FR2517819A1 - LEAD GRAIN IMPROVEMENT FOR HUNTING AMMUNITION - Google Patents

LEAD GRAIN IMPROVEMENT FOR HUNTING AMMUNITION Download PDF

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Publication number
FR2517819A1
FR2517819A1 FR8220592A FR8220592A FR2517819A1 FR 2517819 A1 FR2517819 A1 FR 2517819A1 FR 8220592 A FR8220592 A FR 8220592A FR 8220592 A FR8220592 A FR 8220592A FR 2517819 A1 FR2517819 A1 FR 2517819A1
Authority
FR
France
Prior art keywords
lead
coating
improvement
hunting ammunition
hunting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR8220592A
Other languages
French (fr)
Inventor
Serge G Kelecom
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Herstal SA
Original Assignee
Herstal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Herstal SA filed Critical Herstal SA
Publication of FR2517819A1 publication Critical patent/FR2517819A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/17Metallic particles coated with metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B7/00Shotgun ammunition
    • F42B7/02Cartridges, i.e. cases with propellant charge and missile
    • F42B7/04Cartridges, i.e. cases with propellant charge and missile of pellet type
    • F42B7/046Pellets or shot therefor

Abstract

PERFECTIONNEMENT AUX GRAINS DE PLOMB POUR MUNITIONS DE CHASSE, CARACTERISE EN CE QU'IL CONSISTE A DOTER CHAQUE GRAIN D'UN REVETEMENT OU ENROBAGE EN UNE MATIERE RELATIVEMENT TENDRE ET DUCTILE, CAPABLE DE DIFFUSER SOUS EFFET ELECTROLYTIQUE.IMPROVEMENT WITH LEAD GRAINS FOR HUNTING AMMUNITION, CHARACTERIZED IN THAT IT CONSISTS OF PROVIDING EACH GRAIN WITH A COATING OR COATING IN A RELATIVELY SOFT AND DUCTILE MATERIAL, CAPABLE OF DIFFUSING UNDER ELECTROLYTIC EFFECT.

Description

25178 1 925178 1 9

La présente invention concerne un perfectionnement aux grains de plomb pour munitions de chasse, particulièrement en vue de limiter les risques d'intoxication (saturnisme)  The present invention relates to an improvement in lead pellets for hunting ammunition, particularly with a view to limiting the risks of poisoning (lead poisoning)

du gibier.wild meat.

Lors de la chasse, il est fréquent que le gibier tiré  When hunting, it is common for game drawn

encourt des blessures non létales Chez un animal ainsi at-  incurs non-lethal injury In an animal so

teint, le liquide musculaire dissout une partie de plomb,  complexion, the muscular fluid dissolves part of the lead,

avant l'enrobage du ou des grains Cette partie dissoute pas-  before coating the grain (s) This part does not dissolve

sé dans le sang pour se fixer ensuite en grande partie dans  dried in the blood to then largely settle in

le foie de l'animal.the animal's liver.

On a par ailleurs également constaté, chez le gibier  We have also found, in game

d'eau, l'ingestion de grains de plomb ayant par exemple abou-  water, the ingestion of lead grains having for example

tis dans la vase des étangs Les grains ainsi ingérés séjour-  tis in the mud of the ponds The grains thus ingested stay-

nent un certain temps dans le gésier de l'animal o ils sont  a while in the gizzard of the animal where they are

attaqués par le suc gastrique, les produits de cette dissolu-  attacked by gastric juice, the products of this dissolu-

tion se répendant dans le sang.spreading through the blood.

Selon les normes canadiennes par exemple, le gibier est  By Canadian standards for example, game is

impropre à la consommation dès que le foie de l'animal con-  unfit for consumption as soon as the animal's liver

tient plus de 0,2 ppm de plomb Pour un canard par exemple, cette valeur correspond à la présence dans le foie d'environ  holds more than 0.2 ppm of lead For a duck for example, this value corresponds to the presence in the liver of approximately

microgrammes de plomb.micrograms of lead.

Par sécurité, on estime peu souhaitable de dépasser 0,05  For safety, it is considered undesirable to exceed 0.05

ppm, ce qui, dans l'exemple du canard, correspond à 5 micro-  ppm, which in the duck example corresponds to 5 micro-

grammes de plomb dissous.grams of dissolved lead.

Or un seul plomb dans le gésier fait atteindre cette va-  However, a single lead in the gizzard makes this value reach

leur en une heure environ, tandis qu'il en faudrait quatre dans les tissus musculaires pour le mêmes résultat On voit  their in about an hour, while it would take four in muscle tissue for the same result We see

donc que le problème est réel.so the problem is real.

Une solution serait de remplacer le plomb par du fer, mais la densité et la dureté de ce dernier entraînent des difficultés techniques difficiles à résoudre dans l'état  One solution would be to replace lead with iron, but the density and hardness of the latter lead to technical difficulties which are difficult to solve in the state

actuel de la technique.current technology.

On a déjà proposé de revêtir des grains de plomb soit  It has already been proposed to coat lead grains either

avec du cuivre, soit avec du nickel, surtout en vue d'amélio-  with copper, or with nickel, especially with a view to improving

rer le groupement A première vue, de tels revêtements amé-  At first sight, such coatings improve

lioreraient la résistance à l'attaque chimique.  would improve resistance to chemical attack.

En pratique l n'en est rien car la déformation des grains au départ du coup entraîne la fissuration de la couche  In practice, this is not the case because the deformation of the grains at the start of the blow results in the cracking of the layer.

superficielle et, partant, l'annulation de l'effet protecteur.  superficial and hence the cancellation of the protective effect.

Le but de l'invention est dès lors de fournir une solu-  The object of the invention is therefore to provide a solution

tion efficace au problème sus-décrit.  tion effective to the problem described above.

Ce but est atteint, conformément à l'invention, par un perfectionnement aux grains de plomb consistant à doter ces derniers d'un revêtement d'une matière tolérée par l'organisme humain, ductile et diffusant sous effet électrolytique Une  This object is achieved, in accordance with the invention, by an improvement in lead grains consisting in providing them with a coating of a material tolerated by the human body, ductile and diffusing under the electrolytic effect A

telle matière peut avantageusement être de l'étain.  such a material can advantageously be tin.

Cet enrobage peut s'effectuer par tout procédé adéquat, tel qu'électrodéposition en tambour ou équivalent Il sera  This coating can be carried out by any suitable process, such as drum plating or the like.

avantageusement précédé d'un très fin dépôt de cuivre, for-  advantageously preceded by a very fine deposit of copper,

mant couche d'accrochage pour l'étain.  mant bonding layer for tin.

L'épaisseur du revêtement peut être comprise entre 2 et  The thickness of the coating can be between 2 and

50 microns.50 microns.

Des essais comparatifs ont montré que le niveau critique de dissolution mentionné ci-avant ( 5 ppm) était atteint pour un plomb nu, en 1 heure; pour un plomb nickelé à l'état neuf, en 20 heures; pour un plomb nickelé tiré (endommagé), en 2 heures; pour un plomb étamé selon l'invention, à l'état neuf, en 20 heures;  Comparative tests have shown that the critical dissolution level mentioned above (5 ppm) was reached for bare lead, within 1 hour; for a nickel-plated lead in new condition, in 20 hours; for a nickel lead shot (damaged), in 2 hours; for a tinned lead according to the invention, in new condition, in 20 hours;

pour ce plomb étamé tiré (endommagé), en 10 heures.  for this tinned lead drawn (damaged), in 10 hours.

Il en résulte que l'invention entraîne une amélioration  As a result, the invention results in an improvement

de l'ordre de 10 par rapport-au plomb ordinaire et de l'or-  of the order of 10 compared to ordinary lead and gold

dre de 5 par rapport à un plomb nickelé, ce qui est largement  dre of 5 compared to a nickel-plated lead, which is largely

suffisant pour éviter les risques de saturnisme.  sufficient to avoid the risk of lead poisoning.

25178 1925178 19

Claims (3)

REVENDICATIONS 1. Perfectionnement aux grains de plomb pour munitions de chasse, caractérisé en ce gu'il consiste à doter chaque grain d'un revêtement ou enrobage en une matière tolérée par l'organisme humain, ductile et capable de diffuser sous effet électrolytique.  1. Improvement to lead grains for hunting ammunition, characterized in that it consists in providing each grain with a coating or coating in a material tolerated by the human body, ductile and capable of diffusing under electrolytic effect. 2. Perfectionnement selon la revendication 1, caracté-  2. Improvement according to claim 1, character- risé en ce que ladite matière est l'étain.  laughed in that said material is tin. 3. Perfectionnement selon la revendication 2, caracté-  3. Improvement according to claim 2, character- risé en ce que ledit revêtement a une épaisseur comprise en-  laughed in that said coating has a thickness comprised between tre 2 et 50 microns.be 2 and 50 microns.
FR8220592A 1981-12-09 1982-12-08 LEAD GRAIN IMPROVEMENT FOR HUNTING AMMUNITION Withdrawn FR2517819A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE2/59490A BE891406A (en) 1981-12-09 1981-12-09 IMPROVEMENT IN LEAD GRAINS FOR HUNTING AMMUNITION.
BE891406 1981-12-09

Publications (1)

Publication Number Publication Date
FR2517819A1 true FR2517819A1 (en) 1983-06-10

Family

ID=25659794

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8220592A Withdrawn FR2517819A1 (en) 1981-12-09 1982-12-08 LEAD GRAIN IMPROVEMENT FOR HUNTING AMMUNITION

Country Status (4)

Country Link
AU (1) AU9110582A (en)
BE (1) BE891406A (en)
FR (1) FR2517819A1 (en)
GB (1) GB2111176A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2209065A (en) * 1987-08-25 1989-04-26 Anthony Thomas Best Cartridge shot
DE4227068B4 (en) * 1992-01-25 2006-04-27 Dynamit Nobel Ag Lead-free full storey
SE9202926L (en) * 1992-10-07 1994-04-08 Boliden Mineral Ab Hail for hunting prey and making such hail
SE506479C2 (en) * 1995-03-28 1997-12-22 Boliden Mineral Ab Hail for wet hunting and the production of such hail
GB9715023D0 (en) * 1997-07-17 1997-09-24 Eley Ltd Jacketed projectiles and their manufacture
US9115961B2 (en) * 2012-07-19 2015-08-25 Amick Family Revocable Living Trust Corrosion-inhibited projectiles, and shot shells including the same

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR453321A (en) * 1913-01-18 1913-06-05 Louis Fernand Grasset Improvement of lead bullets for hunting and war shooting cartridges
FR628027A (en) * 1926-07-15 1927-10-17 Western Cartridge Co Projectiles
FR632885A (en) * 1926-10-28 1928-01-16
US2167828A (en) * 1935-07-19 1939-08-01 Univ Minnesota Bird shot
FR1127501A (en) * 1955-06-01 1956-12-18 Process for treating shot pellets and shotgun pellets thus treated
FR1298208A (en) * 1960-08-24 1962-07-06 Dynamit Nobel Ag Advanced lead grains for hunting cartridges
US3664824A (en) * 1968-02-06 1972-05-23 Canadian Patents Dev Agglomerated metal shot
US4027594A (en) * 1976-06-21 1977-06-07 Olin Corporation Disintegrating lead shot

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR453321A (en) * 1913-01-18 1913-06-05 Louis Fernand Grasset Improvement of lead bullets for hunting and war shooting cartridges
FR628027A (en) * 1926-07-15 1927-10-17 Western Cartridge Co Projectiles
FR632885A (en) * 1926-10-28 1928-01-16
US2167828A (en) * 1935-07-19 1939-08-01 Univ Minnesota Bird shot
FR1127501A (en) * 1955-06-01 1956-12-18 Process for treating shot pellets and shotgun pellets thus treated
FR1298208A (en) * 1960-08-24 1962-07-06 Dynamit Nobel Ag Advanced lead grains for hunting cartridges
US3664824A (en) * 1968-02-06 1972-05-23 Canadian Patents Dev Agglomerated metal shot
US4027594A (en) * 1976-06-21 1977-06-07 Olin Corporation Disintegrating lead shot

Also Published As

Publication number Publication date
AU9110582A (en) 1983-06-16
GB2111176A (en) 1983-06-29
BE891406A (en) 1982-06-09

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