FR2856048B1 - PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx - Google Patents

PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx

Info

Publication number
FR2856048B1
FR2856048B1 FR0307006A FR0307006A FR2856048B1 FR 2856048 B1 FR2856048 B1 FR 2856048B1 FR 0307006 A FR0307006 A FR 0307006A FR 0307006 A FR0307006 A FR 0307006A FR 2856048 B1 FR2856048 B1 FR 2856048B1
Authority
FR
France
Prior art keywords
nox
catalysis
purification
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0307006A
Other languages
French (fr)
Other versions
FR2856048A1 (en
Inventor
Beraud Natacha Haik
Serge Moreau
Francois Jantet
Audrey Moulin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR0307006A priority Critical patent/FR2856048B1/en
Priority to CNB2004800164256A priority patent/CN100503427C/en
Priority to EP04767312A priority patent/EP1636134A1/en
Priority to JP2006516281A priority patent/JP2006527297A/en
Priority to PCT/FR2004/001447 priority patent/WO2004110924A1/en
Publication of FR2856048A1 publication Critical patent/FR2856048A1/en
Application granted granted Critical
Publication of FR2856048B1 publication Critical patent/FR2856048B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
FR0307006A 2003-06-11 2003-06-11 PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx Expired - Fee Related FR2856048B1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR0307006A FR2856048B1 (en) 2003-06-11 2003-06-11 PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx
CNB2004800164256A CN100503427C (en) 2003-06-11 2004-06-10 Purification of a mixture of H*/CO by catalysis of the NO*
EP04767312A EP1636134A1 (en) 2003-06-11 2004-06-10 Purification of a mixture of h sb 2 /sb /co by catalysis of the no sb x /sb
JP2006516281A JP2006527297A (en) 2003-06-11 2004-06-10 Purification of H2 / CO mixture by catalytic reaction of NOx
PCT/FR2004/001447 WO2004110924A1 (en) 2003-06-11 2004-06-10 Purification of a mixture of h2/co by catalysis of the nox

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0307006A FR2856048B1 (en) 2003-06-11 2003-06-11 PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx

Publications (2)

Publication Number Publication Date
FR2856048A1 FR2856048A1 (en) 2004-12-17
FR2856048B1 true FR2856048B1 (en) 2005-08-05

Family

ID=33484344

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0307006A Expired - Fee Related FR2856048B1 (en) 2003-06-11 2003-06-11 PURIFICATION OF A H2 / CO MIXTURE BY CATALYSIS OF NOx

Country Status (5)

Country Link
EP (1) EP1636134A1 (en)
JP (1) JP2006527297A (en)
CN (1) CN100503427C (en)
FR (1) FR2856048B1 (en)
WO (1) WO2004110924A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006070018A1 (en) * 2004-12-30 2006-07-06 Shell Internationale Research Maatschappij B.V. Improvements relating to coal to liquid processes
ATE515477T1 (en) 2007-11-20 2011-07-15 Shell Int Research METHOD FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM
KR101011830B1 (en) * 2009-09-30 2011-01-31 상명대학교 산학협력단 Mixed metal oxide catalyst for decomposition of nitrogen oxide
CN106606927B (en) * 2015-10-22 2019-08-20 中国石油化工股份有限公司 Steam cracking produces the method for denitration and its denitrating system for the cracking flue gas that low-carbon alkene generates

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3564816A (en) * 1968-12-30 1971-02-23 Union Carbide Corp Selective adsorption process
US4117081A (en) * 1973-05-28 1978-09-26 Hitachi Shipbuilding & Engineering Co., Ltd. Method of and catalysts for removal of nitrogen oxides
DE2433479C2 (en) * 1974-07-12 1985-01-10 Hitachi Shipbuilding & Engineering Co., Ltd., Osaka Process for the reductive removal of nitrogen oxides from gases
JPS54126689A (en) * 1978-03-27 1979-10-02 Daiyo Sanso High purity hydrogen gas generating method
JPS54150387A (en) * 1978-05-17 1979-11-26 Osaka Soda Co Ltd Corrosion preventing method for hydrogen gas piping equipment
JPS6257628A (en) * 1985-09-05 1987-03-13 Kobe Steel Ltd Pretreatment of by-product gas from ironworks
JPH034937A (en) * 1989-05-31 1991-01-10 Nkk Corp Catalyst for decomposing organosulfur component, nox and dienes
JPH04106194A (en) * 1990-08-27 1992-04-08 Kawasaki Steel Corp Process for refining coke oven gas
US5792436A (en) * 1996-05-13 1998-08-11 Engelhard Corporation Method for using a regenerable catalyzed trap
AU6873100A (en) * 1999-09-09 2001-04-17 Kubota Corporation Novel compound and microporous material and method for production thereof
FR2799991B1 (en) * 1999-10-26 2002-10-11 Air Liquide PROCESS FOR THE PRODUCTION OF HYDROGEN USING A CARBON ADSORBENT WITH SELECTED DUBININ PARAMETERS

Also Published As

Publication number Publication date
FR2856048A1 (en) 2004-12-17
EP1636134A1 (en) 2006-03-22
JP2006527297A (en) 2006-11-30
CN1805900A (en) 2006-07-19
CN100503427C (en) 2009-06-24
WO2004110924A1 (en) 2004-12-23

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Effective date: 20150227