FR2498177A1 - Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques - Google Patents

Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques Download PDF

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Publication number
FR2498177A1
FR2498177A1 FR8100717A FR8100717A FR2498177A1 FR 2498177 A1 FR2498177 A1 FR 2498177A1 FR 8100717 A FR8100717 A FR 8100717A FR 8100717 A FR8100717 A FR 8100717A FR 2498177 A1 FR2498177 A1 FR 2498177A1
Authority
FR
France
Prior art keywords
sep
naphthalene
catalyst
acid
isopropylnaphthalene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8100717A
Other languages
English (en)
French (fr)
Other versions
FR2498177B1 (enrdf_load_stackoverflow
Inventor
George Andrew Olah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Pechiney SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Priority to FR8100717A priority Critical patent/FR2498177A1/fr
Publication of FR2498177A1 publication Critical patent/FR2498177A1/fr
Application granted granted Critical
Publication of FR2498177B1 publication Critical patent/FR2498177B1/fr
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/274—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C5/2743—Acids of sulfur; Salts thereof; Sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR8100717A 1981-01-16 1981-01-16 Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques Granted FR2498177A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8100717A FR2498177A1 (fr) 1981-01-16 1981-01-16 Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8100717A FR2498177A1 (fr) 1981-01-16 1981-01-16 Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques

Publications (2)

Publication Number Publication Date
FR2498177A1 true FR2498177A1 (fr) 1982-07-23
FR2498177B1 FR2498177B1 (enrdf_load_stackoverflow) 1983-02-18

Family

ID=9254203

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8100717A Granted FR2498177A1 (fr) 1981-01-16 1981-01-16 Preparation regioselective du b-isopropylnaphtalene sur des catalyseurs superacides solides ou supportes a base d'acides perfluorosulfoniques

Country Status (1)

Country Link
FR (1) FR2498177A1 (enrdf_load_stackoverflow)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4721559A (en) * 1986-10-17 1988-01-26 Olah George A Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239575A (en) * 1965-03-02 1966-03-08 Socony Mobil Oil Co Inc Hydrocarbon conversion with low cross-linked sulfonated resins
JPS5069055A (enrdf_load_stackoverflow) * 1973-10-26 1975-06-09
FR2366242A1 (fr) * 1976-10-02 1978-04-28 Bergwerksverband Gmbh Procede de preparation de b-isopropyl-naphtalene
US4188308A (en) * 1976-02-23 1980-02-12 Varen Technology Conversion of pendant sulfonate groups to sulfonic acid groups on perfluorvinylether-tetrafluoroethylene copolymer catalysts

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239575A (en) * 1965-03-02 1966-03-08 Socony Mobil Oil Co Inc Hydrocarbon conversion with low cross-linked sulfonated resins
JPS5069055A (enrdf_load_stackoverflow) * 1973-10-26 1975-06-09
US4188308A (en) * 1976-02-23 1980-02-12 Varen Technology Conversion of pendant sulfonate groups to sulfonic acid groups on perfluorvinylether-tetrafluoroethylene copolymer catalysts
FR2366242A1 (fr) * 1976-10-02 1978-04-28 Bergwerksverband Gmbh Procede de preparation de b-isopropyl-naphtalene

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1975 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4721559A (en) * 1986-10-17 1988-01-26 Olah George A Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts

Also Published As

Publication number Publication date
FR2498177B1 (enrdf_load_stackoverflow) 1983-02-18

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