotes a radical NN and X denotes the symbol E or E ', E or E', which may be identical or different, denotes a divalent radical which is a straight or branched chain alkylene radical containing up to 7 carbon atoms in the unsubstituted main chain or substituted with hydroxyl groups and which may further comprise oxygen, nitrogen, sulfur, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide groups, alcohol, ester and / or urethane; b) polymers of formula: -D-X-D-X- (XII) where D denotes a radical / \ N N and X denotes the symbol E or E 'and at least once E'; E having the meaning indicated above and E 'is a bivalent radical which is a straight or branched chain alkylene radical having up to 7 carbon atoms in the main chain, substituted or unsubstituted by one or more hydroxyl radicals and 2864779 38 having one or more nitrogen atoms, the nitrogen atom being substituted by an optionally interrupted alkyl chain by an oxygen atom and necessarily comprising one or more carboxyl functions or one or more hydroxyl functions and betaineized by reaction with the chloroacetic acid or sodium chloroacetate.

  (9) (C1-C5) alkyl vinyl ether / maleic anhydride copolymers partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semi-esterification with an N, N-dialkanolamine. These copolymers may also comprise other vinylic comonomers such as vinylcaprolactam.

  The amphoteric polymers that are particularly preferred according to the invention are those of the family (1).

  According to the invention, the cationic or amphoteric polymer or polymers may represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight and more particularly from 0.02 to 5% by weight relative to total weight of the final composition.

  According to a preferred embodiment of the invention, the compositions may further comprise at least one silicone other than the amino silicones according to the invention.

  As silicones that can be used in the compositions of the present invention, mention may be made especially of volatile or non-cyclic or acyclic, branched or unbranched volatile silicones, organomodified or otherwise, as described below.

  The silicones that can be used in accordance with the invention may be soluble or insoluble in the composition and in particular may be polyorganosiloxanes that are insoluble in the composition of the invention; they may be in the form of oils, waxes, resins or gums.

  According to the invention, all the silicones can be used as such or in the form of solutions, dispersions, emulsions, nanoemulsions or microemulsions.

  Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968) Academic Press. They can be volatile or nonvolatile.

  When they are volatile, the silicones are more particularly chosen from those having a boiling point between 60 ° C. and 260 ° C., and more particularly still from: (i) cyclic silicones containing from 3 to 7 silicon atoms and, preferably, from 4 to 5. It is, for example, octamethylcyclotetrasiloxane marketed in particular under the name "VOLATILE SILICONE 7207" by UNION CARBIDE or "SILBIONE 70045 V 2" by RHODIA, decamethylcyclopentasiloxane sold under the name of "SILICONE VOLATILE 7158" by UNION CARBIDE, "SILBIONE 70045 V 5" by RHODIA, as well as their mixtures.

  Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by UNION CARBIDE, of chemical structure: pD D 'DD' 7 CH3 1 with D: with D ': Si O 1 CsH17 It is also possible to mention mixtures of cyclic silicones with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- ( hexa- 2,2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile silicones having 2 to 9 silicon atoms and preferably having a viscosity less than or equal to 5 × 10 -6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH Silicones included in this class are also described in the article published in Cosmetics 2864779 40 and toiletries, Vol 91, Jan. 76, 27-32 - TODD & BYERS Volatile Silicone fluids for cosmetics ".

  Non-volatile silicones and more particularly polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, polyorganosiloxanes modified with organofunctional groups and their mixtures are preferably used.

  These silicones are more particularly chosen from polyalkylsiloxanes, among which, for example, polydimethylsiloxanes containing trimethylsilyl end groups having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. and preferably 1 × 10 -5 to 1 m 2 / s may be mentioned. The viscosity of the silicones is, for example, measured at 25 ° C. according to ASTM 445 Appendix C. Among these polyalkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE oils of the 47 and 70 047 series or the MIRASIL oils marketed by RHODIA, such as, for example, 70 047 V 500 000; oils of the MIRASIL series marketed by RHODIA; oils of the 200 series of Dow Corning, such as, more particularly, DC200 with a viscosity of 60,000 mm 2 / s; - VISCASIL oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC.

  Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups, known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA.

  In this class of polyalkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX 9800 and 9801" by GOLDSCHMIDT, which are poly (C1-C20) alkylsiloxanes.

  The polyalkylarylsiloxanes are particularly chosen from polydimethyl / methylphenylsiloxanes and linear and / or branched polydimethyldiphenylsiloxanes with a viscosity of from 1.10-5 to 5.10-2 m2 / s at 25 C.

  Among these polyalkylarylsiloxanes, mention may be made, by way of example, of the products sold under the following names: SILBIONE oils of the 70 641 series from RHODIA; the RHODORSIL 70 633 and 763 RHODIA series of oils; 5. DOW CORNING DOW CORNING 556 COSMETIC GRAD FLUID oil; silicones of the PK series from BAYER, such as the product PK20; silicones of the PN and PH series from BAYER, such as the PN1000 and PHI000 products; 10. Certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265.

  The silicone gums that can be used in accordance with the invention are in particular polydiorganosiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures.

  The following products may more particularly be mentioned: polydimethylsiloxane - polydimethylsiloxane / methylvinylsiloxane, polydimethylsiloxane / diphenylsiloxane, polydimethylsiloxane / phenylmethylsiloxane, polydimethylsiloxane / diphenylsiloxane / methylvinylsiloxane gums.

  More particularly useful products according to the invention are mixtures such as: mixtures formed from an end-hydroxylated polydimethylsiloxane or dimethiconol (CTFA) and a cyclic poly-dimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by the company Dow Corning; mixtures formed from a polydimethylsiloxane gum with a cyclic silicone such as the product SF 1214 Silicone Fluid from GENERAL ELECTRIC, this product is a SF 30 gum corresponding to a dimethicone, having an average molecular weight of number of 500,000 solubilized in SF 1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane; mixtures of two PDMS of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of a SE 30 gum defined above having a viscosity of 20 m 2 and a SF 96 oil with a viscosity of 5 × 10 -6 m 2. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil.

  The organopolysiloxane resins that may be used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2 12, R 3 SiO 11 2, RSiO 3 12 and SiO 4 12 in which R represents a hydrocarbon group having 1 to 16 carbon atoms or a phenyl group. Among these products, those that are particularly preferred are those in which R denotes a C1-C4 lower alkyl group, more particularly methyl, or a phenyl group.

  Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethylltrimethylsiloxane structure.

  Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin-Etsu.

  The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group.

  Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C6-C24 alkyl groups such as the products known as dimethicone-copolyol sold by the company Dow Corning under the name DC 1248 or SILWET oils L 722, L 7500, L 77, L 711 2864779 43 from UNION CARBIDE and the (C 12) -methicone-copolyol alkyl marketed by the company Dow Corning under the name Q 5200; thiol groups, such as the products sold under the names "GP 72 A" and "GP 71" from GENESEE; alkoxylated groups, such as the product marketed under the name "SILICONE COPOLYMER F-755" by SWS SILICONES and ABIL WAX 2428, 2434 and 2440 by the company GOLDSCHMIDT; hydroxyl groups, such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FR-A-85 16334.

  acyloxyalkyl groups such as, for example, the polyorganosiloxanes described in US-A-4957732.

  anionic groups of the carboxylic type, such as, for example, in the products described in the patent EP 186 507 of the company Chisso Corporation, or of the alkyl-carboxylic type, such as those present in the product X-22-3701E from the company Shin- ETSU; 2-hydroxyalkylsulphonate; 2hydroxyalkylthiosulphate such as the products sold by GOLDSCHMIDT under the names "ABIL S201" and "ABIL S255".

  hydroxyacylamino groups, such as the polyorganosiloxanes described in patent application EP 342 834. Mention may be made, for example, of the product Q28413 from Dow Corning.

  The silicones as described above may be used alone or as a mixture, in an amount of between 0.01 and 20% by weight, preferably between 0.05 and 5% by weight relative to the total weight of the composition.

  By cosmetically acceptable aqueous medium is meant a medium compatible with keratin materials such as in particular the skin, the eyelashes, and the hair.

  The cosmetically acceptable aqueous medium may consist solely of water or a mixture of water and a cosmetically acceptable solvent such as a lower alcohol C1-C4, such as ethanol, isopropanol Tert-butanol, n-butanol; alkylene glycols such as propylene glycol, polyol ethers and mixtures thereof.

  Preferably, the composition comprises from 50 to 95% by weight of water relative to the total weight of the composition.

  The washing compositions according to the invention have a final pH generally of between 3 and 10. Preferably, this pH is between 4.5 and 8. The adjustment of the pH to the desired value can be done conventionally by adding a base (organic or inorganic) in the composition, for example ammonia or a primary, secondary or tertiary (poly) amine such as monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or propanediamine-1,3, or again by adding an acid, preferably a carboxylic acid such as for example citric acid.

  The compositions in accordance with the invention may contain, in addition to the combination defined above, viscosity-regulating agents such as electrolytes, or thickeners (associative or non-associative). Mention may in particular be made of sodium chloride, sodium xylene sulphonate, scleroglucans, xanthan gums, fatty acid alkanolamides, and optionally oxyethylenated alkyl ether carboxylic acid alkanolamides with up to 5 moles of oxide. ethylene such as the product marketed under the name "AMINOL A15" by CHEM Y, crosslinked polyacrylic acids and copolymers of acrylic acid such as copolymers of acrylic acid and C10-alkyl acrylates. C30 crosslinked. These viscosity control agents are used in the compositions according to the invention in proportions of up to 10% by weight relative to the total weight of the composition.

  The compositions in accordance with the invention may also preferably contain up to 5% of pearlescent or opacifying agents well known in the state of the art, such as, for example, fatty alcohols higher than C16, acylated fatty-chain derivatives such as ethylene glycol or polyethylene glycol monostearates or distearates, fatty chain ethers (C10-C30) such as, for example, distearyl ether or 1- (hexadecyloxy) -2-octadecanol.

  The compositions in accordance with the invention may optionally also contain at least one additive chosen from foam synergists such as C10-C18 1,2-alkanediols or fatty alkanolamides derived from mono- or diethanolamine, silicone sunscreens or no, anionic or nonionic polymers, cationic surfactants, proteins, protein hydrolysates, ceramides, pseudoceramides, C12-C40 linear or branched chain fatty acids such as 18-methyl eicosanoic acid, hydroxy acids, vitamins, provitamines such as panthenol, animal, mineral or synthetic oils and any other additive conventionally used in the cosmetic field which does not affect the properties of the compositions according to the invention.

  The washing compositions according to the invention can of course also contain all the usual adjuvants encountered in the field of shampoos, such as, for example, perfumes, preserving agents, sequestering agents, softeners, colorants, moisturizing agents, agents and the like. anti-pineal or anti-seborrhoeic, and others.

  Of course, those skilled in the art will take care to choose this or these optional additional compounds and / or their amounts in such a way that the advantageous properties intrinsically attached to the combination according to the invention are not, or not substantially, altered by the addition or additions envisaged.

  These compositions may be in the form of liquids, optionally thickened, creams or gel and they are mainly suitable for washing, care and / or styling hair.

  The present invention also relates to a process for the cosmetic treatment of keratinous substances, which consists in applying an effective amount of a composition as described above to the keratin materials, to rinsing after a possible exposure time.

  According to a preferred embodiment of the invention, the composition can be used as a shampoo.

  When the compositions in accordance with the invention are used as conventional shampoos, they are simply applied to wet hair and the foam generated by massage or friction with the hands is then removed, after a possible pause time, by rinsing with water. water, the operation being repeatable one or more times.

  Concrete but non-limiting examples illustrating the invention will now be given.

EXAMPLES 1 to 3

  Shampoo compositions according to the invention were produced: 1 2 3 Copolymer (90/10 mol) 0.6% MA 0.5% MA- acrylamide and dimethylaminoethyl quaternized with benzyl chloride (MW> 5.106) dispersion in concentrated aqueous salt solution (ULTIMER from ONDEO) Copolymer (10190 mol) of - - 0.5% MA dimethyl Aminoethyl Acrylate quaternized with methyl chloride and acrylamide (MW> 5.106) dispersed in concentrated aqueous saline solution Sodium lauryl ether sulfate 2.2 15% MA 13% MA 12.5% MA

oE

  Coco Amido propyl betaine 5% MA 4% MA 2.5% MA Amodimethicone 1% MA - 0.8% MA (DC 939 from Dow Corning 35% MA) Chitosan PCA - 0.3% 0.2% 2864779 47 (Kytamer PC from AMERCHOL) Trimethylsilylamodimethicone - 1% - (DC2 8566 Amino Fluid from Dow Corning) Ethanol - 1% - NaCl - - 2% Citric acid or NaOH qs pH 6.5 pH 6.5 pH 6.5 Water qs 100% 100% 100% Treated hair with this shampoo have good styling and corporalisation properties.

Claims (5)

48 CLAIMS   1- Washing composition of keratin materials, characterized in that it comprises, in a cosmetically acceptable aqueous medium, at least one aminosilicone, at least one anionic, nonionic or amphoteric detergent surfactant and at least one polymer exhibiting superior spinning power at 5 cm.   2- Composition according to Claim 1, characterized in that the detergent surfactant or surfactants are chosen from anionic surfactants.   3- Composition according to claim 1 or 2, characterized in that said surfactant is present in a weight content of between 4% and 50% relative to the total weight of the composition.   4- Composition according to claim 3, characterized in that said content is between 8% and 25%.   5. Composition according to any one of claims 1 to 4, characterized in that the filamentous polymer is chosen from: either (a1) a dispersion of particles of a water-soluble polymer having a weight average molecular weight greater than 106 in an aqueous salt solution, obtained by heterogeneous radical polymerization of water-soluble monomers with precipitation of the polymer formed, at least one of the monomers being cationic or (a2) an aqueous solution of a water-soluble polymer having a weight average molecular weight greater than 106, obtained by heterogeneous radical polymerization of water-soluble monomers with precipitation of the polymer formed, at least one of the monomers being cationic.   6. Composition according to the preceding claim, characterized in that the water-soluble monomer or monomers are chosen from cationic, anionic or nonionic monomers comprising at least one ethylenic double bond or a mixture thereof.   7. Composition according to claim 6, characterized in that the anionic monomers are chosen from acrylic acid, methacrylic acid, acrylamido-2-methylpropanesulfonic acid and itaconic acid.   8- Composition according to Claim 6, characterized in that the nonionic monomers are chosen from acrylamide, methacrylamide, N-vinylformamide, N-vinylacetonamide, hydroxypropyl acrylate and hydroxypropyl methacrylate. .   9- Composition according to claim 6, characterized in that the cationic monomers are chosen from di (C1-alkyl) diallylammonium salts and compounds of formula (I) N (RI (I) DNR2 X \ R4 R3 in which RI represents a hydrogen atom or a methyl group, R2 and R3, which may be identical or different, each represent a hydrogen atom or a linear or branched C14 alkyl group, R4 represents a hydrogen atom, a C1-alkyl group; linear or branched or an aryl group, D represents the following unit Cyn (A) - in which Y represents an amide, ester, urethane or urea function, A represents a linear, branched or cyclic C 1 -C 10 alkylene group, which may be substituted or interrupted by a divalent aromatic or heteroaromatic ring, or which may be interrupted by a heteroatom chosen from O, N, S and P, and which may comprise a ketone, amide, ester, urethane or urea function, n is 0 or 1, and X- repro feel against an anionic ion such as a halide ion or sulphate.   10- Composition according to any one of claims 5 to 9, characterized in that the water-soluble polymer is polymerized from at least one cationic monomer of formula (I).   11- Composition according to claim 10, characterized in that the water-soluble polymer is polymerized from a monomer mixture consisting of 0 to 30 mol% of acrylic acid, from 0 to 95.5 mol% of acrylamide and from 0.5 to 100 mol% of at least one cationic monomer of formula (I).   12- Composition according to claim 11, characterized in that the water-soluble polymer is polymerized from a mixture of monomers consisting of acrylic acid and a cationic monomer of formula (I), the number of moles of the cationic monomer of formula (I) being greater than the number of moles of acrylic acid.   13- Composition according to claim 11, characterized in that the water-soluble polymer is polymerized from a monomer mixture consisting of 10 mol% of acryloyloxyéthyldiméthylbenzylammonium chloride and 90 mol% of acrylamide.   14- Composition according to claim 11, characterized in that the water-soluble polymer is polymerized from a monomer mixture consisting of 30 mol% of acryloyloxytrimethylammonium chloride, 50 mol% of acryloyloxyéthyldiméthybenzylammonium chloride and 20 mol% of acrylamide.   A composition according to claim 11, characterized in that the water-soluble polymer is polymerized from 10 mol% of acryloyloxyethyltrimethylammonium chloride and 90 mol% of acrylamide.   16- Composition according to claim 11, characterized in that the water-soluble polymer is polymerized from 30 mol% of diallyldimethylammonium chloride and 70 mol% of acrylamide.   17- Composition according to any one of claims 5 to 16, characterized in that the concentration of the water-soluble polymer particles dispersed in an aqueous salt solution in (a1) is between 0.01 and 20% by weight.   18. Composition according to any one of claims 5 to 17, characterized in that the concentration of the water-soluble polymer in solution in (a2) is between 0.01 and 20% by weight.   19- Composition according to any one of claims 5 to 18, characterized in that the aqueous salt solution in (a1) or (a2) contains at least one anionic salt.   20- The composition as claimed in claim 19, characterized in that the anionic salt is chosen from ammonium sulphate, ammonium hydrogen sulphate, sodium sulphate, sodium hydrogen sulphate, magnesium sulphate, magnesium hydrogen sulfate, aluminum sulphate, aluminum hydrogen sulphate.   21- Composition according to any one of the preceding claims, characterized in that the polymers having a spinning power greater than 5 cm are present in the compositions of the invention at a concentration of between 0.01 and 10% by weight, preferably between 0.05 and 5% relative to the total weight of the composition.   22. Composition according to any one of the preceding claims, characterized in that the amino silicone is chosen from: (a) the polysiloxanes designated in the CTFA dictionary "amodimethicone" and corresponding to the formula: CH3 Si O CH3 HO   Wherein O '(CH 2) 3 NH (CH 2) 2 H (VIII) NH 2 Y' wherein x 'and y' are integers dependent on molecular weight, generally such that said number average molecular weight is between 5,000 and 500,000; (b) amino silicones corresponding to the formula: R'aG3-a-Si (OSiG2) n (OSiGbR'24)) mO-SiG3-a-R'a (IX) in which: G is a hydrogen atom, or a phenyl, OH or C 1 -C 8 alkyl group, for example methyl, a denotes the number 0 or an integer from 1 to 3, in particular 0, b denotes 0 or 1, and in particular 1, m and n are numbers such that the sum (n + m) may vary in particular from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149 and m being able to designate a number of From 1 to 2,000, and especially from 1 to 10; R 'is a monovalent radical of formula - CqH2qL in which q is a number from 2 to 8 and L is an optionally quaternized amino group chosen from the groups: ## STR2 ## N (R ") 2 -N (R") 3 A _   -NH (R ") 2 N" -NH 2 O (R ") A- -N (R") - CH 2 -CH 2 -N R "H 2 A", wherein R "may denote hydrogen, phenyl, benzyl, or a radical monovalent saturated hydrocarbon, for example an alkyl radical having 1 to 20 carbon atoms and A "represents a halide ion such as, for example, fluoride, chloride, bromide or iodide.   (c) the amino silicones corresponding to the formula: ## STR2 ## wherein R 1 is SiO Si O Si (R 5) 3 R 5 R 5 s (XI) in which R5 represents a monovalent hydrocarbon radical having 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, or C2-C18 alkenyl, for example methyl; R6 represents a divalent hydrocarbon radical, in particular a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, for example C1-C8, linked to Si by an SiC bond; Q "is an anion such as a halide ion, in particular chloride or an organic acid salt (acetate, etc.), r represents an average statistical value of 2 to 20 and in particular 2 to 8; average statistical value from 20 to 200 and in particular from 20 to 50.   d) the quaternary ammonium silicones of formula: ## STR5 ## in which R 7, which may be identical or different, represent a monovalent hydrocarbon radical having from 1 to 5 carbon atoms; at 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a ring comprising 5 or 6 carbon atoms, for example methyl; R6 represents a divalent hydrocarbon radical, especially a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, for example C1-C8 linked to Si by an SiC bond; R8, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a -R6-NHCOR7 radical; ; X - is an anion such as a halide ion, especially chloride or an organic acid salt (acetate, etc.); r represents an average statistical value of 2 to 200 and in particular 5 to 100; e) the amino silicones of formula (XIII): R _   If O Si O (InH2n) _ R2 INH (CmH2m) NH2 in which: R7 Si-O R7 R7 OH I + 1 R8-N-CH2-CH-CH2 R6 R7 r X   (XIII) R3 Si R5 R4 2864779 55 - R1, R2, R3 and R4, identical or different, denote a C1-C4 alkyl radical or a phenyl group, - R5 denotes a C1-C4 alkyl radical or a hydroxyl group, n is an integer varying from 1 to 5, m is an integer ranging from 1 to 5, and wherein x is chosen such that the amine number is between 0.01 and 1 meq / g.   23- Composition according to any one of the preceding claims, characterized in that the amino silicone is present at a concentration of between 0.001% and 20% by weight relative to the total weight of the composition, preferably between 0.01% and 10% by weight.   24. Composition according to any one of the preceding claims, characterized in that the composition further comprises a cationic polymer.   25- The composition according to the preceding claim, characterized in that said cationic polymer is selected from cationic cyclopolymers, vinylpyrrolidone and vinylimidazole quaternary polymers, crosslinked homopolymers or copolymers of methacryloyloxyalkyl (C1-C4) trialkyl salts (C1- C4) ammonium, and pyrrolidonecarboxylate chitosan and mixtures thereof.   26- Composition according to any one of claims 24 or 25, characterized in that the cationic polymer or polymers represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight relative to total weight of the final composition.   27- Composition according to any one of the preceding claims, characterized in that the composition further comprises a silicone different from the amino silicones.   28- Composition according to the preceding claim, characterized in that the silicone is used in an amount of between 0.01 and 20% by weight, preferably between 0.1 and 5% by weight relative to the total weight of the composition.   29. Composition according to any one of the preceding claims, characterized in that it has a pH of between 3 and 10.   30. Use in cosmetics of a composition as defined in any one of the preceding claims for the cleaning and / or care and / or conditioning and / or styling of the hair.